PINNAACLE CLASSES

3 +¿( II) ¿

26. Three complexes, [ CoCl ( NH 3 )5 ]

2+¿( I), [ Co ( NH 3 )5 H 2 O ] ¿ 30. For octahedral Mn (II) and tetrahedral ¿(II )
3+¿(III )¿
complexes, consider the following statements:
and [ Co ( NH 3 )6 ] absorb light in the visible (i) both the complexes can be high spin.
region. The correct order of the wavelength of light (ii) ¿(II ) complex can very rarely below spin.
absorbed by them is: (iii) with strong field ligands, Mn (II) complexes
can be low spin.
(a) (III )>(I )>(II ) (b) (III) >(II )>(I ) (iv) aqueous solution of Mn (II) ions is yellow in
(c) (II) >(I )> (III) (d) (I )>(II )>(III ) colour.
The correct statements are :
27. The crystal field stabilization energy (CFSE) of (a) (I ) , (III ) and (IV ) only
(b) (I ) and (II ) only
[ Fe ( H 2 O )6 ] Cl2and K 2 [ NiCl 4 ] respectively are :
(c) (II ), (III ) and (IV ) only
(a) −0.6 Δ0 and −0.8 Δ t (b) −0.4 Δ0 and −0.8 Δ t (d) (I ) , (II ) and (III ) only
(c) −2.4 Δ0 and −1.2 Δt (d) −0.4 Δ0 and −1.2 Δt
31. The one that is not expected to show isomerism is
2+¿ ¿
28. The complex ion that will lose its crystal field (a) [Pt (NH 3)2 Cl2 ] (b) [¿( NH 3)4 ( H 2 O)2 ]
stabilization energy upon oxidation of its metal to (c) ¿ ¿ (d) [¿(NH 3)2 Cl2 ]
+3 state is:

32. The values of the crystal field stabilization

energies for a high spin d 6 metal ion in
octahedral and tetrahedral fields, respectively,
(a) −1.6 Δ 0 and −0.4 Δt (b) −2.4 Δ0 and
−0.64 t
(c) −0.4 Δ0 and −0.27 Δt (d) −0.4 Δ0 and
(a) ¿ ¿ (b) ¿ ¿ −0.6 Δt
(c) ¿ ¿ (d) ¿ ¿

33. Correct IUPAC name of

29. Complete removal of both the axial ligands (along
[Pt (N H 3)2 Cl(N H 2 C H 3 )]Cl is
the z -axis) from an octahedral complex leads to
(a) Bis(ammine)chlorido(methylamine)platinum
which of the following splitting patterns? (relative
orbital energies not on scale)
(II ) chloride
(b) Diamminechlorido(methanamine)platinum
(II ) chloride
(c) Diamminechlorido(aminomethyl)platinum
(II ) chloride
(a) (b) (d) 'hloridobis(ammine)methylamineplatinum(II )
chloride

34. The incorrect statement among the following is :

(a) VOSO 4 is a reducing agent

(b) Red colour of ruby is due to the presence of
3+¿¿
CO
(c) Cr 2 O 3is an amphoteric oxide

(c) (d) (d) RuO 4is an oxidizing agent

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35. What is the correct order of the following elements 40. Spin only magnetic moment of an octahedral
with respect to their density? complex of in the presence of a strong field
(a) Cr < Fe < Co < Cu < Zn ligand in BM is :
(a)4.89 (b)2.82
(b) Cr < Zn < Co < Cu < Fe
(c) 0 (d)3.46
(c) Zn < Cu < Co < Fe < Cr
41. Which one of the following species responds to a
(d) Zn < Cr < Fe < Co < Cu external magnetic field?

36. Match List-I with List-II : (a) (b)

List I List II

(a) [ Co ( NH 3 )6 ] ¿ (i) Linkage isomerism (c) (d)

(b) [ Co ( NH 3 )3 ( NO 2 )3 ] (ii) Solvate
42. Which one of the following metal complexes ismost
isomerism stable?
(c) [ Cr ( H 2 O )6 ] Cl 3 (iii) Co-ordination
(a) (b)
isomerism
(d) cis-[CrCl ¿ ¿ (iv) Optical isomerisma
(c) (d)
Choose the correct answer from the options
given below:
43. The type of hybridisation and magnetic property of
(a) (a) −(iii),(b)−(i),( c)−(ii), (d)−( iv ) (b)
(a)-(iv), (b)-(ii), (c)-(iii), (d)-( i ) the complex , respectively, are :
(c) (a)-(ii), (b)-( i ), (c)-(iii), (d)-(iv) (a) and diamagnetic
(d) (a)-( i ), (b)-(ii), (c)-(iii), (d)-(iv)
(b) and diamagnetic
37. The addition of dilute NaOH to Cr 3+salt solution will
(c) and paramagnetic
give :
(a)a solution of [Cr(OH)4]− (d) and paramagnetic
(b) precipitate of
Cr2O3(H2O)n 44. Given below are two statements :
(c) precipitate of [Cr(OH)6]3−
(d) precipitate of Statement I: and
Cr(OH)3
are hybridised.
38. Which one of the following complexes is violet in
colour? Statement II : and are
(a)[Fe(CN)6]4− paramagnetic and have 4 and 5 unpaired
(b)[Fe(SCN)6]4−
electrons, respectively.
(c)Fe4[Fe (CN6)]3⋅ H2O
(d)[Fe(CN)5NOS]4 In the light of the above statements, choose the
correct answer from the options given below:
39. According to the valence bond theory the (a) Statement I is correct but statement II is false
hybridization of central metal atom is for which (b) Both statement I and statement II are false
one of the following compounds? (c) Statement I is incorrect but statement II is
true
(a) (b)
(d) Both statement I and statement II are true

(c) (d) 45. Which of the following complex will show largest
splitting of d-orbitals?
(a) [Fe(C2O4)3]3- (b) [FeF6]3-
3-
(c) [Fe(CN)6] (d) [Fe(NH3)6]3+
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 PINNAACLE CLASSES

46. The total number of coordination sites in

ethylenediaminetetraacetate ¿ is

47. The total number of unpaired electrons present in

the complex K 3 ¿ is____.

48. The number of optical isomers possible for

[Cr(C2O4)3]3−is ____.

49. The spin-only magnetic moment value for the

complex is ___ BM.

[At. no. of Co=27]

50. 3 moles of metal complex with formula

gives 3 moles of silver chloride on treatment with
excess of silver nitrate. The secondary valency
ofCo in the complex is(Round off to the nearest
integer)

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