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Question One
With the help of a phase envelop diagram, explain the following reservoir fluid types.
Question Two
Question Three
Question Four
Question Five
(a) Discuss the diagenetic processes that occur from deposition of sediments until deep burial.
(10 marks)
(b) Explain how any five of the diagenetic processes affect reservoir quality (porosity and permeability.
(10 marks)
Question Six
Question Seven
(a) An Oil Field has acreage of 650 acres. The oil bearing region has an average thickness of 30 ft. The
following rock properties are known:
Calculate:
(b) State three (3) means of recovering this initial 42%. (3 marks)
(c) Discuss in detail two (2) secondary oil recovery methods that can be used to recover the remaining 58%. (3
marks each)
(d) What do you understand by the terms drainage and imbibition? (2 marks each)
Solutions;
Question One
The reservoir can produce different types of fluids. Each different fluid type has characteristics that petroleum
engineers need to be aware of in order to produce the reservoir efficiently. Generally the reservoir fluid types
are classified into 5 separate categories from a phase diagram. They are:
1. Black Oil
2. Volatile Oil
3. Gas Condensate
4. Wet Gas
5. Dry Gas
The fluid type can be identified by the shape of it’s phase diagram and the position of it’s critical point relative
to the reservoir temperature. In the following figures, we assume that the reservoir pressure declines at a
constant temperature (isothermal condition).
1. Black Oil
The figure below shows the pressure decline of a black oil reservoir on a phase diagram. The vertical line
from point 1 to point 3 represents the reservoir pressure decline path at a constant temperature. The pressure
and temperature of a separator at the surface is also shown in the diagram.
For a black oil reservoir, the initial pressure at point 1 is much larger than the bubble point pressure. When
reservoir pressure is above the bubble point (between point 1 and point 2), we call this
the Undersaturated reservoir state. Undersaturated implies that the oil can absorb more gas if more gas became
present in the reservoir. When the pressure hits the bubble point line at point 2, the first bubble of gas forms.
Below point 2, gas starts to evolve out of the oil into the reservoir. We call this the saturated reservoir state.
Saturated implies that the oil cannot absorb more gas if more gas became present in the reservoir. As the
pressure declines further to point 3, more gas evolves out of the oil into the reservoir. At point 3, the reservoir
pressure can no longer push the fluids to the surface under its current state. At the surface separator condition,
more gas evolves out of the oil. For black oil reservoirs, a large percentage of the oil phase is recovered at the
surface.
2. Volatile Oil
The figure below show the pressure decline of a volatile oil reservoir on a phase diagram.
A volatile oil reservoir starts out like a black oil reservoir with the initial reservoir pressure lying above the
bubble point line. However for a volatile oil, the initial pressure is much closer to the bubble point pressure.
This is because a volatile oil reservoir contains more lighter hydrocarbon components than the black oil
reservoir, thus the phase diagram shifts up and to the left. Further, the quality lines are closer together. This
means that a small reduction of pressure below the bubble point line will release a large quantity of gas. For a
volatile oil reservoir, more gas is produced at the surface because more solution gas evolves out of the oil. This
lead to less liquid recovery as indicated in the phase diagram above. The dividing line between volatile oils and
black oils are somewhat arbitrary. But it should be clear that volatile oils produce a higher quantity of gas than
black oils.
3. Gas Condensate
The figure below shows the pressure decline of a gas condensate oil reservoir on a phase diagram:
A gas condensate reservoir is identified by its temperature. The reservoir temperature falls between the critical
point temperature and the cricondentherm. As pressure declines below the dew point line, the heavier
hydrocarbons fall out in the reservoir as liquid. This liquid more or less is immobile and blocks the pore space
near the wellbore. Thus less gas is produced because the liquid partially blocks the gas flow. Liquid continues to
form in the reservoir as long as the pressure is within the retrograde region. As pressure falls below the
retrograde region, the liquid re-vaporizes into gas. This type of reservoir is pretty bizarre, but it can be
explained by a phase diagram.
4. Wet Gas
The figure below shows the pressure decline of a wet gas reservoir on a phase diagram:
A wet gas reservoir has a reservoir temperature above the cricondentherm. As the pressure declines, the
reservoir never enters into the two-phase region. This means liquid will never drop out in the reservoir and it
will only contain gas over its producing life. However, liquid will form at surface separator conditions as shown
in the figure above. That is why they call it “wet” gas because condensate drops out of the gas at the surface.
5. Dry Gas
A dry gas is primarily pure methane and the phase diagram is short and condensed. As the reservoir pressure
declines, the pressure depletion path never enters the two-phase region. Further, the pressure and temperature at
surface conditions falls outside of the two-phase region. This means that the fluid stays in the gas phase at
reservoir and surface conditions. A dry gas reservoir is simply a gas reservoir and is the easiest reservoir to
model analytically.
Question Two
Crude oil is a complex liquid mixture composed of a vast number of hydrocarbon compounds. These
compounds primarily consist of carbon (C) and hydrogen (H), with varying proportions. Additionally, small
amounts of other organic compounds containing sulfur, oxygen, nitrogen, and trace metals like vanadium,
nickel, iron, and copper are also present. The main classes of hydrocarbons found in crude oil are as follows:
o Examples: Methane, ethane, propane, butane, isobutane, pentane, hexane, and more.
o State: They can exist as gases or liquids at room temperature, depending on the specific
molecule.
2. Olefins (Alkenes):
4. Aromatics:
o General Formula: C₆H₅-Y (where Y is a longer, straight molecule that connects to the benzene
ring).
o The rings contain six carbon atoms with alternating double and single bonds between them.
Crude oil is classified based on both physical and chemical characteristics. Here are the primary
classifications:
o Often yields more valuable products like gasoline and jet fuel.
o Used for a variety of purposes, including diesel fuel and heating oil.
o Used for industrial processes and as a feedstock for asphalt and lubricants.
Question Three
The Society of Petroleum Engineers (SPE) provides standardized definitions for petroleum reserves and
resources. These definitions allow for consistent comparison of quantities worldwide. Here are the key terms
related to reserves:
o Significance: Proved reserves are the most reliable and economically viable.
o Definition: Probable reserves have a 50% certainty of commercial extraction with existing
technology.
o Definition: Possible reserves have a 10% certainty of commercial extraction with existing
technology.
4. Contingent Resources:
o Definition: Contingent resources are estimated quantities potentially recoverable from known
accumulations.
5. Remaining Reserves:
o These are the resources beyond the proved, probable, and possible categories.
o Significance: Remaining reserves account for future discoveries and improved recovery
techniques.
(b) Unconventional Hydrocarbon Resources
Unconventional hydrocarbons differ from conventional ones due to their unique geology, extraction methods,
and reservoir characteristics. Here are five types of unconventional resources:
1. Shale Gas:
o Extraction: Horizontal drilling and hydraulic fracturing (fracking) are used to release gas from
the shale matrix.
o Extraction: Similar to shale gas, hydraulic fracturing is essential for tight oil production.
o Extraction: Wells are drilled into coal seams, and water is pumped out to release the gas.
o Description: Oil sands contain heavy crude oil mixed with sand, clay, and water.
o Extraction: Surface mining or in-situ methods (e.g., steam-assisted gravity drainage) are used.
5. Gas Hydrates:
o Significance: Gas hydrates hold immense potential but pose technical challenges.
Question Four
Furthermore, the composition of the produced well fluids will not change as the reservoir is depleted. This is
true for any accumulation with this hydrocarbon composition where the reservoir temperature exceeds the
cricondentherm, or maximum two-phase temperature (250°F for the present example).
Although the fluid left in the reservoir remains in one phase, the fluid produced through the wellbore and into
surface separators, although the same composition, may enter the two-phase region owing to the temperature
decline, as along line. This accounts for the production of condensate liquid at the surface from a single-phase
gas phase in the reservoir.
Of course, if the cricondentherm of a fluid is below approximately 50°F, then only gas will exist on the surface
at usual ambient temperatures, and the production will be called dry gas. Nevertheless, even dry gas may
contain valuable liquid fractions that can be removed by low-temperature separation.
Next, consider a reservoir containing the same fluid of Fig. 1.4 but at a temperature of 180°F and an initial
pressure of 3300 psia, point B. Here the fluid is also initially in the one-phase gas state, because the reservoir
temperature exceeds the critical-point temperature. As pressure declines due to production, the composition of
the produced fluid will be the same as reservoir A and will remain constant until the dew-point pressure is
reached at 2700 psia, point B1.
Below this pressure, a liquid condenses out of the reservoir fluid as a dew. This type of reservoir is commonly
called a dew-point or a gas-condensate reservoir. This condensation leaves the gas phase with a lower liquid
content. The condensed liquid remains immobile at low concentrations. Thus the gas produced at the surface
will have a lower liquid content, and the producing gas-oil ratio therefore rises. This process of retrograde
condensation continues until a point of maximum liquid volume is reached, 10% at 2250 psia, point B2.
The term retrograde is used because generally vaporization, rather than condensation, occurs during isothermal
expansion. After the dew point is reached, because the composition of the produced fluid changes, the
composition of the remaining reservoir fluid also changes, and the phase envelope begins to shift. The phase
diagram of Fig. 1.4 represents one and only one hydrocarbon mixture. Unfortunately, this shift is toward the
right and further aggravates the retrograde liquid loss within the pores of the reservoir rock.
Neglecting for the moment this shift in the phase diagram, for qualitative purposes, vaporization of the
retrograde liquid occurs from B2 to the abandonment pressure B3. This revaporization aids liquid recovery and
may be evidenced by decreasing gas-oil ratios on the surface. The overall retrograde loss will evidently be
greater (1) for lower reservoir temperatures, (2) for higher abandonment pressures, and (3) for greater shift of
the phase diagram to the right—the latter being a property of the hydrocarbon system. The retrograde liquid in
the reservoir at any time is composed of mostly methane and ethane by volume, and so it is much larger than the
volume of stable liquid that could be obtained from it at atmospheric temperature and pressure. The
composition of this retrograde liquid is changing as pressure declines so that 4% retrograde liquid volume at, for
example, 750 psia might contain as much surface condensate as 6% retrograde liquid volume at 2250 psia.
If the initial reservoir fluid composition is found at 2900 psia and 75°F, point C, the reservoir would be in a
one-phase state, now called liquid, because the temperature is below the critical-point temperature. This is
called a bubble-point (or black-oil or solution-gas) reservoir. As pressure declines during production, the
bubble-point pressure will be reached, in this case at 2550 psia, point C1.
Below this pressure, bubbles, or a free-gas phase, will appear. When the free gas saturation is sufficiently large,
gas flows to the wellbore in ever increasing quantities. Because surface facilities limit the gas production rate,
the oil flow rate declines, and when the oil rate is no longer economic, much unrecovered oil remains in the
reservoir.
Finally, if the initial hydrocarbon mixture occurred at 2000 psia and 150°F, point D, it would be a two-phase
reservoir, consisting of a liquid or oil zone overlain by a gas zone or cap. Because the composition of the gas
and oil zones are entirely different from each other, they may be represented separately by individual phase
diagrams that bear little relation to each other or to the composite. The liquid or oil zone will be at its bubble
point and will be produced as a bubble-point reservoir modified by the presence of the gas cap.
Question Five
Diagenesis refers to the processes that alter sedimentary rocks after deposition but before they undergo
metamorphism or lithification (conversion into solid rock).
1. Compaction:
o Description: Compaction occurs due to the weight of overlying sediments. It reduces pore space
by squeezing grains closer together.
o Effect: Compaction decreases porosity and permeability, making the rock denser and less
porous.
2. Cementation:
o Description: Cementation involves the precipitation of minerals (such as quartz, calcite, or clay)
in pore spaces.
o Effect: Cementation can occlude pores, reducing both porosity and permeability.
3. Dissolution:
o Description: Dissolution is the removal of minerals from the rock matrix by water.
o Effect: Dissolution can enhance porosity by creating larger interconnected pores, but it may also
weaken the rock.
4. Authigenesis:
o Description: Authigenesis refers to the formation of new minerals within the rock during
diagenesis.
o Effect: Authigenic minerals can either enhance or reduce porosity and permeability, depending
on their type and distribution.
5. Recrystallization:
1. Quartz Cementation:
o Effect: Excessive quartz cementation reduces porosity and permeability in sandstone reservoirs.
o Example: Tight sandstones with abundant quartz cement have low reservoir quality.
o Effect: Clay minerals (e.g., illite) can fill pore spaces, reducing porosity and permeability.
3. Carbonate Cementation:
o Effect: Carbonate minerals (e.g., calcite) can precipitate in pore spaces, affecting porosity and
permeability.
4. Compaction:
o Example: Acid fluids during diagenesis can dissolve feldspar and carbonate cement.
Question Six
A dry gas reservoir primarily contains natural gas (methane) without any significant liquid hydrocarbons (such
as oil or condensate).These reservoirs are characterized by low liquid content and high gas saturation. Dry gas
reservoirs are often found in tight formations or unconventional formations.
Overburden Pressure:
Overburden pressure refers to the weight of the rock and fluids (such as water and hydrocarbons) above a
specific depth within the Earth’s crust. It plays a critical role in maintaining reservoir pressure and influencing
rock compaction and deformation.
The gas compressibility factor, denoted as Z, quantifies the deviation of real gases from ideal behavior. It
accounts for gas density changes due to pressure and temperature variations. Deviations from ideal behavior
occur at high pressures and low temperatures.
In a solution gas drive, dissolved gas (usually in oil) comes out of solution as pressure decreases during
production. This released gas helps maintain reservoir pressure and drives oil toward producing wells.
A secondary gas cap forms above an oil reservoir when gas accumulates due to capillary forces. It enhances oil
recovery by providing additional energy to displace oil toward production wells.
It represents the remaining gas saturation after water or gas injection displaces most of the oil. It characterizes
the non-wetting phase (oil) left behind during displacement processes.
Interfacial Tension:
Interfacial tension refers to the force per unit length acting at the interface between two immiscible fluids (e.g.,
oil and water). It affects fluid distribution and capillary pressure in porous media.
The productivity index measures the well’s ability to deliver hydrocarbons to the surface. It relates production
rate to drawdown pressure and reservoir properties.
Drainage Process:
The drainage process involves the movement of fluids (oil, gas, or water) through porous rock toward producing
wells. It occurs as reservoir fluids are produced and the pressure decreases, allowing fluids to flow from higher-
pressure regions to lower-pressure regions
Question seven
(a) Initial Oil in Place (OOIP): To calculate the initial oil in place, we’ll use the following information:
Vb × ɸ×(1−Sw)
OOIP ( N )=
Boi
22039500× 0.1125
OOIP=
1.306
2479443.75
OOIP=
1.306
2479443.75
OOIP=
1.306
So, the initial oil in place is approximately 1,897,836.4 stock tank barrels (STB).
(b) Recovery Methods for Initial 42%: Three common methods for recovering the initial 42% of oil are:
© Secondary Oil Recovery Methods for Remaining 58%: Two secondary oil recovery methods to recover
the remaining 58% are:
(d)
1. Drainage:
o Drainage refers to the movement of fluids (such as oil, gas, or water) through porous rock or
soil.
o During drainage, the fluid phase with higher mobility displaces the other immiscible fluid phase.
o In an oil reservoir, for instance, drainage occurs as oil is produced from the reservoir, leading to
a decrease in reservoir pressure.
o The driving force for drainage is typically the pressure gradient, which pushes fluids from
regions of higher pressure to regions of lower pressure.
2. Imbibition:
o Imbibition is the opposite process of drainage.
o It involves the movement of a wetting fluid (usually water) into a porous medium containing a
non-wetting fluid (such as oil or gas).
o Capillary forces play a significant role in imbibition. These forces cause the wetting phase to
infiltrate the porous rock against gravity.
o Imbibition can occur during water injection into an oil reservoir, where water displaces oil from
the rock matrix.
In summary:
More questions
11. Draw and explain the phase diagram of a multi-component hydrocarbon system.
12. What is retrograde condensation?
13. What is the difference between a wet gas and a retrograde gas condensate reservoir?
14. What are disadvantages of producing gas condensate field on depletion? How can these loses be minimised?
15. What is the difference between a high shrinkage and a low shrinkage oil reservoir? Draw the phase envelope to
illustrate the difference?
16. What is gas deviation factor or Z-factor of natural gases?
17. What are pseudo-critical and pseudo-reduced properties for mixtures of natural gases?
18. What are the different methods of obtaining representative reservoir fluid sample?
19. When is re-combination sampling preferred?
20. What are different PVT studies carried out for normal black oil system?
21. What other PVT studies are done for gas-condensate systems?
22. Why is multi-stage separation done?
23. What is the difference between flash liberation and differential liberation process?
24. What is formation volume factor. Show its relationship with pressure?
25. How does viscosity of undersaturated oil changes with pressure?
26. What are different uses of PVT data in reservoir engineering studies?
27. In absence of laboratory data how can the properties of oil and gas be estimated? What all basic data is required
for PVT correlations?
28. In FVF and pressure relationship, when pressure decreases from initial, the FVF increases upto bubble point and
then subsequently declines with pressure. Why?
1. What is EOR? What are the different types of EOR methods being used?
2. What are the basic screening criterions for identifying appropriate EOR techniques?
3. What is the difference between enhanced oil recovery process and artificial lift method?
4. What is the difference between a miscible displacement and immiscible displacement?
5. What is the role of polymer flooding in reservoirs? What advantages it offers over waterflooding?
6. What is the purpose of Surfactant EOR processes?
7. What is viscous fingering? How can it be minimised?
8. What is the difference between a cyclic steam process (huff-n-puff) and steam flooding?
9. What is the concept that works behind Polymer flooding process?
10. What is the concept that works behind Thermal processes?
11. What is the concept that works behind Surfactant flooding?
12. Name the fields and EOR methods under application in ONGC?