Test ID : 401

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XI (CBSE) CUMULATIVE TEST - 32 (CHEMISTRY – ANSWER KEY) - 11.03.24
Note :
For every correct answer four marks will be awarded. For every wrong answer one mark
will be reduced. For unanswered questions zero mark.
Choose the correct answer : 30 x 4 = 120
3X o 1 mh
1. 1) A 5. 1)
4 2 π
Solution : Solution :
2
n h h
r∝ ∆X.∆P = ⇒ ∆x. m∆V =
Z 4π 4π
rBe+3 ZLi +2 Given ∆X = ∆V
=
rLi+2 ZBe+3 h
∴ ∆ V m ∆V = ⇒ multiply m on both sides
rBe+3 4π
3
o
= mh mh
XA 4 m ∆V.m∆V = ⇒ (m∆V)2 =
4π 4π
3X o
rBe+3 = A mh
4 ⇒ (∆P) 2 =
4π
2. 2) 8π XAo
1 mh
Solution : ⇒ ∆P =
2 π
2πr = nλ
6. 2) 2, 8, 12, 2
2πr4 = 4λ ------ (1)
Solution :
r4 = r1 x 42 Ao
(2, 8, 2) = 1s22s22p63s2,
r4 = 16 r1 Ao
(2, 8, 12, 2) = 1s22s22p63s23p63d44s2
From (1)
(2, 8, 13, 1) = 1s22s22p6, 3s23p63d54s1
2π 16 XA = 4λ (r1 = XA )
o o
(2, 8, 18, 1) = 1s22s22p6, 3s23p63d104s1
λ = 8πXAo
7. 4) dz2
3. 2) 95%
Solution :
Solution :
Fact NCERT In case of dz2 all lobes are present like a donut
ring around the nucleus on the X – Y plane
1
4. 4) 4 1 –3 – and a single dumbbell on Z-axis
2
8. 2) I, II, III
Solution :
Solution :
1
Always n > l l≥|m| s= ±
2
 2 Test ID : 401
–30
In the balmer series of H-atom the transition = 14.672 x 10
takes place from the higher energy level to n = 2 % ionic character =
level µ obs 6.104 x10−30
x100 = = 41.5%
∴ the longest λ corresponds to n1= 2 and n2 = 3 µ cal 14.672 x10 −30 x100
As the wave length decreases, the lines in the 16. 1) Tetrahedral [PCl4]+ and octahedral [PCl6]–
series converges. Hence, statement I, II, III are
Solution :
correct
2PCl5(s) → [PCl4]+ + [PCl6]–
9. 2) 12 and 5
Tetrahedral octahedral
Solution :
2 2 6 2 6 1 5 17. 4) ClF3, XeOF2, XeF3+
1s 2s 2p 3s 3p 4s 3d
Solution :
l = 1 means p subshell = 12 electrons
ClF3 sp3d –| shape
l = 2 means d subshell = 5 electrons
XeOF2 sp3d –| shape
10. 1) in the region of a and c
XeF3+ sp3d –| shape
Solution :
18. 4) sp3d2
Probability of finding are electron will have
Solution :
maximum value at both a and c and at b zero
probability
11. 4) LiF
Solution :
| Z+ || Z− |
Ionic strength = 1.44 x
(r+ + r− ) 2
12. 3) F – H ---- F sp3d2 has 12(90o)
Solution : 19. 3) 6
Greater the E.N difference, stronger is the Solution :
H-bond F
13. 2) CO F F
Solution : I F
NO → 1 unpaired electron in π* F F
CO → all paired electron KK F
σ2s π2p = π2p σ2p σ * 2p
2 2
x
2
y
2
z
2
2 20. 1) charge on the ion and size of the ion
14. 4) An anti bonding π orbital Solution :
Solution : Lattice energy depends upon charge on ions as
If one lobe +ve and other one –ve indicate out well as size of the ion
of phase and anti bonding molecular orbital 21. 4) 0.25
15. 4) 41.5% Solution :
Solution :
µcal = δ x l = 1.6 x 10–19 x 9.17 x 10–11
 3 Test ID : 401
2HI ⇌ H2 + I2 1
[Fe+3] = x[Fe +3 ]*
64
Initial moles 2 0 0
⇒ [Fe+3]* = 64 [Fe+3]
Eq. moles 2–2∝ ∝ ∝
26. 4) 4.3 x 10–32
moles dissociated
% dissociation = x100 Solution :
initial moles
3O2(g) ⇌ 2O3(g)
2
50 = x100
2 [O3 ]2
Kc = 3
⇒ [O3 ]2 = K c [O 2 ]3
∝x∝ 0.5 x 0.5 0.5 x 0.5 [O 2 ]
Kc = = =
(2 − 2 ∝) 2
(2 − 2 x 0.5) 2
(2 − 1)2 ⇒ [O3]2 = 3 x 10–59 x (0.04)3 = 1.9 x 10–64
Kc = 0.25
[O3] = 19 x10−64 = 4.38 x 10–32 M
22. 2) –5.7058 kJ
27. 4) All of these
Solution :
Solution :
∆Go = –2.303 x 8.314 x 298 log 10
Kp = Kc(RT)∆ng ; ∆ng = 2 – 4
= –5705.85 J = –5.7058 kJ
23. 2) forward = –2
28. 3) Statement-I is true and Statement-II is false
Solution :
Solution :
CO + Cl2 → COCl2
When Qc < Kc, the reaction will be fast in
As per Lechatelier principle, if conc. of
forward reaction
products decrease reaction favours forward
29. 3) Addition of potassium thio cyanate
0.25
24. 2) Solution :
5.6
If SCN– is added conc. of SCN– increases
Solution :
intensity also increases.
Active mass = molarity
30. 4) (A) is false and (R) is true
5.6 1 1 0.25
= x = = Solution :
22.4 56 22.4 5.6
25. 4) 64 1
SO2(g) + O2(g) ⇌ SO3(g) + heat is an
2
Solution :
exothermic reactions, As per Lechatelier
Fe(OH)3 ⇌ Fe+3 + 3OH– principle forward reaction is favoured at low
Kc = [Fe+3] [OH–]3 temperature and moderate temperature
3
1 1 * 1 
Given [OH–] = K c =  Fe +3   OH − 
4 4 
Kc = K1c
3
1
[Fe ] [OH ] = [Fe ]   [OH − ]3
+3 – 3 +3

4