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Neutron NEET Chemistry Sankalp

Chemical Bonding
PNS – 01

Assertion & Reason


(a) If both assertion and reason are true
1. Assertion: 𝐶𝐼𝐹3 molecule is not and reason is the correct explanation of
isoelectronic with 𝑆𝐹4 . assertion.
Reason: Five electron pairs present in (b) If both assertion and reason are true
𝐶𝐼𝐹3 consists of two lone pairs and three but reason is not the correct explanation
bond pairs, and its shape is T-shaped. of assertion.
(a) If both assertion and reason are true (c) If assertion is true but reason is false
and reason is the correct explanation of (d) If both assertion and reason are false.
assertion.
5. Assertion: 𝑂2 is paramagnetic.
(b) If both assertion and reason are true
but reason is not the correct explanation Reason: It has one unpaired electron
of assertion.
(c) If assertion is true but reason is false (a) If both assertion and reason are true
(d) If both assertion and reason are false. and reason is the correct explanation of
2. Assertion: The hybridization possessed assertion.
by boron atom in 𝐵𝐶𝑙3 molecule is 𝑠𝑝2 . (b) If both assertion and reason are true
Reason: 𝑠𝑝2 hybrid structures have but reason is not the correct explanation
trigonal planar geometry. of assertion.
(a) If both assertion and reason are true (c) If assertion is true but reason is false
and reason is the correct explanation of (d) If both assertion and reason are false.
assertion. 6. Assertion: Both 𝜋(2𝑝𝑥 ) and 𝜋 ∗ (2𝑝𝑥 )
(b) If both assertion and reason are true MO’s have one nodal plane each.
but reason is not the correct explanation
of assertion. Reason: All MO’s formed by side way
overlapping of 2p-orbitals have one nodal
(c) If assertion is true but reason is false
plane.
(d) If both assertion and reason are false.
3. Assertion: 𝐻2 𝑆 has greater dipole (a) If both assertion and reason are true
moment than 𝐵𝐹3 . and reason is the correct explanation of
Reason: Fluorine is less electronegative assertion.
than Sulphur. (b) If both assertion and reason are true
(a) If both assertion and reason are true but reason is not the correct explanation
and reason is the correct explanation of of assertion.
assertion. (c) If assertion is true but reason is false
(b) If both assertion and reason are true (d) If both assertion and reason are false.
but reason is not the correct explanation
of assertion. 7. Assertion: 𝐵𝑂33− and 𝑆𝑂32− are not
isostructural.
(c) If assertion is true but reason is false
(d) If both assertion and reason are false. Reason: In 𝑆𝑂32− , sulphur has one lone
pair of electrons.
4. Assertion: p-Hydroxybenzoic acid has a
higher boiling point than o- (a) If both assertion and reason are true
hydroxybenzoic acid. and reason is the correct explanation of
assertion.
Reason: p-Hydroxybenzoic acid has
(b) If both assertion and reason are true
intermolecular hydrogen bonding. but reason is not the correct explanation
of assertion.
(c) If assertion is true but reason is false

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Neutron NEET Chemistry Sankalp
Chemical Bonding
PNS – 01

(d) If both assertion and reason are false. (a) If both assertion and reason are true
and reason is the correct explanation of
8. Assertion: 𝐶𝐶𝑙4 is non-polar while 𝐶𝐻2 𝐶𝑙2
assertion.
is polar molecule.
(b) If both assertion and reason are true
Reason: Molecule with zero dipole but reason is not the correct explanation
moment is non-polar in nature. of assertion.
(c) If assertion is true but reason is false
(a) If both assertion and reason are true (d) If both assertion and reason are false.
and reason is the correct explanation of
assertion. 12. Assertion: Ionic compounds conduct
(b) If both assertion and reason are true electricity in solution as well as in molten
but reason is not the correct explanation form.
of assertion.
Reason: Ionic compounds are formed by
(c) If assertion is true but reason is false
sharing of electrons.
(d) If both assertion and reason are false.
(a) If both assertion and reason are true
9. Assertion: Shape of 𝑁𝐻3 molecule is
and reason is the correct explanation of
pyramidal.
assertion.
Reason: In 𝑁𝐻3, nitrogen is 𝑠𝑝2 (b) If both assertion and reason are true
hybridized. but reason is not the correct explanation
of assertion.
(a) If both assertion and reason are true (c) If assertion is true but reason is false
and reason is the correct explanation of (d) If both assertion and reason are false.
assertion.
(b) If both assertion and reason are true 13. Assertion: Greater the lattice enthalpy,
but reason is not the correct explanation more stable is the ionic compound.
of assertion.
Reason: The lattice enthalpy is greater
(c) If assertion is true but reason is false
for ions of higher charge and smaller
(d) If both assertion and reason are false. radii.
(a) If both assertion and reason are true
10. Assertion: 𝑆𝐹6 and 𝑃𝐹5 are examples of and reason is the correct explanation of
expanded octet molecules. assertion.
Reason: 𝑃 in 𝑃𝐹5 and 𝑆 in 𝑆𝐹6 are in 𝑠𝑝3 (b) If both assertion and reason are true
𝑑 and 𝑠𝑝3 𝑑2 hybridization respectively. but reason is not the correct explanation
of assertion.
(a) If both assertion and reason are true (c) If assertion is true but reason is false
and reason is the correct explanation of (d) If both assertion and reason are false.
assertion.
(b) If both assertion and reason are true 14. Assertion: Electron affinity refers to the
but reason is not the correct explanation attraction for an additional electron in an
of assertion. isolated gaseous atom while
(c) If assertion is true but reason is false electronegativity is the ability of an atom
(d) If both assertion and reason are false. of an element to attract shared pair of
electrons towards itself.
11. Assertion: Bond energy has order like
𝐶 − 𝐶 < 𝐶 = 𝐶 < 𝐶 ≡ 𝐶. Reason: Electron affinity is a relative
number and electronegativity is
Reason: Bond energy increases with experimentally measurable.
increase in bond order.

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Neutron NEET Chemistry Sankalp
Chemical Bonding
PNS – 01

(a) If both assertion and reason are true (c) If assertion is true but reason is false
and reason is the correct explanation of (d) If both assertion and reason are false.
assertion.
18. Assertion: All 𝐹 − 𝑆 − 𝐹 angle in 𝑆𝐹4 is
(b) If both assertion and reason are true
greater than 90° but less than 180°.
but reason is not the correct explanation
of assertion. Reason: The lone pair-bond pair
(c) If assertion is true but reason is false repulsion is weaker than bond pair-bond
(d) If both assertion and reason are false. pair repulsion.
15. Assertion: 𝐵𝐹3 molecule has zero dipole (a) If both assertion and reason are true
moment. and reason is the correct explanation of
assertion.
Reason: 𝐹 is electronegative and 𝐵 − 𝐹
(b) If both assertion and reason are true
bonds are polar in nature.
but reason is not the correct explanation
(a) If both assertion and reason are true of assertion.
and reason is the correct explanation of (c) If assertion is true but reason is false
assertion. (d) If both assertion and reason are false.
(b) If both assertion and reason are true
19. Assertion: 𝐶𝑙𝐹3 has T-shape structure.
but reason is not the correct explanation
of assertion. Reason: It has two lone pairs arranged at
(c) If assertion is true but reason is false 90° angle.
(d) If both assertion and reason are false.
(a) If both assertion and reason are true
16. Assertion: 𝐻2 𝑆 is liquid while 𝐻2 𝑂 is a and reason is the correct explanation of
gas. assertion.
(b) If both assertion and reason are true
Reason: H-bonding is present in both
but reason is not the correct explanation
the cases.
of assertion.
(a) If both assertion and reason are true (c) If assertion is true but reason is false
and reason is the correct explanation of (d) If both assertion and reason are false.
assertion.
20. Assertion: The oxygen-oxygen bonds in
(b) If both assertion and reason are true
the 𝑂3 molecule is intermediate between
but reason is not the correct explanation
a single and double bond.
of assertion.
(c) If assertion is true but reason is false Reason: Resonance averages the bond
(d) If both assertion and reason are false. characteristic.
17. Assertion: 𝐵2 molecule is paramagnetic. (a) If both assertion and reason are true
and reason is the correct explanation of
Reason: The highest occupied molecular
assertion.
orbital is of 𝜎 type.
(b) If both assertion and reason are true
(a) If both assertion and reason are true but reason is not the correct explanation
and reason is the correct explanation of of assertion.
assertion. (c) If assertion is true but reason is false
(b) If both assertion and reason are true (d) If both assertion and reason are false.
but reason is not the correct explanation
of assertion.

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Neutron NEET Chemistry Sankalp
Chemical Bonding
PNS – 01

Answer Key

S1. Ans. (b)

S2. Ans. (b)

S3. Ans. (c)

S4. Ans. (a)

S5. Ans. (c)

S6. Ans. (d)

S7. Ans. (a)

S8. Ans. (a)

S9. Ans. (c)

S10. Ans. (b)


S11. Ans. (a)

S12. Ans. (c)

S13. Ans. (b)

S14. Ans. (c)

S15. Ans. (b)

S16. Ans. (d)

S17. Ans. (c)

S18. Ans. (c)

S19. Ans. (c)

S20. Ans. (a)

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Neutron NEET Chemistry Sankalp
Chemical Bonding
PNS – 02

Statement Type
4. Statement I: In 𝐻𝑁𝑂2 molecule, all 𝑁 − 𝑂
1. Statement I: The removal of an electron bond lengths are unequal.
takes place from 𝜋𝑏𝑜𝑛𝑑𝑖𝑛𝑔 orbital when 𝑁2 Statement II: Contributions of all
converts into 𝑁2+ . resonating structures are identical.
Statement II: Bond order increases by (a) If both Statement I and Statement II
0.5 when 𝑁2 converts to 𝑁2+ . are true and Statement II is the correct
(a) If both Statement I and Statement II explanation of Statement I.
are true and Statement II is the correct (b) If both Statement I and Statement II
explanation of Statement I. are true but Statement II is not the
(b) If both Statement I and Statement II correct explanation of Statement I.
are true but Statement II is not the (c) If Statement I is true but Statement II
correct explanation of Statement I. is false
(c) If Statement I is true but Statement II (d) If both Statement I and Statement II
is false are false.
(d) If both Statement I and Statement II
are false. 5. Statement I: 𝑆2 is paramagnetic.
Statement II: It has one unpaired
2. Statement I: In TBP geometry, the electron
equatorial hybrid orbitals have 20% (a) If both Statement I and Statement II
𝑠 −character. are true and Statement II is the correct
Statement II: In TBP geometry, the axial explanation of Statement I.
orbitals also have 20% s-character. (b) If both Statement I and Statement II
(a) If both Statement I and Statement II are true but Statement II is not the
are true and Statement II is the correct correct explanation of Statement I.
explanation of Statement I. (c) If Statement I is true but Statement II
(b) If both Statement I and Statement II is false
are true but Statement II is not the (d) If both Statement I and Statement II
correct explanation of Statement I. are false.
(c) If Statement I is true but Statement II
is false 6. Statement I: In 𝐶𝑟2 𝑂72− , 𝐶𝑟 − 𝑂 − 𝐶𝑟 bond
(d) If both Statement I and Statement II angle is greater than 𝐻 − 𝑂 − 𝐻 bond
are false. angle in 𝐻2 𝑂.
Statement II: 𝐶𝑟 − 𝑂 bond length is
3. Statement I: 𝐼2 𝐶𝑙6 is planar having each larger than 𝑂 − 𝐻 bond length.
I atom with 𝑠𝑝3 𝑑2 hybridization. (a) If both Statement I and Statement II
Statement II: The number of 2𝑐 − 2𝑒 are true and Statement II is the correct
bonds is 8. explanation of Statement I.
(a) If both Statement I and Statement II (b) If both Statement I and Statement II
are true and Statement II is the correct are true but Statement II is not the
explanation of Statement I. correct explanation of Statement I.
(b) If both Statement I and Statement II (c) If Statement I is true but Statement II
are true but Statement II is not the is false
correct explanation of Statement I. (d) If both Statement I and Statement II
(c) If Statement I is true but Statement II are false.
is false
(d) If both Statement I and Statement II
are false.

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Neutron NEET Chemistry Sankalp
Chemical Bonding
PNS – 02

7. Statement I: 𝑠𝑝3 𝑑2 hybrid orbitals are at 9. Statement I: The shape of the molecule
90° to one another. depends upon hybridization of the
Statement II: There are eight 90° angles central atom.
in regular octahedral geometry. Statement II: Hybridization of the
(a) If both Statement I and Statement II central atom cannot explain the shape of
are true and Statement II is the correct the molecule.
explanation of Statement I. (a) If both Statement I and Statement II
(b) If both Statement I and Statement II are true and Statement II is the correct
are true but Statement II is not the explanation of Statement I.
correct explanation of Statement I. (b) If both Statement I and Statement II
(c) If Statement I is true but Statement II are true but Statement II is not the
is false correct explanation of Statement I.
(d) If both Statement I and Statement II (c) If Statement I is true but Statement II
are false. is false
(d) If both Statement I and Statement II
8. Statement I: When 𝐵𝐹3 and 𝐵𝐶𝑙3 are are false.
mixed together, it produces 𝐵𝐹2 𝐶𝑙 and
𝐵𝐹𝐶𝑙2 through exchange. 10. Statement I: 𝐵𝑒2 𝐶𝑙4 molecule has an
Statement II: Figure below is the incomplete octet.
intermediate for the above process Statement II: In 𝐵𝑒2 𝐶𝑙4 each be atom is
𝑠𝑝2 hybridized.
(a) If both Statement I and Statement II
are true and Statement II is the correct
explanation of Statement I.
(b) If both Statement I and Statement II
(a) If both Statement I and Statement II are true but Statement II is not the
are true and Statement II is the correct correct explanation of Statement I.
explanation of Statement I. (c) If Statement I is true but Statement II
(b) If both Statement I and Statement II is false
are true but Statement II is not the (d) If both Statement I and Statement II
correct explanation of Statement I. are false.
(c) If Statement I is true but Statement II
is false
(d) If both Statement I and Statement II
are false.

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Neutron NEET Chemistry Sankalp
Chemical Bonding
PNS – 02

Answer Key

S1. Ans. (d)

S2. Ans. (b)

S3. Ans. (b)

S4. Ans. (b)

S5. Ans. (c)

S6. Ans. (c)

S7. Ans. (c)

S8. Ans. (d)

S9. Ans. (b)

S10. Ans. (b)

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Neutron NEET Chemistry Sankalp
Chemical Bonding
PNS – 03

Match up

1. Match the bond enthalpies given in column II with the molecules given in column I and
mark the appropriate choice.
Column I (Bond enthalpies) Column II (Molecules)
(A) Hydrogen (𝐻2 ) (i) 498.0 kJ 𝑚𝑜𝑙 −1

(B) Oxygen (𝑂2 ) (ii) 946.0 kJ 𝑚𝑜𝑙 −1

(C) Nitrogen (𝑁2 ) (iii) 435.8 kJ 𝑚𝑜𝑙 −1

(a) (A) → (i), (B) → (ii), (C) → (iii)


(b) (A) → (iii), (B) → (ii), (C) → (i)
(c) (A) → (i), (B) → (iii), (C) → (ii)
(d) (A) → (iii), (B) → (i), (C) → (ii)

2. Match the molecules given in column I with their shapes given in column II and mark the
appropriate choice.
Column I Column II (Shape)
(Molecule)
(A) 𝑆𝐹6 (i)

(B) 𝑆𝑖𝐶𝑙4 (ii)

(C) 𝐴𝑠𝐹5 (iii)

(D) 𝐵𝐶𝑙3 (iv)

(a) (A) → (iv), (B) → (ii), (C) → (iii), (D) → (i)


(b) (A) → (iv), (B) → (i), (C) → (ii), (D) → (iii)
(c) (A) → (iii), (B) → (i), (C) → (ii), (D) → (iv)
(d) (A) → (ii), (B) → (iii), (C) → (i), (D) → (iv)

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Neutron NEET Chemistry Sankalp
Chemical Bonding
PNS – 03

3. Given below is the table showing shapes of some molecules having lone pairs of electrons.
Fill up the blanks left in it.
Molecule Bond pair lone pair Shape Example
𝐴𝐵2 𝐸2 2 𝑃 Bent 𝐻2 𝑂
𝐴𝐵3 𝐸2 3 2 𝑄 𝐶𝑙𝐹3
𝐴𝐵5 𝐸 5 𝑅 𝑆 𝐵𝑟𝐹5
𝐴𝐵4 𝐸2 4 2 𝑇 𝑈

P Q R S T U
(a) 2 Square 2 T-shaped Square 𝐻2 𝑂2
Planar
(b) 4 T-shaped 5 Square Square 𝑆𝑂3
Planar Pyramidal
(c) 2 T-shaped 1 Square Square 𝑋𝑒𝐹4
Pyramidal Planar
(d) 3 Square 2 T-shaped Square 𝐵𝑟𝐶𝑙3
Planar Pyramidal

4. Match the column I with column II and mark the appropriate choice.
Column I (molecule) Column II (hybridization)
(A) 𝐶2 𝐻2 (i) 𝑠𝑝3 𝑑2
(B) 𝑆𝐹6 (ii) 𝑠𝑝3 𝑑2
(C) 𝑆𝑂2 (iii) 𝑠𝑝
(D) 𝐼𝐹7 (iv) 𝑠𝑝2

(a) (A) → (i), (B) → (iii), (C) → (ii), (D) → (iv)


(b) (A) → (iii), (B) → (i), (C) → (iv), (D) → (ii)
(c) (A) → (ii), (B) → (iii), (C) → (i), (D) → (iv)
(d) (A) → (iv), (B) → (i), (C) → (iii), (D) → (ii)

5. Match List-I with List-II.

List I (molecule) List II (shape)


(A) 𝑃𝐶𝑙5 (i) Square pyramidal
(B) 𝑆𝐹6 (ii) Trigonal planar
(C) 𝐵𝑟𝐹5 (iii) Octahedral
(D) 𝐵𝐹3 (iv) Trigonal bipyramidal

Choose the correct answer from the options given below.


(a) (A) → (iv), (B) → (iii), (C) → (ii), (D) → (i)
(b) (A) → (iv), (B) → (iii), (C) → (i), (D) → (ii)
(c) (A) → (ii), (B) → (iii), (C) → (iv), (D) → (i)
(d) (A) → (iii), (B) → (i), (C) → (iv), (D) → (ii)

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Chemical Bonding
PNS – 03

6. Match the Xenon compounds in Column-I with its structure in Column-II and assign the
correct code:

Column-I (molecule) Column-II (shape)


(A) 𝑋𝑒𝐹4 (i) Pyramidal
(B) 𝑋𝑒𝐹6 (ii) Square planar
(C) 𝑋𝑒𝑂𝐹4 (iii) Distorted octahedral
(D) 𝑋𝑒𝑂3 (iv) Square pyramidal

(a) (A)-(i) (B)-(ii) (C)-(iii) (D)-(iv)


(b) (A)-(ii) (B)-(iii) (C)-(iv) (D)-(i)
(c) (A)-(ii) (B)-(iii) (C)-(i) (D)-(iv)
(d) (A)-(iii) (B)-(iv) (C)-(i) (D)-(ii)

7. Match the species in Column I with the bond order in Column II.

Column I(Molecules) Column II(Bond order)


(A) NO (i) 1.5
(B) CO (ii) 2.0
(C) 𝑂2− (iii) 2.5
(D) 𝑂2 (iv) 3.0

(a) (A)-(iii) (B)-(iv) (C)-(i) (D)-(ii)


(b) (A)-(i) (B)-(ii) (C)-(iii) (D)-(v)
(c) (A)-(v) (B)-(iv) (C)-(iii) (D)-(ii)
(d) (A)-(iv) (B)-(v) (C)-(iii) (D)-(ii)

8. Match the items given in Column I with examples given in Column II.

Column I Column II
(A) Hydrogen bond (i) C
(B) Resonance (ii) LiF
(C) Ionic solid (iii) 𝐻2
(D) Covalent solid (iv) HF
(v) 𝑂3

(a) (A)-(iii) (B)-(iv) (C)-(i) (D)-(ii)


(b) (A)-(i) (B)-(ii) (C)-(iii) (D)-(v)
(c) (A)-(v) (B)-(iv) (C)-(iii) (D)-(ii)
(d) (A)-(iv) (B)-(v) (C)-(ii) (D)-(i)

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Chemical Bonding
PNS – 03

Answer Key

S1. Ans. (d)

S2. Ans. (b)

S3. Ans. (c)

S4. Ans. (b)

S5. Ans. (b)

S6. Ans. (b)

S7. Ans. (a)

S8. Ans. (d)

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SANGHARSH General Instructions

NEET SERIES
SNS - 01
DURATION: 30 MINUTES Topic Wise Test-01

Syllabus

Subject : Chemistry

Chapter : Chemical Bonding

Topic : Classification of Bonds, Fajan’s Rule, Covalency

1
Chemistry

Q 1. Which condition favours the bond Q 7. Which one of the following show
formation: correct order of covalent character?
(a) Maximum attraction and (a) ZnO < ZnS
maximum potential energy
(b) ZnS = ZnO
(b) Minimum attraction and
minimum potential energy (c) ZnS < ZnO
(c) Minimum potential energy and (d) None
maximum attraction
(d) None of these Q 8. Lattice energy (LE) affects which of the
following factors?
Q 2. Which among the following shows the (a) Stability of ionic compound
limitation of Lewis octet rule? (b) Melting point of ionic compound
(a) CH4 (c) Boiling point of ionic compound
(b) NO
(d) All of the above
(c) CO2
(d) NH4+
Q 9. Which of the following configuration
Q 3. Ionic bond formation involves: - shows second excitation state of
(a) Elimination of protons Iodine?
(b) Sharing of electrons
(c) Overlapping of orbitals (a)
(d) Completion of octets
(b)
Q 4. As compared to covalent compounds
electrovalent compounds generally
(c)
possess: -
(a) High m.p. and high b.p.
(d)
(b) Low m.p. and low b.p.
(c) Low m.p. and high b.p.
(d) High m.p. and low b.p. Q 10. Nitrogen does not form NF5 because:
(a) Nitrogen is a member of 15th
Q 5. The correct order of lattice energy is group
given by: - (b) It contains no empty ‘d’ orbital
(a) NaF > NaCl > NaBr > NaI (c) The bond energy N  N is very
(b) NaCl > NaF > NaBr > NaI high
(c) NaBr > NaCl > NaF > NaI
(d) NaI > NaBr > NaCl > NaF (d) Nitrogen cannot react with F2

Q 6. Among LiCl, BeCl2, BCl3 and CCl4, the


covalent bond character follows the
order:
(a) LiCl < BeCl2 > BCl3 > CCl4
(b) LiCl > BeCl2 < BCl3 < CCl4
(c) LiCl < BeCl2 < BCl3 < CCl4
(d) LiCl > BeCl2 > BCl3 > CCl4
.

2
Answer Kay

S1. Ans. (c)

S2. Ans. (b)

S3. Ans. (d)

S4. Ans. (a)

S5. Ans. (a)

S6. Ans. (c)

S7. Ans. (a)

S8. Ans. (d)

S9. Ans. (c)

S10. Ans. (b)

3
––––
NEUTRON NEET

SANGHARSH General Instructions

NEET SERIES
SNS - 01
DURATION: 30 MINUTES Topic Wise Test-02

Syllabus

Subject : Chemistry

Chapter : Chemical Bonding

Topic : VBT, Hybridization, VSEPR Theory, Resonance, Formal Charge

1
Chemistry

Q 1. Which of the following is correct Q 7. Which of the following two are


according to VBT: isostructural:
(a) Co-lateral overlapping has a (a) XeF2 , IF2−
greater extent of overlap.
(b) NH3 , BF3
(b) As the value of ‘n’ increases,
bond strength decreases. (c) CO2− 2−
3 , SO3
(c) Directional orbitals have lesser (d) PCl5 , ICl5
extent of overlap.
(d) Both (a) and (b) Q 8. Hybridisation of ClO3 is:
(a) sp
Q 2. Which type of orbital take part in
(b) sp3d
overlapping (Covalent Bond
(c) sp2
formation): -
(d) sp3
(a) Fully filled orbitals
(b) Half-filled orbitals
(c) Vacant orbitals Q 9. Which of the following ions has
(d) Any orbitals resonating structures >
(a) SO2−4
Q 3. Geometry of sp3d hybridisation is: - (b) PO3− 4
(a) Linear (c) SO2−3
(b) Trigonal planar (d) All of these
(c) Square bipyramidal
(d) Trigonal bipyramidal
Q 10. One of the resonating structure of SO2−
4
Q 4. Hybridisation of SF6 is: is
(a) sp2
(b) sp3
(c) sp3d
(d) sp3d2

Q 5. The number of lone pairs and shape of


XeF4 is: Which set of formal charge on oxygen
(a) 2, Octahedral and bond order is correct?
(b) 4, Square planar (a) 0.5 and 1.5
(c) 2, Linear (b) 1.5 and 3
(d) 2, Distorted octahedral (c) 2 and 3
(d) 1.5 and 1.5
Q 6. Which of the following having a square
planar structure is:
(a) NH4+
(b) BF4−
(c) XeF4
(d) CCl4

2
Answer Kay

S1. Ans. (b)

S2. Ans. (b)

S3. Ans. (d)

S4. Ans. (d)

S5. Ans. (b)

S6. Ans. (c)

S7. Ans. (a)

S8. Ans. (d)

S9. Ans. (d)

S10. Ans. (a)

3
––––
NEUTRON NEET

SANGHARSH General Instructions

NEET SERIES
SNS - 01
DURATION: 30 MINUTES Topic Wise Test-03

Syllabus

Subject : Chemistry

Chapter : Chemical Bonding

Topic : Dipole Moment : MOT, H-Bonding

1
Chemistry

Q 1. Which of the following is a non-polar Q 7. Which of the following species will


molecule? have the minimum bond energy:
(a) CH3Cl (a) N2
(b) SO2
(b) N2−
(c) NH3
(d) SF6 (c) N2+
(d) N2−2
Q 2. The dipole moment of NH3 is:
(a) Less than dipole moment of NCl3 Q 8. H2O boils at higher temperature than
(b) Higher than dipole moment of H2S, because it is capable of forming:
NCl3 (a) Ionic bonds
(c) Equal to the dipole moment of (b) Covalent bonds
NCl3
(d) None of these (c) Hydrogen bonds
(d) Metallic bonds
Q 3. Bond order in C2+ is:
(a) 1/2 Q 9. The boiling point of p-nitrophenol is
(b) 2/3 higher than that of o-nitrophenol
(c) 3/2 because:
(d) 1 (a) NO2 group at p-position behaves
in a different way from that at o-
Q 4. On the basis of molecular orbital theory
position
which molecules does not exist:
(b) intramolecular hydrogen
(a) H2
bonding exists in p-nitrophenol
(b) He2
(c) He2+ (c) there is intermolecular hydrogen
(d) Li2 bonding in p-nitrophenol
(d) p-nitrophenol has a higher
Q 5. In which molecule last electron is filled molecular weight than o-
in 2pz: nitrophenol
(a) C2
(b) N2 Q 10. The incorrect order of decreasing
(c) B2 boiling points is:
(d) O2
(a) NH3 > AsH3 > PH3
Q 6. In which of the following set, the value (b) H2O > H2Se > H2S
of bond order will be 2.5 (c) Br2 > Cl2 > F2
(a) O+ +2 (d) CH4 > GeH4 > SiH4
2 , NO, NO , CN
(b) CN, NO+2, CN − , F2
(c) O+ +2 +2
2 , NO , O2 , CN

(d) O−2 − +
2 , O2 , O2 , O2

2
Answer Kay

S1. Ans. (d)

S2. Ans. (b)

S3. Ans. (c)

S4. Ans. (b)

S5. Ans. (b)

S6. Ans. (a)

S7. Ans. (d)

S8. Ans. (c)

S9. Ans. (c)

S10. Ans. (d)

3
––––
NEUTRON NEET

SANGHARSH General Instructions

NEET SERIES
SNS - 02

DURATION: 60 MINUTES Chapter Wise Test

Syllabus

Subject : Chemistry

Chapter : Chemical Bonding

1
Chemistry
Q1. The strength of bonds by 2s - 2s, 2p - Q7. Which statement is correct?
2p and 2p -2s overlapping has the (a) All the compounds having polar
order: - bonds, have dipole moment
(a) s – s > p – p > s – p (b) SO2 is non-polar
(b) s – s > p – s > p – p (c) H2O molecule is non polar, having
(c) p – p > s – p > s – s polar bonds
(d) p – p > s – s > p – s (d) PH3 is polar molecule having non
polar bonds
Q2. Which of the following elements can-
not exhibit sp3d hybridisation state: - Q8. PCl5 is non polar because: -
(1) C (a) P – Cl bond is non-polar
(2) P (b) Its dipole moment is zero
(3) Cl (c) P – Cl bond is polar
(4) B (d) P and Cl have equal
Correct answer is: - electronegativity
(a) 1, 3
(b) 1, 4 Q9. Which of the following has the highest
(c) 2, 3 value of dipole moment:
(d) 2, 4 (a) HCl
(b) HF
Q3. Which of the following has pyramidal (c) HI
shape? (d) HBr
(a) BF3
(b) H3O+ Q10. The molecule does not have zero
(c) NO+ dipole moment: -
3
(a) CO2
(d) CO2−
3 (b) CCl4
Q4. Amongst CO2− 3− − (c) BF3
3 , AsO3 , eeO3, ClO3 ,
3− 2− (d) HCl
BO3 and SO3 the non-planar
species are: - Q11. The ion that is isoelectronic with CO
(a) eeO3, ClO− 2− 3−
3 , SO3 , AsO3 and having same bond order is:
3− 2−
(b) AsO3 , eeO3, CO3 (a) CN −
(c) BO3− 2−
3 , CO3 , SO3
2−
(b) O+
2
(d) AsO3− 3−
3 , BO3 , CO3
2−
(c) O−
2
(d) N2+
Q5. When p-character of hybridised orbital
(formed by s and p orbitals) increases. Q12. Which of the following is
Then the bond angle paramagnetic:
(a) Decreases (a) O−
2
(b) Increases (b) CN −
(c) Becomes twice (c) CO
(d) Remains unaltered (d) NO+
Q6. The hybridization states of the central Q13. Which of the following ion do not have
atoms of the ions I3− , ICl− −
4 and ICl2 are bond order of 2.5?
respectively: (a) O−
2
(a) sp2, sp3d, sp3 (b) O+
2
(b) sp3d, sp3d2 and sp3d
(c) sp3d, sp3d, sp (c) N2+
(d) sp, sp, sp2 (d) N2−

2
Q14. The minimum bond length will be Q17. Strongest hydrogen bond is shown by:
observed in: - (a) Water
(a) O2 (b) Ammonia
(b) O−
2
(c) Hydrogen fluoride
(c) O+ (d) Hydrogen sulphide
2
(d) O2−
2 Q18. Which of the following does not show
electrical conduction?
Q15. Which is correct electronic
(a) diamond
configuration for singly positive
(b) graphite
nitrogen molecule:
(c) sodium chloride (fused)
(a) 1s2 *1s2 2s2 *2s2 2px2
(d) potassium
2py2 2pz1
(b) 1s2 *1s2 2s2 *2s2 2px2 Q19. The most covalent halide is
2px2 *2pz1 (a) AlF3
(c) 1s2 *1s2 2s2 *2s2 2pz2 (b) AlCl3
2px2 2py2 (c) AlBr3
(d) 1s2 *1s2 2s2 *2s2 2pz2 (d) All3
2px1 2pz1
Q20. Correct order of covalent character of
Q16. The bonds present in N2O5 are: alkaline earth metal chloride is
(a) Only ionic (a) BeCl2 < MgCl2 < CaCl2 < SrCl2
(b) Covalent & coordinate (b) BeCl2 < CaCl2 < SrCl2 < MgCl2
(c) Only covalent (c) BeCl2 < MgCl2 < CaCl2 < SrCl2
(d) Covalent & ionic (d) SrCl2 > BeCl2 > CaCl2 > MgCl2

3
Answer Key

S1. Ans. (c)

S2. Ans. (b)

S3. Ans. (b)

S4. Ans. (a)

S5. Ans. (a)

S6. Ans. (b)

S7. Ans. (d)

S8. Ans. (b)

S9. Ans. (b)

S10. Ans. (d)

S11. Ans. (a)

S12. Ans. (a)

S13. Ans. (a)

S14. Ans. (c)

S15. Ans. (a)

S16. Ans. (b)

S17. Ans. (c)

S18. Ans. (a)

S19. Ans. (d)

S20. Ans. (c)

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