Professional Documents
Culture Documents
Bank
Visit to download the full and correct content document:
https://testbankdeal.com/download/chemistry-6th-edition-mcmurry-test-bank/
Chemistry, 6e (McMurry/Fay)
Chapter 10 Liquids, Solids, and Phase Changes
1
Copyright © 2012 Pearson Education, Inc.
6) The dipole moment of ClF is 0.88 D, and its bond length is 163 pm. What is the percent ionic
character of the Cl F bond?
A) 0.54%
B) 7.8%
C) 11%
D) 25%
Answer: C
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments
7) The dipole moment of BrF is 1.29 D, and its bond length is 178 pm. What is the percent ionic
character of the Br F bond?
A) 3.9%
B) 8.5%
C) 15%
D) 33%
Answer: C
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments
8) AgCl is found to have 78.1% ionic character, and its gas phase dipole moment is 11.5 D. What is the
distance between the Ag and Cl atoms in gaseous AgCl?
A) 9.19 x 10-10 pm
B) 14.7 pm
C) 307 pm
D) 903 pm
Answer: C
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments
9) Which compound, shown with its dipole moment, is expected to exhibit the smallest percent ionic
character?
A) HCl, 1.11 D
B) HF, 1.83 D
C) LiH,6.00 D
D) LiF, 6.28 D
Answer: A
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments
10) The HI bond has a length of 161 pm and 4.92% ionic character. What is the experimental dipole
moment of HI?
A) 0.380 D
B) 0.772 D
C) 3.80 D
D) 7.72 D
Answer: A
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments
2
Copyright © 2012 Pearson Education, Inc.
11) Which compound below could have a zero dipole moment?
A) CCl2F2 (tetrahedral)
B) CuCl2F2 (tetrahedral)
C) PtCl2F2 (square planar)
D) SCl2F2 (see-saw)
Answer: C
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments
3
Copyright © 2012 Pearson Education, Inc.
16) Which substance in each of the following pairs is expected to have the larger dispersion forces?
17) Which of the following compounds exhibits only dispersion and dipole-dipole intermolecular
interactions?
A) N2
B) HBr
C) CO2
D) H2O
Answer: B
Topic: Section 10.2 Intermolecular Forces
19) When a narrow diameter glass tube is inserted into a body of water, water rises in the tube and its
surface inside is concave upwards. Which statement, concerning the strength of the intermolecular
forces between glass and water molecules compared to those between water molecules, is accurate?
A) The forces of attraction between the glass and water are weaker than those in water.
B) The forces of attraction between the glass and water are stronger than those in water.
C) The forces of attraction between the glass and water are the same as those in water.
D) Intermolecular forces are irrelevant to this situation.
Answer: B
Topic: Section 10.3 Some Properties of Liquids
4
Copyright © 2012 Pearson Education, Inc.
20) Which of the intermolecular forces is the most important contributor to the high surface tension
shown by water?
A) dipole-dipole forces
B) dispersion forces
C) hydrogen bonding
D) ion-dipole forces
Answer: C
Topic: Section 10.3 Some Properties of Liquids
21) The property of a liquid that measure the liquid’s resistance to flow is
A) boiling point.
B) heat of vaporization.
C) surface tension.
D) viscosity.
Answer: D
Topic: Section 10.3 Some Properties of Liquids
22) Which of the following is most likely to have the highest viscosity at 25°C?
A) C4H10
B) HOCH2CH2OH
C) C8H18
D) C2H5NH2
Answer: B
Topic: Section 10.3 Some Properties of Liquids
24) The magnitude of the heats of vaporization, fusion and sublimation of a substance reflect the
A) density of the substance.
B) magnitudes of the boiling and melting points of the substance.
C) strength of the covalent bonds between atoms in each molecule of the substance.
D) strength of the intermolecular forces of the substance.
Answer: D
Topic: Section 10.4 Phase Changes
27) For which of the following phase changes is the sign of ΔS negative?
A) boiling of water
B) formation of snow from water vapor in clouds
C) melting of ice cream
D) sublimation of I2
Answer: B
Topic: Section 10.4 Phase Changes
28) When a substance melts at its normal melting point, the sign of ΔH is ________ and the sign of ΔS
of this phase change is ________.
A) +, -
B) -, +
C) +, +
D) -, -
Answer: C
Topic: Section 10.4 Phase Changes
29) Ethyl chloride, C2H5Cl, is used as a local anesthetic. It works by cooling tissue as it vaporizes. The
heat of vaporization is 26.4 kJ/mol. How much heat could be removed by 10.0 g of ethyl chloride?
A) 4.09 kJ
B) 170 kJ
C) 264 kJ
D) 1700 kJ
Answer: A
Topic: Section 10.4 Phase Changes
30) Bromine is one of only two elements that is a liquid at room temperature. Bromine has a heat of
vaporization of 30.91 kJ/mol and its boiling point is 59°C. What is the entropy of vaporization for
bromine?
A) -301 J/(mol ∙ K)
B) -93.1 J/(mol ∙ K)
C) 10.7 J/(mol ∙ K)
D) 93.1 J/(mol ∙ K)
Answer: D
Topic: Section 10.4 Phase Changes
6
Copyright © 2012 Pearson Education, Inc.
31) CFC-11 (trichlorofluoromethane, CCl3F) has been used for many years as the working fluid in
refrigerators. Given its heat of vaporization is 26.88 kJ/mol and its entropy of vaporization is 90.51
J/(mol ∙ K), what is the boiling point of CFC-11?
A) -272.9°C
B) 0.297°C
C) 2.44°C
D) 23.8°C
Answer: D
Topic: Section 10.4 Phase Changes
32) How much heat is released when 75.0 g of steam at 100.0°C is cooled to ice at -15.0°C? The
enthalpy of vaporization of water is 40.67 kJ/mol, the enthalpy of fusion for water is 6.01 kJ/mol, the
molar heat capacity of liquid water is 75.4 J/(mol ∙ °C), and the molar heat capacity of ice is 36.4 J/(mol
∙ °C).
A) 54.8 kJ
B) 195 kJ
C) 228 kJ
D) 248 kJ
Answer: C
Topic: Section 10.4 Phase Changes
35) As a liquid evaporates at a temperature below its boiling point, the temperature of the liquid
A) decreases.
B) decreases at low temperatures, but increases at high temperatures.
C) increases.
D) remains unchanged.
Answer: A
Topic: Section 10.5 Evaporation, Vapor Pressure, and Boiling Point
7
Copyright © 2012 Pearson Education, Inc.
36) Molecules of a liquid can pass into the vapor phase only if the
A) liquid has little surface tension.
B) molecules have sufficient kinetic energy to overcome the intermolecular forces in the liquid.
C) temperature of the liquid is near its boiling point.
D) vapor pressure of the liquid is high.
Answer: B
Topic: Section 10.5 Evaporation, Vapor Pressure, and Boiling Point
39) Which of the following compounds has the highest boiling point?
A) H2O
B) HCl
C) H2S
D) NH3
Answer: A
Topic: Section 10.5 Evaporation, Vapor Pressure, and Boiling Point
40) Which of the following substances has the highest boiling point?
A) CH3-CH2-CH2-CH2-CH3
B) Xe
C) CH3-CH2-CH3
D) (CH3)4C
Answer: A
Topic: Section 10.5 Evaporation, Vapor Pressure, and Boiling Point
41) Which of the following compounds has the highest boiling point?
A) CH3CH2OH
B) HOCH2CH2OH
C) H3C-O-CH3
D) CH3CH2CH2CH3
Answer: B
Topic: Section 10.5 Evaporation, Vapor Pressure, and Boiling Point
8
Copyright © 2012 Pearson Education, Inc.
42) Arrange the following in order of increasing boiling point.
CH3CH2OH CH3CH2CH3 H3C-O-CH3 CH3CH2NH2
I II III IV
A) IV < III < II < I
B) II < III < IV < I
C) I < IV < III < II
D) II < III < I < IV
Answer: B
Topic: Section 10.5 Evaporation, Vapor Pressure, and Boiling Point
43) The normal boiling point for HBr is higher than the normal boiling point for HCl. This can be
explained by
A) larger dipole-dipole forces for HBr.
B) larger dispersion forces for HBr.
C) larger hydrogen-bond forces for HBr.
D) larger dipole-dipole forces, larger dispersion forces, and larger hydrogen-bond forces for HBr.
Answer: B
Topic: Section 10.5 Evaporation, Vapor Pressure, and Boiling Point
44) A kitchen pressure cooker operates at 1.50 atm. The ΔHvap of water is 40.7 kJ/mol. What is the
boiling point of water in the pressure cooker?
A) 362 K
B) 373 K
C) 385 K
D) 410 K
Answer: C
Topic: Section 10.5 Evaporation, Vapor Pressure, and Boiling Point
45) While mercury is very useful in barometers, mercury vapor is toxic. Given that mercury has a
ΔHvap of 59.11 kJ/mol and its normal boiling point is 356.7°C, calculate the vapor pressure in mm Hg
at room temperature, 25°C.
A) 2.68 × 10-3 mm Hg
B) 2.99 mm Hg
C) 372 mm Hg
D) 753 mm Hg
Answer: A
Topic: Section 10.5 Evaporation, Vapor Pressure, and Boiling Point
46) Hydroquinone is an antioxidant that is also used as a photographic reducer and developer. The
normal boiling point of hydroquinone is 310°C. Calculate the pressure at which hydroquinone will boil
at 200°C given that its ΔHvap is 73.38 kJ/mol.
A) 1.210 × 10-4 mm Hg
B) 1.35 mm Hg
C) 22.5 mm Hg
D) 757 mm Hg
Answer: C
Topic: Section 10.5 Evaporation, Vapor Pressure, and Boiling Point
9
Copyright © 2012 Pearson Education, Inc.
47) The vapor pressure of liquid chloroform, CHCl3, is 400.0 torr at 24.1°C and 100.0 torr at -6.3°C.
What is ΔHvap of chloroform?
A) 15.3 kJ/mol
B) 30.1 kJ/mol
C) 57.6 kJ/mol
D) 86.7 kJ/mol
Answer: B
Topic: Section 10.5 Evaporation, Vapor Pressure, and Boiling Point
51) Which of the following statements is not consistent with the properties of a molecular solid?
A) a compound that conducts electricity when molten
B) a low melting solid
C) a solid formed by the combination of two nonmetallic elements
D) a solid that is a nonconductor of electricity
Answer: A
Topic: Section 10.6 Kinds of Solids
57) The wavelength of light used to observe an object must be ________ than the object itself.
A) larger
B) smaller
C) of higher energy
D) of lower energy
Answer: B
Topic: Section 10.7 Probing the Structure of Solids: X-Ray Crystallography
11
Copyright © 2012 Pearson Education, Inc.
58) The structure of a solid can be determined by diffraction of radiation in which region of the
electromagnetic radiation spectrum?
A) infrared
B) microwave
C) visible
D) X-ray
Answer: D
Topic: Section 10.7 Probing the Structure of Solids: X-Ray Crystallography
59) How many atoms are in one face-centered cubic unit cell of a metal?
A) 1
B) 2
C) 3
D) 4
Answer: D
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids
60) How many atoms are in one body-centered cubic unit cell of a metal?
A) 1
B) 2
C) 3
D) 4
Answer: B
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids
61) When cubic unit cells stack together, how many unit cells share a common corner?
A) 2
B) 4
C) 6
D) 8
Answer: D
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids
62) How many unit cells share an atom that is on the face of a face-centered cubic unit cell?
A) 1
B) 2
C) 4
D) 8
Answer: B
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids
63) Which type of spherical packing has the most unused space?
A) body-centered cubic
B) cubic closest-packed
C) cubic closest-packed and hexagonal closest-packed
D) simple cubic
Answer: D
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids
12
Copyright © 2012 Pearson Education, Inc.
64) Iron crystallizes in a body-centered cubic cell having an edge length of 287 pm. What is the density
of iron in g/cm3.
A) 1.99
B) 7.85
C) 11.9
D) 15.9
Answer: B
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids
65) What is the edge length of a face-centered cubic unit cell made up of atoms having a radius of 175
pm?
A) 247 pm
B) 495 pm
C) 700 pm
D) 1400 pm
Answer: B
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids
66) Rhodium has a face-centered cubic structure and has a density of 12.4 g/cm3. What is its atomic
radius?
A) 134 pm
B) 268 pm
C) 380 pm
D) 1070 pm
Answer: A
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids
67) Silver crystallizes in a face-centered cubic structure. What is the edge length of the unit cell if the
atomic radius of silver is 144 pm?
A) 204 pm
B) 288 pm
C) 333 pm
D) 407 pm
Answer: D
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids
68) An element forms a body-centered cubic crystalline substance. The edge length of the unit cell is
287 pm and the density of the crystal is 7.92 g/cm3. Calculate the atomic weight of the substance.
A) 45.0 amu
B) 48.0 amu
C) 56.4 amu
D) 63.5 amu
Answer: C
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids
13
Copyright © 2012 Pearson Education, Inc.
69) Cesium has a radius of 272 pm and crystallizes in a face-centered cubic unit cell. What is the edge
length of the unit cell?
A) 314 pm
B) 385 pm
C) 544 pm
D) 769 pm
Answer: D
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids
70) Manganese crystallizes in a body-centered cubic structure. What is the coordination number of each
atom?
A) 4
B) 6
C) 8
D) 12
Answer: C
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids
72) The highest coordination number for spherical packing is found in the
A) body-centered cubic structure.
B) simple cubic structure.
C) body-centered cubic and face-centered cubic.
D) cubic closest-packing and hexagonal closest packing.
Answer: D
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids
73) KCl crystallizes in a cubic unit cell with Cl- ions on each corner and each face. How many K+ ions
and Cl- ions are in each unit cell of KCl?
A) 1 K+ ion and 1 Cl- ion
B) 2 K+ ions and 2 Cl- ions
C) 4 K+ ions and 4 Cl- ions
D) 8 K+ ions and 8 Cl- ions
Answer: C
Topic: Section 10.9 Structures of Some Ionic Solids
14
Copyright © 2012 Pearson Education, Inc.
74) An ionic compound crystallizes in a unit cell having a face-centered cubic array of anions, X–, and
half of the tetrahedral holes filled with metal ions, Mn+ The empirical formula of this ionic compound is
A) MX.
B) MX2.
C) M2X.
D) M2X7.
Answer: A
Topic: Section 10.9 Structures of Some Ionic Solids
75) An ionic compound crystallizes in a unit cell having a face-centered cubic array of metal ions, Mn+,
and all of the tetrahedral holes occupied by anions, X–. The empirical formula of this ionic compound is
A) MX.
B) MX2.
C) M2X.
D) M7X4.
Answer: B
Topic: Section 10.9 Structures of Some Ionic Solids
76) The edge length of a face-centered cubic lattice of NaCl is 564 pm. What is the density of NaCl in
g/cm3?
A) 0.720
B) 1.08
C) 2.16
D) 4.32
Answer: C
Topic: Section 10.9 Structures of Some Ionic Solids
77) How many Cl- ions are around each K+ ion in KCl, which has a cubic unit cell with Cl- ions on each
corner and each face?
A) 1
B) 4
C) 6
D) 8
Answer: C
Topic: Section 10.9 Structures of Some Ionic Solids
78) A binary ionic compound, MxAy, crystallizes in a cubic structure that contains eight anions (A)
entirely within its unit cell and a cation (M) on each corner and on each face. What is the empirical
formula of this compound?
A) MA
B) MA2
C) M2A
D) M4A8
Answer: B
Topic: Section 10.9 Structures of Some Ionic Solids
15
Copyright © 2012 Pearson Education, Inc.
79) O2 and O3 are ________ of oxygen.
A) allotropes
B) isomers
C) isotopes
D) stereomers
Answer: A
Topic: Section 10.10 Structures of Some Covalent Network Solids
16
Copyright © 2012 Pearson Education, Inc.
85) Which transition could occur if a solid is heated at a pressure below the triple point pressure?
A) condensation
B) deposition
C) melting
D) sublimation
Answer: D
Topic: Section 10.11 Phase Diagrams
86) Which transition could occur if a solid is heated at a pressure above the triple point pressure?
A) condensation
B) deposition
C) melting
D) sublimation
Answer: C
Topic: Section 10.11 Phase Diagrams
89) In the drawing of acetaldehyde, CH3CHO, the largest partial positive charge (δ+) occurs on
A) atom (a).
B) atom (b).
C) atom (c).
D) atom (d).
Answer: B
Topic: Conceptual Problems
17
Copyright © 2012 Pearson Education, Inc.
90) In the drawing of acetaldehyde, CH3CHO, the largest partial negative charge (δ -) occurs on
A) atom (a).
B) atom (b).
C) atom (c).
D) atom (d).
Answer: C
Topic: Conceptual Problems
91) In the drawing of acetic acid, CH3CO2H, a partial positive charge (δ+) occurs on
A) only atom (a).
B) only atom (b).
C) atoms (a) and (c).
D) atoms (b) and (d).
Answer: D
Topic: Conceptual Problems
92) In the drawing of acetic acid, CH3CO2H, a partial negative charge (δ-) occurs on
A) only atom (a).
B) only atom (b).
C) atoms (a) and (c).
D) atoms (b) and (d).
Answer: C
Topic: Conceptual Problems
18
Copyright © 2012 Pearson Education, Inc.
93) Which drawing best accounts for the polarity of water, H2O, and the bond polarities that make a
major contribution to the overall molecular polarity?
A) drawing (1)
B) drawing (2)
C) drawing (3)
D) drawing (4)
Answer: D
Topic: Conceptual Problems
19
Copyright © 2012 Pearson Education, Inc.
94) Which drawing best accounts for the polarity of methanol, CH3OH, and the bond polarities that
make a major contribution to the overall molecular polarity?
A) drawing (1)
B) drawing (2)
C) drawing (3)
D) drawing (4)
Answer: B
Topic: Conceptual Problems
20
Copyright © 2012 Pearson Education, Inc.
95) Which drawing best shows the molecular polarity of methylamine, CH3NH2, and the bond polarities
that make a major contribution to the overall molecular polarity?
A) drawing (1)
B) drawing (2)
C) drawing (3)
D) drawing (4)
Answer: A
Topic: Conceptual Problems
21
Copyright © 2012 Pearson Education, Inc.
96) Which drawing best shows the direction of the dipole moment in H2C=CCl2?
A) drawing (1)
B) drawing (2)
C) drawing (3)
D) drawing (4)
Answer: C
Topic: Conceptual Problems
22
Copyright © 2012 Pearson Education, Inc.
97) Which best indicates the direction of the dipole moment in formaldehyde, H2C=O?
A) drawing (1)
B) drawing (2)
C) drawing (3)
D) drawing (4)
Answer: C
Topic: Conceptual Problems
23
Copyright © 2012 Pearson Education, Inc.
98) Which best indicates the direction of the dipole moment in acetone, (CH3)2C=O?
A) drawing (1)
B) drawing (2)
C) drawing (3)
D) drawing (4)
Answer: B
Topic: Conceptual Problems
A) drawing (1)
B) drawing (2)
C) drawing (3)
D) drawing (4)
Answer: C
Topic: Conceptual Problems
24
Copyright © 2012 Pearson Education, Inc.
100) Which drawing below best represents hydrogen bonding methanol, CH3OH?
A) drawing (1)
B) drawing (2)
C) drawing (3)
D) drawing (4)
Answer: C
Topic: Conceptual Problems
25
Copyright © 2012 Pearson Education, Inc.
101) Which drawing best represents hydrogen bonding in methylamine, CH3NH2?
A) drawing (1)
B) drawing (2)
C) drawing (3)
D) drawing (4)
Answer: A
Topic: Conceptual Problems
102) If figure (1) represents the vapor pressure of water at 25°C, which figure represents the vapor
pressure of water at 45°C?
A) figure (2)
B) figure (3)
C) figure (4)
Answer: B
Topic: Conceptual Problems
26
Copyright © 2012 Pearson Education, Inc.
103) If figure (1) represents the vapor pressure of water at 25°C in a 1 liter container, which figure
represents the vapor pressure of water at 25°C in a 2 liter container?
A) figure (2)
B) figure (3)
C) figure (4)
Answer: B
Topic: Conceptual Problems
104) If figure (1) represents the vapor pressure of water at 25°C, which figure represents the vapor
pressure of ethanol, CH3CH2OH at 25°C?
A) figure (2)
B) figure (3)
C) figure (4)
Answer: B
Topic: Conceptual Problems
105) If figure (1) represents the vapor pressure of diethyl ether, CH3CH2OCH2CH3, at 25°C, which
figure represents the vapor pressure of ethanol at 25°C?
A) figure (2)
B) figure (3)
C) figure (4)
Answer: C
Topic: Conceptual Problems
27
Copyright © 2012 Pearson Education, Inc.
106) If figure (1) represents the vapor pressure of water, at 25°C, which figure represents the vapor
pressure of mercury at 25°C?
A) figure (2)
B) figure (3)
C) figure (4)
Answer: C
Topic: Conceptual Problems
The plots below represent vapor pressure vs. temperature curves for diethyl ether, ethanol, mercury, and
water, not necessarily in that order.
107) Based on the relative strengths of the intermolecular forces of attraction of each substance, which is
the most likely vapor pressure vs. temperature curve for diethyl ether?
A) curve (a)
B) curve (b)
C) curve (c)
D) curve (d)
Answer: A
Topic: Conceptual Problems
108) Based on the relative strengths of the intermolecular forces of attraction of each substance, which is
the most likely vapor pressure vs. temperature curve for ethanol?
A) curve (a)
B) curve (b)
C) curve (c)
D) curve (d)
Answer: B
Topic: Conceptual Problems
109) Based on the relative strengths of the intermolecular forces of attraction of each substance, which is
the most likely vapor pressure vs. temperature curve for mercury?
A) curve (a)
B) curve (b)
C) curve (c)
D) curve (d)
Answer: D
Topic: Conceptual Problems
28
Copyright © 2012 Pearson Education, Inc.
110) Based on the relative strengths of the intermolecular forces of attraction of each substance, which is
the most likely vapor pressure vs. temperature curve for water?
A) curve (a)
B) curve (b)
C) curve (c)
D) curve (d)
Answer: C
Topic: Conceptual Problems
111) From the plot of vapor pressure as a function of temperature shown below, the normal boiling point
for tert-butyl alcohol is approximately
A) 0°C.
B) 40°C.
C) 85°C.
D) 100°C.
Answer: C
Topic: Conceptual Problems
29
Copyright © 2012 Pearson Education, Inc.
The picture shown below represents a two-dimensional lattice of atoms M and X.
112) Which of the areas designated A, B, and C are smallest repeating units, analogous to two-
dimensional unit cells?
A) only A
B) only B
C) only C
D) A, B, or C
Answer: D
Topic: Conceptual Problems
A) body-centered cubic
B) cubic closest packed (face-centered cubic)
C) hexagonal closest packed
D) simple cubic
Answer: B
Topic: Conceptual Problems
30
Copyright © 2012 Pearson Education, Inc.
115) Identify the packing in the figure shown below.
A) body-centered cubic
B) cubic closest packed (face-centered cubic)
C) hexagonal closest packed
D) simple cubic
Answer: D
Topic: Conceptual Problems
A) body-centered cubic
B) cubic closest packed (face-centered cubic)
C) hexagonal closest packed
D) simple cubic
Answer: C
Topic: Conceptual Problems
A) body-centered cubic
B) cubic closest packed (face-centered cubic)
C) hexagonal closest packed
D) simple cubic
Answer: A
Topic: Conceptual Problems
31
Copyright © 2012 Pearson Education, Inc.
A certain mineral crystallizes in the cubic unit cell shown below.
119) How many cations and how many anions are in the unit cell?
A) 4 cations and 4 anions
B) 4 cations and 8 anions
C) 4 cations and 14 anions
D) 8 cations and 4 anions
Answer: A
Topic: Conceptual Problems
120) A certain mineral crystallizes in the cubic unit cell shown below. M represents the cations and A
represents the anions. What is the empirical formula of the mineral?
A) MA
B) MA2
C) M2A
D) M4A4
Answer: A
Topic: Conceptual Problems
32
Copyright © 2012 Pearson Education, Inc.
A certain mineral, MxM'yAz, crystallizes in the cubic unit cell shown below. M and M' represent cations
and A represents the anions.
124) If cation M has a 2+ charge and anion A has a 2- charge, what is the oxidation state of cation M'?
A) +1
B) +2
C) +3
D) +4
Answer: D
Topic: Conceptual Problems
33
Copyright © 2012 Pearson Education, Inc.
125) Consider a compound that undergoes sublimation at 125°C and a pressure of one atm. Which of the
following could be a heating curve appropriate for heating the compound from 100°C to 150°C?
A) graph a
B) graph b
C) graph c
D) graph d
Answer: B
Topic: Conceptual Problems
34
Copyright © 2012 Pearson Education, Inc.
Use the diagram below to answer the following questions.
128) The solid and liquid phases can exist in equilibrium along line
A) AC.
B) CB.
C) CD.
D) BD.
Answer: B
Topic: Conceptual Problems
129) The temperature and pressure at which all three phases can coexist in equilibrium is
A) 0.25 atm and 110°C.
B) 1.0 atm and 140°C.
C) 1.25 atm and 300°C.
D) 0.45 atm and 130°C.
Answer: D
Topic: Conceptual Problems
35
Copyright © 2012 Pearson Education, Inc.
130) From the phase diagram above, the minimum pressure at which this substance can exist in the
liquid phase is
A) 0.25 atm.
B) 0.45 atm.
C) 1.0 atm.
D) 1.2 atm.
Answer: B
Topic: Conceptual Problems
132) What phases can be present at 200°C and 0.75 atm pressure?
A) only the vapor phase
B) only the liquid phase
C) only the solid phase
D) both the solid and vapor phases
Answer: B
Topic: Conceptual Problems
133) What phase changes occur when the temperature is held constant at 140°C and the pressure is
increased from 0.25 atm to 1.4 atm?
A) gas → liquid → solid
B) gas → solid → liquid
C) liquid → solid → gas
D) solid → liquid → vapor
Answer: A
Topic: Conceptual Problems
134) What phase changes occur when the pressure is held constant at 0.25 atm and the temperature
increases from 100°C to 300°C?
A) liquid → gas
B) solid → gas
C) solid → liquid
D) solid → liquid → gas
Answer: B
Topic: Conceptual Problems
36
Copyright © 2012 Pearson Education, Inc.
The phase diagram of a substance is shown below.
137) What is the physical phase of the substance at T = 100 K and P = 0.1 atm?
A) gas
B) liquid
C) solid
D) supercritical fluid
Answer: C
Topic: Conceptual Problems
138) What is the physical phase of the substance at T = 225 K and P = 1.1 atm?
A) gas
B) liquid
C) solid
D) supercritical fluid
Answer: B
Topic: Conceptual Problems
37
Copyright © 2012 Pearson Education, Inc.
139) What is the physical phase of the substance at T = 400 K and P = 2.0 atm?
A) gas
B) liquid
C) solid
D) supercritical fluid
Answer: A
Topic: Conceptual Problems
38
Copyright © 2012 Pearson Education, Inc.
5) Which is expected to have the largest dispersion forces?
A) C3H8
B) C12H26
C) F2
D) Be Cl2
Answer: B
Topic: Section 10.2 Intermolecular Forces
9) Which of the following compounds exhibits only dispersion and dipole-dipole intermolecular
interactions?
A) H2
B) HI
C) CO2
D) CH3NH2
Answer: B
Topic: Section 10.2 Intermolecular Forces
39
Copyright © 2012 Pearson Education, Inc.
10) The normal boiling point for H2Te is higher than the normal boiling point for H2Se . This can be
explained by
A) larger dipole-dipole forces for H2Te .
B) larger dispersion forces for H2Te .
C) larger hydrogen-bond forces for H2Te .
D) larger dipole-dipole forces, larger dispersion forces, and larger hydrogen-bond forces for H2Te .
Answer: B
Topic: Section 10.2 Intermolecular Forces
11) Ethyl chloride, C2H5Cl, is used as a local anesthetic. It works by cooling tissue as it vaporizes; its
heat of vaporization is 26.4 kJ/mol. How much heat could be removed by 20.0 g of ethyl chloride?
A) 8.18 kJ
B) 341 kJ
C) 528 kJ
D) 3410 kJ
Answer: A
Topic: Section 10.4 Phase Changes
12) How much heat is released when 105 g of steam at 100.0°C is cooled to ice at -15.0°C? The
enthalpy of vaporization of water is 40.67 kJ/mol, the enthalpy of fusion for water is 6.01 kJ/mol, the
molar heat capacity of liquid water is 75.4 J/(mol ∙ °C), and the molar heat capacity of ice is 36.4 J/(mol
∙ °C).
A) 54.8 kJ
B) 273 kJ
C) 319 kJ
D) 347 kJ
Answer: C
Topic: Section 10.4 Phase Changes
40
Copyright © 2012 Pearson Education, Inc.
15) Which type of bonding does Sr form upon solidification?
A) covalent network
B) ionic
C) metallic
D) molecular
Answer: C
Topic: Section 10.6 Kinds of Solids
16) What is the edge length of a face-centered cubic unit cell made up of atoms having a radius of 128
pm?
A) 181 pm
B) 362 pm
C) 512 pm
D) 1020 pm
Answer: B
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids
17) Nickel has a face-centered cubic structure and has a density of 8.90 g/cm3. What is its atomic
radius?
A) 125 pm
B) 249 pm
C) 353 pm
D) 997 pm
Answer: A
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids
18) A certain metal crystallizes in a face-centered cubic structure. What is the edge length of the unit
cell if the atomic radius of the metal is 144 pm?
A) 204 pm
B) 288 pm
C) 333 pm
D) 407 pm
Answer: D
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids
19) Cesium has a radius of 272 pm and crystallizes in a body-centered cubic structure. What is the edge
length of the unit cell?
A) 314 pm
B) 385 pm
C) 544 pm
D) 628 pm
Answer: D
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids
41
Copyright © 2012 Pearson Education, Inc.
20) Lithium crystallizes in a body-centered cubic structure. What is the coordination number of each
atom?
A) 4
B) 6
C) 8
D) 12
Answer: C
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids
21) Na Cl crystallizes in a cubic unit cell with Cl- ions on each corner and each face. How many Na+
and Cl- ions are in each unit cell of Na Cl?
A) 1 Na+ ion and 1 Cl- ion
B) 2 Na+ ions and 2 Cl- ions
C) 4 Na+ ions and 4 Cl- ions
D) 8 Na+ ions and 8 Cl- ions
Answer: C
Topic: Section 10.9 Structures of Some Ionic Solids
22) How many H- ions are around each Na+ ion in NaH, which has a cubic unit cell with H- ions on
each corner and each face?
A) 1
B) 4
C) 6
D) 8
Answer: C
Topic: Section 10.9 Structures of Some Ionic Solids
2) In the molecule BF3 there is a δ+ charge on the ________ atom and a δ– charge on the ________
atom.
Answer: boron, fluorine
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments
3) LiH has an experimental dipole moment, μ = 6.00 D. If LiH were 100% ionic, the distance between
positive and negative charges would be 161 pm. What is the percent ionic character in the LiH bond?
Answer: 77.7%
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments
4) The Br-Cl bond has 5.05% ionic character and a dipole moment of 0.518 D. What is the distance
between atoms in BrCl?
Answer: 214 pm
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments
42
Copyright © 2012 Pearson Education, Inc.
5) The HBr bond has a length of 141 pm and 12.1% ionic character. What is the dipole moment of HBr?
Answer: 0.82 D
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments
6) Pt(NH3)2Cl2 is square planar. The isomer of Pt(NH3)2Cl2 that has a non-zero dipole moment has a
Cl-Pt-Cl bond angle of ________ degrees.
Answer: 90
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments
7) The intermolecular forces formed when NaCl is dissolved in water are ________ forces.
Answer: ion-dipole
Topic: Section 10.2 Intermolecular Forces
8) The intermolecular forces responsible for CH3CH2OH being at liquid at 20°C are ________ bonds.
Answer: hydrogen
Topic: Section 10.2 Intermolecular Forces
9) Helium can be liquefied when He atoms are attracted to one another by intermolecular ________
forces.
Answer: dispersion (or London dispersion)
Topic: Section 10.2 Intermolecular Forces
10) The property of a liquid that is a measure of the liquid’s resistance to increase its surface area is
________.
Answer: surface tension
Topic: Section 10.3 Some Properties of Liquids
11) Of C2H5OH and C3H5(OH)3 the one expected to have the higher viscosity is ________, and the
one expected to have the higher surface tension is ________.
Answer: C3H5(OH)3, C3H5(OH)3
Topic: Section 10.3 Some Properties of Liquids
12) The phase change H2(g) → H2(s) is called ________, and the enthalpy change, ΔH, for this phase
change has a ________ sign.
Answer: deposition, negative (–)
Topic: Section 10.4 Phase Changes
13) Of C2H5OH and C3H5(OH)3 the one expected to have the higher vapor pressure is ________, and
the one expected to have the higher boiling point is ________.
Answer: C2H5OH, C3H5(OH)3
Topic: Section 10.5 Evaporation, Vapor Pressure, and Boiling Point
14) The solids formed by K, K2O2, SiO2, and O2 are classified as ________, ________, ________, and
________, respectively.
Answer: metallic, ionic, covalent network, molecular
Topic: Section 10.6 Kinds of Solids
43
Copyright © 2012 Pearson Education, Inc.
15) Rubber is classified as an ________ solid, whereas diamond is classified as a ________ solid.
Answer: amorphous, covalent network
Topic: Section 10.6 Kinds of Solids
16) A low-melting crystalline compound that does not conduct electricity in the solid or liquid state is
classified as a ________ solid.
Answer: molecular
Topic: Section 10.6 Kinds of Solids
17) First-order diffraction of X-rays with d = 154.2 pm at an angle of 32.5° is caused by layers of atoms
in a crystalline solid with a spacing of ________ pm.
Answer: 143
Topic: Section 10.7 Probing the Structure of Solids: X-Ray Crystallography
18) Layers of atoms having a spacing of 105 pm will diffract X-rays with d = 154.2 pm at an angle of
________ degrees.
Answer: 47.2
Topic: Section 10.7 Probing the Structure of Solids: X-Ray Crystallography
19) The cubic closest-packed arrangement of atoms is the same as which cubic unit cell?
Answer: face-centered cubic
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids
20) The two most efficiently packed unit cells have the hexagonal closest-packed and the ________ the
atomic arrangements.
Answer: cubic closest-packed
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids
21) The coordination number of each atom in a simple cubic unit cell is ________.
Answer: 6
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids
22) The cubic unit cell in which the radius of an atom is 31/2 d/4, where d is the unit cell edge length, is
the ________ unit cell.
Answer: body-centered cubic
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids
23) A certain metal can exist in two different cubic cells, body-centered cubic and face-centered cubic.
Which unit cell will have the greater density?
Answer: face-centered
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids
24) Ni has a face-centered unit cell. The number of Ni atoms in the unit cell is ________.
Answer: four
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids
44
Copyright © 2012 Pearson Education, Inc.
25) A compound having A ions on each corner and B ions on each face of a cubic unit cell has the
empirical formula ________.
Answer: AB3
Topic: Section 10.9 Structures of Some Ionic Solids
45
Copyright © 2012 Pearson Education, Inc.
Another random document with
no related content on Scribd:
The Project Gutenberg eBook of Negerleben in
Ostafrika
This ebook is for the use of anyone anywhere in the United States
and most other parts of the world at no cost and with almost no
restrictions whatsoever. You may copy it, give it away or re-use it
under the terms of the Project Gutenberg License included with this
ebook or online at www.gutenberg.org. If you are not located in the
United States, you will have to check the laws of the country where
you are located before using this eBook.
Language: German
Credits: Peter Becker, Jude Eylander, Reiner Ruf, and the Online
Distributed Proofreading Team at https://www.pgdp.net
(This file was produced from images generously made
available by The Internet Archive)
Von
Zweite Auflage.
Leipzig:
F. A. Brockhaus.
1909.
Vorwort.
K. Weule.
Inhaltsverzeichnis.
Seite
Vo r w o r t V
Erstes Kapitel. Die Ausreise 1
Z w e i t e s K a p i t e l . Die Ziele 15
D r i t t e s K a p i t e l . Es kommt anders 30
V i e r t e s K a p i t e l . Lehrzeit an der Küste 42
F ü n f t e s K a p i t e l . Einmarsch ins Innere. Die ersten
Eindrücke 64
S e c h s t e s K a p i t e l . Umschau 87
S i e b e n t e s K a p i t e l . Einleben ins Volkstum 102
A c h t e s K a p i t e l . Marsch nach Süden. Meine Karawane 136
N e u n t e s K a p i t e l . Bei Matola 170
Z e h n t e s K a p i t e l . Mit und unter den Yao 194
E l f t e s K a p i t e l . Weitere Ergebnisse 238
Z w ö l f t e s K a p i t e l . Rovuma-Idyll und Zug ins Pori 254
D r e i z e h n t e s K a p i t e l . Unyago überall 283
V i e r z e h n t e s K a p i t e l . In voller Ernte 297
F ü n f z e h n t e s K a p i t e l . „Und will sich nimmer erschöpfen
und leeren“ 338
S e c h z e h n t e s K a p i t e l . Schlußzeit in Newala 388
S i e b z e h n t e s K a p i t e l . Wiederum zum Rovuma 405
A c h t z e h n t e s K a p i t e l . Die Meisterzeit 429
N e u n z e h n t e s K a p i t e l . Zur Küste zurück 477
Z w a n z i g s t e s K a p i t e l . Rückblick 495
Register 515
Abbildungen.
Seite
Karl Weule (Titelbild)
Kap Guardafui 1
Hafen von Daressalam 2
Eingeborenentanz in Daressalam 6
Straße im Eingeborenenviertel von Daressalam 10
Karte der großen Karawanenstraße.
Eingeborenenzeichnung 15
Dolcefarniente in einem Hofe von Daressalam 19
Im Europäerviertel von Daressalam 24
Bucht von Lindi 30
Dampfer Rufidyi. Eingeborenenzeichnung 32
Mündungsgebiet des Lukuledi oberhalb Lindi (Separatbild) 33
Reede von Lindi 37
Arabische Dhau. Eingeborenenzeichnung 41
Kettengefangene. Eingeborenenzeichnung 42
Seliman Mamba 45
Yao-Frauen von Mtua (Separatbild) 49
Mädchen aus Lindi 51
Tanz der Weiber in Daressalam 53
Alter portugiesischer Turm in Lindi 55
Unter Palmen 57
Die Ngoma Liquata. Eingeborenenzeichnung 64
Makua-Frauen aus dem Lukuledi-Tal (Separatbild) 65
Mueramann und Yao 67
Ruinen der Missionsstation Nyangao 71
Wamuerafrau 76
Muerajüngling 77
Muerafrau mit Unterlippenpflock 79
Lichte Baumgrassteppe mit Barra-barra (Separatbild) 80
Massassiberge. Eingeborenenzeichnung 87
Inselberg von Massassi 89
Unsere Mtandibesteigung. Eingeborenenzeichnung 95
Buschbrand auf dem Makonde-Plateau (bunte Tafel) 96
Wanyassa-Jäger mit Hund. Eingeborenenzeichnung 102
Studienbummel in der lichten Baumgrassteppe 107
Lager in Massassi 111
Am traulichen Herd. Hütteninneres in der Rovuma-Ebene
(Separatbild) 112
Taubenschlag und Speicher 120
Marschbereit vor Massassi 123
Rattenfalle 125
Antilopenfalle 127
Perlhuhnfalle 129
Falle für Großwild 129
Yaohütte 135
Meine Karawane auf dem Marsche.
Eingeborenenzeichnung 136
Yao-Gehöft in Chingulungulu (Separatbild) 136
Lager in Mwiti 142
Jalousie mit Swastika 147
Yaohäuptling Nakaam 149
Hofinneres in Mwiti 155
Ältere Makondefrau im Festschmuck (Separatbild) 160
Hüttentypus der Rovuma-Ebene 162
Hüttengrundriß 162