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Non-renewable Sources
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Oil and Petroleum Products
Crude oil → a mixture of hydrocarbons formed from plants and animals that
lived millions of years ago
Exists in liquid form
Underground pools and reservoirs
Tiny spaces within sedimentary rocks
Near the surface in tar (or oil) sands
Crude oil from ground sent to refineries to be separated into useable
petroleum products
Petroleum products → fuels made from crude oil and other hydrocarbons
contained in natural gas
Can also be made from coal, natural gas, and biomass
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• 1 barrel = 42 gallons
• Numbers represent
gallons in one barrel
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Use of Oil and Petroleum Products
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Hydrocarbons Gas Liquids (HGL)
Hydrocarbons → molecules of carbon and hydrogen in various combinations
HGL → hydrocarbons that are gases at atmospheric pressure and liquids under
higher pressures
Can also be liquefied by cooling
May be described as light or heavy according to number of carbon and
hydrogen atoms in one HGL molecule
Found in raw natural gas and crude oil
Categorized as alkanes or paraffins [1] and alkenes or olefins [2]
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Uses of HGL
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Natural Gas
Fossil energy source that formed deep beneath earth's surface
Contains many different compounds largest being methane CH4
Also contains smaller amounts of natural gas liquids NGL (also hydrocarbon gas
liquids HGL) and nonhydrocarbon gases such as CO2 and water vapor
Types include
Conventional natural gas – found in large cracks and spaces between layers of
overlying rock
Shale gas or tight gas – found in tiny pores (spaces) within some formations of
shale, sandstone, and other types of sedimentary rock
Associated natural gas – found with deposits of crude oil
Coalbed methane – found in coal deposits
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Liquefied Natural Gas or LNG
Natural gas that has been cooled to liquid state at about -260 °F for shipping
and storage
Volume is 600 times smaller than gaseous state
Applications or benefits include
Possible transport of natural gas to places pipelines do not reach
Use natural gas as transportation fuel
Shipped in special ocean-going ships (tankers) between export terminals
(natural gas → liquefied) and import terminals (LNG → re-gassified)
Some power plants store LNG and use it to generate electricity when
electricity demand exceeds natural gas pipeline delivery capacity
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Coal
Combustible black or brownish-black sedimentary rock with high amount of
carbon and hydrocarbons
Non-renewable because takes millions of years to form
Classified as
Anthracite – contains 86%–97% carbon and highest heating value
Mainly used by metals industry
Bituminous – contains 45%–86% carbon
Used to generate electricity and an important fuel and raw material for making iron and
steel
Subbituminous – contains 35%–45% carbon
Lignite – contains 25%–35% carbon and lowest energy content
Converted to synthetic natural gas
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Uses of Coal
Power plants make steam by burning coal and steam turns turbines to
generate electricity
Concrete and paper industries burn large amounts of coal to produce heat
Steel industry uses coal indirectly to make steel
Coke [1] made by baking coal in furnaces used by steel industries
High temperatures created by burning coke give steel the strength and flexibility
needed for bridges, buildings, and automobiles
Converted into gases or liquids called synfuels which produce lower air
pollutants than coal itself
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Nuclear Energy
Enormous energy present in bonds that hold the nucleus together
Released as heat when these bonds are broken via fission [1]
Used to generate steam and drive steam turbines
Uranium most widely used as fuel
Much larger energy released when nuclei combined in fusion reactions (mainly
on stars)
Difficult control of reaction → not yet commercial
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Nuclear Fuel Cycle – Milling
Extract uranium from the ore and produce a uranium oxide concentrate
Ore crushed and ground to fine slurry which is then leached in sulfuric
acid/strong alkaline solution
To separate uranium from the waste rock
Recovered from solution and precipitated as uranium oxide (U3O8)
concentrate
200 tonnes required to keep 1000 MWe plant in operation for 1 year
After drying (and usually heating) → Packed in 200-liter drums as a
concentrate referred to as yellowcake [1]
Remaining ore contains most of radioactive material and rocks
Become tailings disposed carefully in a pit isolated from environment
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Nuclear Fuel Cycle:
Conversion & Enrichment
Additional processing required on U3O8 before being used in reactor
0.7% of natural uranium being fissile [1] must be increased to 3.5 – 5%
Conversion plants convert U3O8 into uranium dioxide for plants which
do not require enriched uranium
Rest sent for enrichment after conversion into uranium hexafluoride
Physical process to concentrate one isotope in fuel over others called
enrichment
Enrichment requires uranium to be in gaseous form
U3O8 converted into uranium hexafluoride (gas at relatively lower
temperatures)
Uranium hexafluoride separated into two gaseous streams
One enriched to required levels known as low-enriched uranium
Other one progressively depleted in U-235 and called tails or depleted
uranium
Low-enriched uranium converted to enriched uranium dioxide 24
Fuel Fabrication
Enriched/non-enriched uranium dioxide converted into pellets and encased into
metal tubes to form fuel rods (27 tonnes required for 1000 MWe plant each year)
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Nuclear Fuel Cycle:
Spent Fuel Reprocessing
Used fuel contains about 96% of its original uranium
Fissile U-235 content reduced to less than 1%
3% of used fuel are waste products while remaining 1% is plutonium
Reprocessing separates uranium and plutonium from waste products
by chopping up fuel rods and dissolving them in acid
Uranium recovered from reprocessing contains higher concentration of
U-235 than that found in nature
Can be used after conversion and enrichment