Class 12

. unit 1 solutions workshee 1

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1.What concentration of nitrogen should be present in a glass of water at room temperature? Assume
a temperature of 𝟐𝟓°C, total pressure of 1 atmosphere and mole fraction of nitrogen in air of 0.78 [𝑲𝑯]
for nitrogen = 𝟖.𝟒𝟐 × 𝟏𝟎−𝟕𝒎𝒎𝐇𝐠
2.What is meant by Colligative properties?
3.Non-ideal solutions exhibit either positive or negative deviations from Raoult’s law. What are These
deviations and why are they caused? Explain with one example for each type.
4.Differentiate between molarity and molality for a solution. How does a change in temperature
Influence their values?
5.Calculate the mole fraction of benzene in solution containing 30% by mass in carbon Tetrachloride.
6.Explain the Henry’s law about dissolution of a gas in a liquid
7.State Raoult’s law for a solution containing volatile components. How does Raoult’s law Become a
special case of Henry’s law?
8.Define an ideal solution and write one of its characteristics.
9.What type of deviation is shown by a mixture of ethanol and acetone? Give reason.
10.A solution of glucose (molar mass = 180 g 𝒎𝒐𝒍−𝟏) in water is labeled as 10% (by mass).What would
be the molality and molarity of the solution?(Density of solution =1.2𝒎𝑳−𝟏)
11.(a) Why is air diluted with helium in the tanks used by scuba divers?
(b) A decrease in temperature is observed on mixing ethanol and acetone.
12.State Henry’s law. Calculate the solubility of CO2 in water at 298 K under 760 mm Hg. (KH for CO2
in water at 298 K is 1.25 x 106 mm Hg)
13.Write two differences between an ideal solution and a non-ideal solution.
14.Give reasons
(a)Aquatic species are more comfortable in cold water than warm water.
(b)At higher altitudes people suffer from anoxia resulting in inability to think.
15.What type of azeotropic mixture will be formed by a solution of acetone and chloroform? Justify on
the basis of strength of intermolecular interactions that develop in the solution.
16.Gas (A) is more soluble in water than Gas (B) at the same temperature. Which one of the two
Gases will have the higher value of KH (Henry’s constant) and why?
17.In non-ideal solution, what type of deviation shows the formation of maximum boiling Azeotropes?
18.On mixing liquid X and liquid Y, volume of the resulting solution decreases. What type of deviation
from Raoult’s law is shown by the resulting solution? What change in temperature Would be observe
after mixing liquids X and Y?
19.A solution is prepared by dissolving 10g of non-volatile solute in 200g of water. It has a vapour
pressure of 31.84 mm Hg at 308K. Calculate the molar mass of the solute. (Vapour Pressure of pure
water at 308K = 32mm Hg)
20.What is meant by positive deviations from Raoult’s law? Given an example? What is the sign Of
Δ𝐦𝐢𝐱𝐇 for positive deviation?
21.Define azeotropes. What type of azeotrope is formed by positive deviation from Raoult’s law? Give
an example
22. What is the significance of Henry's law constant KH ?
23. Henry's law constant for
in water is 1.67x10⁸ Pa at 298 K. Calculate the number of moles of in 500ml of soda water when
packed under 2.53x10⁵ Pa at the same temperature.
24. KH value for Ar(g), CO2(g), HCHO (g) and CH4(g) are 40.39, 1.67, 1.83×10–5 and 0.413
respectively. Arrange these gases in the order of their increasing solubility.
25. Aspirin is very soluble in ether. If 0.372g of aspirin are dissolved in 2.97g of diethyl ether(
molecular weight is 60gmol-1), the vapor pressure of the ether lowers from 0.631 to 0.601 atm at 23⁰C.
What is the molecular weight of the aspirin?