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  • HSC Academic Program 2022 C-19 Chap-04

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    carepathshala
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    The document contains information about several chemical equations and their associated equilibrium constants: 1) It provides the equilibrium constant expression for a general reaction of the form aA + bB ⇌ cC + dD, along with the individual concentration terms. 2) It gives the equilibrium constant expression for acid dissociation involving a generic acid HA dissociating into H3O+ and A-. 3) It provides information about the relationship between the acid dissociation constant Ka and base dissociation constant Kb and how they relate to the autoionization constant of water Kw.

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    HSC Academic Program 2022 ‖ C-19 ‖ Chap-04 ‖ রাসায়নিক পরিবর্তন

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    The document contains information about several chemical equations and their associated equilibrium constants: 1) It provides the equilibrium constant expression for a general reaction of the form aA + bB ⇌ cC + dD, along with the individual concentration terms. 2) It gives the equilibrium constant expression for acid dissociation involving a generic acid HA dissociating into H3O+ and A-. 3) It provides information about the relationship between the acid dissociation constant Ka and base dissociation constant Kb and how they relate to the autoionization constant of water Kw.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    4 views23 pages

    HSC Academic Program 2022 C-19 Chap-04

    Uploaded by

    carepathshala
    The document contains information about several chemical equations and their associated equilibrium constants: 1) It provides the equilibrium constant expression for a general reaction of the form aA + bB ⇌ cC + dD, along with the individual concentration terms. 2) It gives the equilibrium constant expression for acid dissociation involving a generic acid HA dissociating into H3O+ and A-. 3) It provides information about the relationship between the acid dissociation constant Ka and base dissociation constant Kb and how they relate to the autoionization constant of water Kw.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 23

    aA+ bB ⇌ cC+ dD

    C c [D]d 𝐏𝐂𝐜 × 𝐏𝐃𝐝


    Qc = a b Qp =
    A B 𝐏𝐀𝐚 × 𝐏𝐁𝐛

    Q K
    ❖ 𝐂𝐎𝟐 + 𝐇𝟐 = CO + 𝐇𝟐 𝐎 𝐊 𝐜 = 𝟎. 𝟏𝟑𝟕 𝐕 = 𝟐𝐋
    Ts : 5 6 1 1
    ❖ 𝐏𝐂𝐥𝟑 + 𝐂𝐥𝟐 ⇌ 𝐏𝐂𝐥𝟓 𝟐𝟑𝟎°𝐂 𝐊𝐜 𝟒𝟗 𝐏𝐂𝐥𝟑 𝐂𝐥𝟐
    𝟎. 𝟓𝟎 𝟓. 𝟎 𝐥𝐢𝐭
    𝐎𝐇 −
    𝐇+

    𝐇+
    𝐇+
    →

    ▪
    𝐇𝐀 + 𝐇𝟐 𝐎 ⇌ 𝐇𝟑 𝐎+ + 𝐀−
    এসিড ক্ষারক
    𝐇𝟑 𝐎+ [𝐀− ]
    𝐊𝐚 =
    𝐇𝐀 [𝐇𝟐 𝐎]

    𝐇𝟐 𝐎

    𝐇𝟑 𝐎+ [𝐀− ]
    ∴ 𝐊𝐚 =
    𝐇𝐀
    𝐀− + 𝐇𝟐 𝐎 ⇌ 𝐀𝐇 + 𝐎𝐇 −
    ক্ষারক এসিড
    𝐇𝐀 [𝐎𝐇 − ]
    𝐊𝐛 =
    𝐀− [𝐇𝟐 𝐎]

    𝐇𝟐 𝐎

    𝐇𝐀 [𝐎𝐇− ]
    ∴ 𝐊𝐛 =
    𝐀−
    𝐇𝟑 𝐎+ [𝐀− ] 𝐇𝐀 [𝐎𝐇 − ]
    𝐊𝐚 = 𝐊𝐛 =
    𝐇𝐀 𝐀−
    𝐊 𝐰 = 𝐇 + 𝐎𝐇 −

    At 𝟐𝟓𝟎 , 𝐊 𝐰 = 𝟏𝟎−𝟏𝟒 𝐦𝐨𝐥𝟐 𝐋−𝟐

    Temp 𝐊𝐰
    (Acid)
    (Base)
    (Summary)
    ❖ 𝐊 𝐚 = 𝟏. 𝟕 × 𝟏𝟎−𝟓 𝐦𝐨𝐥𝐝𝐦−𝟑
    𝟎. 𝟏𝐦𝐨𝐥𝐝𝐦−𝟑 𝐩𝐇
    ❖ PCl5 g ⇌ PCl3 g + Cl2 ; ∆H = +ve

    PCl5 (g) α
    25°C 1atm 80%

    Kp ।
    1 atm 0.5 atm ।

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