For calculate

𝑀𝑎 = ∑ 𝑦𝑖 𝑀𝐼 , 𝑃𝑝𝑐 = ∑ 𝑦𝑖 𝑃𝑝𝑖 , 𝑇𝑝𝑐 = ∑ 𝑦𝑖 𝑇𝑝𝑖

For Natural Gas

𝑃𝑝𝑐 = 709.604 − 58.718 𝛾𝑔
𝑇𝑝𝑐 = 170.491 − 307.344 𝛾𝑔
For Gas-Condensate
𝑃𝑝𝑐 = 706 − 51.7 𝛾𝑔 − 11.1 𝛾𝑔2
𝑇𝑝𝑐 = 187 − 330 𝛾𝑔 − 71.5 𝛾𝑔2

corrected pseudo-critical temperature and pressure for CO2

and H2S in the sour gas:
′
𝑇𝑝𝑐 = 𝑇𝑝𝑐 − 𝜀
′
′
𝑃𝑝𝑐 𝑇𝑝𝑐
𝑃𝑝𝑐 =
𝑇𝑝𝑐 + 𝐵(1 − 𝐵)𝜀
Where:
𝜀 = 120 [𝐴0.9 − 𝐴1.6 ] + 15(𝐵0.5 − 𝐵4 )
𝐵 = 𝑚𝑜𝑙𝑒 𝑓𝑟𝑎𝑐𝑡𝑖𝑜𝑛 𝑜𝑓 𝐻2𝑆 𝑖𝑛 𝑡ℎ𝑒 𝑔𝑎𝑠 𝑚𝑖𝑥𝑡𝑢𝑟𝑒
𝐴 = 𝑠𝑢𝑚 𝑜𝑓 𝑡ℎ𝑒 𝑚𝑜𝑙𝑒 𝑓𝑟𝑎𝑐𝑡𝑖𝑜𝑛 𝐻2𝑆 𝑎𝑛𝑑 𝐶𝑂2 𝑖𝑛 𝑡ℎ𝑒 𝑔𝑎𝑠
𝑚𝑖𝑥𝑡𝑢𝑟𝑒
For calculate Z-factor by:
𝑧 3 − 𝑧 2 + 𝑧(𝐴𝑚 − 𝐵𝑚 − 𝐵𝑚
2)
− 𝐴𝑚 𝐵𝑚 = 0
Where:
2
𝑃 𝑦𝑖 𝑇𝑐𝑖 𝛼𝑖0.5
𝐴𝑚 = 𝐶𝑎 2 (∑ )
𝑇 𝑃𝑐𝑖0.5
𝑃 𝑦𝑖 𝑇𝑐𝑖
𝐵𝑚 = 𝐶𝑏 ∑
𝑇 𝑃𝑐𝑖
𝐶𝑎 = 0.42749 , 𝐶𝑏 = 0.08664
2
𝛼 = (1 + 𝑠(1 − 𝑇𝑅0.5 ))
𝑠 = 0.48 + 1.574 𝜔 − 0.176 𝜔2
log 𝑃𝑐 − 1.167
𝜔 = 𝐶𝑎 𝑇𝐵 [ ]−1
𝑇𝑐 − 𝑇𝐵

To calculate Molar volume:

𝑧𝑅𝑇
𝑉𝑚 =
𝑃
To calculate formation volume factor:
0.351 𝑧 𝑇
𝐵𝑔 = (𝑃 = 𝑝𝑠𝑖𝑎 , 𝑇 = 𝐾 𝑜 )
𝑃
0.0283 𝑧 𝑇
𝐵𝑔 = (𝑃 = 𝑝𝑠𝑖𝑎 , 𝑇 = 𝑅𝑜 )
𝑃
To calculate viscosity:
∑ 𝑦𝑖 𝜇𝑔𝑖 𝑀𝑖0.5
𝜇𝑔 =
∑ 𝑦𝑖 𝑀𝑖0.5
Or
𝜇𝑔 = 𝐾 10−4 exp(𝑋 𝜌𝑔𝑌 )
Where:
(9.4 + 0.02 𝑀) 𝑇 1.5
𝐾=
209 + 19𝑀 + 𝑇
986
𝑋 = 3.5 + + 0.01 𝑀
𝑇
𝑌 = 2.4 − 0.2 𝑋
𝜇𝑔 = 𝜇𝑙 + 𝑐𝑜𝑟𝑟𝑒𝑐𝑡𝑖𝑜𝑛 𝑓𝑜𝑟 𝐻2𝑆 + 𝑐𝑜𝑟𝑟𝑒𝑐𝑡𝑖𝑜𝑛 𝑓𝑜𝑟 𝑐𝑜2
fluid flow through porous media:
𝑟
𝜇𝑔 𝑇 ln (𝑟𝑒 ) 𝑞𝑠𝑐 𝑧′
𝑤
𝑃𝑤2 = 𝑃𝑒2 −
703 × 10−6 𝑘ℎ
fluid flow through pipes:
0.5
𝑇𝑏 𝑃12 − 𝑃22
𝑞=𝑐 [ ] 𝑑 0.5
𝑃𝑏 𝛾𝑔 𝑓 𝑇 ′ 𝑧 ′ 𝐿
Where:

6 𝑜)
𝑚3
𝑐 = 1.149 × 10 𝑎𝑡 𝑝(𝑘𝑝𝑎), 𝑇(𝐾 , 𝑑 (𝑚), 𝐿(𝑚), 𝑞( )
𝑑𝑎𝑦
fraction factor:
17.96 𝛾𝑔 𝑞
𝑁𝑅𝑒 =
𝜇𝑔 𝑑
1 𝜀 21.25
= 1.14 − 2 log ( + 0.9 )
√𝑓 𝑑 𝑁𝑅𝑒
fluid flow through pipes with correlation:
𝑎3 𝑎4
𝑇𝑏 𝑎2 𝑃12 − 𝑃22 1
𝑞 = 𝑎1 𝐸 ( ) [ ′ ′ ] ( ) 𝑑 𝑎5
𝑃𝑏 𝑇 𝑧𝐿 𝛾𝑔
Equation 𝑎1 𝑎2 𝑎3 𝑎4 𝑎5
Panhandle A 435.87 1.0788 0.5394 0.4604 2.618
Panhandle B 737 1.02 0.51 0.49 2.53
IGT 337.9 1.111 0.556 0.4 2.667
Weymouth 433.5 1 0.5 0.5 2.667

looped pipe:
𝑞𝑜𝑙𝑑
𝑞𝑛𝑒𝑤 = 0.5
1
[1 + 𝑌( − 1)]
(1 + 𝜔)2
𝑑2 2.667
Where: 𝜔 = (𝑑 )
1

equivalent length:
𝑁
5.333
𝐿𝑖
𝐿𝑒 = 𝑑𝑚𝑎𝑥 ∑
𝑑𝑖5.333
𝑖=1
Hydrate:
∆𝑡ℎ 𝑀𝑤𝑖𝑛ℎ
𝜔ℎ = × 100
∆𝑡ℎ 𝑀𝑤𝑖𝑛ℎ + 𝐾ℎ
𝜔ℎ
𝑚𝑖𝑛ℎ = 𝑚𝜔 ( )
𝜔 𝐿 − 𝜔ℎ
𝐾ℎ = 2335 𝑓𝑜𝑟 𝑚𝑒𝑡ℎ𝑎𝑛𝑜𝑙 , 𝐾ℎ = 4000 𝑓𝑜𝑟 𝐸𝐺 𝑎𝑛𝑑 𝐷𝐸𝐺
Methanol EG DEG
Molecular weight 32 62 106
Specific gravity 0.8 1.11 1.12
𝑖𝑏 49.7 69.4 69.9
Density (𝑓𝑡 3 )

𝑚𝜔 = 𝑔𝑎𝑠 𝑓𝑙𝑜𝑤 𝑟𝑎𝑡𝑒 [𝑤𝑎𝑡𝑒𝑟 𝑐𝑜𝑛𝑡𝑒𝑛𝑡 𝑎𝑡 max 𝑃 𝑎𝑛𝑑 𝑇 − 𝑤𝑎𝑡𝑒𝑟 𝑐𝑜𝑛𝑡𝑒𝑛𝑡 𝑎𝑡 min 𝑃 𝑎𝑛𝑑 𝑇]

∆𝑡ℎ = ℎ𝑦𝑑𝑟𝑎𝑡𝑒 𝑡𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒 − 𝑚𝑖𝑛𝑖𝑚𝑢𝑚 𝑡𝑒𝑚𝑝𝑒𝑟𝑎𝑡𝑢𝑟𝑒 𝑖𝑛 𝑡ℎ𝑒 𝑠𝑦𝑠𝑡𝑒𝑚

DIMENSIONLESS SYMBOL DEFINITION

VARIABLES
TIME 𝑡𝐷 2.64 × 10−4 𝑘 𝑡
∅ 𝜇̅ 𝑐̅ 𝑟𝑤2
RADIUS 𝑟𝐷 𝑟
𝑟𝑤
FLOWRATE 𝑞𝐷 1422 𝑇 𝑞𝑠𝑐 𝑧 ′ 𝜇′
𝑘 ℎ 𝑃𝑖
PRESSURE 𝑃𝐷 𝑃2
𝑃𝑖2 𝑞𝐷

k = millidarcies, t = hours, 𝜇 = 𝑐𝑝 , 𝑞𝑠𝑐 = 𝑀𝑠𝑐𝑓𝑑 , P = psia, c = 𝑝𝑠𝑖 −1 , r = ft, T =

𝑅𝑜 , h = ft