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the LPtingA
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ot
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Avenge
Kinetics Chemical 6
 292
[A] Time
Rate [AJ.
=-k Slope
,
Alt versus rate ofPlot time versus [AJ of
Plot
V.
reactions: order representations
zero of Graphical
pressure. high at
+Oxg) 4NO2(g) 2N20sg) tungsten hot Decomposition
onPH3 of
’
Pt
presence
of
2H,0202H,Oy
O2g) + the oxiin
de nitrouscatalyst.
Decomposition
of Examples
i. concentration. reactant concentration. reactant
intalindependent
of is life Half initial proportional
the to islife Half
k ti/2=
2k
0.693 [AL ty=2
(ti2) period life Half
time time dm mol constant
(k) rate of
Units
i.
log10 t k= t k=
2. law Integrated
rate
2.303
[A] =k [dt] Rate=
[AJ= k =kd[A[dt] ] Rat=e
d[A] law Differential
rate
1.
reaction order First reaction order Zero
reactions: order first and Zero
equation chemical balanced Based
on equation chemical balanced based
on NOT
Integer zero fraction
or Integer
or
reactionelementary equation rate the appear
in
anin
partaking
t molecules reactant Number
of thosereactants concentration
terms
of the powersof ofSum
entity
Theoretical
property determinedExperimentally
Molecularity Order
molecularity: and order between Difference
O; ’ O +O;e.g.
involved. reactants Two
C,2NO,+ 2NO,CI
’ reaction
Biomolecular
C1NO,+ Cl’ NO,C+I
CINO,+ NO,Cl
-’ e.g, CzHsl’
+
HICzH, e.g. step. single (husin
step.multiple Occurs
in involved. reactant One
reaction
Unimolecular reactionFlementary
reaction ComplexX
Reaction Types
of
R(hemntry
(S) ANI
293
=x+y reaction
JKmorl 8.314 constant= Gas R= depends.Orofder
energy,Activation =E,
pre-exponential
factor, factor
orFrequency =A reaction ofrate the which Cntrations
on
constant, Rate k=
exponents
of determinedexperimentally are *andy
k[A}|B> reaction= the ofRate
RT
2.303 logio
-A =logiok OR
k=Aet,
/NT law: Differential
rate
3.
equation: Arrhenius 6. dt=+* formation
Dof Rate
of
k reaction
=
t2 order first For li.
0.693 c=+9 dt formation
of ofKate
2k V
[AL t12= reaction order zero For i.
dtdisappearance
=: Bof of
Rate
period: life Half 5.
time constant,
=t Rate k= t, dtdisappearance
-= Aof of
Rate
time reactants
at Concentration
of =x) -(a [AJ.=
reactants, concentration
the of Initial =a= JAlo
a-x logio dt d dt c dt b
dD) 1 =+ =+
2.303
[A] dt
[A] logio t
k=
2.303
reaction: order first For i.
reaction Instantaneous
ofrate 1.
dD: cC+ ’ bBreaction,
+
aA the For 2.
k=
At change the for taken Time
reaction: order zero For i.
A[C] species concentration
aof change
in Total Ea)=
law: Integrated
rate 4. reaction: of
rateAverage 1.
Formulae
-with logiok Variation
of
T
speeds increases increases
Slo=pe Log1ok ’ Reaction Increases decreases decreases
lRT eEa
-E,/RT E,/RT E,If
logioA Y-intercept=
k=Ae-E
/RT
representation: graphical its equation
and Arrhenius
Time Time [AJ
Time
Rate
2303 Slope= logio[AJ
-01 Slope=
Slope
k=
time versus |A|, log1o Plot
time
of versus logio|A| |A| versus rate time
Plot
of ofPlot |AofPlot
versus
reactions: order|representations
first of Graphical
netics Chemical Chapter
6:
 rod
conds? [so,] At 4[SO,] At 12 (C)
con inge
rea
aythe is t A[0,] At At (A)
2B ’ 3A (B) A[SO,]
’+C 2B [2016]
’3A 2B written
as 2SO3(g)
is ’ Og) 2S02g)+
2B’ +3A reaction rate
ofAverage 2.
M/s 0.08 (D) M/s 0.04 (C)
tion
: dt dt (B)
d[B] 12 d[A] M/s 0.02 M/s 0.01 (A)
is [2013]
r of rate the If
4. formedat is
NO, then sM
-d[O) dt
0.02 d|N,0,]= dt - If
+d[SOxg dt 2N,
(D) bromine. liquid in
Oz(g) 4NO2g)+ ’0s(g)
d[s02g)J dt d[SOg dt
reaction Consider
the 1.
2
+1 (C)
reactions Ratofe 6.2
Questions Choice Multiple
k
s|la|e8|-|3
k t(99.9%)
32.303x
100 2.303. 0.1%
k k
2-X 2.303. 1% t(99%)
2.303 100
k
log10
10 k t(90%)
2.303 2.303 10%
100
k
25
log10 k
0.602 x 25% t(75%)
2.303 100 2.303
0.125 x k 75 log1o k t(25%)
75%
2.303 100 2.303
Formula Final Substitution remaining reactant %
required Time
100-X logio k tx%)formula,
= the using
100 2.303
ratecalculated
if bereaction
can completion
of X%
required
for timereaction, order first aFor
Shortcuts
T,temperatures
. and T different two For
respectively. T; rates:reaction dependence
of Temperature 8.
at
constants rate are k,and k collisions successful fraction
of f=
2.303R logio EaRT f=
e
E, k collisions: successful fraction
of The 7.
(PSP)
Chemistry MHT-CET: