CHEMISTRY

SOLUTION : PRACTICE PAPER – 5

SECTION – A

Q. 1. (i) (d)  3,  6

(ii) (a) Crystallisation of liquid into solid

OH

(iii) (b) CF14

CH3
(iv) (d) 175 pm
(v) (b)  107 M

(vi) (a) 1 and 3

(vii) (d) 6 h

(viii) (b) 3-hydroxy butanal

(ix) (b) Boiling point of solvent is lower than that of solution.

(x) (a) n-Butylamine

Q. 2. By Henry’s law, S  KH  P, where S is solubility of the gas in mol dm3, P is the
(i) 
pressure of the gas in atmosphere (or in bar) and KH is Henry’s law constant.
S (mol dm
3)

 KH mol dm3 atm1 or mol dm3 bar1

P(atm)

  Hence the units of Henry’s law constant KH are mol dm3 atm1.

(ii) The thermal stability of interhalogen compounds depends upon the electronegativity of

the combining atoms.

Elements F Cl Br I
Electronegativity 4.0 3.2 3.0 2.7
More the difference between the electronegativity the combining atoms, more is the thermal
stability.
Hence the order of thermal stability is,
ClF  ICl  IBr  BrCl
(iii) The sugar present in DNA is deoxyribose.
Standard enthalpy of combustion or standard heat of combustion : It is defined as
(iv) 
the enthalpy change when one mole of a substance in the standard state undergoes
complete combustion in a sufficient amount of oxygen at constant temperature (298  K)
and pressure (1 atmosphere or 1 bar). It is denoted by * C H 0.

SOLUTIONS TO NAVNEET PRACTICE PAPERS : STD. XII 1

 3
E.g. CH3OH(l)  2 O2(g)  CO2(g)  2H2O

* C H 0    726 kJ mol1

(* C H 0 is always negative.)
(v) The –  C – O linkage is present in terylene or dacron polymer.
O
Isolated system : It is defined as a system which can neither exchange energy nor matter
(vi) 
with its surroundings, e.g. hot water filled in a thermally insulated closed vessel like
thermos flask.
(vii) Carbon black
(viii) By heating chlorates, nitrates and permanganates :
Potassium chlorate in the presence of manganese dioxide on heating decomposes to form
potassium chloride and oxygen.

2KClO3 IIIIIIIJ
*
MnO
2KCl  3O2(g)
2

SECTION – B

Q. 3. Consider the following first order reaction, A IIIJ B

The rate of the chemical reaction is given by the rate law expression as,
Rate, R  k [A]
where [A] is the concentration of the reactant A and k is the velocity constant or specific rate of
the reaction.
  The instantaneous rate is given by,
 d [A]
R  k [A] 
dt
   d [A]
  k.dt
[A]
  If [A]0 is the initial concentration of the reactant and [A]t at time t, then by integrating the above
equation,
[A]t
t
d [A]


[A]0
[A]
   k  dt
0

[A]t
    loge  kt
[A]0

[A]0
 loge  kt
[A]t

1 [A]0
 k  loge
t [A]t

2.303 [A]0
 k log10
t [A ]t
2 SOLUTIONS TO NAVNEET PRACTICE PAPERS : STD. XII
  This is the integrated rate equation for the first order reaction. This is also called integrated rate
law.
Q. 4. 
Phthalimide is reacted with alcoholic KOH to form potassium phthalimide. Further potassium
phthalimide is treated with an ethyl iodide. The product N-ethylphthalimide is hydrolysed with
aq. NaOH to form ethylamine. This reaction is known Gabriel phthalimide synthesis.
CO CO
KOH (alc.) –      + C2H5I
NH NK
– H2O – KI
CO CO
phthalimide potassium phthalimide
–    +
CO COONa
N – C2H5 NaOH (aq.) –    +
+ C2H5 – NH2
CO COONa
N-ethyl phthalimide sodium phthalate ethylamine

Aromatic amines cannot be prepared by this method because aryl halides do not undergo nucleo-
philic substitution with the anion formed by phthalimide.
Q. 5. (1) When a gas expands against an external pressure Pex, changing the volume from V1 to V2,
the work obtained is given by
W    Pex (V2  V1).
(2) Hence the work is performed by the system when it experiences the opposing force or
pressure.
(3) Greater the opposing force, more is the work.
(4) In free expansion, the gas expands in vaccum where it does not experience opposing force,
(P  0). Since external pressure is zero, no work is obtained.
 W    Pex (V2  V1)
   0  (V2  V1)  0
(5) Since during expansion in vacuum no energy is expended, it is called free expansion.
Q. 6. Given : C  0.1 M,   0.0132, C  0.01 M,
  0.0132,   ?
Ka  2C
C  Molar concentration of acetic acid  0.1 M
 Degree of dissociation in 0.1 M solution  0.0132

   ij
Ka
C

If the concentration is C,   ij

Ka
C

 ij  ij  ef10
 C 0.1

 C 0.01

SOLUTIONS TO NAVNEET PRACTICE PAPERS : STD. XII 3

   ef10 1.32102 ef10 log 1.32  0.1206
 4.175  102 1 0.5000
 log10 
2 0.6206
antilog 0.6206  4.175
Ans. Degree of dissociation in 0.01 M solution  4.175  102.
Q. 7. (i) Action of HI : Glucose on prolonged heating with HI gives n-hexane, indicates that all
the six carbon atoms are linked in straight chain.
CHO
J   CH3 – CH2 – CH2 – CH2 – CH2 – CH3
hot HI
(CHOH)4
CH2OH n-hexane
glucose
(ii) Action of hydroxyl amine : Glucose reacts with hydroxyl amine in an aqueous solution to
form glucose oxime. This indicates the presence of CHO group in glucose.
CHO CHNOH
J
NH2 – OH
(CHOH)4 (CHOH)4
hydroxyl amine
CH2OH CH2OH
glucose glucose oxime
Q. 8. (i) The halogens have a tendency to combine amongst themselves forming different compounds
called interhalogen compounds.
(ii) Interhalogens are of the type XX, XX3, XX5 and XX7 where X is larger size halogen than X.
(iii) They are covalent, diamagnetic, reactive and good oxidising agents.
(iv) Preparation :

Cl2  F2 IIIIIIIJ 2ClF

437  K

Br2  3F2 IIIIIIIJ 2BrF3

*

Q. 9. Given : Concentration of solution  m  0.12

Boiling point of the solution  Tb  373.21 K

For solvent (water) T0  373.15 K

Molal elevation constant, Kb  ?

* Tb  Tb  T0

 
 373.21  373.15  0.06 K

* Tb  Kb  m
* Tb
 Kb 
m
0.06
  0.5 K kg mol1
0.12

Ans. Molal elevation constantKb0.5 K kg mol1.

4 SOLUTIONS TO NAVNEET PRACTICE PAPERS : STD. XII

Q. 10.

H2(g) at 1 atmosphere
pressure and 298 K
Copper wire
Glass jacket
Hg contact

Platinised platinum foil

Solution of H+ ions of
unit activity (1 M)

Fig. : Standard hydrogen electrode

Q. 11. 
Phenol reacts with sodium hydroxide, sodium phenoxide is formed. When sodium phenoxide
is heated with methyl iodide, anisole is obtained.
OH ONa O – CH3

B1  NaOH IIIIIJ B1 CH3I

J B1
phenol sodium anisole
phenoxide (methyl phenyl)
ether

Q. 12. 
Zinc oxide ( ZnO ) and titanium dioxide ( TiO2 ) nanoparticles are used sunscreen lotions. The
chemicals protect the skin against harmful uv ( ultraviolet ) rays by absorbing or reflecting the
light and prevent the skin from damage.
Q. 13. (1) The atomic radii of elements of transition elements are intermediate between those of
s-block and p-block elements of the same period.
(2) Atomic radii of transition elements decrease with increase in atomic number.
(3) In transition elements, the last electron enters (n  1) d-subshell. With the d-electrons after
poor screening effective nuclear charge increases.
Hence atomic radii decrease with increase in atomic number.
(4) The decrease in atomic radii is less. There is slight increase in atomic radii of last two
elements Cu and Zn.
Q. 14. There are two principal types of isomerisms in coordination compounds as follows :
(A) Stereoisomerism (B) Structural isomerism (or Constitutional isomerism)
(A) Stereoisomerism is further classified as :
(i) Geometrical isomerism
(ii) Optical isomerism
(B) Structural isomerism is further classified as :
(i) Ionisation isomerism
(ii) Linkage isomerism

SOLUTIONS TO NAVNEET PRACTICE PAPERS : STD. XII 5

 (iii) Coordination isomerism
(iv) Solvate (or hydrate) isomerism

SECTION – C
Q. 15. (i) In the complex, Co carries  3 charge while 6F carry  6 charge. Hence the net charge
on the complex is  3. Therefore it is an anionic complex.

(ii)

A+ B– A+ B– A+
A+
B– B– A+ B–

A+ B– A+ B– A+

B– A+ B– A+ B–

Fig. : Frenkel defect

Frenkel defect : This defect arises when an ion of an ionic compound is missing from
(1) 
its regular site and occupies interstitial vacant position between lattice points.
(2) Cations have smaller size than anions, hence generally cations occupy the interstitial sites.
(3) This creates a vacancy defect at its original position and interstitial defect at new position.
(4) Frenkel defect is regarded as the combination of interstitial defect and vacancy defect.
(5) Conditions for the formation of Frenkel defect :
(i) This defect arises in ionic compounds with a large difference between the sizes of
cation and anion.
(ii) The ionic compounds must have ions with low coordination number.
Q. 16. (i) Cis-isomer : A heteroleptic coordination compound in which two similar ligands are
arranged adjacent to each other is called cis-isomer.
For example, Cis-Diamminedichloroplatinum(II)
Cl NH3

Pt

Cl NH3

(ii) 2-Methylpropan-2-amine
(iii) The chemical name of DDT is p, p-Dichlorodiphenyltrichloroethane.
Q. 17. (i) 
Lanthanoid contraction : The gradual decrease in atomic and ionic radii of lanthanoids
with the increase in atomic number is called lanthanoid contraction.

6 SOLUTIONS TO NAVNEET PRACTICE PAPERS : STD. XII

 (ii) The causes of the lanthanoid contraction are as follows :
(1) As the atomic number of lanthanoids or 4 f-block elements increases the positive
nuclear charge increases and correspondingly electrons are added to the prepenultimate
4 f subshell.
(2) The attraction of nucleus on 4 f-electrons increases with the increase in atomic number.
(3) The outer eleven electrons namely, 5s2, 5p6, 5d1 and 6s2 do not shield inner 4 f-electrons
from the nucleus.
(4) There is imperfect shielding of each 4 f-electron from other 4 f-electrons.
(5) As compared to d subshell, the extent of shielding for 4 f-electrons is less.
(6) Due to these cumulative effects, 4 f-electrons experience greater nuclear attraction and
hence valence shell is pulled towards the nucleus to the greater extent decreasing atomic
and ionic radii appreciably.
(7) From 57
La to Ce, there is a sudden contraction in atomic radius from 187 pm to
58

183 pm but the further decrease up to the last 4f-element, 71Lu is comparatively low
( about 10 pm ).
Q. 18. Action of alkaline KMnO4 : When toluene is heated with alkaline KMnO4, (methyl
(i) 
group gets oxidised to carboxylic group) benzoic acid is obtained
CH3 COOH

A1  3 (O)
alk. KMnO4
  
J A1
benzoic acid

Action of CrO2Cl2 in CS2 : When toluene is treated with solution of chromyl chloride
(ii) 
(CrO2Cl2) in Cs2, brown chromium complex is obtained, which on acid hydrolysis gives
benzaldehyde.

[ ]
CH3 OCrCl2OH CHO
CH  
A1  2CrO2Cl2
CS2
J B2 OCrCl2OH H 2O 
hydrolysis
J B1
toluene          brown chromium complex       benzaldehyde

(iii) Action of acetyl chloride in presence of anhydrous AlCl3 : When toluene is treated with
acetyl chloride in presence of anhydrous AlCl3, 4-methyl acetophenone is obtained.
CH3 CH3

A1 CH3COCl
anhyd. alCl3
J A14
toluene COCH3
4-methyl acetophenone

Q. 19. Given : Cell reaction : 2Cu(aq) IIIIIJ Cu(aq)  Cu(s)

 2

E0Cu+  Cu  0.52 V; E0Cu2+ , Cu+  0.16  V

SOLUTIONS TO NAVNEET PRACTICE PAPERS : STD. XII 7

 1 F  96500  C
E 0cell  ? * G0  ? K  ?

(i) The formulation of the cell :

 2 
Pt  Cu(aq), cu(aq)  Cu(aq)  Cu(s)
LHE Cu(aq) IIIIIJ Cu(aq)  e
 2
(Oxidation at anode)
RHE Cu(aq)  e IIIIIJ Cu(s) (Reduction at cathode)


2Cu(aq) IIIIIJ Cu(aq)  Cu(s)

 2
(Overall cell reaction)
 n1
E 0cell   E 0Cu+/Cu   E 0Cu+2 , Cu+
   (cathode)   ( anode )
   0.52  0.16  0.36 V
(ii) * G0    n FE 0cell
   1  96500  0.36
   34740 J  34.74 kJ

(iii) Electrochemical redox reactions are considered as reversible reactions. If K is the

equilibrium constant for the electrochemical redox reaction, then
[Cu2+]
K
[Cu+]2
0.0592
E 0cell  log10K
n
n  E0cell
 log10K 
0.0592
1  0.36
  6.081
0.0592

 K  Al6.081  1.2  106(mol dm3)1 (or mol1dm3)

Ans. E 0cell  0.36 V; * G0    34.74  kJ; Equilibrium constant  K

 1.2  106 mol1 dm3.

Q. 20. 
Aryl halides are extremely less reactive towards nucleophilic substitution reaction due to the
following reasons :
Resonance effect : In haloarenes, the electron pairs on halogen atom are in conjugation
(1) 
with -electrons of the benzene ring. The delocalization of these electrons C – Cl bond
acquires partial double bond character.
Cl + + +
Cl Cl Cl Cl

(I) (II) (III) (IV) (V)

8 SOLUTIONS TO NAVNEET PRACTICE PAPERS : STD. XII

    Due to partial double bond character of C – Cl bond in aryl halides, the bond cleavage in
haloarene is difficult and are less reactive towards nucleophilic substitution.
Sp2 hybrid state of C : Different hybridization state of carbon atom in C – X bond : In aryl
(2) 
halides, the carbon of C – X bond is sp2-hybridized with more s-character and shorter bond
length of 169 pm which requires more energy to break C – X bond. It is difficult to break
a shorter bond than a longer bond, in alkyl chloride (bond length 178 pm) therefore, aryl
halides are less reactive towards nucleophilic substitution reaction.
Instability of phenyl cation : In aryl halides, the phenyl cation formed due to self
(3) 
ionisation will not be stabilized by resonance which rules out possibility of SN1 mechanism.
Also backside attack of nucleophile is blocked by the aromatic ring which rules out SN2
mechanism. Thus cations are not formed and hence aryl halides do not undergo nucleophilic
substitution reaction easily.
(4) As any halides are electron rich molecules due to the presence of  -bond, they repel
electron rich nucleophilic attack. Hence, aryl halides are less reactive towards nucleophilic
substitution reactions. However, the presence of electron withdrawing groups at o / p position
activates the halogen of aryl halides towards substitution.
Cl OH

A14 (i) NaOH 433 K

(ii) H2O 
J A14
NO2 NO2

Q. 21. (i) 
pH : The negative logarithm, to the base 10, of the molar concentration of hydrogen ions,
H+ is known as the pH of a solution.
pH   log10[H+]
(ii) (A) (i) Sodium carbonate is a salt of weak acid and strong base.
(ii) In aqueous solution it undergoes hydrolysis.
Na2CO3(aq)  2H2O(l)  2NaOH(aq)  H2CO3(aq)
salt     strong base  weak acid
 2  
2Na (aq)  CO 3(aq) 2H2O(l)  2Na (aq)  2OH (aq)  H2CO3(aq)

(iii) Strong base dissociates completely while weak acid dissociates partially hence
[OH]  [H3O+] and the solution is basic.
(B) (i) Ammonium chloride is a salt of strong acid and weak base.
(ii) In aqueous solution it undergoes hydrolysis.
NH4Cl(aq)  H2O(l)  NH4OH(aq)  HCl(aq)
salt    weak base strong acid
   
NH 4(aq) Cl (aq) H2O(l)  NH4OH(aq)H (aq) Cl (aq)

(iii) Since [H+] or [H3O+]  [OH] the solution is acidic.

SOLUTIONS TO NAVNEET PRACTICE PAPERS : STD. XII 9

 CH2Cl CH2OH
Q. 22. (i) B2  aq. KOH
  
J B2  KCl
benzyl chloride benzyl alcohol

H
CH2OH K Cr O / dil. H SO C = O K Cr O / dil. H SO COOH
2 2 7 2 4 2 2 7 2 4
(ii)
(O) (O)
benzyl alcohol benzaldehyde benzoic acid

O dry ether OMgBr H 2O / H + OH

(iii) + CH3 – CH2 MgBr
CH2CH3 CH2CH3
cyclohexanone complex 1-ethyl cyclohexanol

Q. 23. Given : t1/2  1.7 hr; [A]0  100;

[A]t  100  20  80; t  ?

0.693
t1/2 
k
0.693
 k  
t1/2
0.693
 

1.7
 
 0.4076 hr1

2.303 [A]0
 k log10
t [A]t
2.303 100
 t log10
k 80
2.303
 
 log10 1.25
0.4076
2.303  0.09691
 

0.4076
 
 0.5476 hours
 
 0.5476  60 min
 
 32.86 minute
Ans. Time required  t  32.86 min.
Q. 24. The general characteristics of interhalogen compounds are as follows :
(i) In XX 9n, X is the halogen which has larger size and is more electropositive, while X is
the halogen having smaller size and is less electropositive. n is the number of atoms of X
attached to X.
(ii) As the ratio of radii (radius of X : radius of X ) between the atoms X and X increases, the
number of halogen atoms (n) per interhalogen compound also increases.

10 SOLUTIONS TO NAVNEET PRACTICE PAPERS : STD. XII

 (iii) The interhalogen compounds have even number of atoms i.e. 2,4,6,8. For example, ClF3
has 4 atoms and BrF5 has 6 atoms.
(iv) The number of X atoms in the interhalogen compounds are always odd.
(v) The properties of interhalogen compounds are generally intermediate between those of the
halogens from which they are made.
(vi) The oxidation state of the atom X in XXn, is equal to  1,  3,  5,  7 and that of X
is  1.
(vii) 
Interhalogen compounds exist as gases, liquids and solids depending upon their
composition. They are volatile and less stable but not explosive.
Q. 25. Step 1 : Radius of sphere : In simple cubic lattice, the atoms (spheres) are present at
(i) 
eight corners and in contact along the edge in the unit cell.
  If ‘a’ is the edge length of the unit cell and ‘r’ is the radius of the atom, then
a  2r or r  a/2

A
r

r a
B a

Fig. : scc structure

Step 2 : Volume of sphere :

4
Volume of one particle   r3
3
4 a3
   (a/2)3 
3 6

Step 3 : Total volume of particles : Since the unit cell contains one particle, Volume
a3
occupied by one particle in unit cell 
6
Step 4 : Packing efficiency :
Packing efficiency
Volume occupied by particles in unit cell
  100
Volume of unit cell

   a 3/6  100
3

a
3.142  100
    52.36%
6
 Packing efficiency  52.36%

Percentage of void space  100  52.36

 47.64%

SOLUTIONS TO NAVNEET PRACTICE PAPERS : STD. XII 11

 (ii) Electrochemical series (Electromotive series) : It is defined as the arrangement in a series
of electrodes of elements (metal or non-metal in contact with their ions) with the electrode
half reactions in the decreasing order of their standard reduction potentials.
Q. 26. (1) Hexaamminecobalt(III) ion, [CO(NH3)6]3+ is a cationic complex, the oxidation state of
cobalt is  3 and the coordination number is 6.
(2) Electronic configuration : 27Co [Ar]18 3d 74s2
Electronic configuration : Co3+ [Ar]18 3d 64s04p0
3d 6 4s0 4p0
Co3+ (Ground state)

(3) Since NH3 is a strong ligand, due to spin pairing effect, all the four unpaired electrons in 3d
orbital are paired giving two vacant 3d orbitals.
3d 6 4s0 4p0
Co3+ (Excited state)
ZIIIII d 2sp3 hybridisation IIIIIJ

(4) Since the coordination number is 6, Co3+ ion gets six vacant orbitals by hybridisation of
two 3d vacant orbitals, one 4s and three 4p orbitals forming six d 2sp3 hybrid orbitals giving
octahedral geometry. It is an inner complex.
Co3+
3d 6 d 2sp3 hybrid orbitals
(5) 6 lone pairs of electrons from 6NH3 ligands are accommodated in the six vacant d 2sp3
hybrid orbitals. Thus six hybrid orbitals of Co3+ overlap with filled orbitals of NH3 forming
6 coordinate bonds giving octahedral geometry to the complex.
Co3+ NH3 NH3 NH3 NH3 NH3 NH3
[Co(NH3)6]3+      
3d 6 d 2sp3 hybrid orbitals
Since the complex has all electrons paired, it is diamagnetic.

NH3 3+
H3N NH3

Co [Co(NH3)6 ]3+

H3N NH3
NH3

Fig. : Structure of [ Co(NH3)6 ]3+

Complex Hybridisation Geometry Magnetic property

[ Co(NH3)6 ]3+ d 2sp3 (inner) Octahedral Diamagnetic (  0)

12 SOLUTIONS TO NAVNEET PRACTICE PAPERS : STD. XII

 SECTION – D

Q. 27. (i) (a) Cl2 reacts with F2 in equal volumes at 437 K to give chlorine monofluoride ClF.

Cl2  F2 IIIIIIIIJ 2 ClF

437 K

(equal volumes)

(b) Br2 reacts with excess of F2 to give bromine trifluoride BF3.

Br2  3F2 IIIIIIIIJ 2BrF3

*

(excess)
(ii) (a) Number of moles of Zn2   0.1 mol
Zn2   2e  IIIIIJ Zn
 1 mol electrons  1 Faraday
 0.2 mol electrons  0.2  1  0.2 Faradays
(b) (i) In interhalogen compound ICl and I2 the atoms are bonded by covalent bonds.
(ii) The covalent bond between dissimilar atoms, I and Cl atoms in ICl is weaker than
between similar atoms in I2.
(iii) Therefore bond dissociation enthalpy of ICl bond is less than that of I2 bond.
Hence ICl is more reactive than I2.

Q. 28. i(i) (1) nHOOC – R – COOH  nHO – R – OH

–[ ]–
C – R –  C – O – R – O
O O n

Polymer

(2) H2N – (CH2)5 – COOH

–[ HN –( CH2 )–5 CO  ]–n
   Polymer

(ii) (1) Nanotechnology has revolutionalized electronics and computing.

(2) Nanotechnology has benefited the energy sector by making solar power more economical
and energy storage more efficient.
(3) Nanotechnology has transformed the medical field with the manufacture of smart drugs
which help cure the life threatening diseases like cancer and diabetes faster and without
side effects.
J

Q. 29. (i) C2H5Br      NaOH C2H5OH          NaBr
  

ethyl bromide   ethanol

J C2H5NH2  HBr

(ii) C2H5Br  NH3
pressure

ethyl bromide (alc.) ethyl amine
J

(iii) CH3COOAg  C2H5Br   
CH3COOC2H5  AgBr
silver acetate ethyl bromide ethyl acetate

J

(iv) C2H5Br  AgCN C2H5NC         AgBr
  
ethyl bromide (alc.) ethyl isocyanide

SOLUTIONS TO NAVNEET PRACTICE PAPERS : STD. XII 13

Q. 30. (i) Given : Concentration of the solution  C
 0.2 M
 0.2 mol dm3
 0.2  103 mol m3
Temperature  T  300 K
R  8.314 J mol1 K1
The osmotic pressure,  is given by,
  CRT
 0.2  103  8.314  300
 4.988  105 Nm2 (or Pa)
Ans. Osmotic pressure  4.988  105 Nm2.
(ii) Given : 2H2O(l)  O2(g) IIIIIJ 2H2O2(l)
* H 0    196 kJ
*S 0    126 JK1  0.126 kJ K1
T  298 K
* G0  ?
Cross over temperature  T  ?
* G0 * H 0  T * S 0
 196  298 (  0.126)
 196  37.55
     233.55 kJ
 * G 0  0, the reaction is non-spontaneous.
  * H 0  0, * S 0  0,
Since at all temperatures, * G 0  0, there is no cross over temperature.
Ans. The reaction is non-spontaneous.
There is no cross-over temperature for the reaction.
OMgI OH
Q. 31. (i) A is CH3 – C – CH3 ; B is CH3 – C – CH3 tert-butyl alcohol (2-Methylpropan-2-ol)
CH3 CH3

(ii) A is CH3 – CNMgBr ; B is CH3 – CO Acetone (Propan-2-one)

CH3 CH3

————

14 SOLUTIONS TO NAVNEET PRACTICE PAPERS : STD. XII