&chapter

1
Average rate [Alfinal
= -
[A] initial

tifinal -
initial

2. differential rate
equation:

at +
bB -
c( + dD

3. rate

canizer.
k rate
=
inedand
law

constant

[AJ:COM. If
reactant A

[BJ COU. of
= realtanB
reaction
m order with
=
respect to realtant A
reaction.

y:order with respect to rectant B

city:overall order reaction.

U. unit
for "n" rate constant

zero order most

-

som
1storder s1 1
2x M
=

and order =mts -1

 [A]

S
1
[A],

-
=>

A. Zero order
st

①Integrated law equation:[AT[A]0 -

it ② rate h
=

[A]0 -
[AJt ht
=

Als
[A]c [A]t ht
② half
- =

life yc.
+

/ >E
B. First order

⑪ Integrated law
equation in [AJ0-in /AJt=h7 ⑧ rate a [A]
=

*
3.
in

inversycortional
=
goo.
in [A] in [A]0 -
4-

② half-life y
in
+

c. Second order.

①integrated
itsf +
law equation: =
+
h
[A70

#z cE30
=ht

② rat u[AT
=

↓
& half life
+1x

⑨ iremans
=

k[A]O
a
linearly
Arrhenius Equation
-
EalRT -4
=Al
in
inv -
(t)
-
=
A
+

-
Tin +273.1sK
Kelvin,
A
frequency
=
factor.