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Chemistry 6th Edition McMurry Test

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Chemistry, 6e (McMurry/Fay)
Chapter 10 Liquids, Solids, and Phase Changes

10.1 Multiple-Choice Questions

1) The bonds in the polyatomic ion CO32– are classified as


A) ionic
B) metallic
C) nonpolar covalent
D) polar covalent
Answer: D
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments

2) Which covalent bond is the most polar?


A) N F
B) C F
C) Cl F
D) F F
Answer: B
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments

3) Which has a dipole moment?


A) CO2
B) CO32–
C) SO2
D) SO42–
Answer: C
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments

4) Which of the following molecules does not have a dipole moment?


A) CH2=CH2
B) NH3
C) CH3NH2
D) HCl
Answer: A
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments

5) Which of the following should have the largest dipole moment?


A) H2(g)
B) CO2(g)
C) KCl(g)
D) CH3F(g)
Answer: C
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments

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6) The dipole moment of ClF is 0.88 D, and its bond length is 163 pm. What is the percent ionic
character of the Cl F bond?
A) 0.54%
B) 7.8%
C) 11%
D) 25%
Answer: C
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments

7) The dipole moment of BrF is 1.29 D, and its bond length is 178 pm. What is the percent ionic
character of the Br F bond?
A) 3.9%
B) 8.5%
C) 15%
D) 33%
Answer: C
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments

8) AgCl is found to have 78.1% ionic character, and its gas phase dipole moment is 11.5 D. What is the
distance between the Ag and Cl atoms in gaseous AgCl?
A) 9.19 x 10-10 pm
B) 14.7 pm
C) 307 pm
D) 903 pm
Answer: C
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments

9) Which compound, shown with its dipole moment, is expected to exhibit the smallest percent ionic
character?
A) HCl, 1.11 D
B) HF, 1.83 D
C) LiH,6.00 D
D) LiF, 6.28 D
Answer: A
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments

10) The HI bond has a length of 161 pm and 4.92% ionic character. What is the experimental dipole
moment of HI?
A) 0.380 D
B) 0.772 D
C) 3.80 D
D) 7.72 D
Answer: A
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments

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11) Which compound below could have a zero dipole moment?
A) CCl2F2 (tetrahedral)
B) CuCl2F2 (tetrahedral)
C) PtCl2F2 (square planar)
D) SCl2F2 (see-saw)
Answer: C
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments

12) Which has the smallest dipole-dipole forces?


A) CH3F
B) HCl
C) N2
D) CO
Answer: C
Topic: Section 10.2 Intermolecular Forces

13) Which of the following compounds exhibits hydrogen bonding?


A) CH3Cl
B) HI
C) H3C-O-CH3
D) NH3
Answer: D
Topic: Section 10.2 Intermolecular Forces

14) Which of the following exhibits ion-dipole forces?


A) NaCl(s)
B) NaCl(aq)
C) Na(s)
D) Cl2(g)
Answer: B
Topic: Section 10.2 Intermolecular Forces

15) Which is expected to have the largest dispersion forces?


A) C2H6
B) C8H18
C) N2
D) CO2
Answer: B
Topic: Section 10.2 Intermolecular Forces

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16) Which substance in each of the following pairs is expected to have the larger dispersion forces?

A) Br2 in set I and n-butane in set II


B) Br2 in set I and isobutane in set II
C) I2 in set I and n-butane in set II
D) I2 in set I and isobutane in set II
Answer: C
Topic: Section 10.2 Intermolecular Forces

17) Which of the following compounds exhibits only dispersion and dipole-dipole intermolecular
interactions?
A) N2
B) HBr
C) CO2
D) H2O
Answer: B
Topic: Section 10.2 Intermolecular Forces

18) In liquid methanol, CH3OH, which intermolecular forces are present?


A) Dispersion, hydrogen bonding and dipole-dipole forces are present.
B) Only dipole-dipole and ion-dipole forces are present.
C) Only dispersion and dipole-dipole forces are present.
D) Only hydrogen bonding forces are present.
Answer: A
Topic: Section 10.2 Intermolecular Forces

19) When a narrow diameter glass tube is inserted into a body of water, water rises in the tube and its
surface inside is concave upwards. Which statement, concerning the strength of the intermolecular
forces between glass and water molecules compared to those between water molecules, is accurate?
A) The forces of attraction between the glass and water are weaker than those in water.
B) The forces of attraction between the glass and water are stronger than those in water.
C) The forces of attraction between the glass and water are the same as those in water.
D) Intermolecular forces are irrelevant to this situation.
Answer: B
Topic: Section 10.3 Some Properties of Liquids

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20) Which of the intermolecular forces is the most important contributor to the high surface tension
shown by water?
A) dipole-dipole forces
B) dispersion forces
C) hydrogen bonding
D) ion-dipole forces
Answer: C
Topic: Section 10.3 Some Properties of Liquids

21) The property of a liquid that measure the liquid’s resistance to flow is
A) boiling point.
B) heat of vaporization.
C) surface tension.
D) viscosity.
Answer: D
Topic: Section 10.3 Some Properties of Liquids

22) Which of the following is most likely to have the highest viscosity at 25°C?
A) C4H10
B) HOCH2CH2OH
C) C8H18
D) C2H5NH2
Answer: B
Topic: Section 10.3 Some Properties of Liquids

23) Which is expected to have the highest surface tension at 25°?


A) C5H12
B) C6H6
C) C2H5OH
D) C3H5(OH)3
Answer: D
Topic: Section 10.3 Some Properties of Liquids

24) The magnitude of the heats of vaporization, fusion and sublimation of a substance reflect the
A) density of the substance.
B) magnitudes of the boiling and melting points of the substance.
C) strength of the covalent bonds between atoms in each molecule of the substance.
D) strength of the intermolecular forces of the substance.
Answer: D
Topic: Section 10.4 Phase Changes

25) For a particular compound, which is expected to be the largest in general?


A) the heat required to raise the temperature of one mole of the gas 10.0°C
B) the heat required to raise the temperature of one mole of the liquid 10.0°C
C) the molar heat of fusion at the normal melting point
D) the molar heat of vaporization at the normal boiling point
Answer: D
Topic: Section 10.4 Phase Changes
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26) Which of the following phase changes has a positive value for its entropy change?
A) boiling water
B) formation of raindrops from a cloud
C) making dry ice from gaseous CO2
D) making ice cubes from liquid water
Answer: A
Topic: Section 10.4 Phase Changes

27) For which of the following phase changes is the sign of ΔS negative?
A) boiling of water
B) formation of snow from water vapor in clouds
C) melting of ice cream
D) sublimation of I2
Answer: B
Topic: Section 10.4 Phase Changes

28) When a substance melts at its normal melting point, the sign of ΔH is ________ and the sign of ΔS
of this phase change is ________.
A) +, -
B) -, +
C) +, +
D) -, -
Answer: C
Topic: Section 10.4 Phase Changes

29) Ethyl chloride, C2H5Cl, is used as a local anesthetic. It works by cooling tissue as it vaporizes. The
heat of vaporization is 26.4 kJ/mol. How much heat could be removed by 10.0 g of ethyl chloride?
A) 4.09 kJ
B) 170 kJ
C) 264 kJ
D) 1700 kJ
Answer: A
Topic: Section 10.4 Phase Changes

30) Bromine is one of only two elements that is a liquid at room temperature. Bromine has a heat of
vaporization of 30.91 kJ/mol and its boiling point is 59°C. What is the entropy of vaporization for
bromine?
A) -301 J/(mol ∙ K)
B) -93.1 J/(mol ∙ K)
C) 10.7 J/(mol ∙ K)
D) 93.1 J/(mol ∙ K)
Answer: D
Topic: Section 10.4 Phase Changes

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31) CFC-11 (trichlorofluoromethane, CCl3F) has been used for many years as the working fluid in
refrigerators. Given its heat of vaporization is 26.88 kJ/mol and its entropy of vaporization is 90.51
J/(mol ∙ K), what is the boiling point of CFC-11?
A) -272.9°C
B) 0.297°C
C) 2.44°C
D) 23.8°C
Answer: D
Topic: Section 10.4 Phase Changes

32) How much heat is released when 75.0 g of steam at 100.0°C is cooled to ice at -15.0°C? The
enthalpy of vaporization of water is 40.67 kJ/mol, the enthalpy of fusion for water is 6.01 kJ/mol, the
molar heat capacity of liquid water is 75.4 J/(mol ∙ °C), and the molar heat capacity of ice is 36.4 J/(mol
∙ °C).
A) 54.8 kJ
B) 195 kJ
C) 228 kJ
D) 248 kJ
Answer: C
Topic: Section 10.4 Phase Changes

33) For the process: HNO3(g) ⇌ HNO3(l)


ΔH° is -39.04 kJ/mol and ΔS° is -111.74 J/(mol ∙ K). What is the normal boiling point of pure HNO3?
A) 2.86°C
B) 76.2°C
C) 270.3°C
D) 349.4°C
Answer: B
Topic: Section 10.4 Phase Changes

34) When a liquid is heated at its boiling point, the


A) covalent bonds are broken, allowing vaporization to occur.
B) temperature of the liquid increases.
C) temperature of the liquid remains the same as long as any liquid is present.
D) temperature of the vapor phase increases.
Answer: C
Topic: Section 10.4 Phase Changes

35) As a liquid evaporates at a temperature below its boiling point, the temperature of the liquid
A) decreases.
B) decreases at low temperatures, but increases at high temperatures.
C) increases.
D) remains unchanged.
Answer: A
Topic: Section 10.5 Evaporation, Vapor Pressure, and Boiling Point

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36) Molecules of a liquid can pass into the vapor phase only if the
A) liquid has little surface tension.
B) molecules have sufficient kinetic energy to overcome the intermolecular forces in the liquid.
C) temperature of the liquid is near its boiling point.
D) vapor pressure of the liquid is high.
Answer: B
Topic: Section 10.5 Evaporation, Vapor Pressure, and Boiling Point

37) The vapor pressure of a pure liquid increases as the


A) average kinetic energy of the molecules in the liquid phase decreases.
B) intermolecular attractive forces increase.
C) temperature of the liquid phase decreases.
D) temperature of the liquid phase increases.
Answer: D
Topic: Section 10.5 Evaporation, Vapor Pressure, and Boiling Point

38) The normal boiling point occurs when the


A) intermolecular forces within the liquid phase are broken.
B) temperature of the pure liquid equals the external temperature.
C) vapor pressure of a pure liquid equals an external pressure of one atmosphere.
D) vapor pressure of the liquid equals the external pressure.
Answer: C
Topic: Section 10.5 Evaporation, Vapor Pressure, and Boiling Point

39) Which of the following compounds has the highest boiling point?
A) H2O
B) HCl
C) H2S
D) NH3
Answer: A
Topic: Section 10.5 Evaporation, Vapor Pressure, and Boiling Point

40) Which of the following substances has the highest boiling point?
A) CH3-CH2-CH2-CH2-CH3
B) Xe
C) CH3-CH2-CH3
D) (CH3)4C
Answer: A
Topic: Section 10.5 Evaporation, Vapor Pressure, and Boiling Point

41) Which of the following compounds has the highest boiling point?
A) CH3CH2OH
B) HOCH2CH2OH
C) H3C-O-CH3
D) CH3CH2CH2CH3
Answer: B
Topic: Section 10.5 Evaporation, Vapor Pressure, and Boiling Point

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42) Arrange the following in order of increasing boiling point.
CH3CH2OH CH3CH2CH3 H3C-O-CH3 CH3CH2NH2
I II III IV
A) IV < III < II < I
B) II < III < IV < I
C) I < IV < III < II
D) II < III < I < IV
Answer: B
Topic: Section 10.5 Evaporation, Vapor Pressure, and Boiling Point

43) The normal boiling point for HBr is higher than the normal boiling point for HCl. This can be
explained by
A) larger dipole-dipole forces for HBr.
B) larger dispersion forces for HBr.
C) larger hydrogen-bond forces for HBr.
D) larger dipole-dipole forces, larger dispersion forces, and larger hydrogen-bond forces for HBr.
Answer: B
Topic: Section 10.5 Evaporation, Vapor Pressure, and Boiling Point

44) A kitchen pressure cooker operates at 1.50 atm. The ΔHvap of water is 40.7 kJ/mol. What is the
boiling point of water in the pressure cooker?
A) 362 K
B) 373 K
C) 385 K
D) 410 K
Answer: C
Topic: Section 10.5 Evaporation, Vapor Pressure, and Boiling Point

45) While mercury is very useful in barometers, mercury vapor is toxic. Given that mercury has a
ΔHvap of 59.11 kJ/mol and its normal boiling point is 356.7°C, calculate the vapor pressure in mm Hg
at room temperature, 25°C.
A) 2.68 × 10-3 mm Hg
B) 2.99 mm Hg
C) 372 mm Hg
D) 753 mm Hg
Answer: A
Topic: Section 10.5 Evaporation, Vapor Pressure, and Boiling Point

46) Hydroquinone is an antioxidant that is also used as a photographic reducer and developer. The
normal boiling point of hydroquinone is 310°C. Calculate the pressure at which hydroquinone will boil
at 200°C given that its ΔHvap is 73.38 kJ/mol.
A) 1.210 × 10-4 mm Hg
B) 1.35 mm Hg
C) 22.5 mm Hg
D) 757 mm Hg
Answer: C
Topic: Section 10.5 Evaporation, Vapor Pressure, and Boiling Point

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47) The vapor pressure of liquid chloroform, CHCl3, is 400.0 torr at 24.1°C and 100.0 torr at -6.3°C.
What is ΔHvap of chloroform?
A) 15.3 kJ/mol
B) 30.1 kJ/mol
C) 57.6 kJ/mol
D) 86.7 kJ/mol
Answer: B
Topic: Section 10.5 Evaporation, Vapor Pressure, and Boiling Point

48) Solids having no ordered long-range structure are classified as


A) amorphous
B) crystalline
C) metallic
D) molecular
Answer: A
Topic: Section 10.6 Kinds of Solids

49) Which is classified as an amorphous solid?


A) palladium(II) chloride
B) phosphorus tetrachloride
C) plastic
D) platinum
Answer: C
Topic: Section 10.6 Kinds of Solids

50) Which of the following forms a molecular solid?


A) CaO
B) C10H22
C) C(graphite)
D) gold
Answer: B
Topic: Section 10.6 Kinds of Solids

51) Which of the following statements is not consistent with the properties of a molecular solid?
A) a compound that conducts electricity when molten
B) a low melting solid
C) a solid formed by the combination of two nonmetallic elements
D) a solid that is a nonconductor of electricity
Answer: A
Topic: Section 10.6 Kinds of Solids

52) Which of the following forms an ionic solid?


A) Ag
B) C7H15NH2
C) RbI
D) SO3
Answer: C
Topic: Section 10.6 Kinds of Solids
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53) A crystalline solid of unknown origin forms an aqueous solution that conducts an electrical current.
The solid has a high melting point and shatters when struck with a hammer. The solid is likely to be
A) a covalent network solid.
B) an ionic solid.
C) a metallic solid.
D) a molecular solid.
Answer: B
Topic: Section 10.6 Kinds of Solids

54) Which of the following compounds forms a covalent network solid?


A) Li
B) C (diamond)
C) O2
D) CO2
Answer: B
Topic: Section 10.6 Kinds of Solids

55) Which of the following compounds forms a covalent network solid?


A) C8H18
B) NO2
C) SiO2
D) SnCl4
Answer: C
Topic: Section 10.6 Kinds of Solids

56) Which type of bonding does Mg form upon solidification?


A) covalent network
B) ionic
C) metallic
D) molecular
Answer: C
Topic: Section 10.6 Kinds of Solids

57) The wavelength of light used to observe an object must be ________ than the object itself.
A) larger
B) smaller
C) of higher energy
D) of lower energy
Answer: B
Topic: Section 10.7 Probing the Structure of Solids: X-Ray Crystallography

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58) The structure of a solid can be determined by diffraction of radiation in which region of the
electromagnetic radiation spectrum?
A) infrared
B) microwave
C) visible
D) X-ray
Answer: D
Topic: Section 10.7 Probing the Structure of Solids: X-Ray Crystallography

59) How many atoms are in one face-centered cubic unit cell of a metal?
A) 1
B) 2
C) 3
D) 4
Answer: D
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids

60) How many atoms are in one body-centered cubic unit cell of a metal?
A) 1
B) 2
C) 3
D) 4
Answer: B
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids

61) When cubic unit cells stack together, how many unit cells share a common corner?
A) 2
B) 4
C) 6
D) 8
Answer: D
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids

62) How many unit cells share an atom that is on the face of a face-centered cubic unit cell?
A) 1
B) 2
C) 4
D) 8
Answer: B
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids

63) Which type of spherical packing has the most unused space?
A) body-centered cubic
B) cubic closest-packed
C) cubic closest-packed and hexagonal closest-packed
D) simple cubic
Answer: D
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids

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64) Iron crystallizes in a body-centered cubic cell having an edge length of 287 pm. What is the density
of iron in g/cm3.
A) 1.99
B) 7.85
C) 11.9
D) 15.9
Answer: B
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids

65) What is the edge length of a face-centered cubic unit cell made up of atoms having a radius of 175
pm?
A) 247 pm
B) 495 pm
C) 700 pm
D) 1400 pm
Answer: B
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids

66) Rhodium has a face-centered cubic structure and has a density of 12.4 g/cm3. What is its atomic
radius?
A) 134 pm
B) 268 pm
C) 380 pm
D) 1070 pm
Answer: A
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids

67) Silver crystallizes in a face-centered cubic structure. What is the edge length of the unit cell if the
atomic radius of silver is 144 pm?
A) 204 pm
B) 288 pm
C) 333 pm
D) 407 pm
Answer: D
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids

68) An element forms a body-centered cubic crystalline substance. The edge length of the unit cell is
287 pm and the density of the crystal is 7.92 g/cm3. Calculate the atomic weight of the substance.
A) 45.0 amu
B) 48.0 amu
C) 56.4 amu
D) 63.5 amu
Answer: C
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids

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69) Cesium has a radius of 272 pm and crystallizes in a face-centered cubic unit cell. What is the edge
length of the unit cell?
A) 314 pm
B) 385 pm
C) 544 pm
D) 769 pm
Answer: D
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids

70) Manganese crystallizes in a body-centered cubic structure. What is the coordination number of each
atom?
A) 4
B) 6
C) 8
D) 12
Answer: C
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids

71) Cubic closest-packing


A) has a body-centered cubic unit cell.
B) has a face-centered cubic unit cell.
C) has a simple cubic unit cell.
D) has the same unit cell as hexagonal closest-packing.
Answer: B
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids

72) The highest coordination number for spherical packing is found in the
A) body-centered cubic structure.
B) simple cubic structure.
C) body-centered cubic and face-centered cubic.
D) cubic closest-packing and hexagonal closest packing.
Answer: D
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids

73) KCl crystallizes in a cubic unit cell with Cl- ions on each corner and each face. How many K+ ions
and Cl- ions are in each unit cell of KCl?
A) 1 K+ ion and 1 Cl- ion
B) 2 K+ ions and 2 Cl- ions
C) 4 K+ ions and 4 Cl- ions
D) 8 K+ ions and 8 Cl- ions
Answer: C
Topic: Section 10.9 Structures of Some Ionic Solids

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74) An ionic compound crystallizes in a unit cell having a face-centered cubic array of anions, X–, and
half of the tetrahedral holes filled with metal ions, Mn+ The empirical formula of this ionic compound is
A) MX.
B) MX2.
C) M2X.
D) M2X7.
Answer: A
Topic: Section 10.9 Structures of Some Ionic Solids

75) An ionic compound crystallizes in a unit cell having a face-centered cubic array of metal ions, Mn+,
and all of the tetrahedral holes occupied by anions, X–. The empirical formula of this ionic compound is
A) MX.
B) MX2.
C) M2X.
D) M7X4.
Answer: B
Topic: Section 10.9 Structures of Some Ionic Solids

76) The edge length of a face-centered cubic lattice of NaCl is 564 pm. What is the density of NaCl in
g/cm3?
A) 0.720
B) 1.08
C) 2.16
D) 4.32
Answer: C
Topic: Section 10.9 Structures of Some Ionic Solids

77) How many Cl- ions are around each K+ ion in KCl, which has a cubic unit cell with Cl- ions on each
corner and each face?
A) 1
B) 4
C) 6
D) 8
Answer: C
Topic: Section 10.9 Structures of Some Ionic Solids

78) A binary ionic compound, MxAy, crystallizes in a cubic structure that contains eight anions (A)
entirely within its unit cell and a cation (M) on each corner and on each face. What is the empirical
formula of this compound?
A) MA
B) MA2
C) M2A
D) M4A8
Answer: B
Topic: Section 10.9 Structures of Some Ionic Solids

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79) O2 and O3 are ________ of oxygen.
A) allotropes
B) isomers
C) isotopes
D) stereomers
Answer: A
Topic: Section 10.10 Structures of Some Covalent Network Solids

80) Which of the following is not an allotrope of carbon?


A) coal
B) diamond
C) fullerene
D) graphite
Answer: A
Topic: Section 10.10 Structures of Some Covalent Network Solids

81) The layers of graphite are held together by


A) covalent bonds.
B) dipole-dipole forces.
C) London dispersion forces.
D) All of these
Answer: C
Topic: Section 10.10 Structures of Some Covalent Network Solids

82) Diamond is held together by


A) covalent bonds.
B) dipole-dipole forces.
C) London dispersion forces.
D) All of these
Answer: A
Topic: Section 10.10 Structures of Some Covalent Network Solids

83) Pencil lead is actually


A) fullerene.
B) graphite.
C) lead.
D) silica.
Answer: B
Topic: Section 10.10 Structures of Some Covalent Network Solids

84) The critical temperature of a substance is the


A) highest temperature at which the liquid phase can exist in equilibrium with the gas phase.
B) temperature above which the compound decomposes.
C) temperature at which all three phases can exist in equilibrium.
D) temperature at which sublimation occurs.
Answer: A
Topic: Section 10.11 Phase Diagrams

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85) Which transition could occur if a solid is heated at a pressure below the triple point pressure?
A) condensation
B) deposition
C) melting
D) sublimation
Answer: D
Topic: Section 10.11 Phase Diagrams

86) Which transition could occur if a solid is heated at a pressure above the triple point pressure?
A) condensation
B) deposition
C) melting
D) sublimation
Answer: C
Topic: Section 10.11 Phase Diagrams

87) A supercritical fluid refers to a substance


A) above both its critical temperature and its critical pressure.
B) at its triple point.
C) that is in the liquid crystal state.
D) with a viscosity of zero.
Answer: A
Topic: Section 10.11 Phase Diagrams

88) The liquid crystal state


A) is a liquid in which the molecules tend to assume an overall orientation with respect to each other.
B) occurs when a supercritical fluid is rapidly cooled below the critical point.
C) occurs when an amorphous solid first begins to melt.
D) occurs when the first crystals form in the liquid during freezing.
Answer: A
Topic: Chapter 10 Interlude - Ionic Liquids

89) In the drawing of acetaldehyde, CH3CHO, the largest partial positive charge (δ+) occurs on
A) atom (a).
B) atom (b).
C) atom (c).
D) atom (d).
Answer: B
Topic: Conceptual Problems
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90) In the drawing of acetaldehyde, CH3CHO, the largest partial negative charge (δ -) occurs on
A) atom (a).
B) atom (b).
C) atom (c).
D) atom (d).
Answer: C
Topic: Conceptual Problems

91) In the drawing of acetic acid, CH3CO2H, a partial positive charge (δ+) occurs on
A) only atom (a).
B) only atom (b).
C) atoms (a) and (c).
D) atoms (b) and (d).
Answer: D
Topic: Conceptual Problems

92) In the drawing of acetic acid, CH3CO2H, a partial negative charge (δ-) occurs on
A) only atom (a).
B) only atom (b).
C) atoms (a) and (c).
D) atoms (b) and (d).
Answer: C
Topic: Conceptual Problems

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93) Which drawing best accounts for the polarity of water, H2O, and the bond polarities that make a
major contribution to the overall molecular polarity?

A) drawing (1)
B) drawing (2)
C) drawing (3)
D) drawing (4)
Answer: D
Topic: Conceptual Problems

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Copyright © 2012 Pearson Education, Inc.
94) Which drawing best accounts for the polarity of methanol, CH3OH, and the bond polarities that
make a major contribution to the overall molecular polarity?

A) drawing (1)
B) drawing (2)
C) drawing (3)
D) drawing (4)
Answer: B
Topic: Conceptual Problems

20
Copyright © 2012 Pearson Education, Inc.
95) Which drawing best shows the molecular polarity of methylamine, CH3NH2, and the bond polarities
that make a major contribution to the overall molecular polarity?

A) drawing (1)
B) drawing (2)
C) drawing (3)
D) drawing (4)
Answer: A
Topic: Conceptual Problems

21
Copyright © 2012 Pearson Education, Inc.
96) Which drawing best shows the direction of the dipole moment in H2C=CCl2?

A) drawing (1)
B) drawing (2)
C) drawing (3)
D) drawing (4)
Answer: C
Topic: Conceptual Problems

22
Copyright © 2012 Pearson Education, Inc.
97) Which best indicates the direction of the dipole moment in formaldehyde, H2C=O?

A) drawing (1)
B) drawing (2)
C) drawing (3)
D) drawing (4)
Answer: C
Topic: Conceptual Problems

23
Copyright © 2012 Pearson Education, Inc.
98) Which best indicates the direction of the dipole moment in acetone, (CH3)2C=O?

A) drawing (1)
B) drawing (2)
C) drawing (3)
D) drawing (4)
Answer: B
Topic: Conceptual Problems

99) Which drawing best represents hydrogen bonding?

A) drawing (1)
B) drawing (2)
C) drawing (3)
D) drawing (4)
Answer: C
Topic: Conceptual Problems

24
Copyright © 2012 Pearson Education, Inc.
100) Which drawing below best represents hydrogen bonding methanol, CH3OH?

A) drawing (1)
B) drawing (2)
C) drawing (3)
D) drawing (4)
Answer: C
Topic: Conceptual Problems

25
Copyright © 2012 Pearson Education, Inc.
101) Which drawing best represents hydrogen bonding in methylamine, CH3NH2?

A) drawing (1)
B) drawing (2)
C) drawing (3)
D) drawing (4)
Answer: A
Topic: Conceptual Problems

102) If figure (1) represents the vapor pressure of water at 25°C, which figure represents the vapor
pressure of water at 45°C?
A) figure (2)
B) figure (3)
C) figure (4)
Answer: B
Topic: Conceptual Problems

26
Copyright © 2012 Pearson Education, Inc.
103) If figure (1) represents the vapor pressure of water at 25°C in a 1 liter container, which figure
represents the vapor pressure of water at 25°C in a 2 liter container?

A) figure (2)
B) figure (3)
C) figure (4)
Answer: B
Topic: Conceptual Problems

104) If figure (1) represents the vapor pressure of water at 25°C, which figure represents the vapor
pressure of ethanol, CH3CH2OH at 25°C?
A) figure (2)
B) figure (3)
C) figure (4)
Answer: B
Topic: Conceptual Problems

105) If figure (1) represents the vapor pressure of diethyl ether, CH3CH2OCH2CH3, at 25°C, which
figure represents the vapor pressure of ethanol at 25°C?
A) figure (2)
B) figure (3)
C) figure (4)
Answer: C
Topic: Conceptual Problems

27
Copyright © 2012 Pearson Education, Inc.
106) If figure (1) represents the vapor pressure of water, at 25°C, which figure represents the vapor
pressure of mercury at 25°C?
A) figure (2)
B) figure (3)
C) figure (4)
Answer: C
Topic: Conceptual Problems

The plots below represent vapor pressure vs. temperature curves for diethyl ether, ethanol, mercury, and
water, not necessarily in that order.

107) Based on the relative strengths of the intermolecular forces of attraction of each substance, which is
the most likely vapor pressure vs. temperature curve for diethyl ether?
A) curve (a)
B) curve (b)
C) curve (c)
D) curve (d)
Answer: A
Topic: Conceptual Problems

108) Based on the relative strengths of the intermolecular forces of attraction of each substance, which is
the most likely vapor pressure vs. temperature curve for ethanol?
A) curve (a)
B) curve (b)
C) curve (c)
D) curve (d)
Answer: B
Topic: Conceptual Problems

109) Based on the relative strengths of the intermolecular forces of attraction of each substance, which is
the most likely vapor pressure vs. temperature curve for mercury?
A) curve (a)
B) curve (b)
C) curve (c)
D) curve (d)
Answer: D
Topic: Conceptual Problems

28
Copyright © 2012 Pearson Education, Inc.
110) Based on the relative strengths of the intermolecular forces of attraction of each substance, which is
the most likely vapor pressure vs. temperature curve for water?
A) curve (a)
B) curve (b)
C) curve (c)
D) curve (d)
Answer: C
Topic: Conceptual Problems

111) From the plot of vapor pressure as a function of temperature shown below, the normal boiling point
for tert-butyl alcohol is approximately

A) 0°C.
B) 40°C.
C) 85°C.
D) 100°C.
Answer: C
Topic: Conceptual Problems

29
Copyright © 2012 Pearson Education, Inc.
The picture shown below represents a two-dimensional lattice of atoms M and X.

112) Which of the areas designated A, B, and C are smallest repeating units, analogous to two-
dimensional unit cells?
A) only A
B) only B
C) only C
D) A, B, or C
Answer: D
Topic: Conceptual Problems

113) What is the formula of the compound formed from M and X?


A) MX
B) MX2
C) MX3
D) MX4
Answer: A
Topic: Conceptual Problems

114) Identify the packing in the figure shown below.

A) body-centered cubic
B) cubic closest packed (face-centered cubic)
C) hexagonal closest packed
D) simple cubic
Answer: B
Topic: Conceptual Problems

30
Copyright © 2012 Pearson Education, Inc.
115) Identify the packing in the figure shown below.

A) body-centered cubic
B) cubic closest packed (face-centered cubic)
C) hexagonal closest packed
D) simple cubic
Answer: D
Topic: Conceptual Problems

116) Identify the packing in the figure shown below.

A) body-centered cubic
B) cubic closest packed (face-centered cubic)
C) hexagonal closest packed
D) simple cubic
Answer: C
Topic: Conceptual Problems

117) Identify the packing in the figure shown below.

A) body-centered cubic
B) cubic closest packed (face-centered cubic)
C) hexagonal closest packed
D) simple cubic
Answer: A
Topic: Conceptual Problems

31
Copyright © 2012 Pearson Education, Inc.
A certain mineral crystallizes in the cubic unit cell shown below.

118) What kind of packing do the anions adopt?


A) body-centered cubic
B) cubic closest packed (face-centered cubic)
C) hexagonal closest packed
D) simple cubic
Answer: B
Topic: Conceptual Problems

119) How many cations and how many anions are in the unit cell?
A) 4 cations and 4 anions
B) 4 cations and 8 anions
C) 4 cations and 14 anions
D) 8 cations and 4 anions
Answer: A
Topic: Conceptual Problems

120) A certain mineral crystallizes in the cubic unit cell shown below. M represents the cations and A
represents the anions. What is the empirical formula of the mineral?

A) MA
B) MA2
C) M2A
D) M4A4
Answer: A
Topic: Conceptual Problems

32
Copyright © 2012 Pearson Education, Inc.
A certain mineral, MxM'yAz, crystallizes in the cubic unit cell shown below. M and M' represent cations
and A represents the anions.

121) How many cations M are in the unit cell?


A) 1
B) 2
C) 4
D) 8
Answer: A
Topic: Conceptual Problems

122) How many anions are in the unit cell?


A) 1
B) 2
C) 3
D) 6
Answer: C
Topic: Conceptual Problems

123) What is the empirical formula of the mineral?


A) MM'A
B) MM'A3
C) M2M'A3
D) M8M'A6
Answer: B
Topic: Conceptual Problems

124) If cation M has a 2+ charge and anion A has a 2- charge, what is the oxidation state of cation M'?
A) +1
B) +2
C) +3
D) +4
Answer: D
Topic: Conceptual Problems

33
Copyright © 2012 Pearson Education, Inc.
125) Consider a compound that undergoes sublimation at 125°C and a pressure of one atm. Which of the
following could be a heating curve appropriate for heating the compound from 100°C to 150°C?

A) graph a
B) graph b
C) graph c
D) graph d
Answer: B
Topic: Conceptual Problems

34
Copyright © 2012 Pearson Education, Inc.
Use the diagram below to answer the following questions.

126) According to the diagram, the solid phase of this substance


A) has the same density as the liquid phase.
B) is less dense than water.
C) is less dense than the liquid phase.
D) is more dense than the liquid phase.
Answer: D
Topic: Conceptual Problems

127) Melting occurs along the


A) AC line.
B) CB line.
C) CD line.
D) All of these
Answer: B
Topic: Conceptual Problems

128) The solid and liquid phases can exist in equilibrium along line
A) AC.
B) CB.
C) CD.
D) BD.
Answer: B
Topic: Conceptual Problems

129) The temperature and pressure at which all three phases can coexist in equilibrium is
A) 0.25 atm and 110°C.
B) 1.0 atm and 140°C.
C) 1.25 atm and 300°C.
D) 0.45 atm and 130°C.
Answer: D
Topic: Conceptual Problems
35
Copyright © 2012 Pearson Education, Inc.
130) From the phase diagram above, the minimum pressure at which this substance can exist in the
liquid phase is
A) 0.25 atm.
B) 0.45 atm.
C) 1.0 atm.
D) 1.2 atm.
Answer: B
Topic: Conceptual Problems

131) The normal boiling point of this substance is approximately


A) 25°C.
B) 140°C.
C) 300°C.
D) 350°C.
Answer: C
Topic: Conceptual Problems

132) What phases can be present at 200°C and 0.75 atm pressure?
A) only the vapor phase
B) only the liquid phase
C) only the solid phase
D) both the solid and vapor phases
Answer: B
Topic: Conceptual Problems

133) What phase changes occur when the temperature is held constant at 140°C and the pressure is
increased from 0.25 atm to 1.4 atm?
A) gas → liquid → solid
B) gas → solid → liquid
C) liquid → solid → gas
D) solid → liquid → vapor
Answer: A
Topic: Conceptual Problems

134) What phase changes occur when the pressure is held constant at 0.25 atm and the temperature
increases from 100°C to 300°C?
A) liquid → gas
B) solid → gas
C) solid → liquid
D) solid → liquid → gas
Answer: B
Topic: Conceptual Problems

36
Copyright © 2012 Pearson Education, Inc.
The phase diagram of a substance is shown below.

135) The approximate normal boiling point of this substance is


A) 180 K.
B) 190 K.
C) 300 K.
D) 430 K.
Answer: C
Topic: Conceptual Problems

136) The approximate normal melting point of this substance is


A) 100 K.
B) 190 K.
C) 300 K.
D) 430 K.
Answer: B
Topic: Conceptual Problems

137) What is the physical phase of the substance at T = 100 K and P = 0.1 atm?
A) gas
B) liquid
C) solid
D) supercritical fluid
Answer: C
Topic: Conceptual Problems

138) What is the physical phase of the substance at T = 225 K and P = 1.1 atm?
A) gas
B) liquid
C) solid
D) supercritical fluid
Answer: B
Topic: Conceptual Problems

37
Copyright © 2012 Pearson Education, Inc.
139) What is the physical phase of the substance at T = 400 K and P = 2.0 atm?
A) gas
B) liquid
C) solid
D) supercritical fluid
Answer: A
Topic: Conceptual Problems

10.2 Algorithmic Questions

1) Which covalent bond is the most polar?


A) N- F
B) C- F
C) Cl- F
D) F- F
Answer: B
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments

2) Which of the following should have the largest dipole moment?


A) F2(g)
B) BCl3(g)
C) KBr(g)
D) CH3I(g)
Answer: C
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments

3) Which of the following molecules does not have a dipole moment?


A) C2H2
B) H2O
C) CH3CH2OH
D) H I
Answer: A
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments

4) Which has the smallest dipole-dipole forces?


A) CH3Cl
B) HBr
C) O2
D) NO
Answer: C
Topic: Section 10.2 Intermolecular Forces

38
Copyright © 2012 Pearson Education, Inc.
5) Which is expected to have the largest dispersion forces?
A) C3H8
B) C12H26
C) F2
D) Be Cl2
Answer: B
Topic: Section 10.2 Intermolecular Forces

6) Which of the following compounds exhibits hydrogen bonding?


A) CH3Cl
B) HI
C) CH3OCH3
D) NH3
Answer: D
Topic: Section 10.2 Intermolecular Forces

7) Which of the following compounds has the highest boiling point?


A) H2O
B) H Cl
C) H2S
D) N H3
Answer: A
Topic: Section 10.2 Intermolecular Forces

8) In liquid propanol, CH3CH2CH2OH, which intermolecular forces are present?


A) Dispersion, hydrogen bonding and dipole-dipole forces are present.
B) Only dipole-dipole and ion-dipole forces are present.
C) Only dispersion and dipole-dipole forces are present.
D) Only hydrogen bonding forces are present.
Answer: A
Topic: Section 10.2 Intermolecular Forces

9) Which of the following compounds exhibits only dispersion and dipole-dipole intermolecular
interactions?
A) H2
B) HI
C) CO2
D) CH3NH2
Answer: B
Topic: Section 10.2 Intermolecular Forces

39
Copyright © 2012 Pearson Education, Inc.
10) The normal boiling point for H2Te is higher than the normal boiling point for H2Se . This can be
explained by
A) larger dipole-dipole forces for H2Te .
B) larger dispersion forces for H2Te .
C) larger hydrogen-bond forces for H2Te .
D) larger dipole-dipole forces, larger dispersion forces, and larger hydrogen-bond forces for H2Te .
Answer: B
Topic: Section 10.2 Intermolecular Forces

11) Ethyl chloride, C2H5Cl, is used as a local anesthetic. It works by cooling tissue as it vaporizes; its
heat of vaporization is 26.4 kJ/mol. How much heat could be removed by 20.0 g of ethyl chloride?
A) 8.18 kJ
B) 341 kJ
C) 528 kJ
D) 3410 kJ
Answer: A
Topic: Section 10.4 Phase Changes

12) How much heat is released when 105 g of steam at 100.0°C is cooled to ice at -15.0°C? The
enthalpy of vaporization of water is 40.67 kJ/mol, the enthalpy of fusion for water is 6.01 kJ/mol, the
molar heat capacity of liquid water is 75.4 J/(mol ∙ °C), and the molar heat capacity of ice is 36.4 J/(mol
∙ °C).
A) 54.8 kJ
B) 273 kJ
C) 319 kJ
D) 347 kJ
Answer: C
Topic: Section 10.4 Phase Changes

13) Which of the following forms a molecular solid?


A) NH4NO3
B) C6H4Cl2
C) SiO2
D) copper
Answer: B
Topic: Section 10.6 Kinds of Solids

14) Which of the following forms an ionic solid?


A) Ag
B) C7H15NH2
C) Rb I
D) S O3
Answer: C
Topic: Section 10.6 Kinds of Solids

40
Copyright © 2012 Pearson Education, Inc.
15) Which type of bonding does Sr form upon solidification?
A) covalent network
B) ionic
C) metallic
D) molecular
Answer: C
Topic: Section 10.6 Kinds of Solids

16) What is the edge length of a face-centered cubic unit cell made up of atoms having a radius of 128
pm?
A) 181 pm
B) 362 pm
C) 512 pm
D) 1020 pm
Answer: B
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids

17) Nickel has a face-centered cubic structure and has a density of 8.90 g/cm3. What is its atomic
radius?
A) 125 pm
B) 249 pm
C) 353 pm
D) 997 pm
Answer: A
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids

18) A certain metal crystallizes in a face-centered cubic structure. What is the edge length of the unit
cell if the atomic radius of the metal is 144 pm?
A) 204 pm
B) 288 pm
C) 333 pm
D) 407 pm
Answer: D
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids

19) Cesium has a radius of 272 pm and crystallizes in a body-centered cubic structure. What is the edge
length of the unit cell?
A) 314 pm
B) 385 pm
C) 544 pm
D) 628 pm
Answer: D
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids

41
Copyright © 2012 Pearson Education, Inc.
20) Lithium crystallizes in a body-centered cubic structure. What is the coordination number of each
atom?
A) 4
B) 6
C) 8
D) 12
Answer: C
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids

21) Na Cl crystallizes in a cubic unit cell with Cl- ions on each corner and each face. How many Na+
and Cl- ions are in each unit cell of Na Cl?
A) 1 Na+ ion and 1 Cl- ion
B) 2 Na+ ions and 2 Cl- ions
C) 4 Na+ ions and 4 Cl- ions
D) 8 Na+ ions and 8 Cl- ions
Answer: C
Topic: Section 10.9 Structures of Some Ionic Solids

22) How many H- ions are around each Na+ ion in NaH, which has a cubic unit cell with H- ions on
each corner and each face?
A) 1
B) 4
C) 6
D) 8
Answer: C
Topic: Section 10.9 Structures of Some Ionic Solids

10.3 Short Answer Questions

1) The bonds in the polyatomic ion NO3– are classified as ________.


Answer: polar covalent.
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments

2) In the molecule BF3 there is a δ+ charge on the ________ atom and a δ– charge on the ________
atom.
Answer: boron, fluorine
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments

3) LiH has an experimental dipole moment, μ = 6.00 D. If LiH were 100% ionic, the distance between
positive and negative charges would be 161 pm. What is the percent ionic character in the LiH bond?
Answer: 77.7%
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments

4) The Br-Cl bond has 5.05% ionic character and a dipole moment of 0.518 D. What is the distance
between atoms in BrCl?
Answer: 214 pm
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments

42
Copyright © 2012 Pearson Education, Inc.
5) The HBr bond has a length of 141 pm and 12.1% ionic character. What is the dipole moment of HBr?
Answer: 0.82 D
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments

6) Pt(NH3)2Cl2 is square planar. The isomer of Pt(NH3)2Cl2 that has a non-zero dipole moment has a
Cl-Pt-Cl bond angle of ________ degrees.
Answer: 90
Topic: Section 10.1 Polar Covalent Bonds and Dipole Moments

7) The intermolecular forces formed when NaCl is dissolved in water are ________ forces.
Answer: ion-dipole
Topic: Section 10.2 Intermolecular Forces

8) The intermolecular forces responsible for CH3CH2OH being at liquid at 20°C are ________ bonds.
Answer: hydrogen
Topic: Section 10.2 Intermolecular Forces

9) Helium can be liquefied when He atoms are attracted to one another by intermolecular ________
forces.
Answer: dispersion (or London dispersion)
Topic: Section 10.2 Intermolecular Forces

10) The property of a liquid that is a measure of the liquid’s resistance to increase its surface area is
________.
Answer: surface tension
Topic: Section 10.3 Some Properties of Liquids

11) Of C2H5OH and C3H5(OH)3 the one expected to have the higher viscosity is ________, and the
one expected to have the higher surface tension is ________.
Answer: C3H5(OH)3, C3H5(OH)3
Topic: Section 10.3 Some Properties of Liquids

12) The phase change H2(g) → H2(s) is called ________, and the enthalpy change, ΔH, for this phase
change has a ________ sign.
Answer: deposition, negative (–)
Topic: Section 10.4 Phase Changes

13) Of C2H5OH and C3H5(OH)3 the one expected to have the higher vapor pressure is ________, and
the one expected to have the higher boiling point is ________.
Answer: C2H5OH, C3H5(OH)3
Topic: Section 10.5 Evaporation, Vapor Pressure, and Boiling Point

14) The solids formed by K, K2O2, SiO2, and O2 are classified as ________, ________, ________, and
________, respectively.
Answer: metallic, ionic, covalent network, molecular
Topic: Section 10.6 Kinds of Solids

43
Copyright © 2012 Pearson Education, Inc.
15) Rubber is classified as an ________ solid, whereas diamond is classified as a ________ solid.
Answer: amorphous, covalent network
Topic: Section 10.6 Kinds of Solids

16) A low-melting crystalline compound that does not conduct electricity in the solid or liquid state is
classified as a ________ solid.
Answer: molecular
Topic: Section 10.6 Kinds of Solids

17) First-order diffraction of X-rays with d = 154.2 pm at an angle of 32.5° is caused by layers of atoms
in a crystalline solid with a spacing of ________ pm.
Answer: 143
Topic: Section 10.7 Probing the Structure of Solids: X-Ray Crystallography

18) Layers of atoms having a spacing of 105 pm will diffract X-rays with d = 154.2 pm at an angle of
________ degrees.
Answer: 47.2
Topic: Section 10.7 Probing the Structure of Solids: X-Ray Crystallography

19) The cubic closest-packed arrangement of atoms is the same as which cubic unit cell?
Answer: face-centered cubic
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids

20) The two most efficiently packed unit cells have the hexagonal closest-packed and the ________ the
atomic arrangements.
Answer: cubic closest-packed
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids

21) The coordination number of each atom in a simple cubic unit cell is ________.
Answer: 6
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids

22) The cubic unit cell in which the radius of an atom is 31/2 d/4, where d is the unit cell edge length, is
the ________ unit cell.
Answer: body-centered cubic
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids

23) A certain metal can exist in two different cubic cells, body-centered cubic and face-centered cubic.
Which unit cell will have the greater density?
Answer: face-centered
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids

24) Ni has a face-centered unit cell. The number of Ni atoms in the unit cell is ________.
Answer: four
Topic: Section 10.8 Unit Cells & Packing of Spheres in Crystalline Solids

44
Copyright © 2012 Pearson Education, Inc.
25) A compound having A ions on each corner and B ions on each face of a cubic unit cell has the
empirical formula ________.
Answer: AB3
Topic: Section 10.9 Structures of Some Ionic Solids

45
Copyright © 2012 Pearson Education, Inc.
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The Project Gutenberg eBook of Negerleben in
Ostafrika
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Title: Negerleben in Ostafrika


Ergebnisse einer Ethnologischen Forschungsreise

Author: Karl Weule

Release date: November 14, 2023 [eBook #72124]

Language: German

Original publication: Leipzig: F. A. Brockhaus, 1909

Credits: Peter Becker, Jude Eylander, Reiner Ruf, and the Online
Distributed Proofreading Team at https://www.pgdp.net
(This file was produced from images generously made
available by The Internet Archive)

*** START OF THE PROJECT GUTENBERG EBOOK


NEGERLEBEN IN OSTAFRIKA ***
Anmerkungen zur Transkription
Der vorliegende Text wurde anhand der Buchausgabe von 1909 so weit wie möglich
originalgetreu wiedergegeben. Typographische Fehler wurden stillschweigend korrigiert.
Ungewöhnliche und heute nicht mehr verwendete Schreibweisen bleiben gegenüber dem
Original unverändert; fremdsprachliche Ausdrücke wurden nicht korrigiert.
In der im Original gewählten Frakturschrift wird nicht zwischen den Großbuchstaben ‚I‘
und ‚J‘ unterschieden. Zur Übertragung in die heute üblichen Antiquaschriftarten wurden
aber im Register die Einträge getrennt nach den beiden Anfangsbuchstaben aufgeführt.
Das Original wurde in Frakturschrift gesetzt. Passagen in Antiquaschrift werden hier
kursiv wiedergegeben. Abhängig von der im jeweiligen Lesegerät installierten Schriftart
können die im Original g e s p e r r t gedruckten Passagen gesperrt, in serifenloser Schrift,
oder aber sowohl serifenlos als auch gesperrt erscheinen.
In einigen Lesegeräten ist es zurzeit nicht möglich, Tondateien direkt abzuspielen oder
Daten in MusicXML-Format herunterzuladen. Aufgrund der stets fortschreitenden
technischen Entwicklungen wurde diese Möglichkeit hier dennoch vorgesehen, um solche
zukünftigen Funktionen der Endgeräte zu unterstützen.
Negerleben in Ostafrika.
Negerleben in Ostafrika.
Ergebnisse einer ethnologischen Forschungsreise.

Von

Dr. Karl Weule


Professor an der Universität und Direktor des Museums für Völkerkunde in
Leipzig.

Mit 196 Abbildungen, darunter 4 bunte Vollbilder, und einer Karte.

Zweite Auflage.

Leipzig:
F. A. Brockhaus.
1909.
Vorwort.

O„ rt, Datum, Adresse, kurz, ein Briefkopf — also die üblichen


Reisebriefe!“ Gemach, mein Herr oder meine Gnädigste! Schon
zwischen Brief und Brief besteht, trotzdem er heute den Charakter
des Kunstwerks längst verloren hat, ein Unterschied; um wieviel
mehr beim Reisebrief, dessen Form und Inhalt in ungleich höherem
Grade durch die Umstände, aus denen heraus er entsteht, bedingt
werden. Ehrlich will ich zudem — falls die Briefform nun einmal ein
Verbrechen ist — gestehen, daß die Kapitel dieses Buches ihre
jetzige Form erst in Leipzig angenommen haben. Meine Reise
besaß auf Grund ihrer besonderen Ziele auch einen ganz
besonderen Charakter. Ich sollte den Menschen erforschen, sollte in
den Sitten und Gebräuchen, den Erzählungen und Mythen die
Negerpsyche ergründen. Das bedingte einen unausgesetzten,
innigen Verkehr mit den schwarzen Leuten. Masumgumso nennt der
Suaheli die Tätigkeit, die ich ein halbes Jahr hindurch getrieben
habe; unsere Wörterbücher übersetzen das mit „Unterhaltung“. Das
trifft den Sinn meines Masumgumso nur so obenhin; dieses hatte
stets den ernsten Hintergrund der wissenschaftlichen Forschung,
nicht den des Zeitvertreibs. Maneno, Worte, waren es gleichwohl,
aus denen es sich zusammensetzte. Kann nur der Leser eine
geeignetere Form der Darstellung nennen als die von mir gewählte,
die die gesamten Eindrücke eines bestimmten, soeben zum
Abschluß gelangten Zeitraumes noch gänzlich unverwischt, dabei
jedoch harmonisch ineinander verarbeitet und wissenschaftlich
vollkommen verwertbar wiedergibt, ohne dabei in das trockne
Einerlei des Tagebuches zu verfallen?
Meine Ostafrikareise liegt bereits um mehr als ein Jahr zurück;
eine Unsumme von Berufsgeschäften hat mich an der sofortigen
Herausgabe meiner Eindrücke gehindert. Der drohenden Gefahr des
Verblassens dieser Eindrücke bin ich dadurch begegnet, daß ich
über die Geschehnisse und Ergebnisse jener Reise genau Buch
geführt, ja, wo es die Zeit zuließ, sogar Wortlaut und Tonfall des
Masumgumso schriftlich festgehalten habe. Vieles habe ich
gleichzeitig an Verwandte und Freunde berichtet, besonders an den
trefflichen Alfred Kirchhoff, den ich leider nicht mehr wiedersehen
sollte. Bei meiner Rückkehr am letzten Januar 1907 war er bereits
schwer krank; am 8. Februar ist er verschieden.
Aus meinen gewissenhaften Aufzeichnungen habe ich das
jetzige Buch zu komponieren vermocht, ohne den einzelnen
Auftritten im Busch und im Urwald, auf dem Marsch und im
Negerdorf Gewalt anzutun, und ohne die Milieustimmung zu
verderben. Das ist wichtig, gerade bei jenen einzelnen Bausteinen,
aus denen das große Gebäude der Wissenschaft vom Menschen
von vielen Mitarbeitern nach und nach errichtet werden soll.
Weltbewegende Ereignisse bleiben dem Negerleben im allgemeinen
vorenthalten; da macht die Stimmung, aus der das kleine
Geschehnis geboren wird, alles. Daß ich sie i m m e r getroffen hätte,
möchte ich nicht behaupten; im großen und ganzen wird der Leser
indes mit mir zufrieden sein können; mir persönlich steigen jedenfalls
beim Lesen meiner Zeilen alle die seltsamen Szenen, deren Zeuge
ich gewesen bin, wieder mit einer Deutlichkeit vor das Auge, als
hätte ich erst gestern vom dunkeln Weltteil Abschied genommen.
Zum nicht geringen Teil verdanken wir die Anschaulichkeit
unseren modernen Forschungsmitteln. Die photographische Kamera
ist freilich nicht mehr neu, doch bewährt auch sie sich noch immer,
sogar weit besser, will mich dünken, als in der Hand der Reisenden
früherer Jahrzehnte. Das bringen die feinen Objektive und die guten
Platten mit sich. Auf meine mehr als tausend tadellosen Aufnahmen
von Land und Leuten irgendwie stolz zu sein, habe ich darum
keinerlei Ursache.
Neuer ist schon der Phonograph, und kaum erst in die exotische
Völkerforschung eingeführt der Kinematograph. Die Leistungen der
Sprech- und Singmaschine haben den Vorzug, auch den Lesern
eines Buches zu Gesicht und zu Gehör gebracht werden zu können;
ich habe darum wenigstens eine kleine Auswahl der von mir
gesammelten Eingeborenenlieder abgedruckt. Der
Kinematographenfilm ist das Demonstrationsmittel des
Vortragssaals; zugleich ist er das Archiv der dahinschwindenden
Sitten unserer Naturvölker. In dieser Eigenschaft sollte seine
Anwendung mit allen Mitteln und in größter Ausdehnung angestrebt
werden, solange es noch Zeit ist. Es liegt in der Natur der Sache,
daß er seinem eigenen Herrn, der ihn selbst mit den Szenen aus
dem Eingeborenenleben bedeckt hat, am meisten erzählt; ihn
versetzt er schon beim Aufblitzen des ersten Bildchens in das alte
Forschungsgebiet zurück. Der Anschaulichkeit des Buches kommt
damit auch er, wenn auch nur indirekt, zugute.
Mein gänzlicher Mangel an musikalischer Bildung hat die
Transkription meiner Lieder durch musikalische Freunde bedingt;
gern statte ich den Herren Dr. von Hornbostel in Berlin und Dr. Albert
Thümmel in Leipzig den wohlverdienten Dank ab.
Nicht geringe Schwierigkeiten bereitet die Wiedergabe gewisser
Bantusprachlaute durch unser deutsches Alphabet; am größten sind
sie beim Laute „tschi“. So hart wie ihn unsere Sprechweise bedingt,
ist der Laut nicht; das „t“ ist kaum hörbar; aus diesem Grunde habe
ich vorgezogen, die Silbe nach dem Standardalphabet „chi“ zu
schreiben.
Das Buch ist Stückwerk. Natürlich. Wie sollte es dem einzelnen
Forscher auch möglich sein, die Gesamtheit der Lebensformen einer
ganzen Rasse zu erfassen! Selbst einer Rasse wie der des Negers.
Wir nennen den schwarzen Mann Naturvolk; für uns klebt er am
Boden, mit dem er bei seiner offenkundigen Ruhelosigkeit
gleichwohl nicht verwachsen scheint. Nur scheint; in Wirklichkeit ist
er bodenständig wie kaum ein anderer Teil der Menschheit. Afrika ist
Sitz und Heimat des Negers seit jeher; in seinen weiten Räumen ist
er entstanden; dort ist er physisch zu dem geworden, was er heute
ist; dort hat er auch seine Kultur entwickelt. Diese Kultur ist anders
als die unsrige; sie ist sicherlich nicht so hoch; doch gewährt auch
sie ein ganz bestimmtes, scharf umrissenes Bild. Ob es reizvoll ist,
sich in dieses Bild zu vertiefen? Lies dies Buch: es hat in breiten,
kräftigen Strichen eine Anzahl Züge jenes Bildes festzuhalten
versucht. Nachher magst du selbst urteilen.

Leipzig, 19. September 1908.

K. Weule.
Inhaltsverzeichnis.

Seite
Vo r w o r t V
Erstes Kapitel. Die Ausreise 1
Z w e i t e s K a p i t e l . Die Ziele 15
D r i t t e s K a p i t e l . Es kommt anders 30
V i e r t e s K a p i t e l . Lehrzeit an der Küste 42
F ü n f t e s K a p i t e l . Einmarsch ins Innere. Die ersten
Eindrücke 64
S e c h s t e s K a p i t e l . Umschau 87
S i e b e n t e s K a p i t e l . Einleben ins Volkstum 102
A c h t e s K a p i t e l . Marsch nach Süden. Meine Karawane 136
N e u n t e s K a p i t e l . Bei Matola 170
Z e h n t e s K a p i t e l . Mit und unter den Yao 194
E l f t e s K a p i t e l . Weitere Ergebnisse 238
Z w ö l f t e s K a p i t e l . Rovuma-Idyll und Zug ins Pori 254
D r e i z e h n t e s K a p i t e l . Unyago überall 283
V i e r z e h n t e s K a p i t e l . In voller Ernte 297
F ü n f z e h n t e s K a p i t e l . „Und will sich nimmer erschöpfen
und leeren“ 338
S e c h z e h n t e s K a p i t e l . Schlußzeit in Newala 388
S i e b z e h n t e s K a p i t e l . Wiederum zum Rovuma 405
A c h t z e h n t e s K a p i t e l . Die Meisterzeit 429
N e u n z e h n t e s K a p i t e l . Zur Küste zurück 477
Z w a n z i g s t e s K a p i t e l . Rückblick 495
Register 515
Abbildungen.

Seite
Karl Weule (Titelbild)
Kap Guardafui 1
Hafen von Daressalam 2
Eingeborenentanz in Daressalam 6
Straße im Eingeborenenviertel von Daressalam 10
Karte der großen Karawanenstraße.
Eingeborenenzeichnung 15
Dolcefarniente in einem Hofe von Daressalam 19
Im Europäerviertel von Daressalam 24
Bucht von Lindi 30
Dampfer Rufidyi. Eingeborenenzeichnung 32
Mündungsgebiet des Lukuledi oberhalb Lindi (Separatbild) 33
Reede von Lindi 37
Arabische Dhau. Eingeborenenzeichnung 41
Kettengefangene. Eingeborenenzeichnung 42
Seliman Mamba 45
Yao-Frauen von Mtua (Separatbild) 49
Mädchen aus Lindi 51
Tanz der Weiber in Daressalam 53
Alter portugiesischer Turm in Lindi 55
Unter Palmen 57
Die Ngoma Liquata. Eingeborenenzeichnung 64
Makua-Frauen aus dem Lukuledi-Tal (Separatbild) 65
Mueramann und Yao 67
Ruinen der Missionsstation Nyangao 71
Wamuerafrau 76
Muerajüngling 77
Muerafrau mit Unterlippenpflock 79
Lichte Baumgrassteppe mit Barra-barra (Separatbild) 80
Massassiberge. Eingeborenenzeichnung 87
Inselberg von Massassi 89
Unsere Mtandibesteigung. Eingeborenenzeichnung 95
Buschbrand auf dem Makonde-Plateau (bunte Tafel) 96
Wanyassa-Jäger mit Hund. Eingeborenenzeichnung 102
Studienbummel in der lichten Baumgrassteppe 107
Lager in Massassi 111
Am traulichen Herd. Hütteninneres in der Rovuma-Ebene
(Separatbild) 112
Taubenschlag und Speicher 120
Marschbereit vor Massassi 123
Rattenfalle 125
Antilopenfalle 127
Perlhuhnfalle 129
Falle für Großwild 129
Yaohütte 135
Meine Karawane auf dem Marsche.
Eingeborenenzeichnung 136
Yao-Gehöft in Chingulungulu (Separatbild) 136
Lager in Mwiti 142
Jalousie mit Swastika 147
Yaohäuptling Nakaam 149
Hofinneres in Mwiti 155
Ältere Makondefrau im Festschmuck (Separatbild) 160
Hüttentypus der Rovuma-Ebene 162
Hüttengrundriß 162

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