Mole bolance Conveslon PAn =CoVoReidence hme CSTRS in Series LHSV - VÍ of l19 -at 60F or 75'F

Rote of reaction aA b8 ond soce vencihy), For a fist-order Kn, hHSV - Vo f gas at STP (oc,1 atn)
i-ratt of form fj Fio-Fi t
;<o - reactant
FAO NAo RTo
Vo SV
;>0 - product b Reactor design eg"s
Bateh t : NAg dNA t:
Lerespiel plot Doamköhler
number
Daz-fno
arLjnselectvita
CrO Nu
flding AV -fA
Pro (1+2)0
NA Yield
XA
m ( mass of CSTR Dag kDa< o.1 X<10%
Fp
cotalyst) -TA VeFR Do 10 X>90%
(interfacis orea A+ VosTR Nho-NA Fhp-FA
in hekrogenas $) leR
APA V Fho ARectur selection A+8G Ea
-TA

High A, High 6 Both PFR Ep > EU high T

ArheniuS High A, Lôw 8 - sSemibatch with added Ey < Eu - low T
k= Aexp ( eqwation eeR with e sidestrems
Vm S]
LesTR series with Bfed.b each SubstoBe inhibltion
Stolchiomety Reactions in sernes AyoyU f CSTR
ieFR with recycle
Kt s]+EsJ
Ni CA CAne-kt
Enzyme Kinetics V Vm [s Es E+P
E+S
Ny= NTot sNA Bath FRapid ejilibi um
Michoelis-Me nten
Quosi-stady state LineweoNer- Burk VS
Slope= KM
Fro(1+Stah) Comax at tmoy = Un kz-Lnka Ku Kstk1 Bodie-Hopstee Vm

Hanes-Woolf KM
FloN
En2ne inhibition Uncompetitive Non-comeiive
1+¬X comyeitive E+S h ES ,Er? | E +S
E+s SE+f
Vm EST Vm EL ESL
1+¬X
EI Vm
Tmmdbilizahon
AdSorp ion isotherm_ AB+ s AAB"s moleculor
Enapment External diffusion ratt kc (CAp-Chs) AS+B-S dissoclative
Bound KAACt
Matrix Hembrane ®sorbed colalent Internal aiffusibn rote = kr CAs th kin 1+KA lA JKaAB Ct
1+2 jKAlAO
Molar Flux WA = JA+BA \linenrise KA -dis fexg. uith
icoencopeso
T
Jiineorise
fAB
AS 8Sks
KA for Knudsen disjmt CA0S
Enemal iffusi) in PBK
D Ko (Ces-*ecv)Stognant film CA =Cay - (Cry-CAs) W =B (1-Acz
Concentaton profile

t Sh= kcap
DA8
Sc= Re = Ude For Re 725,
?!sh % o.6(Reo (se)
aw
e-masS per unt catolyst vol.
1-¢ ~ vol of catalyst S -mo3s per unt reactor vol
She NU, Scelr Vol- of ractor ac- surt-area of catalyst per uait e
Volt
 EFfective Diffbsi vity Internol aiffusion throgh a pellet War - De dGA
dr
Thiele modulus i Large h
De = DA6 Sa- surface area per onit moss of catalyst KnCAs R itermal
(te) -rA Sa Gr) rae er Unit cot mass drz
2 dA- kn CA
De
0 De
diffusioN
limited
Smoll n
-fA = S (-rA) rate per unit cat vol. eoctibn
limitkd
Radal concentration profile Tntemol effeciveNeSS factor
For a st-order rn,
-TAacal
1 sinh (At)
sinh(1) Small
-T^suroce S0(face
TUrnover frequeny
f= No- of sobstrate molecules
sinh (7) : e^ ,coth(r)=e+e* Large 1 No. of octive sites x Time
2
e-e
|Knudsen DAb~To5
Overall ectyeneSs factor |TortUsity 115 Rate limiting sep
i : Acual dist.
Nctual Shor test dist. Bulk veloity elet size Temp:
negleg1ble DA(fusivity ond Tewmp - External Linear
aiffusion
WA kc (GA-CAs) CAS KcacCAb
Keac +nk}5,3b Dnternol Exp
aiffUsion
actal
n:Aacva) Reaction EK
6ulk
Keacthisb
Colburn J factor Time course for enzymatic reactons ShrinkiA core model
=0.765 +0:365
= Vm s] Consumption > Mass transfer e Accumulation
sh Re Reo-386 -

Jo = KmtIs]
Re (sc)3 )+ Vm
0453
t KM, 9 =diameter of pellet
m

Monod Kinetics Soling aferential eç^s reocion

0Y +2 -Ve0 As0,Vis finite limhing
A=1,=1 1 int.ifubio
limitin
Km t Cs
orge
r=0|

1 BT2041 ANIRUDH RAO

if required
sinh1 FoRMULA SHEET BEZ18004