4. Which of the following is a/an element 16.

The law of conservation of mass holds good

1) 22 carat gold 2) German silver for all of the following except.
3) Graphite 4) Dry ice. 1) All chemical reactions
5. Which of the following units represents the 2) Nuclear reaction
largest amount of energy. 3) Endo thermic reactions
4) Exo thermic reactions
1) Calorie 2) Erg 3) Joule 4) Electron-volt
17. The % of copper and oxygen in samples of
6. The M.K.S system was first introduced by CuO obtained by different methods were found
1) Archimedes 2) Galileo to be the same. This proves the law of:
3) Newton 4) Giorgi 1) Constant Proportion
7. Which is larger quantity. 2)Reciprocal Proportion
1) Mega 2) Femto 3) Milli 4) Giga 3) Multiple Proportion
8. Dimensions of pressure are same as that of 4) Conservation of mass.
1) Energy 2) Force 18. The mass of nitrogen per gram in hydrazine
3) Energy per unit volume is exactly one and half the mass of nitrogen
4) Force per unit volume in the compound ammonia. The fact
9. The perfix 1018 is illustrates the
1) Law of conservation of mass
1) Giga 2) Nano 3) Mega 4) Exa
2) Multiple valency of nitrogen.
SIGNIFICANT FIGURES 3) Law of multiple proportion
10. The number of significant figures in 0.0045 are 4) Law of definite proportion.
1) Two 2) Three 3) Four 4) Five. 19. Chemical equation is balanced according to the
11. The number of significant figures in 10500 are law of
1) Three 2) Four 1) Multiple proportion 2) Reciprocal proportion
3) Five 4) Can be any of these 3) Conservation of mass 4) Definite proportions
12. 5.041 has how many significant figures. 20. The law of multiple proportions was
1) 1 2) 2 3) 3 4) 4 observed for the pair
1) CO2, NO2 2) N2O, NO2
13. According to Avogadro, equal volumes of two
3) H2O, H2S 4) H2S, SO2
different gases under same conditions of 21. An unbalanced chemical equation is against
temperature and pressure contain equal the law of
number of 1) The law of gaseous volumes
1) Atoms 2) Molecules 2) The law of constant proportions
3) Electrons 4) Protons 3) The law of mass action
14. In Habers process, the volume at S.T.P of 4) The law of conservation of mass
ammonia relative to the total volume of 22. Law of combining volumes was proposed by
reactants at STP is : 1) Lavoisier 2) Gay Lussac
1) One fourth 2) One half 3) Avogadro 4) Dalton
3) Same 4) Three fourth 23. “The total mass of reactants is always equal
to the total mass of products in a chemical
LAWS OF CHEMICAL reaction.” This statement is konwn as
COMBINATIONS 1) Law of conservation of mass
15. One part of an element A combines with two 2) Law of definite proportions
parts of another element B, 6 parts of element 3) Law of equivalent weights
C combines with 4 parts of B. If A and C 4) Law of combining masses
combine together the ratio of their weights, will 24. In the reaction,
be governed by Hydrogen(g) + Oxygen(g)  watervapour,,
1) Law of definite proportion the ratio of volumes is 2 : 1 : 2. This illustrates
2) Law of multiple proportion the law of
3) Law of reciprocal proportion 1) Conservation of mass 2) Combining weights
3) Combining volumes 4) All the above
4) Law of conservation of mass
25. The law of multiple proportions is illustrated 3) Gram molecular mass 4) 1 Litre of molecule
by the two compounds 34. Atomicity is the number of
1) Sodium chloride and sodium bromide 1) Protons present in the atom
2) Ordinary water and heavy water 2) Neutrons present in the atom
3) Caustic soda and caustic potash
3) Atoms present in the molecule
4) Sulphur dioxide and sulphur trioxide.
4) Atoms present in 1 gram mole of a substance
MOLE CONCEPT
35. One amu is equal to [AIIMS, 2000]
26. Which of the following is a octa-atomic molecule 
1) Phosphorus 2) Sulphur 1) 1.33 g 2) 1.66g
3) Methane 4) Oxygen 3) 1.66g 4) 1.66g
27. Which of the following is a penta-atomic 36. The number of molecules present in one milli
molecule litre of a gas at STP is known as
1) Phosphorus 2) Sulphur 1) Avogadro number 2) Boltzman number
3) Ethane 4) Methane 3) Loschmidt number 4) Universal gas constant
28. If we assume 1/24 th part of mass of carbon 37. The vapour density of gas is 22. It cannot be
instead of 1/12 th part of it as 1 amu., mass of 1) Carbon dioxide 2) Nitrous oxide
1 mole of a substance will
3) Propane 4) Methane
1) Remain unchanged 2) Get doubled 3
38. The mass of 112cm of methane at STP
3) Get halved 4) Can’t be predicated
29. Choose the correct statement [ K CET, 2001 ]
The use 12C scale has superseded the older 1) 0.16 g 2) 0.08 g 3) 0.8 g 4) 16 g
16
scale of atomic mass based on O isotope, one 39. The vapour density of a gas is 11.2. The volume
important advantage of the former being occupied by 11.2 gms. of the gas at S.T.P. is
12
1) The atomic masses on C scale became whole 1) 11.2 lit 2) 4 lit. 3) 2 lit 4) 22.4 lit
numbers. 40. Substance having more number of moles is
12 16
2) C is more abundant in the earth’s crust than O 1) 90 gms of water
3) The difference between the physical and 2) 112 litre of hydrogen at S.T.P.
chemical atomic masses got narrowed down 3) 24 gm of helium gas
significantly 4) 3.01 × 1024 molecules of CO2
12
4) C is situated midway between metals and non- 41. Atomicity of oleum (H S O ) is
2 2 7
metals in the periodic table 1) 11 2) 8 3) 7 4) 18
30. Which one of the following properties of an
42. Equivalent weight of Calcium metal is
element can never be variable?
1) 12 2) 24 3) 36 4) 20
1) Valeney 2) Atomic weight
43. Equivalent weight of Potassiumpermaganate
3) Equivalent Mass 4) All the above
in strong alkaline medium is ...
31. 10 grams of each O2, N2 and Cl2 are kept in
three bottles. The correct order of arrangment 1) M.W/1 2) M.W/3 3) M.W/5 4) M.W/6
of bottles containing decreasing number of 44. Equivalent weight of N2H4 is
Molecules. 1) 32 2) 16 3) 48 4) 24
1) O2, N2, Cl2 2) Cl2, N2, O2 45. Equivalent weight of H2S is equal to the
3) Cl2, O2, N2 4) N2, O2, Cl2 equivalent weight of
32. The atomicity of a species is x and its atomic 1) HCl 2) H2O2 2) H2SO2 4) H2O
weight is y. The molecular weight of the 46. The number of parts by mass of the element
species is [ NDA, 1993 ] or compound which combines or displaces
1) x + y 2) y + x 3) xy 4) x - y directly or indirectly one part by mass of
33. Avogadro’s number is the number of molecules Hydrogen is called
present in [AFMC-2003] 1) Atomic mass 2) Molecular mass
1) 1 G of molecule 2) 1 Atom of molecule 3) Equivalent mass 4) Formula weight
 BASIC CONCEPTS OF CHEMISTRY
EQUIVALENT WEIGHT temperature and pressure for every mole Al that
47. Equivalent weight of oxidizing or reducing reacts
agent is 4. 67.2 L LH2(g) at STP is produced for every mole
Al reacts
Formula weight 56. Which of the following is/are not affected by
No.of e  gained (or ) lossed for one temperature?
1)
formulae of compound 1) Molarity 2) Molality
3) Narmality 4) None of these
Formula weight 57. A molar solution is one that contains one mole
Total changein oxidation state of the solute in
2)
for 1 formulae of compound 1) 100 gr of solvent 2) One litre of the solvent
3) 1000 gr of solvent 4) One litre of the solution
3) Both 1&2 58. On dissolving 1 mole of each of the following
Formula weight acids in 1 litre water, the acidwhich does not
4) give a solution of strenth 1 N is
Valency
48. Equivalent weight Ferrous ion is (At.wt.of 1) HCl 2) HClO4 3) HNO3 4) H3PO4
Fe = 56)
CONCEPT OF OXIDATION
1) 56 2) 28 3) 14 4) 32
49. For which of the following salt,Eq.wt is F.W/6 NUMBER AND REDOX
1) NaCl 2) K2SO4 3) Fe2(SO4)3 4) AlCl3 REACTIONS
50. Equivalent weight of NH4OH is 59. Iron in lowest oxidation state is in
1) 35 2) 17.5 3) 42 4) 72 1) FeSO4.7H2O 2) Fe(CO)5
51. Equivalent weight of CaCl2 is 3) Fe0.94O 4) Fe3O4
Formula weight Formula weight 60. Oxidation state of nitrogen is not an integer in
1) 2) 1) Hydroxyl amine (NH2OH)
2 1
Formula weight Formula weight 2) Ammonia (NH3) 3) Hydrazine (N2H4)
3) 3) 4) Hydrazoic acid (N3H)
3 4
61. The oxidation state of phosphorus is maximum in
52. Equivalent weight of dydrated oxalic acid is
1) Phospine (PH3) 2) Diphosphine (P2H4)
1) 44 2) 45 3) 63 4) 126
3) Metaphosphoric acid (HPO3)
E.F AND M.F 4) Phosphorus acid (H3PO3)
53. The emperical formula of Acetic acid is 62. The oxidation state of oxygen is maximum in
1) CH3–COOH 2) C2H4O 1) Bleaching powder (CaOCl2)
3) CH2O 4) CHO 2) Oxygen difluoride (OF2)
54. The empirical formula of a compound is CH2. 3) Dioxygen difluoride (O2F2)
One mole of this compound has a mass of 42 4) Hydrogen peroxide (H O2)
gm. Its molecular formula is : [MP PMT-02] 63. The oxidation number of2chlorine is maximum in
1) CH2 2) C2H2 3) C3H6 4) C3H8 1) HOCl 2) Cl2O6 3) KClO4 4) NaClO3
55. In the reaction, 64. One of the following element always exhibits
+3 -
2Al s  + 6HCl aq   2Al aq  + 6Claq  + 3H 2  g  only -1 oxidation state in all of its compounds
incorrect statement is with other elements. The element is
1) 11.2LH2(g) at STP is produced for every mole 1) Hydrogen 2) Sodium
HCLaqconsumed 3) Fluorine 4) Oxygen
2) 6HCL (aq)is consumed for every 3LH 2(g) 65. In one of the following compounds, the
produced oxidation number of sulphur is not a whole
3) 33.6 LH 2(g) is produced regardless of number
1) Na2S4O6 2) H2SO5 3) H2SO4 4) Na2S2O3
 JEE MAIN JR-CHEM - VOL - II
66. Bromine is converted to Bromate ion. The 75. Na SO  H O  Na SO  H O, in reaction
2 3 2 2 2 4 2
change in oxidation number of bromine is from
1) H2O2 is bleached 2) H2O2 is oxidised
1) 0 to +1 2) 0 to +3 3) 0 to +5 4) 0 to +7
3) H2O2 is dehydrated
67. Which of the following statements is wrong
4) H2O2 is neither oxidised nor reduced
1) Oxidation number of oxygen is +1 in peroxides
76. In which of the following compounds, sulphur
2) Oxidation number of oxygen is +2 in oxygen
atom has different oxidation number
difluoride
3) Oxidation number of oxygen is -1/2 is super 1) H2SO4 2) HSO3 3) SO2Cl2 4) SO3
oxides 77. Change in oxidation number is maximum in the
4) Oxidation number of oxygen is -2 in most of its following reaction
compounds 1) Cu  4 HNO3  Cu  NO3 2  2 NO2  2 H 2O
68. The conversion of Glucose to carbon dioxide
with respect to carbon is 2) H 2 S  4 F2  2 HF  SF6
1) Oxidation 2) Reduction 3) Cl2  2KOH  KCl  KOCl  H2O
3) both oxidation & recution
4) Neither oxidation nor reduction 4) KClO3  H 2 O  F2  KClO4  2 HF
69. In the raction P + NaOH  PH 3 + NaH 2 PO2 78. Which of the following is a redox reaction
1) CH3COOH+C2H5OH  CH3COOC2H5+H2O
1) P is oxidised only 2) P is reduced only
3) Na is reduced 2) 2 NaOH  H 2 SO4  Na2 SO4  2 H 2O
4) P is reduced as well as oxidised 3) Zn  CuSO4  ZnSO4  Cu
70. Compound that acts as oxidant as well as
reductant 4) NaCl  AgNO3  AgCl  NaNO3
1) SO2 2) CrO3 3) SO3 4) Al2O3 79. Which of the following can act as an oxidant
71. Which of the following is comproportionation both in neutral and alkaline medium
reaction : 1) K Cr O 2) KMnO 3) Cl 4) CrO
2 2 7 4 2 3
- - -
1) Cl2(g) + OH (aq)  ClO3(aq) + Cl (aq) + H 2O(l) 80. The oxidation state of N in HNO4 is
1) + 7 2) +10 3) +5 4) +3
2 
2) Ag( aq)  Ag( s )  2 Ag aq 81. Which of the following can act only as a
reducing agent
3) Na( s )  H 2O i   NaOH  aq   H 2( g ) 1) K 2 Cr2 O7 2) CaOCl2 3) PbO2 4) H 2 S
4) Zn( s )  CuSO4(aq )  ZnSO4( aq )  Cu s  82. Which of the following is displacement
reaction:
72. Which of the following is not disproportionation
raction. 1) S s   O2g   SO2g 

1) P4
s 
 OH   aq   PH 3 g   H 2 PO2 aq  2) KClO3s  KCl  s   O2g 

3) Ca  s   H2Ol   Ca  OH 2aq   H2g 

 2 2
2) S s   OH  aq   S  aq   S 2O3aq   H 2Ol 

3) Cl2
g
 OH  aq   ClO  aq   H 2O l  g
 
4) F2   OH  aq   F aq   OF2   H2Ol 
g

4) F2  OH   aq   F   aq   OF2 g   H 2 O l  C.U.Q - KEY

g
01) 4 02) 2 03) 4 04) 3 05) 1 06) 4
73. The oxidation number of Oxygen in KO2 is
07) 4 08) 3 09) 4 10) 1 11) 4 12) 4
1) -2 2) -1 3) -1/2 4) –1/3
13) 2 14) 2 15) 3 16) 2 17) 1 18) 3
74. Oxidation number and covalency of sulphur in
S8 molecule are respectively 19) 3 20) 2 21) 4 22) 2 23) 1 24) 3
1) 6 & 8 2) 0 & 8 3) 0 & 2 4) 6 & 2 25) 4 26) 2 27) 4 28) 1 29) 2 30) 2
 At.Wt
37) 4 38) 2 39) 1 40) 3 41) 1 42) 4 42. Eq.wt 
valency
43) 1 44) 2 45) 2 46) 3 47) 3 48) 2
49) 3 50) 1 51) 1 52) 3 53) 3 54) 3 44. Presence of two L.P its acidity is two
55) 3 56) 2 57) 4 58) 4 59) 2 60) 4 45. Comparing basicities
61) 3 62) 2 63) 3 64) 3 65) 1 66) 3
67) 1 68) 1 69) 4 70) 1 71) 2 72) 4 M .F  n  E .F
73) 3 74) 3 75) 2 76) 2 77) 2 78) 3 54. Mol .Wt
n
79) 2 80) 3 81) 4 82) 3 E .F .Wt
C.U.Q - HINTS
58) H 3 PO4 basicity is 3
1. Smoke is hetrogeneous mixture
59) O.S of metal in metal carbonyls is 0
2. Silica  SiO2  is a compound
66) Br2  BrO3
10. The number of significant figures in 0.0045 are two
because zeros to the left of the first non-zero digit LEVEL-I (C.W)
are not significant.
11. The number 10500 ends in zeros but these zeros
SIGNIFICANT FIGURES
–1
are not to the right of a decimal point. These zeros 1. NKg is the unit of
may or may not be significant. It depends how it is 1) Momentum 2) Velocity
expressed i.e. as 1.5  10 4 or 1.050  104 or 3) Pressure 4) Acceleration
2. The prefix femto stands for
1.0500  104 which have significant figures 3, 4 and 1) 109 2) 10–12 3) 10–15 4) 105
5 respectively. 3. The number of significant figures in
12. Zero between ‘5’ and ‘4’ is also significant No = 6.022  1023 (Avogadro’s number) aree
1) Three 2) Four 3) Five 4) All
14. N 2  3H 2  2 NH 3
4. The correctly reported answer of the addition
26. Rhombic Sulphur exists has S8 rings of 4.523, 2.3 and 6.24 will have significant
figures
27. Atomicity of CH 4 is 5. 1) Two 2) Three 3) Four 4) Five
W 2.568× 5.8
31. No. of molecules = N 5. The answer of the calculation in
MW 4.168
significant figures will be :
32. M .Wt  atomic weight  Atomicity 1) 3.579 2) 3.570 3) 3.57 4) 3.6
37. M .W  2 V .D  2  22  44 6. 0.00025 has how many significant figures
1) 6 2) 3 3) -4 4) 2
 M.Wt of CH 4  16 7. 314.000 has how many significant figures.
1) 6 2) 3 3) 5 4) 4
38. 22, 400cc  16 g
8. The correctly reported difference of 16.4215
112 cc  ? and 6.01 will have significant figures equal to
1) Three 2) Four 3) Five 4) Six
39. M .W  2  VD 9. After rounding off 1.235 and 1.225, we will have
their answers respectively as
W V o lu m e in lit
40. n  or 1) 1.23, 1.22 2) 1.24, 1.23
M 22 .4 3) 1.23, 1.23 4) 1.24, 1.22
 LAWS OF CHEMICAL 3) 2 moles of BaCO3 4) 0.25 moles of BaCO3
COMBINATION 18. The number of atoms present in 4.25 grams of
10. In the formation of SO2 and SO3 the ratio of NH3 is approximately [ BHU , 1995 ]
the weights of oxygen which combines with 1) 1 10 23 2) 1.5  10 23
10kg of sulphur is 3) 2 1023 4) 6 1023
1) 1 : 1 2) 3 : 2 3) 2 : 3 4) 3 : 4 19. 12 gm of an alkaline earth metal gives 14.8 g
11. 14 gm of an element ‘X’ combines with 16 gm of its nitride. The atomic mass of metal is
of oxygen. On basis of this which of the 1) 12 2) 24 3) 20 4) 40
following is correct ? (At.wt of oxygen = 16. 20. The isotopes of chlorine with mass numbers
1) The element X could have an atomic weight of 35 and 37 exist in the ratio of
7 and its oxide formula is XO. 1)1:1 2) 2:1 3) 3:1 4) 3:2
2) The element X could have an atomic weight 14 21. The gas having same number of molecules as
and it’s oxide formula X2O3. 16g. of oxygen is
3) The element X could have an atomic weight 7 1) 16g. of O3 2) 16g. of SO3
and it’s oxide formula X2O. 3) 48g. of SO3 4) 1gm of hydrogen
4) The element X could have an atomic weight 14 22. The weight of gaseous mixture containing
and it’s oxide formula XO2. 6.02 × 1023 molecules of nitrogen and 3.01 × 1023
12. Law of multiple proportions is illustrated by molecules of sulphur dioxide are
one of the following pairs 1) 46 2) 92 3) 60 4) 30
1) H2S and SO2 2) NH3 and NO2 23. The density of a gas at S.T.P. is 1.40 grams
3) Na2S and Na2O 4) N2O and NO per litre. The molecular weight of the gas is
13. Percentage of copper and oxygen in samples 1) 28 2) 30 3) 31.4 4) 35
of CuO obtained by different methods were 24. The no. of electrons present in one mole of
found to be the same. This proves the law of Azide ion are(N–3)
1) Constant proportions 1) 21 N 2) 20 N 3) 22 N 4) 43 N
2) Reciprocal proportions -28
25. If the mass of an electron is 9 × 10 grams,
3) Multiple proportions weight of one mole of electrons is
4) Conservation of mass 1) 9 × 10-28 gm 2) 6 × 10-28
14. A sample of pure carbon dioxide, irrespective 3) 1.008 gm 4) 0.00054 gm
of its source contains 27.27 % carbon and 26. If the weight of 5.6 litres of a gas at S.T.P is 11
72.73% oxygen. The data support grams, the gas is
1) Law of constant composition 1) Phosphine 2) Phosgene
2) Law of conservation of mass 3) Nitric oxide 4) Nitrous oxide
3) Law of reciprocal proportions 27. Number of milli moles in 1.0 gram of water
4) Law of multiple proportions 1) 1.0 2) 18 3) 55.55 4) 100
MOLE CONCEPT ATOMIC 28. Which of the following contains maximum
MASS, MOLECULAR MASS, number of molecules
AVOGADRO NUMBER 1) 4 gm of hydrogen
15. 10
Boron has two isotopes B and B whose 11 2) 22.4 ltrs of oxygen at S.T.P.
relative abundances are 20% and 80% 3) Carbon Dioxide obtained by heating 1 mole of
respectively. Atomic weight of Boron is calcium carbonate
1) 10 2) 11 3) 10.5 4) 10.8 4) 4 gm of helium
16. Which of the following has highest mass 29. A pair of gasses having same number of
1) 50 gms of iron 2) 5 moles of nitrogen molecules are
3) 1 gm atom of silver 1) 22 gm of CO2 and 72 gm of N2
4) 5 × 1023 atoms of carbon
2) 11 gm of CO2 and 28 gm of N2
17. 1.5 moles of oxygen atoms are present in 3) 44 gm of CO2 and 7 gm of N2
1) 0.5 moles of BaCO3 2) 1 mole of BaCO3 4) 11 gm of CO2 and 7 gm of N2
 BASIC CONCEPTS OF CHEMISTRY
30. The total volume of mixture of 2 gms of helium compound is
and 7 gms of nitrogen under S.T.P comditions is 1) 35 2) 70 3) 140 4) 280
1) 22.4 lit 2) 11.2 lit 3) 16.8 lit 4) 5.6 lit 42. Haemoglobin contains 0.33% of Fe by weight.
31. The number of atoms present in 10 gms of If 1 molecule of Haemoglobin contains two Fe
CaCO3 are atoms, the molecular weight of Haemoglobin
1) 5 N 2) 0.5 N 3) 5 4) N will be (at. wt. of Fe=56) nearly
32. How many molecules are present in one gram 1) 67000 2) 34000 3) 17000 4) 20000
of hydrogen ? 43. X and Y are two different elements having their
1) 6.02  10 23 2) 3.01 1023 atomic masses in 1 : 2 ratio. The compound
formed by the combination of X and Y contains
3) 2.5  1023 4) 1.5  1023 50% of X by weight. The empirical formula of
22
33. The mass of 1.205×10 molecules of the compound is
ammonia is 1) X2Y 2) XY2 3) XY 4) X4Y
44. The empirical formula of a gaseous compound
1) 0.34 g 2) 3.4 g 2) 3.4 kg 4) 34 g
is CH2. The density of the compound is 1.25
EQUIVALENT WEIGHT gm/lit. at S.T.P. The molecular formula of the
34. Sulphur forms the chlorides S2Cl2 and SCl2. compound is ‘X’
The equivalent weight of sulphur in SCl2 is 1) C2H4 2) C3H6 3) C6H12 4) C4H8
1) 8 2) 16 3) 64.8 4) 32 45. The empirical formula of an organic compound
35. For which of the following compound equivalent is CH 2 O. Its vapour density is 45. The
weight is equal to molecular weight molecular formula of the compound is
1) H2SO4 2) H3PO2 3. H3PO4 4. H3PO3 1) CH2O 2) C2H4O2
36. The equivalent mass of H3PO4 in the reaction 3) C3H6O3 4) C6H12O6
given below is 46. A compound contains 92.3% of carbon and
H 3 PO4 + NaOH  NaH 2 PO4 + H 2 O 7.7% of hydrogen. The molecule of the
1) 49 2) 98 3) 32.6 4) 40 compound is 39 times heavier than hydrogen
37. In alkaline medium , KMnO4 reacts as follows molecule. The molecular formula of the
compound is
2KMnO4 + 2KOH → 2K 2 MnO4 + H 2 O + O 1) C3H3 2) C2H2 3) C2H4 4) C6H6
Therefore, the equivalent weight of KMnO4 47. 0.132 g of an organic compound gave 50 ml of
will be N2 at NTP. The weight percentage of nitrogen
1) 31.6 2) 52.7 3) 7.0 4) 158.0 in the compound is close to
38. The equivalent mass of nitrogen in nitrogen 1) 15 2) 20 3) 48.9 4) 47.34
pentoxide is 48. In a compound C, H and N atoms are present
1) 14 2) 28 3) 2.8 4) 4.66 in 9 : 1: 3.5 by weight. Molecular weight of
39. Equivalent weight of HI is compound is 108. Molecular formula of
1) 64 2) 127 3) 128 4) 63 compound is [AIEEE 2002]
PERCENTAGE WEIGHT OF 1) C2H6N2 2) C3H4N 3) C6H8N2 4) C9H12N3
ELEMENTS IN COMPOUNDS 49. A certain compound contains Calcium,Carbon
MOLECULAR FORMULA & and Nitrogen in the mass ratio, 20 : 6 : 14. The
empirical formula of the compound is
EMPERICAL FORMULA
1) CaCN 2) CaC2N
40. The percentage of Carbon in CO2 is
3) CaC2(CN)2 4) CaCN
1) 27.27% 2) 29.27%
50. The atomic mass of a metal M is 56, then the
3) 30.27% 4) 26.97%
empirical formulae of its oxide containing 70%
41. A compound has 20% of nitrogen by weight.
metal
If one molecule of the compound contains two
1) MO 2) M2O3 3) M3O2 4) M3O5
nitrogen atoms, the molecular weight of the
51. Which pair of species have same percentage hydrogen? [AIEEE 2003]
of carbon 1) 89.6 L 2) 67.2 L 3) 44.8 L 4) 22.4 L
1) CH 3COOH and C6 H12 O6 61. The weight of KMnO4 required to completely
oxidise 0.25 moles of FeSO4 in acid medium
2) CH 3COOH and C2 H 5OH is ............ (molecular weight of KMnO4 = 158)
3) HCOOCH 3 and C12 H 22O11 1) 5.8 2) 1.5 3) 7.9 4) 0.79
62. How many moles of potassium chlorate should
4) C6 H12O16 and C12 H 22O11 be decomposed completely to obtain 67.2 litres
NUMERICAL CALCULATIONS of oxygen at STP ?
BASED ON CHEMICAL 1) 3 2) 4 3) 1 4) 2
EQUATIONS 63. 0.01 mole of iodoform (CHl3) reacts with excess
52. How many grams of H3PO4 is required to Ag powder to produce a gas whose volume at
completely neutralize 120g of NaOH NTP is [BHU, 1996]
1) 224 ml 2) 112 ml 3) 336ml 4) 448 ml
1) 49 2) 98 3) 196 4) 9.8
53. How much volume of CO2 at S.T.P is liberated METHODS OF EXPRESSING
by the combustion of 100 cm³ of propane CONCENTRATIONS
(C3H8)? [CMC(Vellore.PMT, 2003] 64. What weight of sodium hydroxide is required
1) 100cm3 2) 200cm3 3) 300cm3 4) 400cm3 to neutralise 100 ml of 0.1N HCl ?
54. The composition of residual mixture will be if 1) 4 g 2) 0.4 g 3) 0.04 g 4) 40 g
30 g of Mg combines with 30 g of oxygen 65. H O
2 2
is sold as a solution of approximately
1) 40g MgO + 20g O2 2) 45g MgO + 15g O2 5.0g H2O2 per 100 ml of the solution. The
3) 50g MgO + 10g O2 4) 60g MgO only molarity of this solution is approximately
55. If 5 ml of methane is completely burnt the 1) 0.15M 2) 1.5M 3) 3.0M 4) 3.4M
volume of oxygen required and the volume of 66. The amount of oxalic acid (eq.wt.63) required
CO2 formed under the same conditions are to prepare 500 ml of its 0.10 N solution is
1) 5 ml, 10 ml 2) 10 ml, 5 ml 1) 0.315g 2) 3.150g 3) 6.300g 4) 63.00g
3) 5 ml, 15 ml 4) 10 ml, 10 ml 67. The molality of a solution having 18 g of glucose
56. If 0.5 mole of BaCl2 is mixed with 0.2 mole of dissolved in 500 g of water is
Na3PO4, the maximum number of moles of 1) 1 m 2) 0.5m 3) 0.2m 4) 2 m
Ba3(PO4)2 formed are 68. If 5.85 g of NaCl is dissolved in 90 g of water,
1) 0.7 2) 0.5 3) 0.3 4) 0.1 the mole fraction of solute is
57. KClO3 decomposes to KCl and O2. If the 1) 0.0196 2) 0.01 3) 0.1 4) 0.2
volume of O2 obtained in this reaction is 1.12 lit 69. Mass percentage (w/w) of ethylene glycol
at STP, weight of KCl formed in the reaction is (HOCH2 - CH2OH) in a aqueous solution is
1) 7.45 g 2) 2.48 g 3) 4.96 g 4) 1.24 g 20, then mole fraction of solute is
58. 23g of sodium will react with ethyl alcohol to give 1) 0.5 2) 0.067 3) 0.1 4) 0.4
1) 1 mole of H2 2) 1/2 mole of H2 70. 100ml of ethylalcohol is made upto a
3) 1 mole of O2 4) 1 mole of NaOH litre with distilled water . If the density of
C2H5OH is 0.46 gr/ml. then its molality is
59. How many litres of oxygen at STP. are required
1) 0.55m 2) 1.11m 3) 2.22m 4) 3.33m
for complete combustion of 39 gms of liquid 3
71. 10 cm of 0.1N monobasic acid requires
Benzene? (Atomic weights C = 12, H = 1, O = 16)
15 cm3 of NaOH solution whose
1) 84 2) 22.4 3) 42 4) 11.2
normality is
60. What volume of hydrogen gas, at 273 K and 1
1) 0.066N 2) 0.66N 3) 1.5N 4) 0.15N
atm pressure will be consumed in obtaining
72. The molarity of 0.6N phosphorous acid is
21.6 g of elemental boron (atomic mass = 10.8)
1) 0.3 2) 0.1 3) 0.9 4) 0.6
from the reduction of boron trichloride by
73. 50 ml of 10N H2SO4 , 25ml of 12N HCl and 2) Ag 2  aq   Ag  s   2 Ag 4  aq 
40ml of 5N HNO3 are mixed and the volume of
the mixture is made 1000ml by adding water. 3) Zn  s   CuSO4  aq  
The mormality of resulting solution is
Cu  s   ZnSO4  aq 
1) 1N 2) 2N 3) 3N 4) 4N
74. On dissolving 1 mole of each of the following
4) 2 KClO3  s   2 KCl  s   3O2  g 
acids in one litre water, the acid which does
not give a solution of strength 1N is LEVEL - I (C.W) - KEY
1) HCl 2) HClO4 3)HNO3 4) H3PO4 01) 4 02) 3 03) 2 04) 2 05) 4 06) 4
CONCEPT OF OXIDATION 07) 1 08) 2 09) 4 10) 3 11) 3 12) 4
NUMBER & REDOX REACTIONS 13) 1 14) 1 15) 4 16) 2 17) 1 18) 4
75. Oxidation state of iron in 19) 4 20) 3 21) 4 22) 3 23) 3 24) 3
Na2  Fe  CN 5  NO   is 25) 4 26) 4 27) 3 28) 1 29) 4 30) 3
31) 2 32) 2 33) 1 34) 2 35) 2 36) 2
1) +1 2) +2 3) 0 4) +3
37) 4 38) 3 39) 3 40) 1 41) 3 42) 2
76. Oxidation number of carbon in carbon suboxide
(C3O2) 43) 1 44) 1 45) 3 46) 4 47) 4 48) 3
49) 4 50) 2 51) 1 52) 2 53) 3 54) 3
2 4 4
1) 2) 3) +4 4) 55) 2 56) 4 57) 2 58) 2 59) 1 60) 2
3 3 3 61) 3 62) 4 63) 2 64) 2 65) 2 66) 2
77. Oxidation number of Sodium in Sodium 67) 3 68) 1 69) 2 70) 2 71) 1 72) 1
amalgam
73) 1 74) 4 75) 4 76) 2 77) 4 78) 2
1) +2 2) +1 3) -2 4) 0
78. Oxidation number of iron in Fe0.94O is 79) 3 80) 1 81) 1 82) 4 83) 1
1) 200 2) 200/94 3) 94/200 4) None LEVEL-I (C.W) - HINTS
79. Oxidation number of S in (CH3)2S is N F
1) 0 2) +1 3) -2 4) +3 1.   acceleration
kg m
80. Oxidation number of ‘Co’ in Hg [Co( SCN ) 4 ]
4. 4.523  2.3  6.24  13.063 . As 2.3 has least no.
1) +2 2) +1 3) +3 4) +5
of decimal places i.e. one, therefore sum should be
81. Oxygen can show positive oxidation state in
reported to one decimal place only. After rounding
its compounds with
off, reported sum = 13.1 which has three significant
1) Fluorine 2) Nitrogen
figures.
3) Hydrogen 4) Sulphur
82. Which of the following is a redox reaction 2.568  5.8
5.  3.5735125  3.6
[ AIEEE , 2002 ] 4.168
1) NaC  KNO 3  NaNO 3  KC  6. zeros to the left of number ‘2’ are not significant
7. zeros to the right of decimal are significant
2) CaC2O 4  2HC  CaC 2  H 2C2 O4 8. 16.4215-6.01=10.4115. As 6.01 has least no. of
3) MgOH2  2NH4C  MgC 2  2NH4OH decimal places viz. 2, therefore, reported difference
= 10.41 which has four significant figures.
4) Zn  2Ag CN  2Ag  Zn CN 2 9. If the digit just next to the last digit to be retained is
83. Which one of the following is an example of 5, the last significant figure is left unchanged if is
disproportionation reaction ? (EAMCET - even and is increased by 1 if it is odd. Hence
2013) 1.235=1.24 and 1.225=1.22
1) 3Cl2  g   6OH   aq   20 10  80  11
15. Average relative at Wt. AW
. 
ClO3  aq   5Cl   aq   3H 2O 1 100
 200  880 35. If basicity of acid=1, MW=EW

100 36. No of H  ions given by H 3 PO4 to NaOH is one
1080 43. W % of x = 50
  10.8 g W % of y = 50
100 AW of x = 1
16. 5 x 28 = 140 gms of N2 AW of y = 2
17. 0.5 mole of BaCO3 contains 1.5 moles of oxygen
atoms atomic ratio simple ratio E. F
4.25 50 50
18. 4 1  50 2 X 2Y
17 1 25
19. 2.8 gms of nitrogen combains with 12 gm of metal 50 25
 25 1
14/3gms of nitrogen combins with 20gm of metal 2 25
(eqwt.
mol. wt.
Atomic weight = eqwt x valency 44. MW  2  V .D n = ; M.F. = (E.F.)
.)n
= 20 x 2 = 40gms. E.F.W
20 6 14
p  m1  100  p  m2 49. Ca : C : N  : :
20. Average atomic mass  40 12 14
100
70 30
W 50. :  3: 2 .
21. No. of molecules =  N 56 16
MW
52. H3PO4 + 3NaOH  Na3PO4 + 3H2O
 n1  n2
22. W    MW1    MW2 53. C3 H 8  5O2  3CO2  4 H 2O
N  N
54. 2Mg + O2  2MgO
23. At S.T.P. mol. wt. of a gas = density x 22.4
48g of Mg combines with 32g of oxygen give 80g
24. Azide ion = N 3 of MgO. Oxygen is limiting reagent.

No. of electrons in one N 3 ion = 21+1 55. CH4 + 2O2  CO2 + 2H2O
56. 3BaCl2 + 2Na3PO4  Ba3(PO4)2 + 6NaCl
25. 9  1 0  28  6 .0 2 3  10 23
57. 2KClO3  2KCl + 3O2
26. 5.6 lit  11gm
58. C2 H 5 OH + Na  C2 H 5 ONa+ 12 H 2
22.4lit  ?
27. No. of milli moles = W in mg / MW 59. C6H6(l) + 15/2 O2(g)  6 CO2(g) + 3 H2 O(g)
60. 2BCl3 + 6H2  B2H6 + 6HCl
Wt
28. No. of molecules = N ( or ) 61. 2KMnO4 + 3H2SO4 + 10FeSO4 
GMWt
. .
K2SO4 + 2MnSO4 + 5Fe2 (SO4)3 + 3H2O
Volume at STP
N 2  158 gm of KMnO4
G.M .V
 10 moles of FeSO4?
Wt ¬ 0.25 moles FeSO4
29. No. of molecules = N
GMWt
. . 62. 2KClO3  2 KCl + 3O2
Wt 63. 2CHI 3  6 Ag  6 AgI  C2 H 2
30.  22.4
GMW
64. NaOH + HCl  NaCl + H2O
31. 100--------------5N
w 1000
33. 6 1023    17 g 65. M = GMW  V in ml
1.2 1022     ?
 N×GEW × V(in ml) 8. Ferric sulphate on heating gives sulphur
66. w = trioxide. The ratio between the weights of
1000 oxygen and sulphur present in SO3 obtained
w 1000 by heating 1 kg of ferric sulphate is
67. m  GMW  Wt.of solvent  g  1) 2 : 3 2) 1 : 3 3) 3 : 1 4) 3 : 2
9. The % composition of four hydro carbons is
ns as follows:
68. xs  n  n (i) (ii) (iii) (iv)
s 0
75 80 85.7 91.3 %C
w 1000 25 20 14.3 8.7 %H
70.. m  GMW  Wt.of solvent  g  The data illustrates the law of
1) Constant proportion
71. N1V1  N 2V2 2) Conservation of mass
72. N  M  Basicity of an acid 3) Multiple Proportions
4) Reciprocal Proportions.
N1V1  N 2V2  N 3V3 10. Among the following pairs of compounds, The
73. N 
V one that illustrates the law of multiple
74. H 3 PO4 is a tri basic acid proportions is
1) NH3 & NCl3 2) H2S & SO2
LEVEL - I (H.W) 3) CuO & Cu2O 4) CS2 & FeSO4
11. In compound A, 1.00 g nitrogen combines with
1. The correctly reported answer of the addition 0.57 g oxygen. In compund B,2.00 g nitrogen
of 154.21, 6.142 and 23 will be combines with 2.24 g oxygen. In compound C,
1)183.352 2) 183.35 3) 183.4 4) 183 3.00 g nitrogen combines with 5.11 g oxygen.
2. The nuclear cross section is measured in These results obey the following law.
‘barn’. It is equal to 1) Law of constant proportion
1) 10–20 m2 2) 10–30 m2 2) Law of multiple proportion
3) 10–28 m2 4) 10–14 m2 3) Law of reciprocal proportion
3. The value of Plank’s constant is 6.62618 10–34Js. 4) Dalton’s law of partial pressure
The number of significant figures in it is 12. Carbon and oxygen combine to form two
1) 6 2) 5 3) 3 4) 34 oxides, carbon monoxide and carbondioxide in
4. The number of significant figures in 0.0045 are which the ratio of the weights of carbon and
1) 2 2) 3 3) 4 4) 5 oxygen is respectively 12:16 and 12:32. These
5. The actual product of 4.327 and 2.8 is figures illustrate the
12.1156.The correctly reported answer will be 1) Law of multiple proportions
1) 12 2) 12.1 3) 12.12 4) 12.116 2) Law of reciprocal proportions
6. On dividing 0.46 by 15.374 , the atual answer is 3) Law of conservation of mass
0.029236.The correctly reported answer will be 4) Law of constant proportions
13. Two gaseous samples were analysed. One
1) 0.02 2) 0.029 3) 0.0292 4) 0.02924
contained 1.2 g of carbon and 3.2 g of oxygen.
LAWS OF CHEMICAL The other contained 27.3% carbon and 72.7%
COMBINATIONS oxygen. The experimental data are in
7. Which of the following pairs can be cited as accordance with
an example to illustrate the law of multiple 1) Law of conservation of mass
proportion? 2) Law of definite proportions
1) Na2O,K2O 2) CaO,MgO 3) Law of reciprocal proportions
3) Al2O3,Cr2O3 4) CO,CO2 4) Law of multiple proportions
 MOLE CONCEPT ATOMIC MASS, 3) 6  1023 ‘O’ atoms 4) 6  1023 ‘C’ atoms
MOLECULAR MASS, 26. Maximum number of electrons are present in
AVOGADRO NUMBER 1) 2.24 lit. of SO2 at S.T.P
14. Neon has two isotpoes Ne20 and Ne22. If 2) 0.2 moles of NH 3
atomic weight of Neon is 20.2, the ratio of the 3) 1.5 gm moles of oxygen
relative abundances of the isotopes is 4) 2 mole atoms of sulphur
1) 1 : 9 2) 9 : 1 3) 70 % 4) 80 % 27. When equal masses of methane and sulphur
15. The vapour density of ethyl alcohol vapour is dioxide are taken, then the ratio of their
1) 46 2) 23 3) 92 4) 69 molecules is
16. Maximum number of atoms are present in 1) 1 : 1 2) 1 : 2 3) 2 : 1 4) 4 : 1
1) 14 gms. of carbon monoxide 28. Molecular weight of a gas is 44.The volume
2) 2 gms. of hydrogen occupied by 2.2 grams of the gas
3) 11.2 lit. of nitrogen at STP 1) 1.12 lit 2) 1.14 lit 3) 2.24 lit 4) 5.6 lit
4) 1.5 gm atoms of helium 29. The number of moles of hydrogen in 0.224
17. The number of atoms in 0.004 g of magnesium litres of H2 gas at STP
will be [ AFMC, 2000 ] 1) 1 2) 0.1 3) 0.01 4) 0.001
1) 4 10 20 2) 8 10 3) 10 4) 6.02  1020
20 20
EQUIVALENT WEIGHT
18. Number of atoms in 55.85 gram Fe (at.wt. of 30. Atomic weight of elements is 40 and its valency
Fe = 55.85 g mol1 is . [AIEEE 2003] is 2. What is its equivalent weigt
1) 20 2) 40 3) 80 4) 10
1) Twice that 60 g carbon 2) 6.023  1022
31. Which of the following has equivalent weight
3) Half that in 8g He 4) 558.5  6.023  1023
Molecular weight
19. The total number of valence electrons in 4.2 is equal to
grams of nitride ion are 2
1) H2SO4 2) HCl 3) HNO3 4) NaOH
1) 1.4 N 0 2) 2.4 N 0 3) 3.2 N 0 4) 4.2 N 0 32. Equivalent weight of Pyrophosphoric acid is
20. The total weight of 1022 molecular units of (H4P2O7).
CuSO4 . 5H2O is nearly [ IIT, 1991 ] 1) M.W/1 2) M.W/2 3) M.W/4 3) M.W/3
1) 4.144 g 2) 4.5 g 33. Equivalent weight of metal is 20.If the metal
3) 24.95 g 4) 41.45 g forms tripositive ion, its atomic weight will be
21. 8 gms of O2 has the same number of molecules as 1) 20 2) 40 3) 60 4) 80
1) 7 gm CO 2) 14 gm of CO
3) 22 gm of CO2 4) 44 gms of CO2 PERCENTAGE WEIGHT OF
22. Which one of the following gases contain the ELEMENTS IN COMPOUNDS
least number of molecules ?(At Wt of P = 31, MOLECULAR FORMULA &
Cl = 35.5, N = 14, O = 16, C = 12, H = 1). EMPERICAL FORMULA
1) 4.0 g of laughing gas 2) 3.0 g of Phosphine 34. A compound has 40%of carbon by weight. If
3) 2.0 g of marsh gas 4) 10.0 g of Phosgene molecular weight of the compound is 90, the
23. The number of molecules present in 4.4 g of number of carbon atoms present in 1 molecule
CO2 gas is [Jipmer-1990] of the compound are
1) 6.023  10 23 2) 5.023  10 23 1) 3 2) 2 3) 1 4) 5
3) 6.023  10 24 4) 6.023  10 22 35. A Gaseous compound of Nitrogen and
24. - +2
The number of Cl and Ca ions in 222g. of Hydrogen contains 12.5% by weight of
CaCl2 are Hydrogen. The density of the compound
1) 4N, 2N 2) 2N, 4N 3) 1N, 2N 4) 2N, 1N relative to Hydrogen is 16, the molecular
25. One mole of CO2 contains [AFMC, 1998] formula of the compound is
1) 3 gram atoms of CO2 2) CO2 molecules 1) NH2 2) NH3 3) NH4 4) N2H4
 BASIC CONCEPTS OF CHEMISTRY

36. The percentage of C, H and N in an organic sulphur is burnt in excess of O2 is

compound are 40 %, 13.3% and 46.7% 1) 32 gm 2) 64 gm 3) 40 gm 4) 60 gm
respectively then empirical formula is 48. If 12.0 lit of H2and 8.0 lit of O2 are allowed ot
1. C3H13N3 2) CH2N 3) CH4N 4) CH6N react, the O2left unreacted will be
37. The percentage weight of Deuterium in heavy 1) 4.0 lit 2) 6.0 lit 3) 1.0 lit 4) 2.0 lit
water 49. The volume in lit of CO2liberated at S.T.P when
1) 80% 2) 60% 3) 40% 4) 20% 10g of 90% pure lime is heated completely is
NUMERICAL CALCULATIONS 1) 2.016 2) 20.16 3) 2.24 4) 22.4
BASED ON CHEMICAL 50. 26 cc of CO2are passed over red hot coke. The
volume of CO evolved is
EQUATIONS
1) 15cc 2)10cc 3) 32cc 4) 52cc
38. The weight of oxygen required to completely
react with 27 gms of 'Al' is 51. When 10 ml of hydrogen and 12.5ml of chlorine
1) 8 gm 2) 16 gm 3) 32 m 4) 24 gm are allowed to react the final mixture contains
under the same conditions
39. 20 gms of sulphur on burning in air produced
1) 22.5 ml of HCl 2) 12.5 ml of HCl
11.2 lits of SO2 at STP. The percentage of
3) 20 ml of HCl and 2.5 ml of chlorine
unreacted sulphur
4) 20 ml of HCl only
1) 80% 2) 20% 3) 60% 4) 40%
52. If 0.7 moles of Barium Chloride is treated with
40. The number of moles of Fe2O3 formed when
0.4 mole of potassium sulphate, number of
0.5 moles of O2 and 0.5 moles of Fe are allowed
moles of barium sulphate formed are
to react are 1) 0.7 2) 0.4 3) 0.35 4) 0.2
1) 0.25 2) 0.5 3) 1/3 4) 0.125
41. What is the volume (in lit) of carbon dioxide METHODS OF EXPRESSING
liberated at STP, when 2.12 grams of sodium CONCENTRATIONS
carbonate (mol. wt. = 106) is treated with 53. If 1.26 grams of oxalic acid is dissolved in 250
excess dilute HCl? ml of solution then its normality is
1) 2.28 2) 0.448 3) 44.8 4) 22.4 1) 0.05 2) 0.04 3) 0.02 4) 0.08
42. The amount of zinc required to produce 54. The mass of Na2CO3 required to prepare
224 ml of H2 at NTP on treatment with dilute 500ml of 0.1M solution is
H2SO4 solution will be 1) 10.6g 2) 5.3g 3) 2.65 g 4) 7.95g
1) 0.65 g 2) 0.065 g 3) 65 g 4) 6.5 g 55. The molarity of NaOH in the solution prepared
43. 'X' litres of carbon monoxide is present at STP. by dissolving its 4 g in enough water to form
It is completely oxidized to CO2. The volume 250 mL of the solution is
of CO2 formed is 11.207 litres at STP. What is 1) 0.2 2) 0.4 3) 0.1 4) 0.25
the value of 'X' in litres? ( EAM - 2002) 56. Normality of 2% of H SO solution by
2 4
1) 22.414 2) 11.207 3) 5.6035 4) 44.828 volume is nealy
44. The volume of phosgene formed at STP when 11.2 1) 2 2) 4 3) 0.2 4) 0.4
lit of chlorine reacts with carbon monoxide is 57. The molarity of pure water is
1) 11.2 lit 2) 22.4 lit 3) 5.6 lit 4) 44.8 lit 1) 100 M 2) 55.6M 3) 50 M 4) 18 M
45. If 100 ml hydrogen chloride is completely 58. Density of a solution containing x% by mass
decomposed the volume of H2 formed will be of H2SO4 is y. The normality is
(P and T are constant).
xy  10 xy  10
1) 20 ml 2) 200 ml 3) 100 ml 4) 50 ml 1) 2) 98 y  2
98
46. The volume of H2 STP required to completely
reduce 160 gms of Fe2O3 is xy  10 x 10
3) 2 4)
1) 3  22.4 L 2) 2  22.4 L 3) 22.4L 4) 11.2 L 98 98 y
47. The weight of SO2 formed when 20gms of
59. Number of gram equivalents of solute in 100ml 1) Does not change 2) Changes from +1 to -1
of 5 NHCl solution is 3) Changes from -2 to -1
1) 50 2) 500 3) 5 4) 0.5 4) Changes from 0 to -1
60. A solution is prepared by adding 2 g of 70. M+3 ion loses 3e-. Its oxidation number will be
substance A to 18 g of water. The mass 1) 0 2) +3 3) +6 4) -3
percent of the solute is 71. Oxidation state of carbon is not zero in
1) 10 2) 20 3) 40 4) 25 1) CH2O 2) C6H12O6 3) CH2Cl2 4) CHCl3
CONCEPT OF OXIDATION 72. Which of the following process nitrogen is
oxidised
NUMBER AND REDOX
REACTIONS 1) NH 4  N 2 2) NO3  NO
61. The oxidation state of phosphorus is minimum in 3) NO2  NO2 4) NO3  NH 4
1) P4O6 2) NaH2PO2 73. Iron shows least oxidation state in which of the
3) PH3 4) Na3PO4 following?
62. Oxidation state of phosphorus in
1) K 4  Fe  CN 6  2) K 3  Fe  CN 6 

pyrophosphosphate ion P2O7 is
-4
 3) FeSO4  NH 4  2 SO4 6 H 2O 4) Fe2  CO 9
1) +7 2) +3 3) +8 4) +5
63. Oxidation state of Sulphur in sodium tetra KEY LEVEL - I (H.W)
thionate (Na2S4O6) 01) 4 02) 3 03) 1 04) 1 05) 1 06) 2
1) +2 2) +4 3) +1.5 4) +2.5 07) 4 08) 4 09) 3 10) 3 11) 2 12) 1
64. Oxidation Number of phosphorus in 13) 2 14) 2 15) 2 16) 2 17) 3 18) 3
Ba(H2PO2)2 19) 2 20) 1 21) 1 22) 2 23) 4 24) 1
1) -3 2) +1 3) +3 4) +5 25) 4 26) 4 27) 4 28) 1 29) 3 30) 1
65. When Cl - ions are converted to Cl 2, the 31) 1 32) 3 33) 3 34) 1 35) 4 36) 3
oxidation number of chlorine changes from 37) 4 38) 4 39) 2 40) 1 41) 2 42) 1
1) -1 ot 0 2) -1 to +1 43) 2 44) 1 45) 4 46) 1 47) 3 48) 4
3) -1 to +2 4) -2 to 0
49) 1 50) 4 51) 3 52) 2 53) 4 54) 2
66. 3Cu + 8HNO3  3Cu  NO3  2 + 2NO + 4H 2 O 55) 2 56) 4 57) 2 58) 3 59) 4 60) 1
the wrong statement for the above 61) 3 62) 4 63) 4 64) 2 65) 1 66)3
1) Cu is oxidized 67) 1 68) 1 69) 2 70) 3 71) 4 72)1
2) HNO3 is reduced 73) 4
3) Cu is reduced
4) Cu acts as reducting agent
HINTS LEVEL-I (H.W)
4. zeros to the left of the first non-zero digit are not
67. The oxidising agent in the reaction
significant
- + -2
2MnO4 + 16H + 5C 2O4  14. Let W% of Ne20 = x
2Mn+2 + 8H O + 10CO W % of Ne22 = 100 - x
2 2

1) MnO4– 2) H + x  20  100  x  22
20.2 
3) C2O42– 4) Both 1 & 2 100
68. What is the oxidation state of chlorine in 2020  20 x  2200  22 x
hypochlorous acid?
2 x  2200  2020
1) +1 2) +3 3) +5 4) +7
2 x  180
69. In the reaction NO2  OCl   NO3  Cl  the
x  90 %
oxidaton state of chlorine
w % of Ne20 = 90 %
 w% of Ne22 = 100 - 90 = 10% w 1000
Ne20 : Ne20 = 90 : 10 = 9 : 1 56. N = GEW × V (in ml)
46
15. V.D =  23 w 1
2
57. M = GMW  V in litres
Wt
16. No. of atoms =  N  atomicity
MW pecentage×d×10
58. N =
26. No. of electrons = No. of moles x Avogadro no x GEW
No. of electrons in a molecule
27. Ratio of molecules is equal to inverse ratio of their 59. No.gram equivalents = N×V (in ml )
mol. wts. if the wts. are equal. 1000
Wt M×GMW × V(in ml)
37. % of element   100 60. w =
M .Wt 1000
38. 4Al + 3O2  2Al2O3 66. O.S of Cu increase
39. S + O2  SO2 From oto+2
 cu oxidised
40. 4 Fe  3O2  2 Fe2 O3 67. Oxidising agent undergo reduction
41. Na2CO3 + 2HCl  2 NaCl + CO2 + H2O 68. Hypochlorous acid HClO
42. Zn + H2SO4  ZnSO4 + H2
1
43. CO  O2  CO2
2
44. CO+Cl2 
h COCl2
45. 2HCl  H 2  Cl2
46. Fe2 O3  3H 2  2 Fe  3H 2O
47. S  O2  SO2
1
48. H 2  O2  H 2 O
2
49. CaCO3  CaO  CO2
50. CO2  C  2CO
51. H 2  Cl2  2 HCl
52. BaCl2  K 2 SO4  BaSO4  2 KCl

w 1000
53. N = GEW × V (in ml)

M×GMW × V(in ml)

54. w =
1000
w 1000
55. M = GMW  V in ml
1. SOME BASIC CONCEPTS OF CHEMISTRY
1) i, ii, iii 2) iii, ii, i 3) i, iii, ii 4) ii, iii, i
LEVEL-II (C.W) 8. When 0.44 g of a colourless oxide of nitrogen
SIGNIFICANT FIGURES occupies 224 mL at 1520 mm Hg and 2730C,
then the oxide is
1. The number of significant figures in  are
1) N2O5 2) N2O3 3) NO2 4) N2O
1) Three 2) Infinite number
3) Zero 4) One 9. How many moles of magnesium phosphate
2. Given the numbers: 161cm, 0.161cm, [Mg3(PO4)2] will contain 0.25 mole of oxygen
0.0161cm. The number of significant figure atoms? [AIEEE 2006]
for the three numbers are 1) 3.12510 2 2) 1.25102
1) 3,4 and 5 2) 3, 3 and 3 3) 2.510 2 4) 0.02
3) 3, 3 and 4 4) 3, 4 and 4 10. The number of molecules present in 1.12×10-7
LAWS OF CHEMICAL cc of a gas at STP is
COMBINATIONS 1) 6.02 × 1023 2) 3.01 × 1012
3) 6.02 × 1012 4) 3.01 × 1023
3. Different samples of water were found to
11. Number of electrons in 1.8 grams of H2O are
contain Hydrogen and oxygen in the mass ratio
1) 6.02 × 1023 2) 3.01 × 1023
of 1 : 8. This shows the law of
1) Multiple Proportions 3) 0.602 × 1023 4) 60.22 × 1023
2) Constant Proportions 12. From 320 mg. of O2, 6.023  1020 molecules
3) Reciprocal Proportions are removed, the no. of moles remained are
4) Conservation of mass 1) 9  10-3 moles 2) 9  10-2 moles
4. The % of Hydrogen in water and Hydrogen 3) Zero 4) 3  10-3 moles
peroxide is 11.2% and 5.94% respectively. 13. An oxide of nitrogen has a molecular weight
This illustrates the law of 92. Find the total number of electrons in one
1) Constant Proportions 2) Conservation of mass gram mole of that oxide.
3) Multiple Proportions 1) 4.6N 2) 46N 3) 23N 4) 2.3N
4) Law of Gaseous volume. 14. Total number of species present in 1 mole
of potash alum in terms of avagadro number,
5. The composition of compound A is 40% X and
'N' are
60% Y. The composition of compound B is 25%
1) 3N 2) 5N 3) 8N 4) 32N
X and 75% Y. Accroding to the law of multiple
Proportions the ratio of the weight of element 15. Number of moles of KI required to prepare 0.4
Y in compounds A and B is: moles of K2 Hgl4, when HgCl2 reacts with Kl
1) 1:2 2) 2 : 1 3) 2 : 3 4) 3 :4 1) 0.4 moles of KI 2) 0.8 moles of KI
3) 1.6 moles of KI 4) 3.2 moles of KI
MOLE CONCEPT ATOMIC 16. How many water molecules are there in one
MASS, MOLECULAR MASS, drop of water ( volume 0.0018ml) at room
AVOGADRO NUMBER temperature?
6. The density of water is 1 gm/ml. The volume 1) 6.0231019 2) 1.084 1018
of water drop is 1.8 ml. The no. of molecules 3) 6.0231023 4) 4.841017
present in one water drop are
1) 6.023  1023 2) 6.023  1021 17. 1.5 g of CdCl2 was found to contain 0.9 g of
3) 3.011  1020 4) 6.023  1022 Cd. Calculate the atomic weight of Cd.
7. Increasing order of number of moles of the (EAMCET-2009)
species 1) 118 2) 112 3) 106.5 4) 53.25
i) 3 grams of NO ii) 8.5 grams of PH 3 and
iii) 8 grams of methane is
 EQUIVALENT WEIGHT 25. A compound of phosphorous and sulphur contains
18. 2.0g of a metallic carbonate on decomposition 1.24 gm of phosphorous in 2.2 gm of the
gave 1.5g.of metallic oxide. The equivalent compound. The formula of the compound is
mass of metal is 1) P4S3 2) P3S4 3) P3S2 4) P2S3
1) 58 2) 29 3) 5.8 4) 2.9 26. The relative number of atoms of different
19. The vapour density of a tribasic acid is x. The elements in a compound are as follows: A=1.33,
equivalent mass of that acid is B=1 and C=1.5. The emperical formula of the
x 2x compound is
1) b) x  3 3) 4) 2 x  3 1) A2 B2C3 2) ABC 3) A8 B6C9 4) A3 B3C4
3 3
20. The equivalent weight of divalent metal is 27. A compound has 40% of carbon by weight. If
31.82. The weight of a single atom is molecular weight of the compound is 90, the
23 23
1) 32.55  6.02  10 g 2) 32.77  6.02  10 g number of carbon atoms present in 1 molecule
of the compound are
3) 63.64g 4) 63.64 / 6.02  10 23 g 1) 3 2) 2 3) 1 4) 5
21. When NA is Avogadro’s number then the 28. A compound has 20% of nitrogen by weight. If
number of oxygen atoms in one gm. equivalent one molecule of the compound contains two
of oxygen is nitrogen atoms, the molecular weight of the
NA N compound is
1) N A 2) 3) A 4) 2  N A 1) 35 2) 70 3) 140 4) 280
2 4
PERCENTAGE WEIGHT OF 29. 3.0 gms of an organic compound on combustion
give 8.8 gm of CO2 and 5.4 gm of water. The
ELEMENTS IN COMPOUNDS empirical formula of the compound is
MOLECULAR FORMULA &
1) CH 3 2) C2 H 4 3) C2 H 2 4) C2 H 6
EMPERICAL FORMULA
22. At STP one litre of a gas weighs 1.25 grams. 30. The oxide of a metal contains 40% of oxygen.
The gas contains 85.71% of carbon and The valency of metal is 2. What is the atomic
14.29% of hydrogen. The formula of the weight of the metal ? (EAMCET-2014)
compound is 1) 12 2) 40 3) 36 4) 24
1) CH4 2) C2H6 3) C3H8 4) C2H4 NUMERICAL CALCULATIONS
23. A certain compound contains magnesium,
carbon and Nitrogen in the mass ratio 12 : 12 BASED ON CHEMICAL
: 14. The formula of the compound is EQUATIONS
1) MgCN 2) Mg2CN 31. When a sample of Baking soda is strongly
3) MgCN2 4) Mg(CN)2 ignited in a crucible it suffered a loss in weight
24. An organic compound having molecular mass of 3.1g. The mass of baking soda is
60 is found to contain C = 20%, H = 6.67% 1) 16.8 g 2) 8.4 g 3) 11.6 g 4) 4.2 g
and N = 46.67% while rest is oxygen. On 32. 20 ml of a hydro carbon requires 100 ml of
heating it gives NH3 along with a solid residue. oxygen for complete combustion. In this
The solid residue give violet colour with reaction 60 ml of carbondioxide is produced.
alkaline copper sulphate solution. the The formula of hydro carbon is
compound is [AIEEE 2005] 1) C2H4 2) C3H6 3) C3H8 4) C6H6
1) CH3NCO 2) CH3CONH2
3) (NH2)2CO 4) CH3CH2CONH2
 BASIC CONCEPTS OF CHEMISTRY
33. 18.4 gms of a mixture of calcium carbonate and METHODS OF EXPRESSING CON-
magnesium carbonate on heating gives 4.0 gms
CENTRATIONS
of magnesium oxide. The volume of CO2
40. An aqueous solution of 6.3 g oxalic acid
produced at STP in this process is
dihydrate is made up to 250 ml. The volume of
1) 1.12 lit. 2) 4.48 lit 3) 2.24 lit 4) 3.36 lit.
0.1 N NaOH required to completely neutralize
34. A solution containing 0.2 mole of ferric chloride
10 ml of this solution is
is allowed to react with 0.24 mole of sodium
1) 40 ml 2) 20 ml 3) 10 ml 4) 4 ml
hydroxide. The correct statement for this
41. The normality of orthophosporic acid having
reaction is
purity of 70% by weight (specific gravity is
1) Limiting reagent for this reaction is NaOH
1.54) would be
2) 0.08 moles of Fe(OH.3 is formed 1) 11 N 2) 22 N 3) 33 N 4) 44 N
3) 0.12 mole of FeCl3 is left unreacted 42. Mole fraction of C3H5(OH)3 in a solution of
4) All the above 36 g of water and 46 g of glycerine is
35. CH 4 g  + 2O2 g   CO2 g  + H 2Ol  , as per this 1) 0.46 2) 0.36 3) 0.20 4) 0.40
reaction, if 20ml of CH4 and 20 ml of O2 were 43. The volume of water to be added to 400 ml of
exploded together and if the reaction mixture N/8 HCI to make it exactly N/12 is
is cooled to room temp, the resulting gas 1) 400ml 2) 300ml 3) 200ml 4) 100ml
mixture will have a volume of 44. When 100ml of 10 M solution of H2SO4 and
1) 40 ml 2) 20 ml 3) 60 ml 4) 30 ml 100 ml of 1 M solution of NaOH are mixed
the resulting solution will be
36. The mass of Hydrogen at S.T.P. that is present
1) Acidic 2) Basic
in a vessel which can hold 4 grams of oxygen
3) Neutral 4) Can not predicted
under similar conditions is
45. In order to prepare one litre normal solution
1) 1gm 2) 0.5gm 3) 0.25gm 4) 0.125gm
of KMnO 4, how many grams of KMnO 4
37. KMnO4 reacts with KI in basic medium to from
required if the solution is to be used in acid
I2 and MnO2 . When 250 mL of 0.1 M KI
medium for oxidation
solution is mixed with 250 mL of 0.02M KMnO4
1) 158 2) 79 3) 31.6 4) 790
in basic medium,what is the number of moles
46. 12.5 ml of a solution containg 6 grams of
I2 formed? (EAMCET -2014)
dibasic acid in one litre was found to be
1) 0.0075 2) 0.005 3) 0.01 4) 0.015
neutralised by10 ml of a decinormal solution
38. 19 g og a mixture containing NaHCO3 and
of NaOH. the molecular mass of the acid is
Na2CO3 on complete heating liberated 1,12L
1) 75 2) 110 3) 120 4) 150
of CO2 at STP. The weight of the remaining 47. 50gr of sample of sodium hydroxide required
solid was 15.9 g. What is the weight (in g) of for complete neutralisation, 1 litre 1 NHCl.
Na2CO3 in the mixture before heating? What is the percentage purity of NaOH is
(EAMCET -2011) 1) 50 2) 60 3) 70 4) 80
1)8.4 2) 15.9 3) 4.0 4) 10.6 48. How many grams of 40% pure sodium
39. The number of molecules of CO2 liberated by hydroxide is dissolved in 0.5 M, 250 ml NaOH
the complete combustion of 0.1 g atom of solution?
graphite in air is (EAMCET -2010) 1) 5 gm 2) 2g 3) 12.5 g 4) 4 gm
1) 3.011022 2) 6.02  10 23 49. 100 ml of 0.2N HCl solution is added to 100
3) 6.02  10 22 4) 3.011023 ml of 0.2N AgNO3 solution. The molarity of
nitrate ions in the resulting mixture will be
1) 0.5 M 2) 0.05M 3) 0.1M 4) 0.2M
50. The density of 3 M solution of NaCl is 1.25 g
mL-1. The molality of the solution is
1) 2.79 m 2) 1.79 m 3) 3.5 m 4) 5.58 m
 JEE MAIN JR-CHEM - VOL - II
61. The oxidation state of the most electronegative
OXIDATION & REDUCTION atom in each of the product is
51. The oxidation state of iron in the coordination H 2 + O2  H 2 O2 + H 2 O
sphere of prussain blue is
1)  2,  2 2) 1,  2 3)  2, 1 4) 1,  2
1) +2 2) 0 3) +1 4) +3
52. Oxidation Number of carbon in SCN- ion is 62. Which reaction involves neither oxidation nor
1) +2 2) -2 3) +4 4) -4 reduction
53. In ICl3 oxidation numbers of iodine and 1) CrO42  Cr2O72  2) Cr  CrCl3
chlorine are
1) 0 & 0 2) +3 & -1 3) Na  Na  4) 2S 2O32   S 4O62 
3) -1 & +3 4) -3 & +1 63. In the chemical reaction
54. Lead Nitrate is strongly heated. In this K 2 Cr2O7 + xH 2 SO4 + ySO2 
reaction the oxidation numbers of following
atoms change K 2 SO4 + Cr2  SO4  3 + zH 2O
1) Only in Pb and N 2) Only in N and O Here x, y and z are
3) Pb, N and O 4) Only in N 1) 1,3,1 2) 4,1,4 3) 3,2,3 4) 2,1,2
55. The sum of the oxidation number of the carbon 64. Consider the following reaction
atoms in CH 3CHO is 5H 2O2 + xClO2 + 2OH - 
1) -2 2) +2 3) -4 4) -1 .
xCl - + yO2 + 6H 2 O
56. In the reaction between ethylene and alkaline
KMnO4 the oxidation number of Manganese is The reaction is balanced if
1) Decreases from +7 to +2 1) x = 5, y = 2 2) x = 2, y = 5
2) Decreases from +7 to +6 3) x = 4, y = 10 4) x = 5, y = 5
3) Decreases from +7 to +4 65. In the balanced chemical reaction
4) Increases from +4 to +7 IO3- + al - + bH +  cH 2 O + dI 2
57. The gas bleaches the colour of flowers by a,b,c and d respectively correspond to
reduction, while the other by oxidation 1) 5,6,3,3 2) 5,3,6,3 2) 3,5,3,6 4) 5,6,5,5
1) CO & CI2 2) H2S & Br2
3) SO2 & Cl2 4)NH3 & SO3 KEY LEVEL - II (C.W)
58. In the reaction between acidified KMnO4 and hot 01) 4 02) 2 03) 2 04) 3 05) 1 06) 4
oxalic acid the species that gains electrons is 07) 1 08) 4 09) 1 10) 2 11) 1 12) 1
1) K  2) MnO4 3) C2O42  4) CO2 13) 2 14) 4 15) 3 16) 1 17) 3 18) 1
59. Which of the following have been arranged in 19) 3 20) 4 21) 2 22) 4 23) 4 24) 3
order of decreasing oxidation number of 25) 1 26) 3 27) 1 28) 3 29) 1 30) 4
sulphur? 31) 2 32) 3 33) 2 34) 4 35) 2 36) 2
37) 1 38) 4 39) 3 40) 1 41) 3 42) 3
1) H 2 S 2O7  Na2 S 4O6  Na2 S2O3  S8
43) 3 44) 1 45) 3 46) 4 47) 4 48) 3
2) SO 2  SO42  SO32  HSO4 49) 3 50) 1 51) 1 52) 3 53) 2 54)2
3) H 2 S  SCl2  H 2 SO3  H 2 SO5 55) 1 56) 3 57) 3 58) 2 59) 1 60) 1
61) 4 62) 1 63) 1 64) 2 65) 1
4) H 2 SO4  SO2  H 2 S  H 2 S2O8
HINTS LEVEL - II (C.W)
60. 3HOCl  2HCl + HClO3 is an example of 22  S.F  2
1) Disproportionation reaction 1.
7 S.F  1
2) Displacement reaction so answer is 1 (one).
3) Chemical combination reaction 5. X, Y
4) Decomposition reaction.
 60 21. No:of oxygen
A 1
40 8
atoms=  6.0231023
75 16
B 1
25 22. 1lt  1.25gm
6. 1.8ml  1.8 gm ( d = 1gm/ml) 22.4 l g ives molecular Wt.
W MW
7. No. of moles = M.F = E.F x EF Wt.
MW
8. Volume of oxide is caluculated at STP conditions
Wt
PV
1 1 PV
2 2 23.  no.of gram atoms
by the formula = T  T At.wt
1 2
12 12 14
Weight of the 22400 ml oxide at STP= molecular Mg : C : N  : :
weight 24 12 14
9. 1 mole of megnesium phosphate contains 8 moles 20 6.67 46.67 26.66
of oxygen atoms. 24. C : H : N : O  : : :
12 1 14 16
10. 22400 cc of a gas at STP = 6.02  1023
molecules M .F   E.F  n
1.12  10-7cc of a gas at STP = ? Mol.wt
7 23 n
1.12 10  6.02 10 E.F.weight

22400
1.24 2.2 1.24
= 3.01×1012 molecules 25. P : S  :
31 32
1.8 90  40
11. No. of electrons   10  N
18 27. Wt   36 gm of Carbon
100
Wt No. of molecules
12. No. of moles = or 100  20
M .Wt N 28.
13. No. of electrons in one mole ?  28
Wt  y y
 N x No.of electrons in molecule 29. Cx H y   x   O2  xCO2  H 2O
M .W t
 4 2
14. Potash Alum = K2SO4.Al2(SO4).3 . 24H2O
15. HgCl2 + 4KI  K2Hgl4 + 2KCl 30. 40 g O2 combined with 60g metal
W 8g O2 combined with - ?=12
16. No. of molecules = N
MW
eq.wt of metal =12
17. % Cd in Cd Cl2 (60%) At.wt= 212  24
% Cl2 in Cd Cl2 (40%) 31. The loss in weight is due to mass of H 2O and CO2
40% has -Atwt 71 32. Cx Hy + (x + y/4. O2  x CO2 + y/2 HzO
60% - 106.5 33. MgCO3  CaCO3  MgO  CaO  2CO2
weightof metalcarbonate eqmassof
. metal eqmassof
. CO32 34. FeCl3 + 3NaOH  Fe (OH.3 + 3 NaCl
18. 
weightof metallicoxide eqmassof
. metal eqmassof
. O2 35. CH 4  2O2  CO2  2H 2 O

2  V .D 36. 2gm of H 2  16gm of O2

19. Eq. mass=
Basicity 37. MnO4  I   MnO2  I 2
2  eq.mass No: of milli eq.of
20. Wt.of single atom=
6.023  1023 Mno4  0.02  3 250  15
 JEE MAIN JR-CHEM - VOL - II
No: of milli eq. of
I 2  0.11 250  25
Here Mno4 is limiting reagent.
 No of milli eq. of I 2 formed =15
 No of milli eq. of I 2
15
formed=  0.015
1000
 No of milli moles.of I 2 formed=
0.015
 0.0075
2 54. S  C  N 
38. Total weight=84+106=190
In 190g mix wt of Na2CO3 =106
in 19 g mix wt of Na2CO3 =10.6
39. C s  O2 g  CO2 g
 100  0.2
49. NO3 in the mixture e   0.1
100  100
N1V1  N2V2
51. strength  N  EW
MW  EW  Ba s i city
M  1000
52. m=
1000  d  M  GMW
53. Fe4  Fe  CN 6  3 coordinat ion sphere is
4
 Fe  CN 6 
55. Chlorine is more electronegitive than Iodine
56. Pb  NO3  2  PbO  NO2  O2
57. 2x  4  2  0  2x  2
58. Mn 7 O4  Mn 4 O2

1 mole - 6.023 1023 molecules CO2 59. SO2  2H 2O  H 2 SO4  2  H 

0.1 mole- ? = 6.023  1022 Cl2  H 2O  2HCl   O 
w 1000 65.Balancing according to oxidation number method
40. N= ×
GEW V (in ml) 66.Balancing as per given method
N1V1 = N2V2 67.Balancing as per given method
Percentage×specific gravity×10 LEVEL - II (H.W)
41. N=
GEW
ns LAWS OF CHEMICAL
42. χs = COMBINATIONS
ns + no
1. Two students ‘x’ and ‘y’ report the weiht of
43. N1V1 = N2V2
Volume of water is added = V2 - V1 the same substance as 5.0g and 5.00g
respectively. Which of the following statement
V M -V M is correct.
44. M= 1 1 2 2
V
1) Both are equally accurate
N×GEW× V (in ml)
45. w= 2) ‘x’ is more accurate than ‘y’
1000
3) ‘y’ is more accurate than ‘x’
w 1000 4) bothe are inaccurate scientifically
46. N= ×
GEW V (in ml)
2. 81.4g sample of ethyl alcohol contains 0.002g
47. w = N×GEW ×V (in lit ) of water. The amount of pure ethyl alcohol (to
40 the proper number of significant figures) is
100 = 80%
% of purity of NaOH =
50 1) 81.398 g 2) 81.40g 3) 81.4g 4) 81g
M×GMW × V (in ml) 3. Two samples of lead oxide were separately
48. w = reduced to metallic lead by heating in
1000
hydrogen. The weight of lead from one oxide
 was half the weight of lead obtained from the
other oxide. The data illustrates law of
1) Reciprocal proportions
2) Constant proportions
3) Multiple proportions
4) Equivalent proportions
4. The Rydberg’s constant is 1.097373177 107m–1.
It can be expressed to three significant figures as
1) 1.0974  107 m–1 2) 1.09  107m–1
3) 1.10  107m–1 4) 1.107 m–1
5. The mass of piece of paper is 0.02g and the
mass of a solid substance along with the same
piece of paper is 20.036g. If the volume of the
solid is 2.16 cm3, its density to the proper
number of significant digits will be
1) 9.27 g cm-3 2) 9.3 g cm-3
3) 9.267 4) 43.24 cm-3
6. Which one of the following pairs of
compounds illustrate the law of multiple
proportions:
1) H2O,Na2O 2) MgO,Na2O
3) Na2O,BaO 4) SnCl2,SnCl4
7. Two oxides of a certain metal were seperately
heated in hydrogen till water is produced. It
was observed that 1 gm of each oxide gave
0.125 gm and 0.2263 grams of water
respectivley. This law states that it illustrate
law of
1) Definite proportions 2) Multiple proportions
3) Reciprocal proportions
4) Conservation of mass
8. 4.4 gm of an oxide of nitrogen gives 2.24 lit. of
nitrgoen and 60 gm of another oxide of nitrogen
gives 22.4 lit of nitrogen at STP. This data
illustrates the law of.
1) Conservation of mass 2) Multiple Proportions
3) Constant Proprotions 4) Gaseous volume.
9. 2.16 grams of Cu on reaction withHNO3
followed by ignition of the nitrate gave 2.7 gm
of copper oxide. In another experiment 1.15
gm of copper oxide upon reduction with
hydrogen gave 0.92 gm of copper. This data
illustrate the law of
1) Multiple Proportions 2) Definite Proportions
3) Reciprocal Proportions4) Conservation of mass
10. Two oxides of a metal contain 27.6% and 30%
of oxygen respectively. if the formula of the
first oxide is M 3O4 that of second on is:
1) MO 2) MO2 3) M 2O3 4) M 2O
11. The mass of nitrogen per gram in hydrazine is
exactly one and half the mass of nitrogen in
the compund ammonia. The fact illustrates the
1) Law of conservation of mass
2) Multiple valency of nitrogen.
3) Law of multiple proportion
4) Law of definite Portin
12. Irrespective of the source, pure sample of
water always yields 88.89% mass of oxygen
and 11.11% mass of hydrogen. This is
explained by the law of
1) Conservation of mass 2)Constant Proportions
3) Multiple proportions 4) Constant volume
13. The oxides of nitrogen contain 63.65%,
46.69% and 30.46% of nitrogen respectively.
This data illustrate the law of
1) Constant Proportions 2) Multiple Proportions
3) Reciprocal Proportions4) Conservation of mass
14. The following data are available.
i) % of Mg in MgO and in MgCl2
ii) % of C in CO & CO2
iii) % of Cr in K2 Cr2O7 and K2CrO4
iv) % of Cu isotopes in Cu metal.
The law of multiple proportions may be
illustrated by data.
1) i & ii 2) Only ii 3) i, ii & iii 4) Only iii
MOLE CONCEPT ATOMIC MASS,
MOLECULAR MASS,
AVOGADRO NUMBER
15. The ratio of the mass of C-12 atom to that of
an atom of element X (whose atomicity is four.
is 1 : 9. The molecular mass of element X is
1) 480 g mol–1 2) 432 g mol–1
3) 36 g mol–1 4) 84 g mol–1
16. Study the following table: Which two
compounds have least weight of oxygen
(molecular weights of compounds are given in
brackets)
 JEE MAIN JR-CHEM - VOL - II PERCENTAGE WEIGHT OF
Compound Weightof compound ELEMENTS IN COMPOUNDS
(M.Wt.) in g. taken MOLECULAR FORMULA &
I) CO2 (44) 4.4 EMPERICAL FORMULA
II) NO2 (46) 2.3 25. An oxide of nitrogen contains 36.8% by weight
III) H2O2 (34) 6.8 of nitrogen. The formula of the compound is
IV) SO2 (64) 1.6 1) N2O 2) N2O3 3) NO 4) NO2
1) II & IV 2) I & III 26. A compound contains 28% of Nitrogen and
3) I & II 4) III & IV 72% of metal by weight. Three atoms of metal
17. Which of the following contain 9×10 23 oxygen combines with Two atoms of Nitrogen. The
atoms ? atomic weight of the metal is
1) 0.25 moles of glucose 1) 12 2) 24 3) 36 4) 48
2) 0.5 moles of ethyl alscohol 27. An organic compound contains 40% C, 6.66%
H. The empirical formula of the compound is
3) 1.0 mole of dimethyl ether
4) 0.01 moles of sucrose 1) CH 2 2) CH 2O 3) CHO 4) CHO2
18. Number of gram atoms of oxygen present in 28.` If 75.2% of compound is carbon and the rest
0.3 mole of (COOH)2, 2H2O is of the weight is hydrogen, the formula of the
1) 9 2) 18 3) 0.9 4) 1.8 compound is
19. Ordinary water contain one part of heavy water 1) C3 H 6 2) C2 H 2 3) C2 H 4 4) CH 4
per 6000 parts by weight. The number of heavy
29. X and Y are two different elements havaing
water molecules present in drop of water of
their atomic masses in 1:2 ratio. The
volume 0.01 ml is ( Density of water is 1 gm/ml)
gompound formed by the combination of X and
1) 2.5  1016 2) 2.5  1017 Y contains 50% of X by weight. The emperical
3) 5  1016 4) 7.5  1016 formula of the compound is
20. No. of moles of water in 488.6 gms of 1) X2Y 2) XY2 3) XY 4) X4Y
BaCl 2 .2H 2 O are (molecular weight of 30. 15 cc of gaseous hydrocarbon required 45 cc
BaCl2.2H2O=244.33) of oxygen for complete combusion if 30 cc of
1) 2 moles 2) 4 moles 3) 3 moles 4) 5 moles CO2 is formed, the formula of the gaseous
EQUIVALENT WEIGHT compound is
21. Equivalent weight of metal ‘M” is 1) C3H6 2) C2H2 3) C4H10 4) C2H2
12.Equivalent weight of Y in the compound MY2 31. 0.132 g of an organic compound gave 50 ml of
is (M.W of MY2is 36) N2 at NTP. The weight percentage of nitrogen
1) 24 2) 6 3) 12 4) 16 in the compound is close to
22. The oxide of an element possesses the formula 1) 15 2) 20 3) 48.9 4) 47.34
MO2. If the equivalent mass of the metal is 9. NUMERICAL CALCULATIONS
then the atomic mass of the metal will be BASED ON CHEMICAL
1) 9 2) 18 3) 27 4) 36
23. One mole of chlorine combines with certain EQUATIONS
weight of metal giving 111 gm of its chloride. 32. A gas mixture contains acetylene and
The same amount of metal can displace. 2gm carbondioxide. 20 litres of this mixture requires
hydrogen from an acid. The equivalent weight 20 litres of oxygen for complete combustion.
of metal is.... If all gases are measured under similar
1) 40 2) 20 3) 80 4) 10 conditions of temperature and pressure, the
24. 3.0 g of metal oxide conveted ot 5.0 g of the percentage of acetylene in the mixture is
metal chloride. The equivalent weight of the 1) 50% 2) 40% 3) 60% 4) 75%
metal is 33. When 4.0 g of iron is burnt at high temperature
1) 3.325 2) 66.50 3) 33.25 4) 25.33
 to ferric oxide at constant pressure 29.28 kJ
of heat is evolved. The amount of heat evolved
for producing one mole of ferric oxide is
1) 819.84 kJ 2) 40.99 kJ
3) 81.98 kJ 4) 409.0 kJ
34. 40 ml. of a hydrocarbon undergoes combustion
in 260 ml of oxygen and gives 160 ml of
carbondioxide. If all gases are measured
under similar conditions of temperature and
pressure, the formula of hydrocarbon is
1) C3H8 2) C4H8 3) C6H14 4) C4H10
35. The sulphur dioxide obtained by the
combustion of 8 gms of sulphur is passed into
Bromine water. The solution is then treated
with barium chloride solution. The amount of
barium sulphate formed is
1) 1 mole 2) 0.5 mole
3) 0.25 gms 4) 0.25 gm moles
36. Phosphine on decomposition produces
phosphorus and hydrogen. The change in
percentage in volume
1) 50 ml 2) 80 ml 3) 900 ml 4) 75 ml
37. 0.7 moles of potassium sulphate is allowed to
react with 0.9 moles of barium chloride in
aqueous solutions. The number of moles of the
substance precipitated in the reactions is
1) 1.4 moles of potassium chloride
2) 0.7 moles of barium sulphate
3) 1.6 moles of potassium chloride
4) 1.6 moles of barium sulphate
38. ‘X’ grams of calcium carbonate was completely
burnt in air. The weight of the solid residue
formed is 28 g. What is the value of ‘X’ (in
grams)
1) 44 2) 200 3) 150 4) 50
39. Oxalic acid is heated with conentrated H2SO4
When the resultant gases are passed over red
hot carbon, X is obtained, ‘X’ is
1) CO 2) CH 4 3) CO2 4) C2 H 4
METHODS OF EXPRESSING
CONCENTRATIONS
40. Which of the following solutions has the
highest normality?
1) 172 milli equivalents in 200 ml
2) 84 milli equivalents in 100 ml
3) 275 milli equivalents in 250 ml
4) 43 milli equivalents in 60 ml
41. 12 ml of 0.25N H2SO4 is neutralised with 15ml
of sodium hydroxide solution on titration, then
the normality of NaOH solution is
1) 0.4 N 2) 0.2N 3) 0.1N 4) 0.05N
42. The specific gravity of 98% H2SO4 is 1.8 g/cc.
50 ml of this solution is mixed with 1750 ml of
pure water. Molarity of resulting solution is
1) 0.2 M 2) 0.5 M 3) 0.1 M 4) 1 M
43. What volume of 75 % H2SO4 by mass is
required to prepare 1.5 litres of 0.2 M H2SO4?
(Density of the sample is 1.8 g/c.c)
1)14.2c.c 2)28.4c.c 3) 21.7c.c 4) 7.1 c.c
44. 4.9 grams of H2SO4 is present is 100 ml of the
solution , then its molarity and normal ity are
1) 1, 0.5 2) 1, 1 3) 0.5, 1 4) 0.5, 2
45. How many grams of CH3OH would have to be
added to water to prepare 150 ml of a solution
that is 2M CH3OH ?
1) 9.6 2) 2.4
3) 9.610 3 4) 4.3102
46. What weight of sodium hydroxide is required
to neutralise 100 ml of 0.1N HCl ?
1) 4 g 2) 0.4 g 3) 0.04 g 4) 40 g
47. Which one of these solution has the highest
normality ?
1) 8 gr KOH per 100 ml 2) 0.5M H2SO4
3) 6 gr of NaOH per 100ml 4)1N H3PO4
48. The concentration of sugar (C12H22O11) in
mol L-1. If its 20 g are dissolved in e n o u g h
water to make a final volume up to 2 L ?
1) 0.092 2) 0.029 3) 0.059 4) 0.069
49. The weight of oxalic acid required to reduce
80 ml of 0.4M KMnO4 in acidic medium is
1) 10.08g 2) 7.21 g 3) 16.28 g 4) 12.4 g
50. The volume of water to be added to 400
ml of N/8 HCl to make it exactly N/12 is
1) 400 ml 2) 300 ml 3) 200 ml 4) 100 ml
51. 0.1 N solution of a dibasic acid can be
preapared by dissolving 0.45 gr of the acid in
water and diluting to 100 ml. The molarity of
nitrate ions the resulting mixture will be
1) 45 2) 90 3) 135 4) 180
52. To neutralise 20mL of 0.1 M aqueous solution
of phosphorus acid (H3PO3), the volume of 0.1
M aqueous KOH solution required is
1) 10 mL 2) 20 mL 3) 40 mL 4) 60 mL
53. A solution is prepared by adding 2 g of 62. In the co-ordination compound K4[Ni(CN)4],
substance A to 18 g of water. The mass
percent of the solute. the oxidation state of nickel is
1) 10 2) 20 3) 40 4) 25 1) -1 2) 0 3)+1 4)+2
63. What is the oxidation number of chlorine in
OXIDATION & REDUCTION
ClO3–?
54. The element which has only one oxidation state
in its compounds is 1) +5 2) +3 3) +4 4) +2
1) Hydrogen 2) Oxygen 64. In a balanced equation
3) Nitrogen 4) Fluorine H 2 SO4 + xHI  H2 S + yI2 + zH2 O the values
55. The oxidation number of manganese in
of x,y and z are
potassium manganate is
1) +7 2) +6 3) +4 4) +2 1) x = 3, y = 5, z = 2 2) x = 4, y = 8, z = 5
3) x = 8, y = 4, z = 4 4) x = 5, y = 3, z = 1
56. In the reaction 2BaO2  2BaO + O2 the
KEY LEVEL - II (H.W)
oxidation number of Barium
1) Decreases from +4 to +2 01) 3 02) 3 03) 3 04) 3 05) 1 06) 4
2) Decreases from +2 to 0 07) 2 08) 2 09) 2 10) 3 11) 3 12) 2
3) Increases from -4 to -2 13) 2 14) 2 15) 2 16) 1 17) 1 18) 4
4) Does not change 19) 3 20) 2 21) 3 22) 4 23) 2 24) 3
57. KMnO4 is a strong oxidising agent in acid 25) 2 26) 2 27) 2 28) 4 29) 1 30) 4
medium. To provide acid medium, H2SO4 is 31) 4 32) 2 33) 1 34) 4 35) 4 36) 1
used instead of HCl. this is because.
37) 2 38) 4 39) 1 40) 3 41) 2 42) 2
1) H2SO4 is a stronger acid than HCl
2) HCl is oxidised by KMnO4 to Cl2 43) 3 44) 3 45) 1 46) 2 47) 3 48) 2
3) H2SO4 is a dibasic acid 49) 2 50) 3 51) 2 52) 3 53) 1 54) 4
4) rate is faster in the presence of H2SO4 55) 2 56) 4 57) 4 58) 2 59) 4 60) 1
58. In the reaction 61) 1 62) 2 63) 1 64) 3
2 KMnO4  16 HCl  HINTS LEVEL - II (H.W)
5Cl2  2 MnCl2  2 KCl  8 H 2O 1. 5.00gm has more significant figures than 5.0 gm
2. 81.4  (digits after decimal =1)
reduction product is 0.002  (digits after decimal=3)
1) Cl2 2) MnCl2 3) H 2 O 4) KCl -------
59. A compound of Xe and F is found to the 53.5% 81.402
Xe. What is the oxidation number of Xe in this -------
compound? Round off to one decimal place so ans is
1) -4 2) 0 3) +4 4) +6 81.4
2- - -2
60. In the reaction S2O + 2I  2SO + I 2
8 4
20.036
5.  9.27
1) Oxidaton of iodide into iodine takes place 2.16
2) Reduction of iodine into iodide takes place 10. M O
3) Both oxidation ane reduction of iodine takes place M 3O4  72.4 27.63
4) None of the above
61. The oxidation states of sulphur in the anions M xOy 70 30
SO32  , S 2O42  and S 2O62 follow the order 72.4-3 (metal) 70-?
27.6-4 (oxygen) 30-?
1) S 2O42   SO32   S2 O62 
15. Molecular mass=
2) SO32   S2 O42   S2 O62  weight of molecule
2 2 2
3) S 2O  S 2O  SO 1
4 6 3 weight of th part of C 12 atom
12
4) S 2O62   S2O42   SO32 
16. find out the weight of oxygen as per the data given
 BASIC CONCEPTS OF CHEMISTRY %X %y
29.
by the formulae 1 2
weight of oxygen  no.of moles  32  y y
30 Cx H y   x   O2  xCO2  H 2O
wt  4 2
17. No: of atoms = N
Aw 28 vol.of N  ml  at stp
2
18. No: of gram atoms= NO : of moles  6 31. wt % of N 2  22400  wt.of compound 100
19. 6000- 1
20
0.01- ? 32. C 2 H 2   100
50
w
No: of molecules N 
Mw 1 lit - lit
2
W 20 lit - ?= 50 lit
20. No. of moles =
MW 20
1 mole contains 2 moles of water % C2 H 2   100
50
At.wt 3
21. E.wt = 33. 2 Fe  O2  Fe2O3
valency 2
22. Valency of the metal is 4 4 g of Fe  29.28KJ of Heat
Atomic mass =eq. mass  valency
56 g of Fe  ?
23. MW of MCl2 =111g
 y y
M+71 =111 34. C x H y   x   O2  xCO2  H 2O
 4 2
M=111-71=40
35. 32gm. of sulphur is present in 1 mole of BaSO4.
2 gm of H 2 displaced by 40 gm of metal 8 gm of sulphur is present in 1/4 mole BaSO4.
1 gm of H 2 displaced by ? 36. 2 78gm of benzene needs 15 22.4 lit of O2
37. K 2 SO4  BaCl2  BaSO4  2KCl 3 8 .
wt.of metal oxide
24.  CaCO3  CaO  CO2
wt.of metallic chloride
H 2 SO4
eq.wt of metal  eq.wt of o 2 39.H 2 C2O4 
 H 2O
 CO  CO2

eq.wt of metal  eq.wt of cl  C
CO  CO2   3CO


25. Caluculate relative No: of atoms of Nitrogen and No.of milli equivalents
36.8 100  36.8 40. N = V (in ml)
oxygen N : O= :
14 18 41. N1V1 = N2V2
26. M W = 28+72=100 Percentage×specific gravity×10
Wt. of two’N’ atoms= 28 gm 42. M=
GMW
Wt. of 3 metal atoms= 72 gm M1V1 = M2V2
Wt. of 1 metal atoms = ?
percentage×10×d
72 43. M=
=  24 GMW
3 w 1000
44. M= 
%C % H %O GMW V in ml
27.
12 1 16 N = M  Basicity of an acid
%C % H M×GMW × V (in ml)
28. 45. w=
12 1 1000
 N×GEW× V (in ml) 5. A mixture of HCOOH and H2C2O4 is heated
46. w =
1000 with conc. H 2SO 4. The gas produced is
w 1000 collected and on treating with KOH solution
47. N = GEW × V (in ml) the volume of gas decreases by 1/6th. Calculate
the ratio ( molar . of the two acids in original
N = M  Basicity of an acid
mixture.
w 1 1) 4:1 2) 1:4 3) 3:1 4) 2:1
48. M = GMW  V in litres
6. When burnt in air, 14.0g mixture of carbon and
N × GEW × V (in ml) sulphur gives a mixture of CO2 and SO2 in the
49. w= volume ratio of 2 :1 , volume being measured
1000
at the same conditions of temperature and
50. N1V1  N 2V2 pressure the number of moles of carbon in the
volume of water to be added= V2  V1 mixture is
1) 0.75 2) 0.5 3) 0.40 4) 0.25
w 1000
51. N= × 7. The oxide of a metal contains 60 % of the
GEW V (in ml) metal. What will be the percentage of bromine
52. H 3 PO3  2 KOH  K 2 HPO3  2 H 2 O in the bromide of the metal, if the valency of
the metal is the same in both the oxide and the
For complete neutralisation bromide :
M aVa M bVb 1)  87 2)  70 3)  77 4)  93

na nb 8. Cu2S and M2S are isomorphous in which
percentages of sulphur are 20.14 % and 12.94
mass of solute % respectively. the atomic weight of M is
53. Mass precentage = mass of solution  100
(Cu=63.5)
LEVEL - III 1) 208 2) 108 3) 112 4) 115
9. A sample of 1.0g solid Fe2O3 of 80% purity is
1. The ratio of masses of oxygen and nitrogen in dissolved in a moderately conc. HCl solution
a particular gaseous mixture 1:4. The ratio of which is reduced by Zn dust. The resulting
number of their molecule is : (MAINS-14) solution required 16.7 ml of a 0.1 M solution
1) 1:8 2) 3:16 3) 1:4 4) 7:32 of oxidant. Calculate the number of electrons
2. Versene, a chelating agent having chemical taken up by the oxidant. (Fe=56, O=16)
formula C2H4N2(C2H4O2Na)4. If each mole of 1) 5 2) 2 3) 4 4) 6
this compound could bind 1 mole of Ca , then2+ 10. A gaseous hydrocarbon give upon combustion
the rating of pure versene expressed as mg of 0.72 g of water and 3.08 g of CO 2. The
CaCO3 bound per g of chelating agent is : empirical formula of the hydrocarbon is: (JEE
1) 100 mg 2) 163 mg 3) 200 mg 4) 263 mg MAINS -2013)
3. One mole of a mixture of CO andCO2 requires 1) C3 H 4 2) C6 H 5 3) C7 H 8 4) C2 H 4
exactly 20 g of NaOH in solution for complete 11. 10 mL of gaseous organic compound consisting
conversion of all the CO2 into Na2CO3 if the C, H and O only was mixed with 100 mL of O2
mixture ( one mole . is completely oxidised to CO2: and exploded under identical conditions and
1) 60 g 2) 80 g 3) 40 g 4) 20 g then cooled. The volume left after cooling was
4. 1.23g of Nitro Benzene on reduction with 90 mL. On treatment with KOH a contraction
Zn+NH4Cl then it gives N-Phenyl hydroxyl of 20 mL was observed. If vapour density of
amine that isomerised to 4 - amino phenol. compound is 23, derive molecular formula of
Then No. of electrons involved and the element the compound.
reduced is 1) C3H6O 2) C2H4O 3) C2H6O 4) C3H8O
12. A hydrocarbon contains 10.5g of carbon per
1) 24  103 N 2) 24  1024 N
gram of hydrogen. 1 litre of the hydrocarbon
3) 12  10 N
23 4) 6  10 N
23 at 1270C and 1 atm pressure weighs 2.8g. Find
molecular formula
 1) C7H8 2) C6H10 3) C7H6 4) C6H12 20. Calcium carbonate reacts with aqueous HCl to
13. When K 2 Cr 2 O 7 mixed with H 2 SO 4 and give CaCl2 and CO2 according to the reaction
thoroughly shaken with H2O2 in presence of CaCO3  s   2HCl  aq  
ether. Then the floated blue coloured complex .
is ‘X’.The percentage of Cr in the complex is CaCl2  aq   CO2  g   H 2 O  l 
1) 49.4 2) 29.4 3) 39.4 4) 59.4 The mass of CaCO 3is required to react
14. A 20.0 cm2 mixture of CO, CH4and He gases completely with 25 mL of 0.75 M HCl is
are exploded by an electric discharge at room 1) 1.825g 2) 0.9375g
temperature with excess of oxygen. The 3) 1.8357g 4) 0.4625g
volume contraction is found to be 13.0cm3. A 21. 3.92 g of ferrous ammonium sulphate (FAS) react
further contraction of 14.0cm3 occurs when the completely with 50 ml N/10 KMnO4 solution. The
percentage purity of the sample is
residual gas is treated with KOH solution. Find
1) 50 2) 78.4 3) 80 4) 28
out the composition of the gaseous mixtre in 22. Upon heating one litre of N/2 HCl solution,
terms of volume percentage. Let ‘a’ volume 2.67 gm of hydrogen chloride is lost and the
of CO and ‘b’ volume of CH4 be present in the volume of solution shrinks to 750 ml. The
mixture. normality of resulting solution is
1) CO - 40 % ; CH 4  20 % ; He - 40 % 1) 18.25 N 2) 1.138 N 3) 0.569 N 4) 0.5 N
23. Metal X forms two oxides. Formula of the first
2) CO - 40 %; CH 4  30 %; He - 20 % oxide is XO2. The first oxide contains 50% of
3) CO - 50 %; CH 4  20 %; He - 30 % oxygen. If the second oxide contains 60% of
oxygen, the formula of the second oxide is
4) CO - 50 %; CH 4  10 %, He - 40 % 1) X2O 2) XO3 3) X2O3 4) X3O2
15. 7.36g of a mixture of KCl and KI was dissolved 24. 0.2 moles of a hydro carbon, which cannot
in H2O to prepare 1 litre solution. 25ml of this decolourise bromine water, on complete
required 8.45 ml of 0.2 N AgNO3, what are % combustion produced 26.4 gm of CO2. The
of KI in mixture ?
molecular weight of the hydro carbon is
1) 57.28 2) 47.28 3) 5.72 4)I 49.12
1) 44 2) 42 3) 40 4) 58
16. Equal weights of Zn metal and iodine are mixed
25. In a clinical laboratory, a sample of urine
together and the iodine is completely
containing 0.120 g of urea NH 2 CONH 2
converted to ZnI2. What fraction by weight of
the original zinc remains unreacted ? (M.Wt.60. was treated with excess of nitrous
(Zn=65, I=127). acid. The urea reacted according to the
1) 0.6 2) 0.74 3) 0.47 4) 0.17 following equation NH2CONH2 +2HNO2 
17. A hydrocarbon ‘X’ have 81 % of carbon. CO 2
+2N2+3H2O. The gas formed was passed
Volume of CO2liberated at 298K and 76cm of through aqueous sodium hydroxide and final
Hg when 0.55gm of ‘x’ undergoes combustion volume is measured at STP, what was this
volume.
1) 0.90l 2) 11.09l 3) 1.89l 4) 1.09l
1) 89.6 cc 2) 179.2 cc 3) 44.8 cc 4) 22.4 cc
18. Gastric juice contains 3.0g of HCl per litre. If
a person produces 2.5 litre of gastric juice per 26. 50 vol of a gas X is mixed with 70 vol of oxygen.
day. How many antacid tablets each containing After explosion the gas is passed through
400 mg of Al(OH)3 are needed to neutralize KOH, 45 vol. of oxygen is left. What is the
all the HCl produced in one day? gas X?
1) 18 2)  13 3) 20 4) 17 1) CO2 2) O2 3) CO 4) N2
19. 50.0 kg of N2(g) and 10.0 kg of H2(g). are 27. A certain sample of coal contains 1% of sulphur
mixed to produce NH3(g). The limiting reagent by weight. What is the weight of sulphur
and amount of NH3 formed are dioxide produced when 2106 kg of this coal is
1) H2, 56.67kg 2) H2, 13.1kg burnt ?
3) H2, 1.56kg 4) H2, 36.2kg 1) 2  104 kg 2) 4  104 kg
5
3) 4  10 kg 4) 2  105 kg
28. 5 g of crystalline salt rendered anhydrous lost 38. 5.3 g of Na2CO3 taken in a 250 ml flask and
1.89 g of water. The formula weight of the water added upto the mark.10ml of that
anhydrous salts is 160. The number of water solution was taken in a 50 ml flask water added
molecules of crystallisation is [NSTS, 1991] upto the mark. Find molarity of that dilute
1) 1 2) 2 3) 3 4) 5 solution.
29. n g of a substance X reacts with m g of substance 1) 0.1 M 2) 0.02 M 3) 0.04 M 4) None
Y to from p g of substance R and q g of substance 39. 0.5 g mixture of K2Cr2O7 and KMnO4 was
S. This reaction can be represented as follows : treated with excess of KI in acidic medium.
X+Y=R+S.The relation which can be Iodine liberated required 150cm3 of 0.10N
established in the amounts of the reactants and solution of thiosulphate solution for titration
the products will be : 1) 14.64 2) 34.2 3) 65.69 4) 50
1) n  m  p  q 2) n  m  p  q 40. Find out % of oxalate ion in a given sample of
3) n  m 4) p  q an alkali metal oxalate salt, 0.30 g of it is
30. To neutralize completely 20 ml of 0.1M aqueous dissolved in 100 mL water required 90 mL of
solution of phosphorous acid the volume of 0.1 centimolar KMnO4 solution in acidic medium
M aqueose.KOH solution required is 1) 66% 2) 55% 3) 44% 4) 6.6%
1) 40 ml 2) 20ml 3) 10ml 4) 60ml 41. The molarity of a solution obtained by mixing
31. The density of a 2.05 molar solution of acetic 750 mL of 0.5 (M) HCl with 250 mL of 2(M)
acid in water is 1.02g/ml. The molality of the HCl will be (MAINS- 2013)
soltion is 1) 1.00 M 2) 1.75 M
1)1.14mol/kg 2) 3.28 mol/kg 3) 0.975 M 4) 0.875 M
3) 2.28 mol/kg 4) 0.44mol/kg
42. The density of a solution prepared by
32. The density in g/mL of a 3.60 M H2SO 4
dissolving 120 g of urea ( mol. Mass=60 u) in
solution is 29% H2SO4 by mass will be
1000g of water is 1.15 g/mL. The molarity of
1)1.45 2) 1.64 3) 1.88 4) 1.22
this solution is (MAINS-12)
33. 0.1N solution of a dibasic acid can be prepared
by dissolving 0.45 gm of the acid in water and 1) 0.50 M 2) 1.78 M 3) 1.02 M 4) 2.05 M
diluting to 100 ml . The molecualr mass of the 43. A 5.2 molal aqueous solution of methyl alcohol,
acid is CH3OH is supplied. What is the mole fraction
1) 45 2) 90 3) 135 4) 180 of methyl alcohol in the solution?
34. 100 ml of 0.2 NHCl solution is added to 100ml (JEE MAINS-2011)
of 0.2N AgNO3 solution. The molarity of 1) 0.190 2) 0.086 3) 0.050 4) 0.100
nitrate ions in the resulting mixture will be OXIDATION & REDUCTION
1) 0.5M 2) 0.05M 3) 0.1M 4) 0.2M 44. 1 mole of N2H4 lost 10 moles of electrons and
35. The density of 3 M solution of NaCl is formed a new compound, 'Y' in which all
1.25gmL-1. the molality of the solution is hydrogens are present with out change in the
1) 2.79 m 2) 1.79 m 3) 3.5 m 4) 5.58 m oxidation state. The oxidation number of
Nitrogen in the new compound 'Y' is
36. 0.16 g of dibasic acid required 25 ml of
1) +1 2) +2 3) +3 4) +5
decinormal NaOH solution for complete
45. What is the oxidation state of Fe in the product
neutralisation. The molecular weight of the
formed when acidified Potassium ferrocyanide
acid will be
(K 4[Fe(CN) 6]) is treated with hydrogen
1) 32 2) 64 3)128 4) 256 peroxide?
37. 0.45 N & 0.6 N NaOH solution are mixed in 1) +2 2) +3 3) +1 4) +6
2:1 by volume. The amount of solute present 46. In the reaciton, An+ + MnO4–  A5+ + Mn2+ if
in 1 litre of this solution is 0.05 mole of An+ is oxidized by 0.02 mole of
1) 0.5 g 2) 25 g 3) 20 g 4) 5 g MnO4– , the value of 'n' is
 1) 1 2) 2 3) 3 4) 4 100 103
47. Which of the following sequence is correct with =  263mg
380
reference to the oxidation number of iodine?
20
1) I2< ICl<HI<HIO4 2) HIO4<ICl<I2<HI 3. meq. of CO2 in mixture =  1000  500
3) I2<HI<ICl<HIO4 4) HI<I2<ICl<HIO4 40
48. When KMnO4 acts as an oxidising agent it may  mole of CO2 in mixture
change to MnO4–2, MnO2, Mn2O3 or Mn+2. The 500 1
number of electrons transferred in each case 
2  1000 4

 Eq.wt of CO2  M
2 
respectively are [AIEEE-02 ]
3
1) 4, 3, 1, 5 2) 1, 5, 3, 7  Mole of CO in mixture =
3) 1, 3, 4, 5 4) 3, 5, 7, 1 4
49. In Balancing the reaction If this CO is completely oxidised to CO2 then mole
- + 2+ +
XZn + NO3 + YH  XZn + NH 4 + ZH 2 O, 3
X,Y & Z are of CO2 formed =
4
1) 4, 10, 3 2) 3, 8, 3 3) 3, 10, 3 4) 4, 3, 10
1 3
5 0 . MnO4- + C 2 O42- + H +  CO2 + H 2O + Mn 2+ .  Total mole of CO2 =  1
The correct coefficients of MnO4– C2O4–2 and 4 4
H+ are (MAINS-2013)  Mole of NaOH required =
1) 2, 5, 16 2) 16, 5, 2 3) 5, 16, 2 4)2, 16, 5 2 mole of CO2  2 1  2
51. 1 mole of equimolar mixture of ferric oxalate  wt. of NaOH required = 2 40  80g
and ferrous oxalate will require x mole of
NO2 NHOH
KMnO 4 in acidic medium for complete
oxidation, x is
1) 0.5 mole 2) 0.9 mole 3) 1.2 mole 4) 4.5 mole 4. 4  H  + H2O
KEY LEVEL – III
01) 4 02) 4 03) 2 04) 1 05) 1 06) 2 123g
07) 1 08) 2 09) 4 10) 3 11) 3 12) 1 123g of Nitro Benzene 4 N electrons
13) 3 14) 3 15) 1 16) 2 17) 1 18) 2
H 2 SO4
19) 1 20) 2 21) 1 22) 3 23) 2 24) 1 5. HCOOH 
 Conc 
 H 2O  CO
a moles a moles
25) 1 26) 3 27) 2 28) 4 29) 2 30) 1
H 2 SO4
31) 3 32) 4 33) 2 34) 3 35) 1 36) 3 H 2C2O4 
 Conc 
 H 2O  CO  CO2
b moles b moles b moles
37) 3 38) 3 39) 1 40) 1 41) 4 42) 4
Total no. of moles released as gases
43) 2 44) 3 45) 2 46) 3 47) 4 48) 3
49) 1 50) 1 51) 2 a  b  b  a  2b
HINTS LEVEL–III CO2 is absorbed by KOH
1
w b  a  2b   moles  volume 
1. Moles of O2  6
32
a
4w  4 or a : b :: 4 :1
Moles of N 2  b
28 6. Let weight of C be x g, then S will be 14  x  g
no2 : nN 2  7 : 32 x /12 2

2. 1 mole Ca = 1 mole CaCO3 = 100 g
2
14  x  / 32 1
Rating = mg of CaCO3 needed per g chelating agent 6
( mol. wt = 380 .  x  6g ; moles of C   0 .5
12
7. meq. of metal = meq of oxygen
 60 40 10x = 20 or x = 2

E 8 10  x  y / 4  z / 2   100  70   30
 E  12 or x  y / 4  z / 2  3 or y / 4  z / 2  1 or
Now meq. of metal = meq. of bromide
100  a a y  2z  4...... 1

12 80 Mol. mass = 223  46 12x  y 16z
 a  87% or y 16z  22 ........(2.
8. Suppose the atomic weight of S and M are x and y solving y = 6 and z = 1
respectively. Now, for Cu2 S Formula of the compound  C2 H 6 O \
1 mole of Cu  2  moles of S p1 V1 T2
12. Volume at NTP = 
0.7986 0.2014 T1 P2
1  2       ( I )
63.5 x 11 273 273
=   litre
( 1g of Cu2 S contains 0.786g and 0.2014g of Cu 400 1 400
and S respectively. And for M 2 S , 273
 litre weighs 2.8g at NTP..
0.8706 0.1294 400
1  2       ( II )  22.4 litres ( 1 mole . weighs =
y x
(1g of M2S contains 0.8706g and 0.1294g of M 2.8  400
 22.4 g  91.8974  92g
and S respectively from eqns. 1and 2., we get 273
y = 107.7
 atomic weight of M is 107.70 13. Blue complex is CrO5 .
1 80 52
9. Weight of pure Fe2 O3   0.8 g % of Cr =  100
100 132
Fe2O3  6 HCl  2 FeCl3  3H 2O 1
Zn dust CO  g    O2  g   CO2  g 
2FeCl3  H2  2FeCl2  2HCl 2
14. 1 vol
a vol 1/ 2 vol
1 vol
a vol
 
Fe  Oxidant  Fe  reduc tan t 1/ 2 a vol

Mol.wt 160 CH 4  g  2O2  g   CO2  g   2 H 2O  l 

Eq. wt. of Fe2O3    80g
2 2 1 vol 2 vol 1 vol
b vol 2 b vol b vol
meq. of Fe2O3 = meq of oxidant Tot al initial volume =
0.8  1 
 103  16.7  0.1 x 
80  a   2  a  b  2b  20   a  b  
   
 x6
volume after reaction =  a  b  20   a  b  
 y y
10. Cx H y   x   O2  xCO2  H 2O 1
 4 2
Contraction =   a  2b  13
wt 3.08g. 2
0.72g When treated with KOH, CO2 is absorbed
moles 0.07 0.04 i.e. a  b  14
x 7 Solving both equations a  10,b  4

y 8 CO 10cm3 ;CH4  4cm3 and He  6cm3
y
Cx H yOz   x  y / 4  z / 2 O2  xCO2  H2O i.e; CO  50%;CH 4  20% and He  30%
11. 1 vol  x y/4 z /2 x vol 2
10 x vol
10 vol 10 x  y /4 z /2 15. KI  KCl ; geq of mixture = geq of AgNO3
 xg  7.36  x  g 22. w = 0.5  36.5  1 = 18.25 gr..
Remaining wt. of HCl = 18.25 - 2.67 = 15.58 g
 x 7.36  x  8.45  0.2  40 w 1000
   N 
 166 74.5  1000 GEW V (in ml )
 on solving x = 4.216g
15.58 1000
 % of KI 57.28 % N   0.569 N
16. Let x g be the initial weight of the Zn metal and 36.5 750
iodine each. Since I 2 is completely converted to 50 50
23. X : O  1: 2  Atomic weight of metal : 16
ZnI 2 , we have, Zn +I2  ZnI 2
x x 40 60
Initial no. of moles 0 X :O  :
65 254 32 16
No. of moles at the end of the reaction :
26.4
 x x  x 24. 0.2 mole of hydrocarbon = moles of CO2
   0 44
 65 254  254 1 mole of hydrocarbon = ?
 fraction of Zn remained unreacted
NH2 CONH2 + 2HNO2  CO2 + 2N2 + 3H2 O
 x x  25. 2 mole or  vol
 
1 mole

 65 254   0.74 Aqueous NaOH solution absorbs CO2
= x 60g ..................... 2 x 22.4. lts at S.T.P.
65 0.120 g .................... ?
17. 100 g    81g 26. CO2 is absorbed in KOH solution, therefore the
0.55 g    0.4455 g gas is CO
 nRT 10.0821298  27. Weight of sulphur present in coal
1 2 g  2 4 .4 6 5 8 l V   
 P 1  210 6 1
 210 4 kg S + O2  SO2
0.4455g 0.908l 100
3 32 x 10-2 kg  64 x 10-3 kg. 2 x 104 kg  ?
18. geq of HCl   2.5  0.20548 weight of sulphur dioxide
36.5
= geq of Al  OH 3 210 4  6410 3
= 3
 410 4 kg
32 10
Weight of Al  OH 3 = 28. ( 5-1.89 . grams of salt require 1.89grams of
0.20548  78 Water 160 grams of salt requires ? grams of
 5.342 g  5342mg water.
3
29. n+m=p +q
5342 30. V1N1 = V2N2
 No of tablets =  13.35  14
400 N of H3PO3 = 2 x 0.1 = 0.2 N
19. N 2  3H 2  2 NH 3 M×1000
(H2 is limiting reagent) 31. m=
1000×d - M×GMW
W
20. V  N percentage×10×d
G.E.W 32. M =
GMW
50  1
21. Eq of KMnO4 used =  0.005 w 1000
1000  10 33. N = GEW × V (in ml) (M.Wt. = Eq.Wt x 2)
 Eq of FAS reacted = 0.005
 weight of FAS needed
= 0.005  392  1.96g
  100  0.2 M 1V1  M 2V2
34. Molarity of NO3   0.1 41. M 
200 V
M×1000
35. m = 1000×d - M×GMW 120  1000
M  2.05
42. 1120
36. Ratio of molecules is equal to inverse ratio of their 60 
1.15
mol. wts. if the wts.are equal
43. Mole fraction of solute in aqueous solution
V1 N1 + V2 N 2
37. N=
V m 5.2
  0.086
w 1 = 1000 1000
N= × m  5.2 
GEW V (in lts) 18 18
38. M1V1 = M2V2 44. If 1 mole hydrazine lost 10 moles of electrons than
39. Reactions of K Cr O and KMnO with KI may nitrogen oxidation state changes from -2 to + 3
2 2 7 4
be given as: 45. K4  Fe(CN)6   K3  Fe(CN)6 
K 2Cr2O7  7 H 2 SO4  6 KI  4 K 2 SO4 Fe+2  Fe+3
46. 0.05 moles An+ oxidized by 0.02 moles MnO4- 5
Cr2  SO4 3  7 H 2O  3I 2 moles An+ oxidized by 2 moles MnO4- balanced
2 KMnO4  8H 2 SO4  10 KI  6 K 2 SO4 redox equation is
5 An+ + MnO4-  5A5+ + 2 Mn+2
2 MnSO4  5 I 2 In a redox reaction, increase in O.N. of one atom
Thus, equivalent wt. of = decrease in O.N. of another atom
294 \ 5 (5-n. = 10, 5-n = 2, n=3
K 2 Cr2O7   49 47. Hl < l2 < ICI < HIO4
6
48. Oxidation states MnO42 , MnO2 , Mn2O3 and Mn2
158
equivalent wt. of KMnO4   31.6 are + 6, + 4, + 3, + 2
5
49. Conceptual
 meq . of K 2 Cr2 O 7  meq . of KMnO 4 50. Balance the equation as per the method
=meq. of I 2 =meq. of hypo Fe2  C2 O4 3  MnO4  H   2 Fe3
Let the mass of K 2 Cr2 O7  x g ; 51.
n  6  n  5
 mass of KMnO4   0.5  x  g 6CO2  H 2O
x  0.5  x  FeC2O4  MnO4  H   Fe3
  150  0.110 3 (or)
49 31.6  n  3  n  5 
0.0732
 % of K 2 Cr2 O7   100 2CO2  H 2O
0.5
Total equivalents of
 14.64
W 1  Fe  C O 
2 2 4 3  FeC2 O4 
40. 1000   2  90   5;
24  64 100 =equivalents of KMnO4
W  0.198 g
 0.5 6  0.5 3  x  5
% of oxalate ion in a given sample
moles of KMnO4  x  0.9
0.198
 100  66
0.3
 Excess O
LEVEL-IV D) 0.56 g CO c 2 4) 2.24 L CO2
om 
bustio
n
1. Match the Column-1 with Column-II 5) 22.4 L CO2
Column-I ColumnII(units) 1) A-4, B-1, C-2, D-3 2) A-5, B-1, C-2, D-3
(Basic physical quantities) 3) A-4 , B-1,C-3, D-2 4) A-1, B-4, C-2, D-3
6. List - I
1) Electric current A) Candela
A) One gram atom Al
2) Luminous intensity B) Keivin B) One gram atom Ag
3) Temperature C) Mole C) Our gram atom Mg
4) Amount of substance D) Ampere D) Two moles of hydrogen
1) 1-B, 2-A, 3-D, 4-C 2) 1-D, 2-A, 3-B, 4-C List - II
3) 1-A, 2-D, 3-C, 4-B 4) 1-B, 2-A, 3-C, 4-D 1) One equivalent weight
2) Two equivalent weights
2. Match the Column-1 with Column-II 3) Three equivalent weights
Column-I ColumnII 4) Four equivalent weights
(Quantities) (Multiples) 5) five equivalent weights
1) M icr o ( ) A) 10–9 1) A-3, B-1, C-2, D-4 2) A-3, B-2, C-1, D-4
2) Nano (n) B) 10–6 3) A-2, B-3, C-1, D-4 4) A-2, B-3, C-4, D-1
7. List - I List - II
3) Pico (p) C) 10–12
(compound) (Oxidation no of
4) Femto (f) D) 10–15 sulphur)
1) 1-B, 2-A, 3-D, 4-C 2) 1-D, 2-C, 3-B, 4-A A) H2S2O8 1) +1
3) 1-A, 2-D, 3-C, 4-B 4) 1-B, 2-A, 3-C, 4-D B) H2S 2) +2
C) Na2SO3 3) +6
3. Match the Column-1 with Column-II D) S2Cl2 4) +4
Column-I ColumnII 5) -2
1) 1 L A) 105 dyne 6) +7
2) 1 L-atm B) 1.602210–19J 1) A-3, B-5, C-4, D-2 2) A-3, B-5, C-4, D-1
3) 1 N C) 1dm3 3) A-6, B-5, C-4, D-2 4) A-6, B-4, C-5, D-1
4) 1 eV D) 101.325J 8. List - I
1) 1-C, 2-D, 3-A, 4-B 2) 1-D, 2-C, 3-B, 4-A A) Na2 O2 + H2 SO4  Na2 SO4 + H 2O2
3) 1-A, 2-D, 3-C, 4-B 4) 1-B, 2-A, 3-C, 4-D B) H 2 + Cl 2  2HCl
4. List - I List - II C) Cr  OH  3  CrO4-2
A) Gram molar volume 1) 2.69  1019 D) IO3-  I -
B) Avogadro number 2) 1.67  10–24g List - II
C) Atomic mass unit 3) 6.023  1023 1) Redox reaction
D) Loschmidt number 4) 22.4 lit. at. S.T.P 2) Oxidation reaction
1) A-4, B-2, C-3, D-1 2) A-4, B-3, C-2, D-1 3) Non - redox reaction
4) Reduction reaction
3) A-1, B-2, C-3, D-4 4) A-2, B-1, C-4, D-3
1) A-3, B-1, C-2, D-4 2) A-3, B-2, C-1, D-4
5. Match the following (EAMCET-2008)
List - I List - II 3) A-1, B-3, C-2, D-4 4) A-1, B-3, C-4, D-2
(at STP) ASSERTION & REASONING
A) CH3OH 1) 0.224L CO2 1) Both (A) and (R) are true and (R) is the
Excess HCl
B) 1.06 g Na 2CO3  2) 4.48 L CO2 correct explanation of (A)
ExcessO 2) Both (A) and (R) are true and (R) is not the
C) 2.4 g C  2 3) 0.448 L CO2
combustion correct explanation of (A)
 3) (A) is true but (R) is false
4) (A) is false but (R) is true
9. Assertion (A): Greater the number of significiant
figures in reported result, greater is the precision.
Reason(R): The number of significant figures also
includes the last digit whose value is uncertain.
10. A: Density is a derived physical quantity.
R: A quantity obtained with the help of two of more
fundamental quantities is a derived quantity.
11. Assertion: SI unit of atomic mass is kg.
Reason: One kg of a substance contains
6.0231023 atoms.
12. A : The volume ratio of H2, Cl2 and HC in the
reaction H 2 g +Cl2 g   HCl g  is 1 : 1 : 2
R: Substances always react in such a way that their
volume ratio is simple whole number
13. A: 2S 2O32   I 2  S4 O62  2I  is a redox reaction
R: In redox reactions, both oxidation and reductions
takes place simultaneously
14. A: Fluorine acts as a stronger reducing agent than
oxygen.
R: Fluorine is more electronegative.
15. A: Nitrous acid HNO2  may act as an oxidising
as well as reducing agent
R: The oxidation number of nitrogen remains same
in all the compounds
16. A: In a redox reaction, the oxidation number of
oxidant decreases while that of reductant increases.
R: Oxidant gains electron (s) and reductant loses
electrons (s)
17. A: The reaction
P4  3NaOH  3H 2O  3NaH 2 PO2  PH 3
is a disproportionation reaction
R: In a disproportionation reaction neither oxidation
nor reduction takes place
KEY LEVEL-IV
01) 2 02) 4 03) 1 04) 2 05) 1 06) 1
07) 2 08) 1 09) 1 10) 1 11) 3 12) 3
13) 1 14) 4 15) 3 16) 1 17) 3