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1 GENERAL CHEMISTRY

1. What examples can you find that describe 5. Which statement supports Dipole-Dipole
phases and changes of the kinetic molecular interactions?
theory?
a. Dipole-dipole forces exist between molecules
a. Leaving ice cubes to melt under room that are non-polar - those that have a permanent
temperature dipole moment due to uneven sharing of
b. Boiling of water in hot and closed metal pot electrons.
c. Either A or B b. Substances with dipole-dipole attractions tend
d. Neither A nor B to have lower melting and boiling points
compared to nonpolar molecules.
2. How would you represent the properties of c. Either A or B
liquids and solids? d. Neither A nor B

a. Liquids assumes the shape of the part of the 6. This represents the attraction between
container which it occupies while solids retains molecules that form due to a temporary dipole
a fixed volume and shape. on one molecule inducing a temporary dipole
b. Liquids takes the shape of the filled portion of in neighboring molecules.
its container.
c. Either A or B a. Dipole-Dipole
d. Neither A Nor B b. Ion-Dipole
c. London Dispersion Force
3. How would you explain the movement of gas d. Hydrogen bonding
molecules?
7. How would you differentiate Ion-Dipole
a. In gases the particles move rapidly in one from Hydrogen bonding?
direction, colliding with each other and to the
walls of the container. a. Ion-Dipole is the force between two acetone
b. In gases the particles move rapidly in all molecules while Hydrogen bonding is the force
directions, frequently colliding with each other between two hexane molecules.
and the side of the container b. Ion-Dipole is the force between sodium ion
c. In gases the particles move in a single direction, and water while Hydrogen bonding is the
less likely to collide on the walls of the container H-bonding between ethanol and water; H-
but collide with each other. bonding between two water molecules
d. In gases the particles move slowly in all c. Either A or B
directions, frequently colliding with each other d. Neither A nor B
and the side of the container.
8. How would differentiate Dipole-Dipole from
4. This refers to the type of bonding in which Hydrogen bonding?
hydrogen atom is covalently bonded to
nitrogen, oxygen or fluorine and a very strong a. Dipole-Dipole is the attraction two polar
dipole is formed. molecules while Hydrogen bonsing interaction
involving a hydrogen atom located between a
a. Dipole-Dipole pair of other atoms having a high affinity
b. Hydrogen Bonding for electrons.
c. Covalent Bonding b. Dipole-Dipole is the attraction between an ion
d. London Dispersion Forces and a polar molecule while Hydrogen bonding
is the attraction between two molecules.
2 GENERAL CHEMISTRY
c. Either A or B a. The stronger the intermolecular forces, the
d. Neither A nor B stronger the vapor pressure.
b. Temperature at which the vapor pressure of a
9. How would you describe surface tension at a solid is equal to external pressure.
molecular level? c. Either A or B
d. Neither A nor B
a. It is the property of the surface of a gas that
allows it to resist an external force, due to the 13. How does the structure of water contribute
cohesive nature of its molecules. to its unique properties?
b. It is the energy, or work, required to
increase the surface area of a liquid due to a. Water is a polar molecule, it can be form
intermolecular forces multiple hydrogen bonds which account for
c. Either A or B many of water’s special properties.
d. Neither A nor B b. Water molecules are polar, do not have partial
positive charges on the hydrogen but have a
10. What would happen if you continuously stir partial negative charge on the oxygen, and a bent
a glass of oil? overall structure.
c. Either A or B
a. As the mier speed increases, flow increases d. Neither A or B
proportionately.
b. Pseudoplastic Liquids viscosity decreases as 14. What is the effect of intermolecular forces
shear rate increases, but initial viscosity may be in the properties of substances?
sufficiently great to prevent mixing.
c. Either A or B a. Chemical properties are affected by the
d. Neither A nor B strength of intermolecular forces.
b. Melting, boiling, and freezing increase as
11. How can you change the viscosity of a intermolecular forces increase.
liquid? c. Either A or B
d. Neither A nor B
a. The viscosity of liquids decreases rapidly
with an increase in temperature and the 15. Do high melting points indicate weak
viscosity of gases increases with an increase in intermolecular forces?
temperature. Thus, upon heating, liquids flow
more easily, where gases flow more sluggishly. a. When intermolecular forces occur between
b. The viscosity of liquids increases rapidly with molecules, they typically help to increase the
an decreases in temperature, and the viscosity strength of attraction between these molecules
of gases increases with an increase in b. Higher melting points are indicative of weaker
temperature. Thus, upon heating, liquids flow intermolecular forces rather than weak
more intermolecular forces.
easily, whereas gases flow more sluggishly. c. Either A or B
c. Either A or B d. Neither A nor B
d. Neither A nor B
16. How would you differentiate crystalline
12. What happens to intermolecular forces as from amorphous solids?
vapor pressure increases?
3 GENERAL CHEMISTRY
a. A crystalline solid has long range of ordered
molecules. In contrast, an amorphous 22. How would you describe the heating curve
compound of a substance?
has a short range of ordered molecules. A. A heating curve of a substance shows the
b. A crystalline solid has a sharp melting point. In relationship of temperature, state of matter,
contrast, an amorphous has an irregular and heat.
arrangement of its atoms.
c. Either A or B 23. Which quantity is not determined from a
d. Neither A nor B heating or cooling curve for a substance?
B. A heating curve demonstrates the energy
17. Select the best definition for crystalline changes and temperatures required to change
solids. a substance from one phase to another.

a. Have well-defined edges and faces. 24. How do you determine the freezing point of
b. It diffract x-rays. a cooling curve?
c. It tends to have sharp melting points.
d. All of the above A. Slope of the cooling curve is determined and
plotted as a function of time to identify the end
18. It possess a regularly ordered array of point of freezing.
particles that are held together with the help of B. Slope is decreased and then reached a
uniform intermolecular forces. minimum value, which is identified as the
nucleation of ice.
a. Aqueous solution C. Either A or B.
b. Crystalline solid D. Neither A or B
c. Amorphous Solid
d. None of the above 25. What would be the percent copper in
chalcocite (Cu2S)?
19. How will you interpret the phase diagram of
water and carbon dioxide? A. 79.84% Cu
B. 80.12% Cu
a. CO2 has positive slope of the solid/liquid line C. 81.25% Cu
while H2O has the negative solid/liquid line. D. 82. 36% Cu
b. It can be observed that the entire liquid phase
lies above atmospheric pressure. 26. A solution is prepared from 17.0 g of NaCI
c. Either A or B dissolved in sufficient water to give 150.0 ml of
d. Neither A or B solution. What is the molarity of the solution?
20. Why doesn’t CO2 have a normal melting (The molar mass of NaCI is 58.44 g/mol)
point and a normal boiling point, whereas A. 1.95 M
water does? B. 1.94 M
A. The slopes of the solid-liquid lines in the C. 1.93 M
phase diagram of H2O and CO2 are different. D. 1.92 M

21. How will you describe the difference 27. A solution of copper(II) acetate, Cu
between the phase diagram of H20 and CO2? (CH3CO2)2, is used as a green dye for textiles.
A. The phase diagram of water shows a We want to prepare a 0.150 M solution of
negative slope for the boundary line between copper(II) acetate, starting with 40.0 g of Cu
the liquid and solid state. (CH3CO2)2, What should be the total volume of
4 GENERAL CHEMISTRY
the solution?(The molar mass of Cu a. Since some of the solute molecules will take up
(CH3CO2)2 is 181.6 g/mol) spaces at the surface of a liquid, this will limit
the number of solvent molecules at the surface.
a. 4.35 L solution b. Since only solvent molecules located at the
b. 3.28 L solution surface can escape (evaporate), the sheer
c. 2.91 L solution presence
d. 1.47 L solution of the solute lowers the number of solvent
molecules coming and going and therefore lowers
27. 11. 1.14 mol of CO2 was formed by the the equilibrium vapor pressure.
combustion of C3H8, how many moles of H2-0 c. Either A or B.
were also formed? C3H8(g) + 502(g) → 3C02(g) d. Neither A or B.
+ 4H20(g)
31. How does adding salt affect the vapor
a. 1.34 mol H2-O pressure?
b. 1.52 mol H2-O
c. 1.76 mol H2-O a. When salt is added to water, the number of
d. 1.89 mol H2-O water molecules near the surface increases, and
this results in the increase of the vapour pressure.
28. When liquid bromine is mixed with b. When salt is added to the water, the number
aluminium metal, a combination of reaction of water molecules near the surface
occurs, forming aluminium bromide: 2A(s) + increases, and this results in the increase of the
3Br2(l) —> 2AlBr3(s). What will be the limiting vapour pressure.
reactant and mass of AlBr3 produced when
45.0g Br2 is added to 30.0g of Al. 37. This causes a solution to boil at a higher
a. 43.7g AlBr3 temperature than the boiling point of the pure
b. 45.6g AlBr3 solvent due to the addition of solutes.
c. 48.1g AlBr3
d. 50.0g AlBr3 a. Freezing Point Depression
b. Boiling Point Elevation
29. Ethylene C2H4 undergoes many useful c. Freezing Point Elevation
reactions. However, since it’s a hydro-carbon. It d. Boiling Point Depression
is flammable and burns in the presence of oxygen
according to the equation: C2H4(g) + 302(g) 38. What is the concentration of ethylene glycol
(rectangle symbol) 2CO2 (g) + 2H2O (g). in a solution of water, in molality, if the freezing
Suppose we mix 0.25 mol C2H4 with 1.0 mol point dropped by 2.64oC? The freezing point
02. What will be its limiting reactant and the constant kf, for water, is 1.86 C/m.
number of moles of CO2 that can be formed? a. 1.53
b. 1.42
a. 0.69 mol O2 c. 1.68
b. 0.28 mol O2 d. 1.97
c. 0.34 mol O2
d. 0.75 mol O2 39. A solution of 10.0g of sodium chloride is
added to 100.0g of water in an attempt to elevate
30. What happens to the system if we add a the boiling point. What is the boiling point of the
solute to the solvent? solution? Kb for water is 0.52oC/m
a. 2.64oC
b. 1.78oC
5 GENERAL CHEMISTRY
c. 3.59oC 43. What will be the freezing point depression
d. 0.32oC and the freezing point after adding 100.0 g of
table salt to 400.0 g of water. (Kf of Water =
40. What is the molecular mass of a non- 1.86)
ionizing, non-volatile solute if 0.546g of it are a. 21.4oC
dissolved in 15.0g of benzene (Kf=5.12°C/. F.P= b. 12.3o
5.5°C) and the freezing point depression was c. -13.9oC
0.240°C? d. -15.9oC
a. 375 g/mol
b. 892 g/mol 44. This refers to a measure of the
c. 314 g/mol concentration of a substance in a solution.
d. 776 g/mol
a. Percent by Mass
41. 38.7g of a nonelectrolyte is dissolved into b. Percent by Volume
218g of water. The freezing point of the solution c. Percent by Solution
is measured to be -5.53°C. What is the molar d. Molarity
mass of the solute?
a. 21.6 g/mol 44. This is used as a way of expressing a
b. 41.9 g/mol concentration or a way of describing a
c. 59.7 g/mol component in a mixture.
d. 33.1 g/mol
a. Percent by mass
42. The freezing point of cyclohexane is 6.50 °C. b. Percent by volume
A solution is prepared by dissolving 0.5580g of c. Percent by solution
an unknown solute in 33.50g cyclohexane. The d. Molarity
freezing point of the solution is 4.32 °C. What
will be the molar mass of the unknown solute? Kf 45. This refers to the amount of a substance in a
for cyclohexane is 20.0°C kg/mole. certain volume of a solution. It is defined as the
a. 153 g/mole moles of a solute per litres of a solution.
b. 418 g/mole
c. 391 g/mole a. Percent by Mass
d. 358 g/mole b. Percent Volume
c. Percent by Solution
d. Molarity

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