Chuỗi phản ứng lớp 11

Câu 1.
1 2 3 4 5 6
Al4C3 → CH4 → C2H2 → C2H4 → C2H5OH → C2H4 → C2H4 (OH)2
8 9 10
7 C2Ag2 → C2H2 → C2H3Cl → PVC

Câu 2.
1 2 3 4 8 9
CaC2 → C2H2 → C2H6 → C2H4 → C2H4Br2 → C2H4 → PE
6 7
5 C4H4 → C4H6 → caosu buna 10 C2H6O

Câu 3.
1 3 5 6 7
CH3COONa → CH4 → C2H2 → C2Ag2 → C2H2 → C2H4O
2↓CH3OH 4 C6H6 8↓C2H6

Câu 4. 2 C2H5Cl
1 3 8 9
C4H10 → C2H4 → C2H6O → C2H4 → MnO2
5 6 7
4↓C3H6 → C3H7OH → C3H6 → C3H6(OH)2
10↓CO2

Câu 5.

1 2 3 4
CaCO3 → CaO→ CaC2→ C2H2 → C2H2Br4
6 7
C2H4Cl2 9 5 C4H4 → C4H6 → C4H6Br2
8↓ C4H3Ag

ĐÁP ÁN
Câu1.
1. Al4C3 + 12HCl → 3CH4 + 4AlCl3
15000 C
2. 2CH4 → CH≡CH + 3H2
𝑃𝑑/𝑃𝑏𝐶𝑂3,𝑡𝑜
3. CH≡CH + H2 → CH2=CH2
𝐻+,𝑡𝑜
4. CH2=CH2 + HOH → CH3-CH2OH
H2 SO4 ,1700 C
5. CH3-CH2OH → CH2=CH2 + H2O
6. 3CH2=CH2 + 2KMnO4 + 4HOH → 3CH2OH- CH2OH + 2KOH +2MnO2
7. CH≡CH + 2AgNO3 + 2NH3 → AgC≡CAg + 2NH4NO3
8. AgC≡CAg + 2 HCl → 2 AgCl + CH≡CH

9. CH≡CH + HCl CH2 = CHCl

10. nCH2 = CHCl

Câu 2.
1. CaC2 + 2HCl → CH≡CH + CaCl2
Ni,t0
2. CH≡CH + 2H2 → CH3-CH3
xt,t0
3. CH3-CH3 → CH2=CH2 + H2
4. CH2=CH2 + Br2 →CH2Br-CH2Br
xt,t0
5. 2CH≡CH→ CH2=CH-C≡CH
𝑃𝑑/𝑃𝑏𝐶𝑂3,𝑡𝑜
6. CH2=CH-C≡CH + H2 → CH2=CH-CH=CH2
p,xt,t0
7. nCH2=CH-CH=CH2 → ( CH2-CH=CH-CH2 )n
8. CH2Br-CH2Br + Zn → ZnBr2 + CH2=CH2
𝑡𝑜,𝑝,𝑥𝑡
9. nCH2=CH2→ ( CH2-CH2 ) n
𝐻+,𝑡𝑜
10. CH2=CH2 + HOH → CH3-CH2OH
Câu 3.
CaO,t0
1. CH3COONa + NaOH → CH4 + Na2CO3
p,t0
2. CH4 + ½ O2 → CH3OH
15000 C
3. 2CH4 → CH≡CH + 3H2

6000 Cxt
4. 3CH≡CH → C6H6
5. CH≡CH + 2AgNO3 + 2NH3 → AgC≡CAg + 2NH4NO3
6. AgC≡CAg + 2 HCl → 2 AgCl + CH≡CH
7. CH≡CH + H2O → CH3-CHO
Ni,t0
8. CH≡CH + 2H2 → CH3-CH3

Câu 4.
xt,t0
1. CH3 -CH2- CH2- CH3 → CH3-CH3 + CH2=CH2
2. CH2=CH2 HCl → CH3- CH2Cl
𝐻+,𝑡𝑜
3. CH2=CH2 + HOH → CH3-CH2OH
xt,t0
4. CH3 -CH2- CH2- CH3 → CH4 + CH2=CH-CH3
𝐻+,𝑡𝑜
5. CH2=CH-CH3 + HOH → CH3-CH ( OH)-CH3
H2 SO4 ,1700 C
6. CH3-CH ( OH)-CH3 → CH2=CH-CH3 + H2O
7. 3CH2=CH-CH3 + 2KMnO4 + 4HOH → 3CH2OH- CH(OH)-CH3 + 2KOH +2MnO2
H2 SO4 1700 C
8. CH3-CH2OH → CH2=CH2 + H2O
9. 3CH2=CH2 + 2KMnO4 + 4HOH → 3CH2OH- CH2OH + 2KOH +2MnO2
t0
10. CH2=CH-CH3 + 9/2 O2 → 3CO2 + 3H2O
Câu 5.
t0
1. CaCO3 → CaO + CO2
t0
2. CaO +3 C → CaC2 + CO
3. CaC2 + 2HCl → CH≡CH + CaCl2
4. CH≡CH + 2Br2 → CHBr2-CHBr2
xt,t0
5. 2CH≡CH→ CH2=CH-C≡CH
𝑃𝑑/𝑃𝑏𝐶𝑂3,𝑡𝑜
6. CH2=CH-C≡CH + H2 → CH2=CH-CH=CH2
400 C
7. CH2=CH-CH=CH2 + Br2 → CH2Br-CH=CH-CH2Br
8. CH2=CH-C≡CH + AgNO3 + NH3 CH2=CH-C≡CAg + NH4NO3
9. CH≡CH +2 HCl → CH3 -CHCl2