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Sec: Incoming.Sr.IIT_CO.

SC Date: 05-07-20
Time: 3HRS Max. Marks: 183

Name of the Student: ___________________ H.T. NO:

05-07-20_ Incoming.Sr. IIT_CO.SUPER CHAINA _Jee-Adv_CAT-45_SYLLABUS

PHYSICS: Magnetics(60%), Kinematics(40%)


CHEMISTRY: PRESENT WEEK (50%):Qualitative Analysis: Introduction, flame
test,borax bead test, charcoal test ,micro cosmic bead test, Action of
heat, Acid radicals
PREVIOUS WEEK (25%):Preparation & Properties of some
important compounds: Preparation & Properties of Potassium
permanganate, Oxides, chlorides and sulphates of Fe2+, Cu2+,
Zn2+,Silver oxide, Silver nitrate, Silver thiosulphate,oxides and
chlorides of Sn and Pb
CUMULATIVE(25%): 1) Tollen’s test 2) VBT & magnetic moment of
complexes 3) Properties of colloids & Application of colloids
MATHEAMTICS : PRESENT WEEK (50%):Number of functions, Division of different
things (identical / distinct into different groups ),
PREVIOUS WEEK (25%):Complete combinations, Number of integral
solutions of linear equations, Principle of Inclusion & Exclussion,
Derangement
CUMULATIVE(25%): Binomial theorem
Narayana IIT Academy 05-07-20_Incoming.Sr.IIT_CO SC_JEE-Adv_CAT-45_Q’P
Time: 03:00 Hr’s IMPORTANT INSTRUCTIONS Max Marks: 183
PHYSICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions With Multiple Correct Choice
Sec – I (Q.N : 1 – 7) +4 -2 7 28
(partial marking scheme) (+1,0)
Sec – II (Q.N : 8 – 12) Questions With Integer Answer Type +3 0 5 15

Sec – III (Q.N : 13 – 18) Questions With Single Answer Type +3 -1 6 18


Total 18 61

CHEMISTRY:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions With Multiple Correct Choice
Sec – I (Q.N : 19 – 25) +4 -2 7 28
(partial marking scheme) (+1,0)
Sec – II (Q.N : 26 – 30) Questions With Integer Answer Type +3 0 5 15
Sec – III (Q.N : 31 – 36) Questions With Single Answer Type +3 -1 6 18
Total 18 61

MATHEMATICS:
+Ve - Ve No.of Total
Section Question Type
Marks Marks Qs marks
Questions With Multiple Correct Choice
Sec – I (Q.N : 37 – 43) +4 -2 7 28
(partial marking scheme) (+1,0)
Sec – II (Q.N : 44 – 48) Questions With Integer Answer Type +3 0 5 15
Sec – III (Q.N : 49 – 54) Questions With Single Answer Type +3 -1 6 28
Total 18 61
Narayana IIT Academy 05-07-20_Incoming.Sr.IIT_CO SC_JEE-Adv_CAT-45_Q’P
PHYSICS Max.Marks:61
SECTION – I
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 7 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options, 0 if not attempted and -2 in all wrong cases.
1. A proton of charge ‘e’ and mass ‘m’ enters a uniform and constant magnetic field
 
B  B i with an initial velocity V  Vox i  Voy j . Which of the following will be correct at

any later time ‘t’ :

A) x – component of velocity of the proton will be Vox cos 


qBt 

 m 

B) y – component of velocity will be Voy cos 


qBt 

 m 

C) z – component of velocity will be Voy sin 



qBt 
m
 

 along  k direction

D) x – component of velocity will remains unchanged



2. A charged particle enters into a gravity free space which contains an electric field E and

magnetic field B and it comes out without any change in velocity. Then the possible
cases may be
       
A) E  0, B  0 B) E  0, B  0 C) E  0, B  0 D) E  0, B  0

3. A particle stays at rest as seen in a frame. We can conclude that

A) The frame inertial

B) Resultant force on the particle is zero

C) The frame may be inertial but the resultant force on the particle is zero

D) The frame may be non inertial but there is a nonzero resultant force

4. A particle is thrown with a velocity u at an angle  with the horizontal surface. The
coefficient of restitution between particle and floor is e. Assume that the floor is
frictionless.


Narayana IIT Academy 05-07-20_Incoming.Sr.IIT_CO SC_JEE-Adv_CAT-45_Q’P
A) Time of flight of the particle for the entire motion is infinity

2u sin 
B) Time of flight of the particle for the entire motion is
g 1  e 

C) Displacement of the particle for the entire motion from the point of projection is
infinity

D) Displacement of the particle for the entire motion from the point of projection is
 2 sin 2
g 1  e 

5. A uniform magnetic field B0 k exists to the right of the plane y = x tan  as shown. At

t = 0 a particle of mass m and positive charge q with velocity v0 i enters in magnetic


field at origin. Then

m
A) particle will come out from magnetic field after t 
qB0

2m
B) particle will come out from magnetic field after time = t 
qB0

C) co-ordinate of point from which particle will come out is


 mv0 mv0 
 sin 2, 1  cos 2  , 0
 qB0 qB0 

 mv mv 
D) Co-ordinate of point from which particle will come is  0 sin , 0 1  cos   , 0 
 qB0 qB0 
Narayana IIT Academy 05-07-20_Incoming.Sr.IIT_CO SC_JEE-Adv_CAT-45_Q’P
6. In case figure (a) and (b), a positive charge particle of mass m and charge q is given
velocity ‘v’ at the lowest point of a smooth fixed sphere of radius R. In both cases
circular motion is in the plane of the paper. In case (b) magnetic field is also switched
on in inward direction. If a point p, v1 and v 2 N1 and N 2 , are velocities and normal forces
in two cases respectively then

A) v1  v 2 and N1  N 2 B) v1  v 2 and N1  N 2

C) v1  v 2 and N1  N 2 D) v1  v 2 and N1  N 2

7. Figure shows a square current carrying coil of edge length L. The magnetic field on the
 B0 y  B0 x 
coil is given by B  i j , where B0 is a positive constant.
L L

1
A) If coil is free to rotate about x-axis torque on the coil is given by iAB0 j .
2

1
B) If coil is free to rotate about y-axis torque on coil is given by  iAB0 j .
2

C) Resultant force on coil is zero


 
D) Equation for the torque   where  is magnetic moment of coil is not valid on the
coil.
Narayana IIT Academy 05-07-20_Incoming.Sr.IIT_CO SC_JEE-Adv_CAT-45_Q’P
SECTION-II
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer , 0 if not attempted and 0 in all other cases.
8. A ball is projected inside a room of height 7m with a speed of 20 m/s and at an angle
37 with the horizontal. If its collision with ceiling results in reversal of direction only

of y-component of velocity. T is minimum value of total time of flight (in sec) till it
strikes floor, then T = ?

9. A small ball is projected along the surface of a smooth inclined plane with speed 10m/s
along the direction shown at t = 0. The point of projection is origin, z-axis is along
vertical. The acceleration due to gravity is 10m / s 2 . Minimum speed occurs at t = ____
(in sec)


10. A particle is projected with a velocity v  8j 6jm / s . The time after which is will start

moving perpendicular to its initial direction of motion  g  10jm / s 2  is


 k
sec, where k
3
is ____

11. A non-conducting disc of radius R, having a concentric hole of radius R/2 carries a
uniform positive surface charge of area density  on one face. It is rotated with an
angular velocity  about a perpendicular axis passing through its centre. Its magnetic
moment is R 4 / 8x , find the value of x.

12. A long straight wire, carrying current l, is bent at its midpoint to form an angle of 45 .
Induction of magnetic field at point P, distant R from point of bending is equal to

 
2  1 0 I
. Find the value of x
xR
Narayana IIT Academy 05-07-20_Incoming.Sr.IIT_CO SC_JEE-Adv_CAT-45_Q’P
SECTION – III
(SINGLE CORRECT ANSWER TYPE)
This section contains 6 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Answer Q.13, Q.14 and Q.15 by appropriately matching the information given in the
three columns of the following table.
A charged particle (electron or proton) is introduced at the origin (x = 0, y = 0, z = 0)
 
with a given initial velocity v . A uniform electric field E and a uniform magnetic field
   
B exist everywhere. The velocity v , electric field E and magnetic field B are given in

columns 1, 2 and 3 respectively. The quantities E 0 , B0 are positive in magnitude

COLUMN I COLUMN II COLUMN III


 E0   
I Electron with v  2 x i E  E 0 z P B  B0 x
B0

 E0   
II Electron with v  y ii E   E 0 y Q B  B0 x
B0

  
III Proton with v  0 iii E   E 0 x R B  B0 y

 E0   
IV Proton with v  2  x iv E  E 0 x S B  B0 z
B0

13. In which case will the particle move in a straight line with constant velocity ?

A) (III) (ii) (R) (B) (IV) (i) (S) (C) (III) (iii) (P) (D) (II) (iii) (S)

14. In which case will the particle describe a helical path with axis along the positive z
direction ?

A) (IV) (i) (S) (B) (II) (ii) (R) (C) (III) (iii) (P) (D) (IV) (ii) (R)

15. In which case would the particle move in a straight line along the negative direction of
y-axis (i.e., move along - y ) ?

A) (II) (iii) (Q) (B) (III) (ii) (R) (C) (IV) (ii) (S) (D) (III) (ii) (P)
Narayana IIT Academy 05-07-20_Incoming.Sr.IIT_CO SC_JEE-Adv_CAT-45_Q’P
Answer Q.16, Q.17 and Q.18 by appropriately matching the information given in the
three columns of the following table.
Column I Column II Column III
y

 
I) i) 
u a  10i 10 j P) H=5m
30
x

 
II) ii 
u a  20 j Q) T = 1 sec
)
45
x

ii 
Particle will travel in
III)
ai  5i R) straight line with no
u ) change in direction
x

IV)
u )
 
iv a  10 j
S)
 x 
y  x 1  
 40 

16. If u = 40 m/s, then the correct match satisfying the above condition is
A) (I) (i) (R) B) (II) (ii) (Q) C) (II) (iv) (S) D) (III) (iv) (S)
17. If u  20 2m / s , then the incorrect match satisfying the above condition is
A) (II) (iv) (S) B) (II) (iii) (R) C) (IV) (i) (Q) D) Both B & C
18. If u  20 2m / s , then the correct match satisfying the above condition is
A) (II) (iv) (R) B) (III) (iv) (Q) C) (I) (ii) (P) D) (II) (ii) (P)
Narayana IIT Academy 05-07-20_Incoming.Sr.IIT_CO SC_JEE-Adv_CAT-45_Q’P
CHEMISTRY Max.Marks:61
SECTION – I
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 7 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options, 0 if not attempted and -2 in all wrong cases.
19. Which of the following cations can be detected by the flame test?

A) Mg 2 B) K  C) Sr 2  D) Ba 2 

20. Which of the following compound/compounds will give first a white ppt with hypo
solution, that on standing turns black ?

A) Pb(CH3COO)2 B) I2 C) FeCl3 D) AgNO3

21. The borax bead test can be used to detect the presence of
A) Al3 B) Cr 3 C) Cu 2 D) Co2
22. Which of the following reagents can be used to distinguish between SO2 and CO2
A) Lime water B) BaCl2
C) H 2O2  BaCl2 D) Acidified dichromate paper
23. A metallic oxide (X) strongly acidic forms violet vapours on warming and explodes
violently at 550C giving out oxygen and a weak acidic oxide (Y). The compound (X)
on dissolution in water gives characteristic purple colour of (Z). What will be (X), (Y)
and (Z)

A) X = Mn2O3 B) Y = MnO2 C) Z = HMnO4 D) X = Mn2O7

24. Identify the correct statement(s)

A) AgNO3 is called Lunar caustic

B) AgNO3 heated to red hot forms Ag, NO2 and O2

C) With K2CrO4 silver nitrate solution forms yellow ppt of Ag2CrO4

D) PbCl2 dissolves in Hot water.

25. On being heated with conc. HNO3 and ammonium molybdate solution, a salt solution
gives an yellow ppt. The salt may be

A)Na2HPO4 B) As2O3 C) FeSO4 D) BaCl2


Narayana IIT Academy 05-07-20_Incoming.Sr.IIT_CO SC_JEE-Adv_CAT-45_Q’P
SECTION-II
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer , 0 if not attempted and 0 in all other cases.
26. The presence of nitrate ion is detected by brown ring test. The number of unpaired
electrons present at the metal ion in that complex is.

27. Oxidation state of cobalt in Rinmann green is x. While its oxidation state in Thenards
Blue is y. What is the value of x+2y?

28. In alkaline medium K 2Cr2O7 reacts with 30% H 2O2 and forms a red-brown complex
compound. The oxidation state of Cr is + n in that complex. Then n value is.

29. Addition of 4.0 ml of 0.005 M BaCl2 solution to 16.0 ml of arseneous sulphide sol just
causes the complete coagulation. Find out the flocculating value of the effective ion.

30. How many of the following compounds would give a positive Tollen’s test?

(I) (II)

(III)

(IV)

(V) CH3COOH, (VI) HCOOH (VII) CHOCOOH

(VIII) CHOCHO (IX) CH3COCH2OH (X) CH3COCH(OH)CH3


Narayana IIT Academy 05-07-20_Incoming.Sr.IIT_CO SC_JEE-Adv_CAT-45_Q’P
SECTION – III
(SINGLE CORRECT ANSWER TYPE)
This section contains 6 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Answer Q.31, Q.32 and Q.33 by appropriately matching the information given in the
three columns of the following table.
Anion +acid(dil or Gas Produced +
Test
conc) + Heat other interaction
Dichromate turns green with gas
1 Carbonate ion a CO2 p
produced
white ppt with Lead Acetate
2 ThioSulphate ion b NO2 q Solution which turns black on
standing (original anion)
white ppt with lead acetate solution,
3 Sulphite ion c SO2 r
dissolves on heating (original anion)
white ppt with lead acetate solution
4 Nitrate ion d HCl s
remains the same (original anion)
produces brown ring with Fresh
White
5 Chloride ion e t FeSO4 solution and conc Sulphuric
ppt/colloid
Acid.(original anion)
31. Which of the following options is correct?
A) 1 =a = r B) 2 = e =s C) 2 = c = p,q D) 2 =e = p,s
32. Which of the following options is correct?
A) 3 = e = p B) 3 = c = q C) 3 = c = r D) 3 = c = p
33. Which of the following options is incorrect?
A) 4= b = t B) 5 = d= p,r C) 5 = d = p D) 2 = c,e = p,s
Answer Q.34, Q.35 and Q.36 by appropriately matching the information given in the
three columns of the following table.

Complex Hybridisation Magnetic character


1 [Fe(H2O)6]2+ a sp3d 2 p Diamagnetic, µ = 0
2 [Cr(CO)6] b d 2sp3 q Paramagnetic , µ = 4.9
3 [CoF6]3- c dsp 2 r Paramagnetic, µ = 1.73
2+ 3
4 [Cu(NH3)4] d sp s Paramagnetic, µ = 2.83
5 [NiCl4]2-

34. Which of the following options is correct?


A) 1 = a = q B)1 = a = p C) 3 = a = p D)5 = c = p
35. Which of the following options is correct?
A) 4 = d = r B) 4 = c = r C)2 = b = q D) 2 = a = q
36. Which of the following options is incorrect?
A) 3 = a = q B)2 = b= p C) 4 =d = r D)4 = c = r
Narayana IIT Academy 05-07-20_Incoming.Sr.IIT_CO SC_JEE-Adv_CAT-45_Q’P
MATHEMATICS Max.Marks:61
SECTION – I
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 7 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options, 0 if not attempted and -2 in all wrong cases.
37. All face cards from a pack of 52 playing cards are removed and and remaining 40
cards are arranged in a line. Number of ways in which ……(face cards are J,Q,K and
card with symbol A is consider as smallest )
40!
A) Cards of each suit appear in increasing order of denominations is
10!4
40!
B) Cards of each suit appear in increasing order of denominations is
10!4 .4!
40!
C) Black cards appear in non – decreasing order of denominations is
20!
40! 10
D) Black cards appear in non – decreasing order of denominations is 2
20!
38. The number of words that can be formed by taking ‘n’ letters at a time out of the
letters of the word ‘MATHAMATICS’ .Then which of the following option(s) is/are
incorrect?.....(Any word need not to be meaningful)
A) The number of words that can be formed for value n  4 is 2454.
B) The number of words that can be formed for value n  4 is 1425.
C) The number of words that can be formed for value n  3 is 399
D) The number of words that can be formed for value n  3 is 269

39. lim
n  52  . cos   
n

n 
5  2   is equal to (where n  I and . , 

. denotes greatest

integer function and fractional part function respectively)


A) 0 When n is even B) -1 when n is even
C) -1 when n is odd D) 0 when n is odd
40. Consider a cube of side length 9 units. Let (x, y, z) be coordinates of points on or
inside the cube such that x, y, z  I and 0  x, y, z  9 . If total number of ways of
selecting two distinct points among these such that their midpoint is also having
integral coordinates is N, then

A) N is divisible by 30 B) N is divisible by 31

C) N is divisible by 32 D) Number of positive integral factors of N is 40


Narayana IIT Academy 05-07-20_Incoming.Sr.IIT_CO SC_JEE-Adv_CAT-45_Q’P

Sum of the series S  


n 3r  4  C 
n
3
n 4
  is……(for defined values of n)
Cr 3r

r
41. r 4 n 4
r 0 C4 r 0 C4

A) n3
4n 3
B)
64 22 n 
Cn  n3 Cn1 n 4
Cn

4n 3 4n  4
C) n 4
D) n 4
C4 C4

Let for n  N :  2 x 2  2 x  1    1r ar x r then


n 2n
42.
r 0

2n 2n
A)  ar  1 B)   1r ar  0
r 0 r 1

 
2n
C)  n Ck 2n2k
Cr  2nr ar D)   1r ar a2nr  0 if n is odd
k 0 r 0

43. A group of 10 married couples getting ready for an excursion in a small 5 boats, in
particular, they have to split into five groups of four persons each. In each boat four
persons should sit. Consider all boats are identical. Then the correct option(s) is/are

A) The number of ways can they split and travel in such a way that on each boat there

will be two men and two women is


10!
2
.
1
 2!  5!
10

B) The number of ways can they split and travel in such a way that there be a certain
Mr.X on the same boat with his wife and on each boat there will be two men and two

women is
 9!
2
.
5
 2!8  5!

C) The number of ways in which they can be split and travel so that two particular
men Mr. X and Mr. Y are always with their respective wives, and on each boat there

will be two men and two women is is


 8!2 . 17
 2!8  4!

D) The number of ways they can split and travel is


 20!2 . 1
 4!5  5!
Narayana IIT Academy 05-07-20_Incoming.Sr.IIT_CO SC_JEE-Adv_CAT-45_Q’P
SECTION-II
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer , 0 if not attempted and 0 in all other cases.
44. There is a disease CORONA caused by corona virus spreading everywhere in the
world. So in a hospital ,the staff wants to line up 6 corona patients ,7 doctors,10 police
persons(doctors and police does not have corona) in such a way that every corona
patient stands between a doctor and police, and a doctor and police never stand next to
each other. In The number of ways this can be done by staff is N, then the value of
N
is
495.  6! 7!10!

45. There are 5 different boxes(with numbers 1,2,3,4,5 on them) and 7 different balls. The
number of ways in which these balls can be distributed so that box 2 and box 4 contain
1 ball each and at least 1 box is empty, is N. The order of putting the balls in the boxes
is not considered. Then the unit’s digit of product of digits of sum of digits of
10 2019   N  is
  1 
46. The value of    1 
 is k , Then the value of  is….( 
. is fractional part
 r 2020
r
C2020   300k 
of x , . is greatest integer function of x )
47 . The number of shortest paths from point A to D (as shown in fig) is L, then unit’s
digit of L is
(Note: one can move one step forward or upward from A to reach D, the only edges of
grid must he follow)

48. Let there be three sketch pens of different colors. A regular pentagon with unit side
length is to be drawn using these pens. Only color should used to draw one side of a
pentagon and at least two colors are used to draw the pentagon. If the total number of
ways in which this can be done is equal to N. Then the ten’s place digit of ten times
the product of digits of number of positive integral divisors of N 2 , is
Narayana IIT Academy 05-07-20_Incoming.Sr.IIT_CO SC_JEE-Adv_CAT-45_Q’P
SECTION – III
(SINGLE CORRECT ANSWER TYPE)
This section contains 6 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Answer Q.49, Q.50 and Q.51 by appropriately matching the information given in the
three columns of the following table.
There are 30 balls and three bags.
Number of ways of distributing these 30 balls in to these three bags
Column I Column II Column III
When bags are distinct When bags are distinct When all the bags and
and balls are identical and balls are identical balls are identical
a) such that all the bags p) such that atleast two k) such that all the bags
contain different number bags contain equal number contain different number of
of balls, is 91 of balls and no bag is balls and no bag is empty,
empty is 40 is 91
b) such that all the bags q) such that exactly two l) such that all the bags
contain different number fixed bags contain equal contain different number of
of balls, is 450 number of balls and no balls and no bag is empty,
bag is empty, is 13 is 61
c) such that all the bags r) such that any bag can m) such that exactly two
contain different number contain any number of bags contain equal number
of balls and no bag is balls, is 406 of balls and no bag is empty
empty, is 366 is 15
d) such that all the bags s) such that exactly two n) such that all the bags
contain any number of bags contain equal number contain any number of balls
balls and no bag is of balls and no bag is and no bag is empty, is 75
empty, is 406 empty, is 39

In the following given combinations,in each combination consist of three


statements,taken one every each from column I,II and III.
Given 6 Combinations: (i)aqk (ii)bpn (iii)brn (iv)csm (v)dqk (vi)bpl

49. The number of above given six combinations have at least two true statements?
A) 2 B) 3 C) 4 D) 5
50. The number of above given six combinations have at least one false statement?
A) 2 B) 3 C) 4 D) 5
51. The number of above given six combinations have all false statements or all true
statements?
A) 2 B) 3 C) 4 D) 5
Narayana IIT Academy 05-07-20_Incoming.Sr.IIT_CO SC_JEE-Adv_CAT-45_Q’P
Answer Q.52, Q.53 and Q.54 by appropriately matching the information given in the
three columns of the following table.

COLUMN – I: Contains the arrangement of 6 boys and 5 girls such that


COLUMN – II: No. of ways of arrangements of column-I is 
COLUMN – III:  is divisible by which no.

Column – I Column – II Column – III


I) Two particular boys sit i) 6. 7C5 . 5 P) 5!
together
II) No two girls are together ii) 11! Q) 6!
III) All are seated in a row iii) 7. 5 R) 7!
IV) If all the girls sit together iv) 2.10! S) 8!

52. Which of the following options is the only CORRECT combination?


A) (I) (ii) (P) B) (I) (iii) (Q) C) (II) (i) (Q) D) (II) (ii) (P)
53. Which of the following options is the only CORRECT combination?
A) (I) (iii) (Q) B) (II) (iii) (P) C) (II) (iii) (R) D) (III) (ii) (S)
54. Which of the following options is the only CORRECT combination?
A) (III) (i) (P) B) (III) (iii) (P) C) (I) (iii) (R) D) (IV) (iii) (R)
Sec: Incoming Sr.IIT SC-60 CAT-45 Date: 05-07-20
Time: 3HRS 2017-P1 Max.Marks:
KEY SHEET

PHYSICS
1 BD 2 ACD 3 CD 4 BD 5 BC

6 A 7 ABCD 8 2 9 1 10 5

11 4 12 4 13 D 14 A 15 B

16 C 17 D 18 C

CHEMISTRY
19 BCD 20 AD 21 BCD 22 CD 23 BCD

24 ABD 25 AB 26 3 27 6 28 5

29 1 30 8 31 C 32 D 33 D

34 A 35 B 36 C

MATHS
37 AD 38 ABCD 39 BD 40 BD 41 D

42 BCD 43 ABC 44 4 45 8 46 6

47 6 48 4 49 C 50 C 51 A

52 C 53 D 54 D
Narayana IIT Academy 05-07-20_Incoming.Sr.IIT_CO SC_JEE-Adv_CAT-45_Key & Sol’s
SOLUTIONS
PHYSICS
1. The x-component of velocity, being parallel to magnetic field, shall remain unchanged. The
component of velocity perpendicular to x-axis will always have magnitude Voy , and at any time t it
shall make an angle   t with y-axis as shown.

 y-component of velocity is Voy cos  t and z-component of velocity along negative z-direction at
qB
any time t is Voy sin  t . Where   .
m
2. Conceptual
3. Conceptual

T1 
2u sin 
, T2  2
 eu sin  
, T3  2
 e2u sin  
....
4. g g g
2u sin  2u sin   1 
T 
g
1  e  e2        
g  1 e 

2  u sin   u cos   2  eu sin   u cos   2  e2u sin    u cos  


R1  , R2  , R3 
g g g
u 2 sin 2
 x 1  e  e 2        
g
u 2 sin 2  1 
  
g  1 e 
5. First find centre of circular path and than use

mv
PC  PQ 
qB
arc length
t
v
Narayana IIT Academy 05-07-20_Incoming.Sr.IIT_CO SC_JEE-Adv_CAT-45_Key & Sol’s
6.

F.B.D in two cases is a shown in case (b) normal will be less and in case (b) work done by magnetic
field is zero so height in two cases will be same.

7.

8. Conceptual
9. Conceptual
10. Conceptual
11. Conceptual
12. Conceptual
Narayana IIT Academy 05-07-20_Incoming.Sr.IIT_CO SC_JEE-Adv_CAT-45_Key & Sol’s
13.

14.

15.

16 to 18 u = 20m/s
u sin 2  45 u 2 sin 90 400
2
R    40
10 10 10
 x  x 
So, y  x tan  1    y  x tan 45 1  
 R  40 
 x 
y  x 1  
 40 
If u  20 2
u 2 sin 2 30 800  1/ 4 800
H    5m
2  20 40 100
Narayana IIT Academy 05-07-20_Incoming.Sr.IIT_CO SC_JEE-Adv_CAT-45_Key & Sol’s
CHEMISTRY
19. Conceptual; K – Lilac; Sr – Crimson Red; Ba – Apple Green
20. Pb 2  S2 O32 
 PbS2 O3 
H 2O
 PbS
white ppt Black ppt

Similarly
Ag   S2 O32 
 Ag 2S2 O3 
 H 2 O 
 Ag 2S
white ppt Black ppt

21. Conceptual – Cu+2 – Green/Blue in oxidizing flame


Cr+3 – Green, rarely dark yellow in hot oxidizing flame
Co+2 - Blue
22. Solution – SO2 gets oxidised to Sulphate with D , hence turns the dichromate paper green in colour.
With peroxide and Ba2+, SO2 becomes BaSO4, While CO2 becomes BaCO3. Both are white ppt,
but BaCO3 is soluble in dilute acid while BaSO4 is insoluble in acid.
23. Conceptual
24. Silver Chromate is red in colour, Lead Chloride is a white ppt in cold water and it dissolves in hot
water, it reappears on cooling to give needle shaped white crystals of lead Chloride.
25. Phosphates and Arsenates give Yellow ppt with Ammonium Molybdate. Heating with nitric acid
converts As+3 to As+5.
26. Answer – 3, Fe is in +1 Oxidation state with d7 config, while NO exists as NO+ here.
27. Answer – 6 – x = 2; y = 2; Rinmans’s Green – CoO.ZnO ;
Thenards Blue – CoO.Al2O3
30.

n=+5
31. Since is negative sol, is the effective ion for coagulation.
Total volume of solution = 16 + 4 = 20 ml.
If 20 ml requires 0.02 millimol of requires 1 millimole of
Flocculation value of is 1 ( Flocculation value is expressed in millimole per litre)

32. Answer –8 – Compounds – 1, 2, 3, 6, 7, 8, 9, 10


1 – aldehyde; 2, 3 – Hemi Acetals; 6 – Formic acid gets oxidised to CO2; 7, 8 have CHO groups; 9
and 10 are alpha hydroxy ketones where the alpha hydroxyl group gets oxidised to carbonyl.
33, 34, 35:
– 1 = A= S; 2 = C,E = P,Q (Lead Thiosulphate turns black by becoming PbS on standing);
3 = c = p,s; 4 = b = t; 5 = d = p,r (Lead Chloride is soluble in hot water)

36, 37, 38:


– 1 = a = q; 2 = b = p; 3 = a = q; 4 = c = r; 5=d=s
Tetra ammine copper complex is square planar with dsp2 hybridisation.
Narayana IIT Academy 05-07-20_Incoming.Sr.IIT_CO SC_JEE-Adv_CAT-45_Key & Sol’s
MATHS

37. A) 40
C10 30C10 20
C10 10
C10 B)  40

C20 20! 2!
10

38. MM, AAA, TT, HICS

D = 4 1422

D = 3 265
n
39. n odd,  5  2  is even

n
n is even  5  2  odd

40. 8  125C2  62000  24  53  31

n n 4
Cr Cr  4
41. r 4
 n 4
C4 C4

 2x   x 
2 n
n
42. 2
 x 1 2
  x  1

Put x  1, x  1, x   x

 2x   2x    4 x  1
n n n
2
 x 1 2
 x 1 4

10! 1 10!
43. A)    5!
 2! 5
5!  2!5  5!

9! 1 9!
B)    4!
 2! 4
4!  2!4 4!

8!2  1  8.7 2 6!
C)  
 2!8 4! 3! 2 
6

44. N = 1980.6!.7!.10!

45. N  3906  7
  
C1  6C1  3  25  2  3  
42  93  3906

1 K 1 1 1 
46.     telescopic
n
CK 1 K  n1 CK n CK 
Narayana IIT Academy 05-07-20_Incoming.Sr.IIT_CO SC_JEE-Adv_CAT-45_Key & Sol’s
7! 4!
47.   126  through n 
2!5! 2!2!

6! 5!
  150 N
2!4! 2!3!

126  150  90  186

35  3
48.
5

49,50,51.
SOL: 49,50,51
x1  x2  x3  30
 xi  0
Number of solutions  496

75
450
15
6 45
3

1
496
When boxes and balls are identical.

61
366
13
6 39
3

1
406

52,53,54.

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