PHYSICS

1. (b) Dimension of   kv 2   2k
c = [LT–1] ....(i) or − ng − n  g + 0   = h
G = [M–1L3T–2] ....(ii)   m  m

and h = [ML2T–1] ....(iii)
From equation (i),  kv02 
c3 = [L3T–3] g + 
 m  2k
And from equations (ii) & (iii), we have or n = h …(iii)
Gh = [L5T–3] g m
Gh m  k 2
\ = L2 or h= ln 1 + v
c3 2k  mg 0 
which gives L = G1/2h1/2c–3/2
Again from equation (i), When body comes down from height h, we have
length dv 2
T= m = (mg − kv )
speed dt
1/2 1/2 −3/2 dv  kv 2 
= G h c ∴ v =  g − 
c dy  m 
= G1/2h1/2c–5/2. vdv
2. (c) n1u1 = n2u2 or = dy
 kv 2 
u1  M  L 
3 g − m 
\ n2 = n1 = 8 1   2   
u2  M 2   L1  Integrating both sides of above equation, we
3
 1  5 get
= 8     = 50.
 20   1  v'
vdv
h

1. (a) The net retarding force on the body

∫ kv 2 
= ∫ dy
0 0
dv 2
g − m 
m = −(mg + kv )  
dt
dv  k 2  kv '2 
∴ = − g + v  …(i) g − 
dt  m  or – n  m  = 2kh
 g  m
dv dv
We have = v −1
dt dy  kv '2 
dv  k 2 g −  2kh
∴ v = − g + v  or n  m  = …(iv)
dy  m   g  m
vdv
or = –dy From equation (iii) and (iv), we get
 k 2
 g + v  −1
m   kv 2   kv '2 
g + 0  g − 
Integrating both sides of above equation, we get  m  m 
= 
0 h  g   g 
vdv
∫  k 2  = −∫ dy …(ii)  kv 2 
v0  g + v  0 g + 0  g
 m  or  m  =  
 2 
k  g   g − kv '0 
On substituting g + v 2 = z
m  m 
 k  v0
d  g + v2  After solving we get, v′ =
 m  dz
= kv02
dv dv 1+
mg
k dz  m
or × 2v = or vdv =   dz
m dv  2k 
Substituting these values in equation (ii), we get
0 h
m dz
2k ∫ z
= − ∫ dy
v0 0

0 −2k
or nz v = | y |0h
0 m
0
 k 2 −2k
or ln  g + m v  = h
v0 m
2. (b) Suppose x distance from D the car turns 29. (8) The velocity of the ball just before hitting
off the highway. Let v be the speed of car on the plane is u = 2 gh . Since collision is elas-
highway, then its speed on field will be v/η.
tic, so the ball will rebound with the same
The time of motion,
speed. The velocity component along the plane,
 AD − x  x2 + 2 ux = u sinα and perpendicular to it vy= u cosα.
t=  + …(i)
 v  v/η Using second equation of motion along y-axis
dt 1
t to be minimum, y = uy t – ay t2.
=0 2
dx
Let T is the time of flight then in total time T, y
dt
or = becomes zero.
dx
d  AD − x η 2 2 1/2 
+ (x +  ) 
dx  v v 
[AD is constant] 
os
uc
1 η 1 2 2 −1/2
or 0 = − + × (x +  ) × 2x
v v 2
or η2x2 = x2 + l2

∴ x= . in 
η2 − 1 us

1. (a) Velocity along the line in both side will be

same,
A B 1
∴ 0 = u cosα T – (g cosα) T2
v v 2
2u
⇒ T=
g
v′ = 2 2
V –v
Now, along the plane
2 1
so, t= AB = ux T + a T2
2 2
V –v 2 x
2
 2u  1  2u 
1/2 = u sinα   + (g sinα)  
L  g  2  g 
21. (3) Given, T = 2π  
g 4u 2 sin α
2 =
4π L g
or g=
T2
We have u= 2gh
Dg  DL DT 
\ × 100 =  +2 × 100
g  L T  4( 2 gh )2 sin α
∴ AB = = 8 h sinα.
g
 1 1
=  + 2 ×  × 100  3%
 200 90  30. (2) Take O as the origin and coordinates of
point at which stone hits the plane are (x, y).
17. (8) The velocity component along the plane v cos θ
0.3 ms –1 0.2 ms –1 a = 2 ms –2 and perpendicular to it is v sin θ. As stone hit the
A x
B plane perpendicularly, its velocity component v
cosθ becomes zero. Let t is the time in which it
4m becomes zero, then
For ball A 0 = v cos θ – g sin θ t
u1 = 0.3 ms–1, a1 = –2ms–2, s1 = x, t1 = t v cos θ v
1 which gives, t = = cot θ …(i)
∴ s1 = u1t1 + a1t12 g sin θ g
2
The vertical distance falls by stone in this time t
x = 0.3t – t2 ...(1)
For ball B
u2= 0.2 ms–1, a2 = 2ms–2, s2 = 4 – x, t2 = t
1
∴ s2 = u2t2 + a2t22
2
4 – x = 0.2 t + t2 ...(2)
From (1) and (2) t = 8 sec.
 1
h–y=0+ g t2 …(ii)
2
and x=vt …(iii)
y
Also = tan θ
x
or y = x tan θ
= v t tan θ …(iv)
Substituting values of t and y in equation (ii),
we get
1
h – v t tan θ = g t2
2
2
v  1 v 
or h – v  cot θ  tan θ = g  cot θ 
 g  2  g 
v2 v2
or h – = cot2θ
g 2g
or 2gh – 2v2 = v2 cot2θ
2 gh
or v= .
2 + cot 2 θ

25. A → p, q ; B→ r, s ; C→ r, s ; D→ r, s
(A) (p,q) The unit of GMeMs = Fr2 = Nm2
= kg m3s–2
Also volt × coulomb × metre = joule × metre
= Nm2 = kg m3 s–2
3RT 2
(B) (r,s) The unit of = vms = m2s–2.
M
Also (farad) (volt)2 (kg)–1 = (joule) kg–1
= kg × ms–1 × mkg–1 = m2s–2.
F2
(C) (r, s) F = qvΒ ⇒ v2 = 2 2 = m2s–2.
q B
2GM
(D) (r, s) ve =
R
2GM
⇒ ve2 = m 2s –2 .
=
R

33. A→q;B→r;C→p;D→q

19. A → q; B → p; C → s ; D → r
 CHEMISTRY

1
Using plastic bags should be avoided to protect the environment.

Hence option (c) is the answer.

2
BOD stands for Biochemical Oxygen Demand.

Hence option (c) is the answer.

3
The stratosphere is the layer of atmosphere between 10 km and 50 km above the sea
level.
Hence option (c) is the answer.

1. (a) (I) contains P → O bond while in (II) back 11. (10) D2O = (1+ 1 + 8) = 10
bonding takes places.
12. (17) HF HCl HBr HI
SiH3
H 3Si H 3Si pKa 3 –7 –9 –10
N Si H 3 N
SiH3 9 + 7 – 9 + 10 = 17.
SiH3
13. (32) Si10H22 is the maximum chain length that
O
silicon can achieve so x + y = 32.
P
14. (6)
O O
..
O P O P O .. N
O H2N
O O C C .NH
. 2
Pyrolysis
P NCNC(NH2)2
:N N:
O
C
N
F ||| .NH
. 2
2. (d) O = C 108º S F
F 94º 2–
F F HO OH OH OH
15. (4) Be Be Be
F F HO OH OH OH
180º O F F
ºº I I 90º approx.
O F
F
F O 16. (3) LiCl + 3H 2 O 
→ LiCl ⋅ 3H 2 O
3. (d) Lithium halide generally form trihydrate.
4. (b)
21. A - r, s; B - q, p; C - p; D - t
Orbital Radial Nodes Angular Nodes
3d 0 2
2p 0 1
3p 1 1
5d 2 2
1s 0 0

22. A - p; B - s; C - q; D - r
1. A-q, B-r, C-s, D-p 2. A-s; B-r; C-q; D-p
kZe2 kZe 2 kZe2 1
Vn , Kn , En Vn Kn , 2
K.E. of electron = me v = P.E. of electron = eV
rn 2rn 2rn 2

kn 2 2eV 2 50 e
rn (A) Velocity of electron = =
Z me me

kZe2 e 1
= 10 ms
Vn rn me
(A) 2
Kn kZe2 (B) K.E. = eV =50e J
2rn (C) me2v 2 2evme

kZe2 kZe2 1 Momentum mev = 2eVme

(B) En , rn En
2rn 2 = 2e 50 M e 10 eme

rn En 1 , Hence x 1 h h
(D) Wavelength ;
me v 10 eme
kn 2 1 Z 1
(C) rn , 2
, Z Hence, y = 1
Z rn kn rn
(D) 1s is the lowest orbital, for which l 0
Angular momentum of electron in lowest orbital
h h
= l (l 1) = 0(0 1) =0
2 2
 Chemistry Paper 1 Replace Question 23/09/2023

1
4/ 1. (d) K.E. of electron = – × Potential energy
2

1 Ze 2 1 3e 2
=–
2 r 2 r

5/2. ( a)

7/3. (d) Number of spherical or radial nodes = n – l – 1

=5–4–1=0

9 / 1 .Ans : 653 11 / 3 Ans : 4689

Extreme lines mean first and the last (convergence limit).
1 1 1 Let n1 be the energy level of He+ ion.
v= = RZ 2 – ÷
n12 n22
1 1 1 1
1 – 2 = RZ 2 – – RZ 2 – ÷
1
R 1 2 1
2
– 2÷=
15
R n12 2
n12 ( n1 + 1)2 ÷
H 2 3 36
RZ 2
1 1 1
363 =
R 112 2
– 2÷= R ( n1 + 1)2
Na + 1 2 4
363R 109677.7 22
2.7451 104 = n1 = 3
Hence H
= 4 = 653.4 ( n1 + 1)2
5R
Na + Wavelength of first line in the spectral series
36
1 1 1
= = 109677.7 2 2 – = 4689 10 –8 cm
10 / 2 Ans : 7.45 3 2
42
K.E. of photoelectron = e × stopping potential
= 4689 Å
= 1.602 × 10–19 × 300
= 4.806 × 10–17 J 12 / 4 Ans : 6.57
K.E. of photoelectron h( – c hc
0) =h – + IE = + IE
÷ (K.E.)1 = 1.8 eV = h 1 ......(i)
0 1
( 0 = Threshold frequency) hc
(K.E.)2 = 4.0 eV = h 2 + IE = + IE ......(ii)
3 108 2
4.806 × 10–17 = 6.626 × 10–34 – ÷
1500 10 –10 ÷ 1 1
From (i) and (ii), (K.E.)2 – (K.E.)1 = hc – ÷÷
= 6.626 × 10–34 ( – 2 × 1015) 2 1

4.806 10 –17
– 2 × 1015 = = 72.53 1015 1 – 2 ÷÷
6.626 10 – 34 (4 – 1.8) eV = h × 3.0 × 108
1 2
= 7.45 × 1016 Hz
3.0 108 (800 – 700 ) 10 –10
h
700 10 –10 800 10 –10
(2.2 1.6 10 –19 J) 700 10 –10 800 10 –10 m 2
h=
3.0 108 (ms 1 ) 100 10 –10 (m)
= 6.57 × 10–34 Js
 MATHS
1. 4.

2.

5.

3.

6.
7. 10.

8.
11.

12.

9.

13.
14.