[AIPMT 1994; PMT (Raj.

)
1. Which one of the following is nost:
soluble ?
(b) MnS(Ksp =7x 10-16) 20001
(a) CuS(K =8x l0-3)
(c) Bi,S,(Km =lx 10-70) (d) Ag S(Ksp =6x 10-51)
2. Boron halides behave as Lewis acids,
because of their: TAIPMT 1996; BHU20041
(b) acidic nature
(a) ionic nature
(d) electron deficient nature
(c) covalent nature
3. A buffer solution contains0.1 M of acetic acid and 0.1M of sodium
acetate. What will be ite mty
if pK, ofof aceticacid is 4.75? [MPPMT 1996; DPMT 20011
(a) 4.00 (b) 4.75 (c) 5.00 (d) 5.25
4. Acertain buffer solution contains equal concentration of X and HX. The K, for X is10-10
The pH of the buffer is : [CPMT 1996; PMT (Raj.) 1997; DPMT 20041
(a) 4 (b) 7 (c) 10 (d) 14
5. pH value of N/10 NaOH solution is: TAIPMT 1996; Punjab PMT 20021
(a) 10 (b) 11 (c) 12 (d) 13
6. According to Bronsted-Lowryconcept, base is a substance which is:
[PMT (Raj.) 1997;AFMC 19991
(a) a proton donor (b) an electron pair acceptor
(c) aproton acceptor (d) an electron pair donor
7. Which of the following is Lewis acid? [AFMC 1997; PMT (Raj.) 1999]
(a) BF (b) CI (c) H,0 () NHg
8. The suitable indicator for strong acid and weak base is:
[PMT (Raj.) 1997, 2005]
(a) methyl orange (b) methyl red
(c) phenol red
(d) phenolphthalein
9. IfKsp for HgSO, is 6.4 x 10, then solubility of the
salt is: [AFMC1997; CPMT 2000]
(a) 8 x 10-3
(c) 6.4 x 10-5 (b) 8 x 10-6
(d) 6.4 x10-3
10. If oa is the degree of
ionization, Cthe concentration of a weak electrolyte and Ka
ionization constant, then the correct relationship the acu
between a.,Cand K, is:
(a) a= C
Punjab PMT1998; PMT (Raj.) 2002]
(b) a2 C
(c) a =
Ka (d) a =
11. Why are strong acids
generally used as standard solutions in acid-base 1Ka
titrations?
(a) The pH at the equivalence point [Punjab PMT 1998]
(b) They can be used to titrate will always be 7
(c) Strong acids form more stableboth strong and weak bases
(d) The salts of strong acids do notsolutions than weak acids
hydrolysed
 reaction in aqueous solution Zn 2+
12
For the +XZnX+ the Kea is greatest when X is :
[Punjab PMT 1998]
(a)
F (b) NO, (c) ClO 4 (d) I
Awhitesalt is readily soluble in water and gives a colourless solution withapH of about 9. The
saltwouldbe:
[Punjab PMT 1998]
(a)NH,No, (b) CH;COONa (c) CH,COONH 4 (d) CaCO3
of BaSO4 in water
The solubility
is 2.33 x 10-3 g/litre. Its solubility product will
BaSO, =233)
14
(Molecular mass of
he: 1x10-5 [AIIMS 1998]
(a) (b) 1x 10 -10 (c) lx 10-15 (d) 1x10-20
ThepHvalue of decinormal solution of NH,OH which is 20% ionised, is: [AIPMT 1998]
15.(a)13.30 (b) 14.70 (c) 12.30 (d) 12.95

16. At
infinite dilution, the percentage ionisation for both strong and weak electrolytes is:
[CPMT 1999]
(a)1% (b) 20% (c) 50% (d) 100%
of dissociation of0.1M HCN solution is 0.019%. Its ionisation constant would be
17. The degree [PMT (Raj.) 1999]
(a)10-3 (b)10-5 (c) 10-7 (d) 10-9
solution, the characteristic species of acid is : [PMT (Raj.) 1999]
18. For an aqueous (b) H,0* ion (c) H; ion (d) H,0* ion
(a) H" ion
of ammonium hydroxide:
19, On addition of ammonium chloride to a solution [MPPMT 1999; CPMT 1999]
(a) dissociation of NH OH increases
(b)concentration of OH increases
(C) concentration of OH decreases
increases
(d) concentration of NH and OH
25° Cis 1.0 x 10. What would be the concentration of
BaSO,4 at
4 Ihe solubility product of ions ?
precipitate BaSO fron a solution of 0.01 M Ba
g004 necessary to [PMT (Raj.) 1999]
(c) 10-7 (d) 10-6
(a) 10-9 (b)10-8 PMT 2001]
[MPPMT 1999; Punjab
21. Which pair will show Common ion effect ? (b)NaCl + HCI
(a) BaCl, +Ba(NO 3) 2 (d) AgCN +
KCN
soluble binary
(0) NH,OH +NH,CI solubility product of a sparingly
[MPPMT 1999]
If s and solubility and
Ksp are respectively 1
(d) s=Ksp
electrolyte, then: (c) s=Kap 2
[PMT (Raj.)1999]
(a) s=Kp (b) s= K be:
weak base would
weak acid and
K (d) None of these
HydrolysiKws constant for a salt of
Kw. (c) KA K.K
=

of NaCI ?
(a) Kh =
(b) Kh solution
Ka is passed in a saturated [PMT (Raj.)19991
HCI gas
Pure NaCl is precipitated when
(a) dissolves in HCI
 value of [Naland [CI1 becomes smaller than Ksn of NaCI
(b) The
value of [Naland [CI ] becomes greater than Ksp Of NaCl
(c) The
(d) HCI dissolves in the water
reaction: H,S 2H +S, when NH,OH is added, then:
25. In the (Med.)
[Karnataka CET 1999; AFMC
(a) s is precipitate decreases
(c) concentration of S
(b) no action takes places
(d) concentration of s
increases
mo/t :
20 01
concentration is 6.2 x 10-
26. pH value of asolution, whose hydroniunm ion
[AFMC 1999;
(d) 8.21 AIIMS
2
(a) 6.21 (b) 7.21 (c) 7.75
N
2000]
27. pH values of HCl and NaOH solutions each of
strength
100
will be respectively:

(a) 2 and 2 (b) 2 and 12 (c) 12 and 2 [MPPMT 19991

(d) 2 and 10
28. Solubility of asalt M,X, is ymol dm, The solubility product of the salt will be:
[PMT (Raj.) 1999; MPPMT 20031
5
(a) 6y4 (b) 64y4 (c) 36y (d) 108 y5
29. pHof asolution can be expressed as: [CPMT 19991
(a) -log [H"] (b) -log1o[H] (c) log [H*] (d) log1o [H*]
30. Amongst the following solutions, the buffer solution is: [MPPMT 1999]
(a) NH,Cl + NH,0H solution (b) NH,Cl + NaOH solution
(c) NH,OH + HCl solution (d) NaOH + HCl solution
31. The concentration of[H"] andconcentration of [OH ] of a 0.1
aqueous solution of 2%ionised
weak acid is: (Ionic product of water = 1x 10-4) [AIPMT 1999; DPMT 2004]
(a) 2 x 10- M and 5 x 10 -12 M (b) 1× 10°M and3 x 10 -11 M
(c) 0.02x 10 Mand 5x 10-11 M (d) 3x10- M and 4 x 10-$M
32. The pH of 10 molar aqueous solution of HCl is: [MPPMT 2000]
(a) -8
(c) between 6 and 7 (b) 8
33. The hydrogen ion (d) between 7 and 8
concentration in weak acid of
isnearly equalto: dissociation constant K, and concentra
(a) K/C [PMT (Raj.) 2000]
(b) C/K, (c) K,C
34. Review the
equilibrium
(d) K,C
and choose Statement
HCIO4 + H,0 H,0* +Clo; the Correct
[PMT (Raj.) 2000]
(a) HCIO4 is the
conjugate acid of
(c) H,0 is the conjugate acid of H,0 (b) H,0* is the conjugate base of H,0
H,0+ (a) CIO 4 is the conjugate base of HCIO4
35. The conjugate acid of NH, is :
[AIPMT 2000]
(a) NH, (b) NH;
36. Which of the following (c) NH,OH (d) NH4
(a) H,POs compounds are
(b) H,s diprotic ? Punjab PMT 2000!
(c) HCIO3 (d) H,PO3
 for acid Ais greater than pK, for acid B.The strong acid is:
pk,
[DPMT 2000]
The (b) A (c) both Aand B (d) neither A nor B
(a)B
strongestacidis:
The.
[DPMT 2000]
(a)H,As04
S8. (b) H,AsO (c) H,PO3 (d) H,P04
organic dve, cosine used to detect end point of precipitation titration by adsorption 1S
An
called: [Karnataka CET (Med.) 2000]
(a)absorptionindicator (b) adsorption indicator
ic) chemical indicator (d) none of these
order of acid strength is: [AIIMS 2000; AIPMT 2005, 07;
correct PMT (Raj.) 2006]
0. TheHCIO< HHCIO, <HCIO, < HCIO, (b) HCI04 <HCl0 < HCIO, <HCIo:
(a)
<HCIO, <HCIO4 <HCIO () HCI04< HCIO, <HCIO, < HCIO
(c) HCIO, ’ BCl_: PH3. The Lewis acid is:
process BCl, +PH: [PMT (Raj.) 2000]
1.Inthe (b) BCl3 (c) both (d) none
(a)PH,
Thesolvent which neither accepts proton nor donates proton is called: [PMT(Raj.) 2000]
2. (a) amphoteric (b) neutral (c) aprotic (d) amphiprotic
sparingly soluble salt MX, at 25° Cis l.0x 10-1,the solubility
Ifthe solubility product Ksp of a
litre -1 at this temperature will be: [PMT (Raj.) 2000]
ofthesalt in mol (d) 1.20x 10-10
1014 (b) 1.36 x 10-4 (©) 2.60 x 10-7
(a) 2.46 x
SnS , is: [PMT (Raj.) 2000]
4 The correct representation for solubility product(c)of [Sn2 J[2s1 (d) [Sn*] [2s12
(a) (Sn*J[S12 (b) (Sn 2 J[S12
due to: [PMT (Raj.) 2000]
45. The aqueous solution of FeCI, is acidic (c) hydrolysis (d) dissociation
(a) acidic impurities (b) ionisation required to precipitate BaSO in a solution
46. What is the minimum concentration of SO
4 x 10 ) [MPPMT 2000]
containing 1.0x 10 mole Ba ? (K.
sp
for BaSO, is
M
(d) 2 x 10-
-10
(b) 2x 10- M (c) 4 x 10- M
(a) 4x 10 M
[H,0]concentration equal to 1x 10 ° mol/litre. The value of K,
ht80° C, distilled water has 2001; AlIMS 2002]
[PMT (Raj.) 2000; AFMC(d) 1x10-15
at this temperature will be: (c) 1×10-12
(a) 1x 10-6 (b) 1x 10-9 [PMT (Raj.) 2000]
8. Baking soda is: (c) complex salt (d) double salt
(a) basic salt (b) acidic salt
. What should be the [salt] to [acid)
49. The acid is 10 ?
ionizationConstant of a certain weakpH=5 using this acid and one of the salts
ratio if we have to prepare a buffer with [CPMT 2000]
(d) 4:5
(c) 5:4 105
(a) 1:10 (b) 10:1 are 3.14 x 10* and 1.96 x
S, The dissociation constant of two acids
HA,
HA, and
approximately:[PMT (Raj.) 2000]
acids will be
Tes(a) 1:4pectively. The relative strength of the
(c) 1:16
0.02
(d) 16:1
M in NaCN? (K. for
(b) 4:1 and
S, 0.01 M in HCN [MPPMT 2000]
WhICNat =6.2x
is H] of
10°)
a solution that is
10-10 (d) 3.1x 10
-10
(a) 3.1x1010 (c) 6.2x
(b) 6.2x10
 52. Abase dissolved, in water, yields a solution with a hydroxyl ion Concentration of 0.05
mol litre-. The solution is:
(b) acid (c) neutral [AIPMT 20001
(d) either (b) or (c)
(a) basic pro
of AgClat 20° C is g/L. The solubility product
1.435 x 10-g/L. of AgCl is:
53. Solubility
[AFMC 2000; AIPMT
(a) lx 10-5 (b)1x 10-10 (c) 1.435 x 10
5
(d) 108 × 10-3 20021
pk, + log
[salt) Ifthe acid gets half neutralized, the value of pH
54. Henderson's equation is pH = [acid]
will be:[pK, =4.30] [PMT (Raj.) 2000]
(d) 7
(b) 2.15 (c) 8.60
(a) 4.3
on dissolVing in distilled water will ot
55. How many grams of CaC,04 (molecular mass=128) L]
10 mol [MPPMT 2000]
a saturated solution?[K,(CaC,04)=2.5 x
(a) 0.0064g (b) 0.1280g (c) 0.0128g (d) 1.2800 g
constant K and
56. For every diprotic acid of the type H,X, how would yOu relate ionisation
Ka? [AIPMT 20001
(b) Ka < Kay (c) Ka, < Ka (d) Insufficient data
(a) Ka =Kaz
57. Which of the following solutions will be strongly acidic ? [CPMT 2000]
(a) When pH =0.0 (b) When pOH =4.5
(c) When pOH=14 (d) Both (a) and (c)
58. Which of the following is non-electrolyte ? [CPMT 2001]
(a) NaCl (b) CaCl, (c) CiH22011 (d) CH,COOH
59. NaOH is a strong base because: [AIIMS 2001]
(a) it gives OH ion (b) it can be oxidised
(c) it can be easily ionised (d) both (a) and (c)
60. Which of the following is the strongest conjugate base ?
[Karnataka CET (Med.) 2001;DUMET 2009]
(a) C1 (b) CH,CO0 (c) SO (d) NO,
61. Which of the following is a conjugated acid-base pair ? [DPMT 2001]
(a) HCI, NaOH (b) NH,Cl, NH,OH
(c) H,SO4,HSO4 (d) KCN, HCN
62. The aqueous solution of which one of the following is basic ? [MPPMT 2001]
(a) HOCI (b) NaHSO 4 (c) NH4NO3 (d) NaOCI
63. An aqueous solution of aluminium sulphate shows: [DPMT 2001]
(a) a basic nature (b) an acidic nature
(C) a neutral nature
(d) both acidic and basic nature
64. The most acidic compound in water is: [AIPMT 2001]
(a) AlCIa (b) BeCl2 (c) FeCl, (d) None of these
65. Which halide of nitrogen is least basic ? [DPMT 2001]
(a) NBr3 (b) NI, (c) NCl3
66. The indicator used in the titration of sodium carbonate with (d) NF3
(a) phenolphthalein sulphuric acid is: [DPMT 20o
(b) methyl orange
(c) potassium ferrocyanide (d) potassium ferricyanide
 pHof10-7 MNaOH is:
The
(a)7.01 [MPPMT 2001]
10 (b) between 7 and 8
between 9 and
(c)
At25°CthepH value of ia solution is 6. The (d) greater than 10
68.(a)basic (b) acidic solution is: [AFMC 2001]
(C) neutral (d) both (b) and (c)
weak monoprotic.acid of 0.1M, ionizes to
1% in solution, What will be the
69.A pH of solution ?
(b) 2 [Punjab PMT 2001]
(a)1 (c) 3 (d) 11
strongest Bronsted base in the following anion is:
F0. The [AIIMS 2001; AFMC2002]
(a)Clo (b) Clo, (c) ClO, (d) Cio,
a 10-8 M aqueous KOH solution will be:
1. At 25°
C,pH of [WB JEE 2013]
(a) 6.0 (b) 7.02 (c) 8.02 (d) 9.02
According to Bronsted-Lowry concept, the correct order of relative strength of bases follows
2. theorder:
[Punjab PMT 2001]
CH,COO > CI > OH (b) CH,CO0 >OH>CI
(a)
CHCO0> CI (d) OH">CI >CH,CO0
(c) OH >
73. The
pH of a buffer solution containing 2.0 mol per litre CH,COONa and 1.5 mol per litre
CH,COOH is: (K, for acetic acid is 18x 10-5) [CPMT 2001]
(a) 4.87 (b) 5.8 (c) 2.4 (d) 9.2
[Manipal PMT 2001]
74. What is expression for Kp for PbCl,? (b) [Pb*]/(2CIj2
(a) P][2 CI ] (d) [Pb*]/[CI12
(c) (PbJ[CI-j?
10.The pH of water is: [CPMT 2001]
75. The ionic product of water at 50°C is 4 x it is neutral
(b) 7 and
(a) 6.3 and it is acidic (d) 7.3 and it is basic
(c) 6.7 and it is neutral
buffer solution made up of 0.01 Maceticacid and 0.01 M
to a
0. lx 10 mole of HCIis added (given, pK, of acetic acid is 4.75 at 25° C):
the buffer will be
sodIum acetate. The final pH of [WBJEE 2013]
(d) 4.8
(c) 4.75 [PMT (Raj.) 2002]
(a) 4.60 (b) 4.66
7. is:
The compound that is not a Lewis acid (c) BeCl,
(d) NH;
(a) BF3 (b) AlCl3 mL of 10 MH,SO4, the resulting mixture
[AMU PMT 2002]
8, mixedwith 10
When 100 mL of 1M NaOH solution is
will be: (b) alkaline
(a) acidic (d) strongly alkaline
[PMT(Raj.) 2002]
C) neutral
19, In the the Lewis base is: (d) None of these
+II3,1
(a) 1, reaction
I, (c) 13 [MP PMT 2013]
(b) I solution
solution: NHCl+ NaOH
Abasic buffer NH,4OH solution
(a) NH1,C1+ is made by mixing the (b)
NaOH+ HCI
solution
20031
(d) PMT 2002; MPPMT
(©) [Punjab (d) NaCI
NH,
(a) FeCl3
OH
The pH is less
+ HCl solution
than 7, ofthe solution
(b)NaCN
of: (c) NaOH
82. Conjugate base of NH, is:
(b) NH; (c) NH, () N2
[PMT (Raj.) 20021
(a) NH
processesdue to its:
83. BF, isused as a catalyst in several industrial
(a) strong reducing agent (b) weak reducing agent Kerala PMT 20021
(c) strong Lewis acid nature (d) weak Lewis acid character
84. The acid that results when a base accepts a proton is called:
(a) conjugate base of the acid
[Kerala PMT 20021
(b) conjugate protonated base
(c) lewis base (d) conjugate acid of the base
(e) none of these
85. Which of the following is not Lewis base?
(c) (CH) N
[PMT (Raj.) 2002]
(d) HN,
(a) NH3 (b) PH,
86. Phenolphthalein does not act as an indicator for the titration between: [Punjab PMT 2001
(a) NaOH and CHCOOH (b) H,C,04 and KMnO4
(c) Ba(0H), and HCI (d) KOH and H,SO4
87. Among the following, the weakest base is: [MPPMT 20021
(a) H (b) CH; (c) CH0 (d) Ci
88. The indicator used in the titration of iodine against sodium thiosulphate is: [AFMC20021
(a) starch (b) KFe(CN)6 (c) K,CrO4 (d) potassium
89. Aqueous solution of AlCI, is: [PMT (Raj.) 2002]
(a) acidic (b) basic (c) amphoteric (d) none of these
90. At 298 K, the solubility of PbCl,is 2 x102 mol/litre,then Kp.=: [PMT (Raj.) 2002]
(a) 1x 10-7 (b) 3.2 x 10-7 (c) 1×10-5 (d) 3.2x105
91. Solubility of BaF, in a solution Ba(NO) will be represents by the concentration term:
[CPMT 2002]
(a) [Ba ] (b) [FJ (c) (d) 2 [N0;]
2
92. Solubility of MX, type electrolyte is 0.5 x 10 mol/litre. The value of Ksp of the electrolyte iS.
[AIPMT 2002]
(a) 5x 10-13 (b) 25 x 10-10 (c) 1.25x 10-13 (d) 5x 1012
93. The aqueouS solution of which of the [AIPMT 2002]
(a) NaCIO
following salt has the lowest pH?
(c) NaCIO3 (b) NaClO,
94. On adding solid potassium cyanide to (d) NaCIO 4
water: [CPMT 20021
(a) pH will increase
(c) pH will not change (b) pH will decrease
95. Asolution of MgCl, in water has pH: (d) electrical conductance will not change
[MPPMT 2002]
(a) <7 (b) >7 (c) 7 (d) 14.2
96. pH of human blood is 7.4. Then H" [PMT (Raj.) 2002]
(a) 4x 10-8 concentration willbe:
(b) 2 x 10-8 (c) 4x 104 (d) 2 x 10
-4

97. The pH of the solution containing 10 mL of 0.1 NNaOH and 10 mL of 0.05 NH,SO4 wouldbe:

(a) 0 [Punjab PMT 2002,04)

(b) 1 (c) >7 (d) 7
 solution can be prepared from a mixture of: [MPPMT 2002]
Abuffer
sodiumacetate and acetic acid in water
08.
(a)sodium
(b)
acetate and
hydrochloric acid in water
ammonia and ammonium chloride in water
(c) ammonia and sodium hydroxide in water
(d) offCuBr is 2 x 10
solubility mol/L at 25° C. The K.sp value for CuBr is : [AIIMS 2002]
The
(a)
99. 4x 10mol-2
(b) 4x 10-11 mol?L-1
(c) 4x1O-4 mol²,-2 (d) 4x 10-15 mol2 L2
pH ofa solution at 25° Ccontaining 0.10m sodium acetate and 0.03m acetic acid is: (pKa
00.for
TheCH,COOH=4.57) [AIIMS 2002]
(a)4.09 (b) 5.09 (c) 6.10 (d) 7.09
is the pH of a
What 1M CH,COOH a solution K, of acetic acid =18 x 10?
01.
(K,=10
-14 mol litre): [DPMT 2002]
(a)9.4
(b) 4.8 (c) 3.6 (d) 2.4
Bronsted acids in the reversible reaction are:HCO , (ag.) + OH (aq) Co (aq.) +H,0
102.The
[DPMT 2002]
(b) OH and H,O
(a) OH and Co
(d) HCO; and Co
(c) HCO, and H,0
C is : (pK,, = 13.26 at 50° C)
H08. The pH of pure water or neutral solution at 50°
[Punjab PMT 2002; DPMT 2002]
(b) 7.13 (c) 6.0 (d) 6.63
(a) 7.0
then OH ion concentration of this solution is:
104. An alcoholic drink substance pH=4.7, [PMT (Raj.) 2002]
(K, =10-1 mol?/L?) 5x 10-10
(b)
(a) 3 x 10-10 (d) 5x10-8
(©) 1x 10 -10 and HX. The K, for HX is 10,
equal concentrations of X
l. Acertain buffer solution contains [Manipal PMT 2002]
The pH of the buffer is: (d) 14
(b)8 (c) 11
a) 3
remains exposed to atmospheric CO, which is absorbed,
[DPMT 2002]
Water is kept in vessel and it
then its pH will be:
(b)less than 7 water
(a) greater than 7 (d) depends on ionic product of reaction,
(c) 7 the following
proton donor, the acid in [Kerala (PMT) 2003]
"Accepting the that an acid is a
definition
NH, +H,0 NH; +OH is: (c) NHË
(d) H,0
(a) NH3 (b) H+ ?
[MPPMT 2003]
8. Lewis and Bronsted base (d) None of these
Which
(a) BF3
ofFthe following behaves as both
(c) CO
(b) Cl
conditions of temperatureis given by:
[Kerala PMT 2003]
9.The solubility product of AgCl under standard
(b) 1.5x
10-8
(a) 16x10 10-10
(d) 1.5x
(o)32x l0-10
 sodium acetate and 50 mL 2N acetic acid (K, =18 x
110. pH of a solution of 10 mL. IN
approximately:
(a) 4 (b) 5 (c) 6 (d) 7 TMPPMT 10),
20031
classified as a Bronsted base: [MP PMT 20131
111.Which one of the following can be
(b) H,0* (c) NHÌ (d) CHCOOH
(a) NO3
buffer solution ?
112. Which one of the following is not a [AIIMS 20031
(a) 0.8MH,S +0.8 MKHS (b) 2M C6H,NH, +2M C,H, NH,Br
3M H,CO, +3M KHCO, (d) 0.05M KCIO 4 +0.05 MHCIO,
(c)
113. The solubility product of AgI at 25°C is 1.0 x 10 -1 mol2L2 The solubility of Agl in 10N
solution of KI at 25°C is approximately (in molL-): [AIPMT 20031
(a) 1.0 x 10-8 (b) 1.0 x 10 -16 () 1.0 x 10-12 (d) 1.0 >x 10-10
,10-44 ,l0-54
114. The solubility product of CuS, Ag ,S, HgS are 10-31 respectively. The solubilities
of these sulphides are in the order:
(b) Ag,S> HgS> CuS
[MPPMT 2003]
(a) Ag S> CuS> HgS
(c) HgS > Ag,S> Cus (d) CuS > Ag,S> HgS
115.Amonoprotic acid in a 0.1M solution ionizes to 0.001%. Its ionisation constant is:
[CPMT 2003]
(a) 1.0 x 10-3 (b) 1.0 x 10-6 (c) 1.0 x 10-8 (d) 1.0 x 10-11
116. Ionisation depends upon: [CPMT 2004; PMT (Raj.) 2006]
(a) pressure (b) volume (c) dilution (d) none of these
117.The conjugate acid ofNH, is: [Punjab PMT 2004]
(a) NH3 (b) NH, (c) NH4 (d) NH,OH
118. Strongest conjugate base is: [DPMT 2004]
(a) Ci (b) Br (c) F (d) I
119. For a weak acid, the incorrect statement is: [Punjab PMT 2004]
(a) its dissociation constant is low
(b) its pk, is very low
(c) it is partially dissociated
(d) solution of its sodium salt is alkaline in water
120. Which is a Lewis base ? [CPMT 2004]
(a) B,H, (b) LiAlH4 (c) AlH3 (d) NH,
121. The solubility product of Ag,CrO is 32 × 10 -l2 What is the concentration of Cro 10ns
that solution? [DPMT 2004]
(a) 2 x 10 M (b) 16 x 10-4 M (c) 8 x 10 M (d) 8x 10- M
122. Any precipitate is formed when: [MPPMT 2004]
(a) solution becomes saturated
(b) the value of ionic product is less than the value of
(c) the value of ionic product is equal to the value of
solubility product
(d) the value of ionic product is greater than the valuesolubility product
of solubility product
123. The solubility of Sb,S in water is 1.0 × 10 mol/litre at 298 K. What will be its solubility
product ? 2006]
(a) 108 × 10-25 (b) 1.0x 10-25 [CPMT 2004; PMT (Raj.)
(C) 144 x 10-25 (d) 126 x 10-24
 The
solubility product of a sparingly soluble salt AX, is 3.2 x 10-11 Its solubility (in mol/litre)
L94. [AIPMT 2004]
(a)
iS.: 2x
1O4 (b) 4 x 10-4 (c) 5.6x 10-6
(d) 3.1x 10
concentration of KI and KCl in certain solution containing both is 0.001 M each. If 20 mL of
The,
J25. solution is added to 20 mnL of a saturated solution of AgI in water, what will
this
happen?
[MPPMT 2004]
AgCl will be precipitated (b) Agi will be precipitated
(a) AgCl and AgI will be precipitated (d) There will be no precipitate
(c)Both
The.rapid change of pH near the stoichiometric point of an acid-base titration is the basis of
26.indicator detection. pH of the solution is related to ratio of the concentrations of the conjugate
andIbase the indicator by the expression:
[In]forms of the [AIPMT 2004]
acid[HIn]
[HIn] [In ]
(a)log =pH- pKin (b) log =pH-pKin
[In] [HIn]
[In -pKin -pH [HIn]
(d) log =pKIn -pH
(c) log [HIn] [In ]
pH value of 0.05 MBa(OH), solution? [CPMT 2004; PMT (Raj.) 2006]
127. What will be be (b) 13 (c) 1 (d) 12.96
(a) 12
198. Which is a buffer solution
? [AFMC2004; PMT (Raj.) 2006]
(b) CH,COOH + CH,COONH4
(a) CH,COOH + CH3COONa (d) NaOH + NaCI
() CHCOOH + NH4Cl =1.7x10-10
129. What is the pH of0.01 Mglycine solution? (For glycine, K =4.5 x 10 and Ka
[AIIMS 2004]
at 298 K)
(b) 10.0 (c) 6.1 (d) 7.2
(a) 3.0
sodium hydroxide is dissolved in 10 litres of distilled water. The pH of the
B0.40 mg of pure [Kerala PMT 2004]
solution is: (d) 12
(a) 9.0 (b) 10 (c) 11
(e) 8 [MPPMT 2005]
1B1. Aqueous solution of weak acid and weak base is:
(a) acidic (b) basic
(C) neutral (d) either acidic or basic
[MPPMT 2005]
132. The solubility of Ca(OH) 2is's mol/litre, thesolubility product is: (d) s?
(a) 4s (b) 4s2 (c) s3
The concentration of hydroxv
33, Ar 25C, the dissociation constant of a base BOH is 1.0 x 10
[AIPMT 2005]
ionssin 0.01M aqueous solution ofthe base would be: mol L
(a) 2.0 x10-6 (b) 1.0 x 10-5 molL-1
molL
(e) 10 x 10 -6 mol (d) 1.0>x 10-
L-1 hydrolysis (a) for the
of
relation between hvdrolysis constant (K,) and degree
ollowt
equilibrium is: [MPPMT 2013]
A +H,0AH + OH"
Km
(a) a =, KC (b) a=K, -C
Ka
 Ka
K, C (d) a =
(c) a = VK C

135. A
=Kw
solutionhas pH 5,it is diluted 100 times, then it willbecome:
(b) basic [AFMC 2005]
(a) neutral (d) more acidic
(c) unaffected
=5.0) is titrated against 10 mL of 0.1M
136. When 10 mL of 0.1M acetic acid (pK,
solution (pK; =5.0), the equivalence point occurs
(a) 5.0 (b) 6.0
at pH:
(c) 7.0 (d) 9.0 [AIMSammoni
2005)a
nH.
137. The K.n of Mg(OH), is 1 x 10 ,0.01M Mg(OH) 2 Will precipitate at the limiting

(a) 3 (b) 9 (c) 5 (d) 8 [DPMT 2005]

138. At 298 Ka 0.1M CHCOOH solution is 1.34% ionized. The ionization constant K for
acid willbe:
(a) 1.82x10-5 (b) 18.2 x 10-5
[AFMC 2005]
(c) 0.182 × 10-5 (d) None of these
139. The K
Sp of Mg(OH), is 1x 10-12. 0.01IM Mg* will precipitate at the limiting pH of:

[DPMT 2005]
(a) 3 (b) 9 (c) 5 (d) 8
140. Degree of dissociation of 0.1 N CH,COOH is:
(Dissociation constant =1× 10) [CPMT 2006]
(a) 10-5 (b) 10-4 (c) 10-3 (d) 10-2
141. The conjugate base of HSO, is: [MPPMT 2006]
(a) H,SO3 (b) SO 2 (c) SO (d) H,S
142. Which of the following salts does not get hydrolysed in water? [PMT (Raj.) 2006]
(a) KCIO4 (b) NH,CI (c) CH,COONa (d) None of these
143. Which of the following is a Lewis base ? [PMT (Raj.) 2006]
(a) NaOH (b) NH3 (c) BCl3 (d) All of these
144. Which of the following is not Lewis acid ? [CPMT 2006]
(a) AlCl3 -6H,0 (b) AlCl, (c) SnCl
145. At 298 K, the solubility product of PbCl, is 1.0x 10-,What will be (a) FeCl3
mol/litre ?
the solubility of Pbul2
(a) 6.3 x 10-3
[AFMC2006]
(b) 1.0 x 10-3 (c) 3.0 x 10-3 (d)4.6x 10-14
146.The hydrolysis constant of the salt with NO, ion
is: (K, = 4.5 x 10-l0 for HNO 2)
(a) 2.22 x 10o-5
[MPPMT 2006]
(b) 4.44 x 10-5
147. Aqueous solution of HCIhas the pH =4.
(c) 2.22 x 10 (d) 4.44 x 10-2
(a) 4M Its molarity
would be: [PMT (Raj.)2006]
(c) 0.0001 M (b) 0.4M
(d) 10 M
148.0.005 Macid solution has 5pH.The [PMT(Raj.) 2006]
(a) 0.8%% (b) 0.6% percentage ionisation of acid is:
(c) 0.4% (d) 0.2%
 is 45 fora solution then what
thepHvalue is the value of Ht
concentration ?
I
49
mol/I. [MPPMT 2006]
x 10- (b) 31.62 x 10- mol/L
(a)3.162 x
:10 mol/L (d) 3.162 × 10- mol/L
) 0.3162 ;
of0.001I molarsolution of HCl will be: [AFMC 2006]
ThepH (b) 3 (c) 2 (d)
(a)0.001
Which one of the following electrolytes would dissolve in water to give a 0.1 Msolution with
pHabout9? [Kerala PMT 2006]
(a)CH,COOH (b) CH,COONa (c) NH4Cl (d) KOH
(e)NaCI
40ml of 0.1 M
ammonia solution is mixed with 20 mL of 0.1M HCL What is the pH of the
162. mixture?(pk, ofammonia solution is 4.74) [AIIMS 2006]
(a)4.74
(b) 2.26 (©) 9.26 (d) 5.00
buffer? [AIPMI 2006]
Which ofthe following pairs constitute a (b) HCI and KCI
153. NH4NO3
(a) HNO3 and (d) NaOH and NaCl
(c) HNO, and NaNO , is:
hydrogen ion concentration of a10 °M HCl aqueous solution a298 K(Kw =10 *)
1S4. The [AIPMT 2006; CPMT 2010]
10-M (b) 1.0 >x 10- M
(a) 9.525 x
M (d) 1.0525 x 10- M
(c) 10 x 10 [MPPMT 2006]
155. Which one is the strongest acid ? (c) H,SO4 (d) HCI04
(a) HCIo (b) HCIO2 [AIIMS 2007]
156. The correct order of basic strength is: (b)CH,OH <H,0<CH,0 <OH
(a) H,0< OH"< CH,OH< CH,0 (d) OH" <H,0<CH,0 <
CH,OH
() H,0< CH0H < OH" <CH,0 IfO.100 mole of this acid is dissolved in one litre
of
of 100 x 10s [AIPMT 2007]
oA Weak acid HA has a K: equilibrium is closed to:
of acid dissociated at
water, the percentage (c) 99.9%
(d) 0.100%
(a) 99.0% (b)1.00% dissociated in saturated solution. The
10.8 x 10.It is 50% [AIIMS 2007]
158, Theesolubility product of As,O, is
10-9
(c) 5x10-3 (d) 5.4 x
solubility of salt is: hydroniumions, i. e.,
(a) 10-2 (b) 2 x 10-2 lx 10 "M of
159. Calculate the solution at 25°C that contains [AIPMT 2007]
pOH of a
(d)1.000
H,0*:
(a) 7.000 (b) 4.000
(c) 9.000
Na,SO4 solution, species first
[Ca]in a
[Ba],KpAgS0, [AIIMS 2008]
\60, On each of [Ag], =10)
adding is: (K sp BaSO 4
precipitated
0.1M solution
=10-11
=10
o-11 ,KgpCaso4
-6
4
(c) CaSO4
(d) Allof these
vessel. What will be the
(a) Ag,SO4 (b)BaSO 4 and 5 are
mixedin a[AIPMT (Pre.) 2008]
\61. Equal volumes of three acid solutions
of pH3,4
M (d)3.7x 10
M
l0n concentration in the mixture:? (c) 111x 10
(a) 3,7 x 10-3 M (b)1.11x10M
 ions present in 250 mL of lemon juice ofpH =3 is : [Kerala PMT 2008)
162. Number of H 1.506 x 1020
(b) 1.506 x 1023 (c) (d) 3.012 x 1021
(a) 1.506 x1022
(e) 2.008 x 1023

(a) 0
1 MH SO4?
163. What is the pH value of (b) -0.213 (c) -2 LAIIMS 20081
(d) -0.3010
164. Equimolar solutions of the following were prepared in water separately. Which one of the
[AIPMT 2008; AIPMT
the highest pH ?
solutions will record
(b) CaCl, (c) SrCl, (d) BaCl2(Pre.) 2012)
(a) MgCl2
165. Which of the following solutions will
have pH close to 1.0?
M/10 NaOH
Kerala PMT 20081
(a) 100mL of M/10 HCI + 100 mL of NaOH
(b)55mL of M/1O HCI + 45 mL of M/10 NaOH
(c) 10 mL of M/10 HCl + 90 mL of M/10
(d) 75 mL of M/5HCI + 25mL of M/5NaOH
(e) 50 mL of M/5HCI + 50mL of M/5 NaOH
166. Dissociation constant of a weak acid is decreased by:
(a) addition of a strong acid
[MPPMT 2009)
(b) addition of a salt of the above weak acid
(c) decreasing temperature
(d) dilution of the solution
167. Which of the following molecules acts as a Lewis acid ? [AIPMT 2009]
(a) (CH,),B (b) (CH,),0 (c) (CH3),P (d) (CH,),N
168. The jonization constant of ammonium hydroxide is 1.77 x 10 at 298 K. Hydrolysis constant
of ammonium chloride is: [AIPMT 2009]
(a) 5.65x 10-10 (b) 6.50 x 10-12
(©) 5.65 x 10-13 (d) 5.65 x 10-12
169. Hydrolysis of the salt of a strong acid and weak base will: [MPPMT 2009]
(a) increase with increase in temperature
(b) decrease with increase in temperature
(c) remain unaffected with change in temperature
(d) remain unaffected with change in concentration of the salt
170. When equal volume of AgNO and NaCl solution are mixed. the precipitation of Ag
(Ken =1.81 x 10) will occur with: [AMUPMT 2009]
(a) 10M (Ag*) and 10M (CI) (b) 10- M (Agt) and 10- M (Cl)
(c) 10-M (Ag*) and 10-M (CI-)
(d) 10* M(Agt) and 10 M (CI)
171. Solubility (s) of CaF, in terms of its solubility product is given as: [AMUPMT2009]
(a) s =(K)43 (b) s=(Kso /2)3 (d) s=(Ko/2)2
(c) s=(K14)V3
172. What is the [OH]in the final solution prepared by mixing 20.0 mL of 0.050 M HCI with
30.0 mL of 0.10 MBa(OH) 2? [AIPMT2009]
(a) 0.10M (b) 0.40 M (c) 0.0050 M (d) 0.12M
173. The pH of the solution is 4. The hydrogen ion concentration of the solution in mol/litreis:
[MPPMT2009)
(a) 9.5 (b) 104 (c) 104 (d) 100-2
 of acetic acid and pK, of ammonium hydroxide are 4.76 each. The pH of ammonium
acetateis: [AMUPMT 20091
(b) less then 7 (c) more than 7 (d) zero
(a)7
175.DeterminethepH of the
th solution that results from the addition of 20.00 mL, of 0.01M Ca(OH) 2
mL of 0.01 M HCI: [DUMET 2009]
to.30.00 (b) 10.53 (c) 2.70
(a)11.30 (d) 8.35
order of increasing [H30 ]in the following aqueous solution is: [AFMC 2009]
Thecorrect
176.
0.01/M H,S<0.01M H,SO4 < 0.01M NaCI <0.01M NaNO 2
(a)
0.01M NaCl< 0.01M1 NaNO , <0.01M H,S<0.01M H,SO4
(b)
0.01M. NaNO, <0.01M NaCl < 0.01M H,S <0.01MH,SO 4
(c)
0.01M H,S < 0.01M NaNO, <0.01M NaCl l<0.01MH,SO 4
(d) is 1.77 x 10 at 298 K. Hydrolysis constant
ionization constant of ammonium hydroxide [AIPMT 2009]
chloride is:
ofammonium
10-12 (b) 5.65 x 10-13
)-12
(c) 5.65 x 10 (d) 5.65 × 10 -10
(a) 6.50 x
buffer solution containing equal concentration ofB and HB, the K, for B is 10-0. The
178.Ina [AIPMT (Pre.)2010]
buffer solution is:
pH of (b) 10 (c) 7 (d) 6
(a) 4 [AIPMT (Pre.) 2010]
its K.m is:
is 12, the value of10-6M3
179, If pH of a saturated3 solution of Ba(OH), (b) 4.00x
(a) 5.00 >x 10-7 M
M3 (d) 5.00 x 10-6 M3
(c) 4.00 x10-7
solution that is 0.20M in CHCO0Na and 0.10M in CH,COOH?
180.What is [H]in mol/L of a [AIPMT (Pre.) 2010]
(K,for CH,COOH = 18 x 10 ) (c) 1.1x 10-5 (d) 1.8 x10-5
(b)3.5 x 104
(a) 9.0 x 10-6 of Ir becomes
equilibrium concentration[DPMT
added to water, the 2010]
l61. When solid lead iodide is
2.6 x 10-3M.What is K for Pbl, ? 10-8 (d)3.5 x10-8
(C) 18 x
(b)8.8 x 10-9
(a) 2.2 x 10 -9
hydridesacts as a Lewis acid ? [AIPMT (Pre.) 2010]
molecular
e Which one of the following (c) H,0
(d) B,H6
(a) CH4 (b) NH3 acid is 14% ionized. What is K for
organic
183. A 0.010 Msolution of maleic acid, a monoprotic [DPMT 2010]
(d) 2.0x10-6
maleic acid ? 10-4
(c) 2.0x
(a) 2.3 x 10-3 (b) 2.3 x104 10-?
[DPMT 2010]
ofHOCI, K, =3.5 x 10M (d) 3.7x 10M
84.What is [H]in a 0.40M solution
(a) 1.4 x 10-8 M (b) 12 >x
10M (c) 1.9 x
percentage of ionization in a decimolar
acid
10-, The [Kerala PMT 2010]
185,Tsolution
he is:
K,of a weak monobasic acidis 1x
(c) 0.01
(d) 0.5
(a) 0.1
L (e) 1 (b) 10
PbCrO4 is:
molar solubility of
186.The Ksp of PbCrO 4 is 1.0 x 10-16
Then the

(c) 10x
10-16
[Kerala PMT 2010]
(d) 1.0 x 10-8
(a) 10 x 10 (b) 10x 104
(e) 10 x10-12
 be.
lead iodide (PbI,)is 3.2x 10, its solubility will
of
187. If the solubility product
(b) 4 x 10M rCPMT 20101
(a) 2 x 10-M (d) 18 x 10M
(c) 16 x 10-M solution is given bv.
in 0.100M acetic acid
188. The charge balance equation of species
(b) [H]=[CH,COO] TAMUPMT 20101
(a) [H*]=[OH ] (d) 2 [H*]=[OH"]+ [CH ,CO01
H*]=[OH ]+ [CH,CO0 ]
189. (c)
The pH of asolution prepared by mixing 2.0 mL of HCI solution of pH 3.0 and 3.0 mi. of Na0H
solution of pH 10.0 is: (c) 5.5
[AMUPMT 20101
(d) 6.5
190. (a)
At 2.5 (b) 3.5
25° C, the solubility product of Hg,Cl, in water is 3.2 x 10 mol'dm -9 What is the

solubility of Hg ,Cl, in water at 25° C ? [Kerala PMT 2011]

(a) 1.2 x 10 -12M
(b)3.0 x 10M
(d) 1.2 x 10-16 M (e) 5.2 x 10-°M
(c) 2 x 10M
NH, is 0.30 M and the
191. Abuffer solution is prepared in which the concentration of
concentration of NH}is 0.20 M. If the equilibrium constant (Kp) for NH, equals L8 x105
what is the pH ofthis solution? (log 2.7=0.43) [AIPMT (Pre.)2011]
(a) 9.08 (b) 9.43 (c) 11.72 (d) 8.73
192. Which of the following is least likely to behave as Lewis base?
[AIPMT (Pre.)2011; NEET 2013]
(a) H,0 (b) NH, (c) BF; (d) OH
193. Inqualitative analysis, the metals of group I can be separated from other ions by precipitating
them as chloride salts. A solution initially contains Ag+ and Pb 2 at a concentration of
0.10 M. Aqueous HClis added to this solution until the Cl concentration is 0.10 M. What wl
the concentrations of Ag* and P5* be at equilibrium? ( K for AgCl =1.8 x 10"", for
PbCl, =1.7 x10-5) [AIPMT (Main)2011]
(a) [Ag*]=1.8x 10% M, [(Pb ]=1.7 x10-6M
(b) [Ag»]=18 x 10- M, [Pb 2+]=8.5 x10-5M
(c) [Ag]=18x 10 M, [Pb]=1.7 × 10% M
(d) [Ag*]= 1.8 x 10 - M, [Pb]=1.7 x 10 M
194. Amonobasic weak acid solution has molarity of 0.005 and pH of 5. What is the percentage
ionisation in this solution ? [Kerala PMT 2011)
(a) 2.0 (b) 0.2
(e) 20.0 (c) 0.5 (d) 0.25
195. In which of the following arrangements the given sequence is not strictly according tothe
property indicated against it [AIPMT (Mains) 2012/
(a) HF < HCl< HBr < HI;
(b) H,0 <H,S<HSe < H,Te; increasing acidic strength
(c) NH, <PH, <AsH, < SbH, ;increasing pK, values
(d) CO, <SiO, <SnO, < PbO2 ;increasing acidic character
increasing oxidizing power
 pi
saturated
ofa, solution of Ba(OH) 21s l2. The
196.
is.: l0-7
value of
solubility product (K) of Ba(oH) 2
x
3.3
(a) -6 (b) 5.0 x 107 [AIPMT (Pre.) 2012]
4.0x l0
(c) (d) 5.0 x 10-6
100mL0.1M solution of
ammonium
197.A resulting solution will be acetate is diluted by adding 100 mL of
(pk, of acetic acid is
nearly equal to pK, of water. The pH of
(a)4.9 (b) 5.0 NHOH): [WB JEE 20121
(c) 7.0
Thepk, ofa weak acid, HA is 4.8.The pK, of a (d) 10.0
198. solutionoffthe corresponding salt, BA, will be: wealk base, BOH, is 4.78. The pH of an aqueous
(a)4.79 [Kerala PMT 2012]
(b) 7.01
(c) 9.22 (d) 9.58
199. The pH
of normal rain water is [Kerala PMT 2012]
(a) 6.5 (b) 7.5 (c) 5.6 (d) 3.5
(e) 4.6
200. The pH of a solution obtained by mixing 50 mnL of 0.4 N HCI and 50 mL of 0.2 NNaOH is:
[KCET (Med.) 2012]
(a) -log 2 (b) -log 0.2
(c) 1.0 (d) 2.0
201, IfO.4gm NaOH is present in 1 litre solution, then its pH will be: [AFMC 2012]
(a) 2 (b) 10 (c) 11 (d) 12
[MP PMT 2012]
202. The aqueous solution of sodium acetate with minimum pH is:
(a) 0.01M (b)0.001M
(c) 0.0001M (d) 0.1M
because: [AIPMT (Pre.) 2012]
203. Buffer solution have constant acidity and alkalinity
reaction with added acid or alkali
(a) These give unionized acid or base on shielded from attack by other ions
are
(0)Acids and alkalies in these solutions
(C) They have large exKcess of H" or OH 1ons
() They have fixed value of pH not alter:
pH of 20 mL of 0.1 N HCl will[KCET (Med.) 2012]
204.On adding which of the following the
distilled water
(b) 20 mL of =1
(a) 1 mL of 1 N HCI (d) 500 mL of HCl of pH
(c) 1 mI, of 0.1 N NaOH tissues leads to pain and afeeling
monobasic acid in dissociates. The value of
205. Accumulation of lactic acid (HCH,0), a
solution, lactic acid is 3.7%
[NEET (Karnataka) 2013]
of
fatigue. In a 0.10 Maqueous
dissociation Constant Ka:for this acid will be:
(b) 1.4x
104
(a) 14 x 10-5 (d) 2.8x10-4
If
(C) 3.7 x 10 10-9 respectively at 25°C.
and 1.3
are 4.7x10 ions in water.
A5,Tthehe values of K sp of CaCO3
and CaC,04
washed with water,
whatis the
concentration of Ca *
[NEET (Karnataka) 2013]
mixture of these two is 10-M
(b) 6.856x 105M
la) 5831x 10- M (d) 7.746x
() 3.606x
10-> M
 What will be the pH of neutral
207. At 100° Cthe K. of water is 55 times its value at 25° C.
(log 55 = 174):
(a) 7.00 (b) 7.87 (c) 5.13
[NEET (Karnataka)
(d) 6.13 solution
2013)

water?
208. Which of the following salts will give highest pH in
(a) Na,CO3 (b) CuSO4
(d) NaCl
LAIPMT 2014]
(c) KCI
volume of 0.1 MNaOH and
209. What is the pH of the resulting solution when equal 0.01M HCI and
mixed?
(c) 1.04
TAIPMT(d)(Re-eXam)
12.65
20151
(a) 2.0 (b) 7.0
210. The ratio of volumes of CH,COOH 0.1(N) to CH,COONa 0.1 (N) required to prepare a buffer
is 4.74) :
lution of pH5.74 is (given : pK, of CH,COOH(b) [WB (JEE) 2015)
(a) 10:1 5: 1
(c) 1:5 (d) 1: 10
211. The Ksp of Ag,CrO4, AgCl, AgBr and AgI are respectively, 1.1 x10-, 18 x10-l0,5.0 x10-13
8.3x 10-17,Which one of the following salts will precipitate last if AgNO, solution is added to
the solution containing equal moles of NaCI, NaBr, Nal and Na,CrO4?
[AIPMT (Cancelled) 2015]
(a) AgBr (b) Ag,Cro 4
(c) AgI (d) AgCl
212. At 800 K in asealed vessel, for the equilibrium N g) +O 2(e) 2NO(&), the equilibrium
concentrations of Nr), Otg) and NO() are respectively 0.36 x10M, 4.41x 10*M and
14x 10M.Then, the value of K, for the reaction NO(¡)y2N g)+1/20g) at 800 Kis:
[Kerala (PMT)2015]
(a) 1.1 (b) 0.9 (c) 3x 103 (d)9x10-3
(e) 0.33
213. The solubility product of a salt MX, in water is 4×10-l2 The concentration of M* ionsin
the aqueous solution of the salt is : [Kerala (PMT) 2015]
(a) 1x10M (b) 4×10M
(c) 16 x 10-M (d) 2 x 10M
(e) 12 x 10M
214. Which one of following species cannot act as both Bronsted acid and base ?
[Kerala (PMT) 20151
(a) H,0 (b) HCO3 (c) HS0, (d) NH;
(e) NH,
215. MY and NY3, two nearly insoluble salts, have the same K values of 66.2 x10 -13 at room
sp
temperature. Which statement would be true in regard to MY and Nø3 ?
LNEET (Phase-I)20161
(a) The salts Mø and NY, are more soluble in 0.5
M KY than in pure water. their
(b) The addition of the salt of KY to effect on
solubilities.
solution of MY and NY, will have no
(c) The molar solubilities of MY and NYa in
water are identical.
(d) The molar solubility of MY in water is less
than that of NY.
p1o.The.
solubilityof. AgCle with solubility product 1.6 x 10-10 in0.1M Nacl solution would be :
10-M [NEET (Phase-I) 2016]
1.26x (b) 1.6 x 10M
(a) 10-1M (d) zerO
(c)1.6x
Concentration of the Ag* ions in a saturated solution of
product of Ag ,C,04 is:
Ag.C.0, is 2.2 ×10 mol L
Soluubility
(a)2.66xl0-12 [NEET 2017]
(b) 4.5 x10-11
-12
xl0 (d) 2.42 x10-8
(c)5.3
The
percentage of pyridine (CgH,N) that forms pyridinium ion (C H,N*H) in 0.10M
218. aqueouspyridine solution (K; for CHN=1.7 x10- is: [NEET (Phase-II) 2016]
(a)0.0060% (b) 0.013% (c) 0.77% (d) 1.6%
Following solutions were prepared by mixing different volumes of NaOH and HCI of different
219.
Concentrations: [NEET 2018]
M M M M
(A)60mlL HCl + 40 mL -NaOH (B) 55mLHCI+ 45 mL 10-NaOH
10 10 10
M M M
(C) 75mL MHCI + 25 mL 5
-NaOH (D) 100 mL
10
HCl+ 100 mL
10
-NaOH
5
DH of which one of them will be equal to 1?
(b) A (c) D (d) C
(a) B
90. The solubility of BaSO4 in water is 2.42 x 10gL at 298 K. The value of its solubility
gmol- ) [NEET 2018]
product (Ks) will be : (Give molar mass of BaSO, = 233
L08 x 10-1 mo12L2 (b) 1.08 x 10-1molL-2
(a) (d) 1.08x10-mo12.2
mol2
(c) 1.08 x 10 -1 [NEET 2019]
221. The compound that is most difficult to protonate is :
(b) H H
(a) Ph H
(d) H,C -CH,
(c) H,C H [NEET 2019]
2. Which will make basic buffer?
of 0.1 M NaOH
(a) 100 mL of 0.1 M HCI + 100 mL
M CHgCOOH
(0) 50 mL of 0.1 M NaOH + 25 mL of 0.1
mL of 0.1 M NaOH
100mL of 0.1 M CHCOOH + 100 NH,OH
100mL of 0.1M HCI + 200 mL of 0.1 solubility product (Kp) of Ca(OH), is :
223. DH of a saturated solution of Ca(0H), is 9. The [NEET 2019]
(c) 0.25x 10-10 x 10-l5
() 0.125
[NEET 2019]
(a) 0.5 x 10-10 (b) 0.5x 10-15
are :
Conjugate base for Bronsted acids H,0 and HF (b) OH and H,F,respectively
(a) H
iz0* and H,F*,respectively respectively
(d) OH and F", following
(c) H,0* and F, respectively NaCI. Which of the
CaCl,,MgCl2 and [NEET 2020]
25,HCICompound
was passed through a
(s) crystallise(s)?
solution of
(b) Only MgCl,
(a) Only NaCl and CaCl
(c) (d)Both MgCl,
NaCl, MgCl2 and CaCl,
 226. FËnd out the solubility of Ni(OH), in 0.1M NaOH. Given
that the ionic product of
2x 10-15
(a) 2 x 10-8M (b) 1× 10- M INEETNi(20201
OH)is
(c) 1× 10 M (d) 2x 10 -13 M
-8 What is the motarity of its
227. The solubility product for a salt of the type AB is 4 x 10
solution?
(a) 2 x 10- mol L-1 (b) 16 x 10-16 molI-1 [NEET st20201
andard
(©) 2 x 10-16 mol L (d) 4 x 10- mol L-1
228.The pk, of dimethylamine and pK, of acetic acid are 3.27 and 4.77 respectively at T(K). The
Correct option for the pH of dimethylammonium acetate solution is: [NEET 2021]
(a) 8.50 (b) 5.50
(c) 7.75 (d) 6.25
229. The pH of solution containing 50 mL each of 0.10 M sodium acetate and 0.01 Macetic acid ie .
[Given : pK, of CH aC0OH =4.57] [NEET 2022]
(a) 3.57 (b) 4.57
(c) 2.57 (d) 5.57
 (b) 4 (a) 5. (d) 6. (c)7. (a) 8. (a,b) 9. (a) A0. o
(b) 2. (d)
11. (b) 12. (a)13. (b) 14. (b) 15. (c) 16. (d) 17. (d) 18. (b)19. (c)
20.
21. (c) 22. (c) 23. (c) 24, (c) 25. (d)26. (d) 27. (b) 28. (d) 29. (b)
30. la)
31. (a) 32. (c) 33. (d) 34. (d) 35. (a) 36. (b) 37. (a) 38. (d) 39. (b) 40.
(a)
41. (b) 42. (c) 43. (b) 44. (a) 45. (c) 46. (c) 4 7 (c) (b) 49. (b) 50. (h
(b)
51. (d) 52. (a) 53. (b) 54. (a) 55. (a) 56. (c) 57. (a) 58. (c) 59. (d) 60.
(b)
61. (c) 62. (d)63. (b) 64. (c) 65. (b) 66. (b) 67. (b) 68. (b) 69. (c) 70. la)
(c)70
71 (b) 72. (c)73. (a) 14. (c)75. (c) 76. (b) 77: (d) 78. (a) 79. (b)
(b)0.
80. (a)
81. (a) 82. (c) 83. (c) 84. (d) 85. (d)
(d) 86. (b) 87. (d)88. (a) 89 (a) 90. (d)
91. (c) 92. (a) 93. (d) 94. (a) 95. (a) 96. (a)97, (c) 98. (a,c) 99. (a) 100. (b)

|101. (d) 102. (c) 103. (d) 104. (b) 105. (b)106. (b)107: (d)108. (b) 109. (d) 110. ((a)
111: (a) 112 (d) 113. (c) 114. (a) 115, (d) 116. (c) 117. (b) 118. (c) 119. (b) 120, (a
121 (a) 122. (d) 123. (a) 124. (a) 125. (b) 126 (b) 127. (b)128. (a) 129. (d) 130. (b)
| 131. (d) 132. (a)133. (d) 134. (b) 135. (a) 136. (c) 137. (b) 138. (a) 139. (b) 140. (d)
141. (C) 142. (a) 143. (b) 144. (a)145. (a)146. (a) 147. (c) 148. (d) 149. (a) 150. (b)
151, (b) 152. (c) 153. (c) 154. (d) 155. (d) 156. (c) 157. (b) 158 (b)159. (b) 160. (b)
|161. (d) 162. (c) 163. (d) 164. (d) 165. (d)166. (c) 167. (a) 168. (a)169. (a) 170. (0)
171. (c)112. (a) 173, (b) 174. (a) 175. (a) 176. (c) 177. (d) 178. (a)179. (a) 180. (0(a)
181. (b) 182. (d)
183, (b) 184. (b) 185. (e) 186, (d) 187. (a) 188. 189. (b) 190. (C)
(c)
191. (b) 192. (c) 193. (c)194. (b) 195. (b)
196. (b) 197. (c) 198 (b)199. (a) 20D. (C)
201, (d) 202. (c) 203. (a,d) 204
(d)205 (b) 206. (d) 207. (d) 208 (a)209 (d) 210. (07
211.2 (b) 212, (b) 213, (a)214. (d) 215. a,
(d)216, (b) 211 (c) 218. (b) 213. (07
221. (a) 222, (d) 223, (b) 224: (d) 225, (a)226, (d) 227. (a) 228. (c) 223. (