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  • Lista4 FelipeMiné Termo2

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    dr.akamodo
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    This document describes calculations to determine the composition (x1 and y1) of benzene/toluene mixtures at different temperatures (T) and pressures (P). It provides Antoine equation constants to calculate vapor pressures of the pure components. Using these values and phase equilibrium calculations, it determines x1 and y1 for several given T and P conditions or vice versa. Graphs are used to visualize the vapor-liquid equilibrium.

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    Lista4_FelipeMiné_Termo2

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    This document describes calculations to determine the composition (x1 and y1) of benzene/toluene mixtures at different temperatures (T) and pressures (P). It provides Antoine equation constants to calculate vapor pressures of the pure components. Using these values and phase equilibrium calculations, it determines x1 and y1 for several given T and P conditions or vice versa. Graphs are used to visualize the vapor-liquid equilibrium.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    1 views3 pages

    Lista4 FelipeMiné Termo2

    Uploaded by

    dr.akamodo
    This document describes calculations to determine the composition (x1 and y1) of benzene/toluene mixtures at different temperatures (T) and pressures (P). It provides Antoine equation constants to calculate vapor pressures of the pure components. Using these values and phase equilibrium calculations, it determines x1 and y1 for several given T and P conditions or vice versa. Graphs are used to visualize the vapor-liquid equilibrium.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
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    of 3

    1) Mistura benzeno[1]/tolueno[2]

    a)
    Dados
    x_1 0,33
    T 100 [°C]

    Antoine A B C
    [1] 13,7819 2726,81 217,572
    [2] 13,932 3056,96 217,625

    Psat_1 180,45 [kPa]


    Psat_2 74,26 [kPa]

    P 109,30 [kPa]
    y_1 0,54

    b)
    Dados
    y_1 0,33
    T 100 [°C]

    Antoine A B C
    [1] 13,7819 2726,81 217,572
    [2] 13,932 3056,96 217,625

    Psat_1 180,45 [kPa]


    Psat_2 74,26 [kPa]

    P 92,16 [kPa]
    x_1 0,17

    c)
    Dados
    x_1 0,33
    P 120 [kPa]

    Antoine A B C
    [1] 13,7819 2726,81 217,572
    [2] 13,932 3056,96 217,625
    Tsat_1 85,60 [°C]
    Tsat_2 116,67 [°C]

    T Psat_1 Psat_2 x_1 y_1


    85,60 120,02 47,02 1,00 1,00
    90,00 136,50 54,31 0,80 0,91
    95,00 157,29 63,67 0,60 0,79
    100,00 180,45 74,26 0,43 0,65
    105,00 206,14 86,20 0,28 0,48
    110,00 234,53 99,62 0,15 0,30
    115,00 265,80 114,62 0,04 0,08
    116,67 276,91 120,00 0,00 0,00

    120,00

    115,00

    110,00

    105,00
    y = -13,796x2 - 16,736x + 116,46
    100,00

    95,00

    90,00
    y = 13,141x2 - 43,902x + 116,51

    85,00

    80,00
    0,00 0,10 0,20 0,30 0,40 0,50 0,60 0,70 0,80 0,90 1,00

    T 103,45 [°C] P_sat 197,9148 [kPa]


    y_1 0,54

    d)
    Dados
    y_1 0,33
    P 120 [kPa]

    Reutilizando o gráfico da c)
    120,00

    115,00

    110,00

    105,00
    y = -13,796x2 - 16,736x + 116,46
    y = -13,796x2 - 16,736x + 116,46
    100,00

    95,00

    90,00
    y = 13,141x2 - 43,902x + 116,51

    85,00

    80,00
    0,00 0,10 0,20 0,30 0,40 0,50 0,60 0,70 0,80 0,90 1,00

    T 109,43 [°C] P_sat 231,1815 [kPa]


    x_1 0,64

    e)
    Dados
    T 105 [°C]
    P 120 [kPa]

    Antoine A B C
    [1] 13,7819 2726,81 217,572
    [2] 13,932 3056,96 217,625

    Psat_1 206,14 [kPa]


    Psat_2 86,20 [kPa]

    x_1 0,28
    y_1 0,48

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