Pseudo Reaction

first Order

Az + Bz → Product ( one
step Rxn)

excess

Az B2

r = kÑBz ] 0 .
I tooo

↳ almost constant 0 -
I -
K 1 ooo -
k

'

k = R [ Az ]
0

( modified Rate expression First order

( Not true first order]

pseudo
such reactions are called as Pseudo First Order Reaction

P block C̲ i ̲r ̲c̲l ̲e̲

 Example Acid
hydrolysis Ester
:
catalysed of

A) C. 1-13 COOL 21-15 t H2O CH 3. COOH + Czl-15011

( Excess )

r = k [ CH 300cal-15 ] [ H2O ]

M = R
'
[ CH3C0OC2H5 ]

Pseudo First order kinetic

sucrose + 1-120 → Glucose -1 Fructose

Excess

r= b' [ sucrose]

P block C̲ i ̲r ̲c̲l ̲e̲

 Reaction
Determining order
of a

a)
using of
unit Rate constant
By
' ' '
ne
- -
-

Unit
of k : moe time

Order Ran
n
of
=
.

b)
By using differential Rate law :

[ B) Y
"
r = RCA ]

order

-1g
= a

P block C̲ i ̲r ̲c̲l ̲e̲

e)
By using
Product
conc
of Reactant and and
.

initial rate
of Ren .

AA + BB → Product

[ A] [B ] rate

/
m "
→ k (a) ( y)
'
y r
'
k =

2- 2N
y
22 2r= R ( 2k
)m(y5
3- a

2g
yr 4r= k (a) m(2iÉ
d) By Graphical Method

P block C̲ i ̲r ̲c̲l ̲e̲

 °

hate = RC A)

hate zero order Ran

[A]

e) ( th ) Reaction
By Using Half life of
a

Learn : - n is order of Rxn

1-
=
tyz ✗
-
'
Aon

P block C̲ i ̲r ̲c̲l ̲e̲

Zero Order Ran t' ✗ 1-
:
/z
'
AE

tyz ✗ Ao

s 5min

AOI
Ao Ao >

First order Ran tYz ✗ 1-

Ao

Ao °→ⁿʰ
'

At As
2 4

P block -

C̲ i ̲r ̲c̲l ̲e̲
 Second Order Rah

Ha ✗

÷ .

Aog
Ao
Aoz

f) By using conch
of Reactant at different time
Reaction
of
CONI
0¥ time 0 Co

t aco ki

Qt of co K2

P block C̲ i ̲r ̲c̲l ̲e̲

 }
3. t a Co 123

Ind order of Rkn .

For Zero Order Ran :

-

AoyAt_
R =

co-zga2coth3-co-z.cl?#
,
=
Co -

aco kz =

f-

Ki Rs
if = R2 =
,

Ren
follow Zero order

P block kinetics
C̲ i ̲r ̲c̲l ̲e̲
 Order Reaction mechanism the
of using of
reaction

Ren : Az 1- Bz → QAB

Mech :
step 1 : Az ¥ 2A fast equilibria
kb

Step 2 : B2 + A → AB + B slow

step 3 : A + B → AB fast

→ RDS the Reaction is step step 2

of slowest i e
-

P block C̲ i ̲r ̲c̲l ̲e̲

?⃝
 r = be [ Bz ] [ A ]

By step 1
keg CAI keq= kf-
using
=
,

[ Az] kb

"2 /2

4k¥ )
[ A ] =
( keg [ Az ) ) = ( A2

"
%
(
( Keq )
M=k Ba ) ( Az]
- -

/2
'
' '
k = K [ Bz ] [ Az ) Overall order = 1.5

P block C̲ i ̲r ̲c̲l ̲e̲

② Ph
-

Rxn
-

: -

ctlzctlzcl + OH Ph -
CH=CHz + Cl + 1-120

Mech :

step / : Ph -
CHZCHZCI + OH
-

¥•+Ph - % -

CHZCI + 1-120

Step 2 :
Ph %
- -

ctlz -

CI → Ph -
CH =
CHZ + Cl
-

Slow

(I RDS is step 2

a = R[ Ph -
ÉHCHZCI ] ①
P block C̲ i ̲r ̲c̲l ̲e̲
 Using step 1
, keg = RI = CPhtÉzo ]
Kb [ Phctlzctzcl ] [01-5]

[ Ph⊖CHCHzC1 ] =
Rf [
•
PHCHZCHZCI ] [ OH ]
-

Kb [ H2O ]

[ Ph CHZCI ] =
K
'
[ Phctlzctzcl ] [ OH
-

substitute value in
Eq ①

[ OH ]
'
r K [ Phctlzctlzcl ]
-
=

Overall order = 2

P block C̲ i ̲r ̲c̲l ̲e̲

 3.) Rxn :
203 →
302

7
Mech :
step 1 : 03 02 + 0
fast Equilibrium
step 2 8 03 1- 0 →
202 Slow

50-1
RDS is
step 2

k = R [ 03 ] [ 0] ①

keg =
kf_ = Coz ] [ o ]

Rb [0-3]

P block C̲ i ̲r ̲c̲l ̲e̲

 co ]
¥ ¥3? ]
=

Substitute in ①

( k¥Y÷} )
'

a = k [ ◦ 3)

'
-
t
r = K ( Oz ) ( Oz ) ( Oz)

I
[
-
2
ee = K
'
[ 03 ] Oz ]

P block C̲ i ̲r ̲c̲l ̲e̲

NOTE Rate reaction is close to
constant
of
: main
=
" "
rate the
the constant
of RDS

illustrations 8 ( tew )
µ
I to 5

/ ME A

P block C̲ i ̲r ̲c̲l ̲e̲

made
=
Ans D
-

ie = k [ NOB -02 ] [ No ]

Keg = kf_
k,

[ NO
=

Boz ]
[N0Boz)_
[ no

=
, , ,g , , ]

KI [ No ] (
]
Boz)
Kb

r = K
'
[ No ] [ Bra ] [ NO ]
≥
r = K
'
[ No ] [ 1382 ] NO : Order = 2

P block Boz : order = I

C̲ i ̲r ̲c̲l ̲e̲
✓ ]
} a = kcclz ] [ Has

P block C̲ i ̲r ̲c̲l ̲e̲

 "
'

r = k [ A) [ B)
'
r = k [ A ] [ 2 B)

21k [
'
r = A ] (B) )
'
2h

A①
r =

P block C̲ i ̲r ̲c̲l ̲e̲

 mains
→ RDS

Ee

RDS Reaction is closest to

of overall RDS

RDS is I
step

P block C̲ i ̲r ̲c̲l ̲e̲

 of Gas Reactions
¥ study phase
( First Order)

Reaction is
Progress of measured
by measuring
Pressure
of Reactant or Reaction mixture

different Reaction
at time
of
.

C.
Big)
A- → +
(g) (g)

l0J({n
Rt = 2- 303

log PI
bet = 2- 303 PV= NRT

P=
PA 1- RT
PTA Pressure time t=o
F- CJRT
of A at
=

Pd [ ]
Pa Pressure
of P block
A at time t
C̲ i ̲r ̲c̲l ̲e̲
=
 r

I) Pressure at
of Reactant

1- =
o p

1- = t Pe

30310g ÷
Rt = 2-

→
F) Pressure
of Reaction mixture Reactant & Product

°
1- = o p

t = t PT

P block C̲ i ̲r ̲c̲l ̲e̲

 I
log
Kt = 2- 303

Aeg) Big >

→ +
Cigs
t=o p°

( :X #
t=t P° -

p p p P + P=Pe
)
P= Py - p°
Rt
log
= 2- 303

p° -

p÷Tp
Rt 2- 303
109
=

, _ p°)

P block C̲ i ̲r ̲c̲l ̲e̲

?⃝
 Kt = 2.303
log P°-
¥9 2p° -

py

P block C̲ i ̲r ̲c̲l ̲e̲