I CH i 3110512023

Cto

A
2 oh no 2 A H

It OHO 3 OH
µ
401 204
3 R
404207
R
I 2s 3131

TÉ Diastereomers

a It I H L
le
on

le
A B A
A D

2
b a

YH 3
G s

A R
It or

g G S
H C H
Ion AIR
 chiral centre is
is one
If there
Ite mole ale then
in a
present
is no diastereomers
there

i r R
identical
s s Cer
Homomess
CI R s
Enantiomer
s r

are two chiral

If there
present in a
centres are

then
moleale
RR RR
e Identical
Ss Ss

RR Ss
CT Ss antio
Regen
 Sr Rs mess

RS SR

Cii Rr RS ISR
SS SRI RS

SR SS I R R

RS A RR ISS

Diastereomers
shor tat
E
RR S S
E

I
D D D

D D P D
D
E SE
RS E
 Cfto I

H 2 OH A 2 off to 2 It to 2
H
3
H OH 403 A to 3 A 43 OH

4C H2O H
4 a
I I
I 2 25135 25 30
3s
212 3 R
D
I I
e
I II
D
I I
D
I I
E
I IS

I I T D

iimii fisher projection

on RHS in
 Cito
R
78 to
Dat
Actual SV
CH 204

i 4 I
3

I I
4 Sw

Ffg I 2 3

4
s
3

l z

d su
4
 If least priority group is
on LHS
present
H R

H NH
I
actual s

CH

I 2
4 2

4
G s
ACW
l
I

4
31
2
I
243 4
Gsu
Acw
 Res configuration in wedge dash

formate towards the observer

Above the plane
wedge
a dash Below the plane er

Away from observer

OH

2 R
Hanh y
c w
CH3 NHL

in which the least priority group

below the Plane

alway's present

If the least priority

above the
group is present
High
priority group
Plane for
below the Plane
is present
Opposie
write the configuration
I he 9

Toi

It

IE
OH

16NHL

TIE
 optical active 091061202in
Effy
No chiral centre but it show's
compounds such as
optical activity
Substituted Allen

spiranes

Cyclo alkadieng
Biphenyls

Alley JEE 2012 Advanced

sp2
Egg

H
EIE.EE
Z Pu Pu E
A bond formation
Py Py
in Pz Pz a bond formation
 takes Place

Yz 1 Xz

Allen are optically

substituted
active Cor chiral

3 L Pos
of
no

not c c

chiral
non super imposable
they must be
with eachother
mirror image's
Pos
clap
I
c
C
NO
Pos inactive
optically
Achiral

I i to
ie c c
f
ne
t
CHI
chiral
 spies
P
X
gtfoPos

IoT chiral

Y
ÉÉ
chiral

year
H

HI
 see

NO
pos
KITTY
chiral
active
optically

on
CHI

IIFA
chiral

Biphenyls

Chiral
 IEEE
nos

Achiral

chiral
bulky groups
At ortho position
can be present
such as Moz
Groups
OH 9 H of
 Eernigestey
t into four types
classified
Inductive effet P E
Mesomeric effort
conjugation
Hyper FE
effect
Electromeric
effect
Inductive
soft

E É'ÉÉÉ
2 1
4 3
r electron's
f
the displacement relenting
electron
in pretence of withdrawing
Cor electron
groups bond is
of
the polarisation
inductive effect
known as
 carbon the effect
After 4th
if nullify
distance
dependant
If's

factor alway's
is
polarisation
permanent
8
Tolar bond
element
E n
The more
and
ve charge
bearing
element bearing
Lets E n

charge
positive
into two
It's classified
types
inductive effect
are
effect
ve inductive
 positive inductive
I.fm effect

cha Ctb
CH i
gyms
etc are
Items
ay effect
inductive
positive
as referenc
taken
Here
considered
to be Zerg
it is
inductive
negative effect
xef.tn
T
Nos M
Gort

Toon etc
Nrt
Sogn
 Hyibdage
bond mutual
in covalent
a
single E
of
distribution f fun
in presence
shared
light
At
É IIIT radical
tithon bond S
which covalent
in
of
unequal sharing
broken
two
atoms in
E'S btw

a moleale
AO B
Cil ADB
A B IEN

O O
 At no
Cii AGB
N

B CH
E

Free Radical
A
Cahboniumion
At carbocation CHI
A y carbanion Ctf

III FreeRadeld
so so ie
Retire Elite are
there are 7 electrons
in which
in valence sheer
present Charge
with no
If's neutral

sp
hybridisation
geometry
planar
in nature
paramagnetic

Ihre
 a
µ
H

Emin EI
charged ion
rely
It's
in the
6 electrons
It has
then
valence
sp2 hybridisation
planar
Diamagnetic

stability of carbocation
Relative
a'at Pct City
Jct

carbanion CH
 charged ion
It's very
in the
are sets
There
valence then

sp hybridisation
shape
Pyramidal

A
FIH
Idiot
Relative stability fc
0 300
450 to 2

a
The phenomenon where in
dipole arises in a
permanent to the
due
molence
given the
leal sharing of
unece
election in the mdede
bonding
b ng
can arise in
This effect
the
whereas
bonds i
can
effect
mesomenie A bonds
te
in
an
only

j N atom i such ay
an E
when
introduced to
is
a halogen
atoms the refuting
a chain of
of Elf
an clad sharing
marge
a the
generates through
is
transmitted
which
the chain
cause permanent
This
in the maleate
to arise
dipole Erne atom
in the
where
and the
holds a nee charge
 effect 5616
corresponding
E W D effect
or Ite II

Application
stability fat
in
of c

a d
in

of Alcorn
Acidity
acids
in
aliphatic

basicity famines

Dipole moment
Bond length