VARUN JEE ADVANCED (2024)

Test - 01

DURATION: :180
DURATION 90 Minutes
Minutes DATE : 28/02/2024 M. MARKS: 180

Topics covered
Physics: Kinematics, Newton Laws of Motion
Chemistry: Periodic Table, Chemical Bonding
Mathematics: Quadratic Equations, Sequence and Series

SECTION-1 (Maximum Marks: 24)

This section contains EIGHT (08) questions.
• The answer to each question is a NUMERICAL VALUE.
• For each question, enter the correct integer corresponding to the answer using the mouse and the onscreen virtual
numeric keypad in the place designated to enter the answer. If the numerical value has more than two decimal places,
truncate/round-off the value of TWO decimal places.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.
SECTION-2 (Maximum marks: 24)
• This section contains SIX (06) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are)
correct answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 ONLY if (all) the correct option(s) is(are) chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.

SECTION-3 (Maximum marks: 12)

• This section contains FOUR (04) Matching List Sets.
• Each set has ONE Multiple Choice Question.
• Each set has TWO lists: List-I and List-II.
• List-I has Four entries (I), (II), (III) and (IV) and List-II has Five entries (P), (Q), (R), (S) and (T).
• FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these
four options satisfies the condition asked in the Multiple Choice Question.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.
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 PART-I (PHYSICS)
SECTION-1
Numerical Value Type Questions
1. A point moves according to the law
x = at , y = at (1 − t ) where a and  are positive
constants and t is time. If the moment at which
angle between velocity vector and acceleration
 A
vector is is given by . Find the value of A.
4 
2. A body is thrown up with velocity 100 m/sec. It
travels 5m in the last second of its journey in
upward direction. If the same body is thrown up
with a velocity 200 m/sec, how much distance (in
metres) will it travel in the last second of its
upward journey (g = 10 m/s2)
3. A ball is projected from the origin at time t = 0.
The x and y coordinates of its displacement are
given by x = 3t and y = 4t − 5t2. Where x and y are
in meter and t in second. Find the velocity of
projection (in m/sec)
4. Starting from rest at origin, the acceleration of a
particle moving on a straight line vary with
respect to time and is given by
a = ( 2t − 6 ) iˆ m/s , where t is in seconds. Find
2
the time (in seconds) at which velocity of particle
along negative x-direction is maximum.
5. An elevator is accelerating upwards with an
acceleration of 6 m/s2. Inside it a person of mass
50kg is standing on a weighing machine which is
kept on an inclined plane having angle of
inclination 600. The reading of the weighing
machine is (in Newton): (Take g = 10 m/s2)
6. Two blocks of equal mass 2 kg are placed on a
rough horizontal surface as shown and a force
F = 25iˆ + 10 ˆj N is applied on the upper block.
The system is initially at rest. Find acceleration of
the lower block in m/s2 (Take g = 10 m/s2)
perpendicular to current and the speed of the boat
in still water is u (relative velocity). The distance
through which the boat crossing the river will be
carried away by the current if the width of river is
 CV 
C, will be n  0  . Find the value of n.
 u 
8. A particle is projected with a velocity
v = 8iˆ + 6 ˆj m/s from the earth's surface. The
radius of curvature of the particle at its highest
position is ________m. (Take g = 10m/s2)
SECTION-2
One Or More Then One Correct Type Questions
9. For the following system shown assume that
pulley is frictionless, string is massless (m remains
on M)
M
C
m
AM M B
Choose the correct option(s)
(A) Acceleration of block A is
mg
2M + m
2mg
(B) Acceleration of block A is
2M + m
2 Mmg
(C) Normal reaction on C is
2M + m
( 6M + 5m ) Mg
(D) The force on the ceiling is
2M + m
10. A wedge of mass M is placed on a horizontal
smooth surface. A block of mass m is placed on
the smooth wedge and it is pulled by a constant
force F with the help of a string passing over an
ideal pulley. m is not sliding on the wedge and
both m and M are moving with the same
acceleration. (Given M > 2m )

(A) Pseudo force on the m as seen from M is

m2 g sin 
M + m − m cos 
MF
(B) Pseudo force on M as seen from m is
M+m
(C) Pseudo force on M as seen from m is zero.
7. The current velocity of a river grows in proportion (D) The normal force between M and m for θ =
to the distance from its bank and reaches the
mF
maximum value V0 in the middle. Near the banks 45° is greater than .
the velocity is zero. A boat is moving along the M +m
river in such a manner that it is always
11. In the adjoining figure a bead of mass m is free to velocity. Select the correct option/s from the
slide along the rod of length 2l without friction. following about the motion of particle Y so that all
Initially the bead is at the middle of the rod and the three particles will be at the same straight line
rod is moving horizontally in the horizontal plane if all begins to move simultaneously
with acceleration ‘a’ which makes an angle θ with v
(A) Initial velocity upward
the rod as shown. Choose the incorrect options. 2
a
(B) Initial acceleration upward.
2
v
(C) Initial velocity downward
2
a
(D) Initial acceleration downward.
2

14. The motion of a body is given by the equation

(A) Acceleration of bead with respect to dv(t )
stationary observer is a cos  = 6.0 − 3v(t ) . where v(t ) is speed in m/s
dt
(B) Acceleration of bead with respect to rod is and t in sec . If body was at rest at t = 0
a sin  along the rod. (A) The terminal speed is 2.0 m/s
(C) Acceleration of bead with respect to (B) The speed varies with the time as
stationary observer a sin  v(t ) = 2(1 − e −3t )m/s
(D) Acceleration of bead with respect to rod is (C) The speed is 0.1m/s when the acceleration is
a cos  along the rod.
half the initial value
(D) The magnitude of the initial acceleration is
12. Two trains A and B are moving with same speed
6.0 m/s2
of 100km/hr. Train ‘A’ moves towards east and
train B moves towards west. At an instant when
SECTION-3
the trains are moving side by side, an aeroplane
Matrix Match Type Questions
files above the trains horizontally. For the
15. Configuration of L shaped block and two other
passengers in the train A, the plane appears to fly
blocks are shown. System is set free to move. At
from North to South direction. For the passengers
any moment, match the following parameters. (g
in the train B, the plane appears to fly in a
= 10 m/s2)
direction making an angle 60° East of South.
(A) The speed of the plane with respect to ground
7
is 100 km/hr
3
(B) The speed of the plane with respect to ground
is 100 3 km/hr
(C) The plane moves in a direction at an angle of List-I List-II
3 I Friction force between block A P 50N
tan −1 East of South. (with respect to
2 and B
ground) II Tension in string Q 70N
(D) The plane moves in a direction at an angle of III Normal reaction on block A by R 20N
5 block B
tan −1 East of South. (with respect to IV Normal reaction on block B by S 10N
2
table
ground)
T 40N
I II III IV
13. Three particles X, Y and Z are placed on straight
(A) S P R Q
horizontal line at equal distance from one another.
(B) S P R T
Particle X starts moving vertically up with a
(C) P S R Q
constant velocity v and particle Z vertically down-
(D) S Q T P
ward with constant acceleration a without initial

[4]
16. Starting at t = 0, a body moves in a straight line 18. Two blocks of masses m1 = 5kg and m2 = 2kg are
along a horizontal plane for which displacement connected by threads which pass over the pulleys
s = t 3 − 9t 2 + 24t meter, where t is time in seconds as shown in the figure. The threads are massless
& v is the velocity in m/s. and the pulleys are massless and smooth. The
List-I List-II blocks can move only along the vertical direction.
I For P |v| is decreasing for a part T1 and T2 are the tensions in the string as shown.
t2 of its motion Now match the following:
[take g = 10m/s2]
II For Q |v| is increasing for a part of
2t 4 its motion
III For R s is decreasing
t 3
IV For S s is increasing
t 3
T None of these

I II III IV
(A) P, S P, Q, R P, Q, R P, Q, R, S
(B) Q, S P, R T P, Q, R
(C) P, S Q, R P,Q,S T List-I List-II
(D) P, S P, Q, R P, Q, R, S P, Q, R, S 1 Magnitude of P 500
acceleration of m1 SI units
17. Match the list-I with list-II (symbols have usual 19
with respect to ground
meanings)
2 Magnitude of Q 250
List-I List-II acceleration of m2 SI units
19
I Average speed P v dt  with respect to ground
 dt
3 The value of tension R 60
T1 SI units
19
II d2r
of a particle
Q
 v dt 4 The value of tension S 40
SI units
dt 2
 dt
T2 19
moving in a curve T 150
III Tangential R Rate of change in SI units
acceleration velocity 19
IV Average velocity S Rate of change in I II III IV
speed (A) S R Q P
(B) S R P Q
T Rate of change of
(C) R S T P
displacement
(D) S R P T
I II III IV
(A) Q R P S
(B) Q R S P
(C) P Q R T
(D) P R T Q

PART-II (CHEMISTRY)
SECTION-1 Then calculate value of x + y – z where x is total
Numerical Value Type Questions number of gerade orbitals and y is total number
19. How many of the following molecules are polar? of ungerade orbitals and z is total number of axial
orbitals in given above orbitals.
PCl5(g), SF6, BF3, XeF2, XeO3, , , 21. Consider the following three compounds (i)
AX n2n− , (ii) AX3n and (iii) AX n4n+ , where central
atom A is 15th group element. If total number of
protons in surrounding atom X is n and value of n
is one, then calculate value of “a3 + b2 + c”.
(Where a, b and c are total number of lone pairs
20. Consider the following orbitals: at central atom in compound (i), (ii) and (iii)
(i) 3px (ii) 4d z 2 respectively).
(iii) 3d x 2 − y2 (iv) 3d yz

[5]
22 Consider the following combination of atomic 28. Which of the following statement is/are correct?
orbitals (A) In PCl3F2, the P – F bond length is greater
Combining orbitals (Internuclear axis) than P – Cl bond length.
Combining orbitals (Internuclear axis) (B) N – N bond length in N2H4 is greater than N
(i) s + px(x) (ii) dxy + dxy(x) – N bond length in N2F4.
(iii) dyz + pz(z) (iv) s + s(z) (C) In PCl5, the P – Cl axial bond length is
(v) dyz + dyz(x) (vi) py + py(y) greater than P – Cl equatorial bond length.
(vii) d z + d z (z)
2 2 (viii) dxy + dxy(z) (D) In SF6, all S – F bonds have equal bond
(ix) px + px(y) (x) s + pz(x) length.
Then calculate value of a2+ b2 + 2cd. (where a =
 M. O.; b =  M.O.; c =  M.O.; d = non- 29. Which of the following statement(s) is/are true
for CH2 = CH2 and CH2 = SF4 (Methyl sulphur
bonding M.O.)
tetrafloride)?
23. Number of unpaired electrons in Mn+7 = a (A) In ethylene, nodal plane lies in molecular
Number of d-subshell electrons in Cr = b plane
Number of f-subshell electrons in Hf (Z = 72) = (B) In methylene sulphur tetrafluoride, nodal
c. Find the value of c – b + a. (Where Z is atomic plane of π-bond lies in axial plane
number) (C) In methylene sulphur tetrafluoride, nodal
plane of π-bond lies in equatorial plane
24. Which of the following has less than two bond (D) If the nodal plane lies in equatorial plane, its
order? stability will be less than if its lies in axial
NO3− , CO32 − , F2 , Cl2 , Br2 , O 22 − , plane
30. Which of the following is/are correct :
O −2 , N −2 , O 22 + , O +2 , Li +2 , He +2
(A) Carbon-carbon bond length in CaC2 will be
more than that in CH2CCH2
25. In how many of the following species, bonding is
(B) O–O bond length in KO2 will be more than
taking place in excited state?
that in Na2O2.
BeCl2(g), CCl4, NF3, SO32 − , PCl5(g), OF2, BF3, (C) O–O bond length in O2 [PtF6] will be less
NOCl, H2S than that in KO2
(D) N–O bond length in NO gaseous molecule
26. Find the number of molecule which are planar will be smaller than that in NOCl gaseous
(a) ClF3 (b) SF4 (c) XeF6 (d) XeF2 molecule.
(e) XeF4 (f) H2O (g) H2S (h) NH3
(i) PH3 (j) PCl5 (k) PCl3 (l) OCl2 31. Consider the following values of I.E. (eV) for
elements W and X :
Element I.E.1 I.E.2 I.E.3 I.E.4
SECTION-2
W 10.5 15.5 24.9 79.8
One Or More Then One Correct Type Questions
X 8 14.8 78.9 105.8
27. Which of the following is/are correct for
Other two elements Y and Z have outer electronic
structure given below for [I5]– ?
configuration ns2np4 and ns2np5 respectively. Then
according to given information, which of the
following compound(s) is/are not possible?
(A) W2Y3 (B) X2Y3
(C) WZ2 (D) XZ2
32. There are three elements A, B, and C. Their atomic
number are Z1, Z2 and Z3 respectively. If Z1– Z2 = 2
(A) There are 14 lone pairs of electrons in given Z + Z2
structure for [I5]– and 1 = Z3 − 2 , the electronic configuration
2
(B) There are 5  bonds in given structure for of element A is [Ar]3d64s2, then correct order of
[I5]– spin only magnetic moment is/are:
(C) I(a) has positive formal charge while I(b) (A) B+ > A2+ > C2+ (B) A3+ > B2+ > C
has negative formal charge (C) B > A > C 2+
(D) B = A3+ > C3+
(D) I(a) is sp3 hybridized while I(b) is sp3d
hybridized
[6]
 SECTION-3 35. List – I contains properties and List – II contains
Matrix Match Type Questions moles or ions
33. Match List-I containing pair of species with List- List-I List-II
II containing similarity in their property I 2 lone pair on central atom P XeF5−
List-I (Pair of species) List-II (Similarity in II Zero dipole moment (excluding Q NF3
property) any moment due to cationic or
I SO2 (g) and SO3(g) P Number of pπ-pπ anionic charge)
bond (if present) III Planar R ICl3
II P4O6 and P4O10 Q Hybridisation of IV All adjacent bond angles are S XeF4
central atom equal (Neglect any bond angles 
III SF4 and SOF4 R Planar 180°)
IV C6H6 and B3N3H6 S oxy linkage T PCl3F2
present (A) I→(P, Q); II→(P, Q); III→(R, S); IV→(S, T)
T Aromatic species (B) I→(P, Q, R); II→(P, S, T); III→(P, R, S);
(A) (I) → (P, Q, R); (II) → (Q, S); (III) → (Q); IV→(P, S)
IV→ (P, Q, R, T) (C) I→(P, R, S); II→(P, S, T); III→(Q, R);
(B) (I) → (Q, S); (II) → (P, Q, R); (III) → (Q);
IV→(Q, R, S)
IV→ (P, Q, R, T)
(D) I→(P, R, S); II→(P, S, T); III→(P, R, S);
(C) (I) → (P, Q, R); (II) →(Q); (III) → (Q, S);
IV→(P, Q, R, S)
IV→ (P, Q, R, T)
(D) (I) → (P, Q, R); (II) → (Q, S); (III) → (Q,
36. Match the compounds listed in List-I with
R); IV→ (P, Q, T)
characteristic(s) listed in List-II.
List-I List-II
34. Match the following-
I Chloral P Forms a zig-zag chain in
List-I List-II
 Θ
hydrate both solid and also in
I Na F P Electronegativity
the liquid
2Θ
O  N3Θ II Hydrogen Q Forms two-dimensional
II Li  Na   K  Q Mobility of fluoride sheet with almost

 Rb  Cs  hydrated ions hexagonal symmetry
III O < S < F < Cl R 1st Ionisation III Crystalline R Intramolecular H–bond
energy boric acid
IV ClΘ  K  S Electron affinity IV Sulphuric S Intermolecular H–bond
 Ca 2  Sc3 acid
T Ionic size T No hydrogen bonding
(A) I→(Q); II→(P, T); III→(S); IV→(P, Q, R) (A) I→(R); II→(P, S); III→(Q, S); IV→(S)
(B) I→(T); II→(P, T); III→(R); IV→(P, Q, S) (B) I→(P, T); II→(R, S); III→(Q, S); IV→(R)
(C) I→(R); II→(Q, T); III→(P, S); IV→(S)
(C) I→(Q); II→(R, T); III→(Q); IV→(P, R, S)
(D) I→(R, S); II→(Q, R); III→(S); IV→(P, T)
(D) I→(T); II→(Q, T); III→(S); IV→(P, R, S)

PART-III (MATHEMATICS)
SECTION-1 39. If  and  are the values of k for which the roots
Numerical Value Type Questions of equation x3 + 6x2 + kx – 8 = 0 are in A.P. and
37. Sum of the series G.P. respectively. Then  –  equal to:
 11  1 11  1 1 1 1
1 + 1 +  + 1 + +  + 1 + + +  + ...
 3  2  3 9  4  3 9 27  8
40. The largest positive term (Tn) of the H.P. whose
is equal to
2 12
first two terms are and is:
5 23
38. If s(r) = 2 + 2r + 2r2 + .....  and s(a)  s(–a) =
420, where a, r  (–1, 1). Then the value of
41. If the equation x4 – 4x3 + ax2 + bx + 1 = 0 has four
s ( a ) + s ( –a )
is equal to  a −b 
150 positive roots, then the value of   is equal to
 100 

[7]
42. The largest integral value of a for which all the b p2
roots of the equation (a – 1) (x2 + x + 1)2 = (a + 1) (B) , , a2 are in A.P.
2 2
(1 + x2 + x4) are imaginary, is (C) 1 + b, p, a are in G.P
(D) a, p2, 1 + b are in G.P.
43. If a, b, c are real numbers such that 0 < a < 1, 0 <
b < 1, 0 < c < 1, a + b + c = 2, then the least value 49. For the quadratic equation x2 + 2(a + 1)x + 9a – 5
a b c = 0 which of the following is/are true?
of . . is equal to
1 a 1 b 1 c (A) If 2 < a < 5, then roots are of opposite sign
(B) If a < 0, then roots are of opposite sign
44. If number of integral values of ‘m’ for which exactly (C) If a > 7, then both roots are negative
one root of the equation x2 + 3mx + m2 – 4 = 0 lies (D) If 2  a  5, roots are unreal
k  50. If a, b, c are positive and a = 2b + 3c, then roots
on the interval (–6, 2) is k. Then   =
5 of the equation ax2 + bx + c = 0 are real for
(where [.] denotes greatest integer function) a c
(A) − 11  4 7 (B) − 11  4 7
c a
SECTION-2 b c
One Or More Then One Correct Type Questions (C) −4 2 7 (D) −4 2 7
c b
45. A three digit number N is such that its digits are in
G.P. and the digits of the number obtained by
SECTION-3
subtracting 400 from it form an A.P. then
Matrix -Match Type Questions
(A) The difference between the digits at the
51. Match List-I with List-II.
hundred’s place and at the unit’s place of N is 8
List-I List-II
(B) Sum of digits at the ten’s place and at the I If t1, t2, t3, t4, t5 are first five P 2
unit’s place of N is 5 terms of an A.P., then
(C) Product of digits of N is 54 4(t1 − t2 − t4 ) + 6t3 + t5
(D) N + 69 is a perfect cube of a positive integer is equal
t1
to (t1  0)
46. Let α and β be the roots of equation ax2 + bx + c = 0; II   Q 3
K
(a, b, c  R, a  0), then one of the roots of equation   2n + K is equal to
a3x2 + abcx + c3 = 0 is K =1 n =1

(A) α2 + β (B) α β2 III If Tn denotes the nth term of the R 4

H.P. from the beginning such
(C) α β2
(D) α + β2
T
that 2 = 9 , then the value
T6
47. Let a, b, c are positive real numbers forming an
A.P. The equation ax2 + 2bx + 5c = 0 will have T5
of is equal to
real roots for T19

a c IV The value of S 5
(A) 2 5 2 6 12
c a + 3 + 3
1 1 + 2 1 + 23 + 33
3 3

a c 20
(B) 2 5 + 3 + ...
c a 1 + 23 + 33 + 43
upto infinity is equal to
a c
(C) 4 T 6
c a
Which of the following is the only correct
a c combination?
(D) 4 I II III IV
c a
(A) S Q P T
(B) P Q R T
48. a and b are non-zero real numbers and the
(C) Q P S R
equations ax2 – p2x + ab = 0, x2 – ax – bx + ab = 0
(D) T R Q S
may have a common root, then
p2
(A) a2, , b are in A.P.
2

[8]
52. Match the Lists 5 11 17
+ + + ...
List- I List -II 12  42 42  7 2 7 2 102
I Let Sn, S2n, S3n be the sums of first P 3 is
n, 2n, 3n terms of an arithmetic III If the first two terms of the R 1
S3 n Harmonic progression are 3
progression, then is equal
S2n − Sn 1 1
and , then the Harmonic
to 2 3
II n i j Q 4 mean of the first four terms is
The value   1 = 220, then IV The sum of the series S 36
i =1 j =1 k =1
2 1 4
the value of n equals 1 + + + + .....
3 3 27
III Let gn be the nth terms of the R 6
T 9
geometric progression of positive
100
10
4
numbers. If  g 2n = 3 and I II III IV
n =1
(A) P Q R S
100
5
 g2n−1 = 9 , then the common (B) R S T P
n =1 (C) S P R Q
ratio of geometric progression, is (D) Q R P T
IV A geometric progression consists of S 8
an even number of terms. If the sum 54. Match the values of x given in List-II satisfy the
of all the terms is 5 times the sum of exponential equation given in List-I. Remember
terms occupy the odd place, then its
that for a > 0, the term ax is always greater than
common ratio is
zero  x  R
T 10
List- I List -II
I II III IV
I 42/x – 5 (41/x) + 4 = 0 P 3
(A) P T R Q
II 22x+1 – 33(2x – 1) + 4 = 0 Q –2
(B) P Q R S
–1
− 9  2 x + 2  + 8 = 0
III 2
+2 2 R
(C) T R P Q 4x
 
(D) R S P Q
IV 52 x − 7 x − 52 x ( 35 ) + 7 x ( 35 ) = 0 S 0

53. Match List-I with List-II T 1

List- I List -II I II III IV
I The arithmetic mean of two P 2 (A) T P, S Q, S R
positive numbers is 6 their 7 (B) R S, T T R
geometric mean G and
(C) T P, Q R, T S
harmonic mean H satisfy the
(D) R R P T
relation G2 + 3H = 48, then
product of the two number is
II The sum of the series Q 32

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