Sec: IN SR-IIT-STAR SC(MODEL-B) WTA-41 Date: 14.04.

2024
Time: 3Hrs Max. Marks: 180
KEY SHEET
MATHEMATICS
1 B 2 A 3 C 4 D 5 1
6 4 7 3 8 2 9 1 10 4
11 ABD 12 ABC 13 AD 14 4 15 ABC
16 ABCD 17 5 18 5 19 3

PHYSICS
20 C 21 D 22 D 23 D 24 684
25 676 26 5 27 3 28 80 29 7
30 ABC 31 ABCD 32 CD 33 AD 34 BC
35 D 36 8 37 2 38 3

CHEMISTRY
39 C 40 B 41 B 42 A 43 4
44 5 45 254 46 173 47 4 48 50.40
49 ABC 50 AD 51 CD 52 ABCD 53 BD
54 BC 55 9 56 3 57 9
NARAYANA IIT ACADEMY IN SR IIT STAR SC_JEE ADV_2021_P1 (WTA-41) SOL
SOLUTIONS
MATHEMATICS
1.

Equation of AB is yy1  2a  x  x1 
y1 y1  2a  x1  x1 
 PM 
y12  4a 2


y 2
1  4 ax1 
y12  4a 2
1
Also length of AB 
a
y 2
1  4ax1  y12  4a 2 
Thus, area of PAB is
3
1 1 2
2
  
AB PM 
2a
y1 4 ax1
2

2. An equation of tangent to E at P is
x y
cos  sin   1 …. (i)
a b
And an equation of tangent to C at Q is
x y
cos  sin   1 ….. (ii)
a a
b
Slope of (i) is m1   cot 
a
And slope of (ii) is m2   cot 
Let  be angle between (i) and (ii), then
m  m2  a  b  cot 
tan   1 
1  m1m2 a  b cot 2 
ab

a tan   b cot 
a b
 2

a tan   b cot   2 ab 
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a b
max  tan   
2 ab
This value is attained when
a tan   b cot 
b b
 tan   i.e.,    tan 1  
a a
a b
Thus, max  tan   
2 ab
1
3. Let I   dx
1  sin 4 x
dx

1  sin x 1  sin 2 x 
2

1 1  sin 2 x  1  sin 2 x
 dx
2  1  sin 2 x 1  sin 2 x 
1 1 1 1
 dx  dx
2  1  sin 2 x 2  1  sin 2 x
1 1 d  tan x 
 tan x  
2 2 1  2 tan 2 x
1 1
 tan x 
2 2 2

tan 1 2 tan x  C 
21 3
sin12  sin9 2cos  .sin 
2 2
4.  2cos 7  1 d    2 7  d
2  2cos  1  1
 2 
7  7  3
2  cos  4cos 2  3   sin
2  2  2
 d
2 7
4cos 3
2
  sin  5   sin  2   d
cos5 cos 2
  C
5 2
5. & 6.
dx dx
I  2 2

cos x  cot x cos x 1  1  cot 2 x 
2

sec 2 xdx

2  cot 2 x
Let t  tan x  dt  sec2 xdx

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tan 2 x  sec2 x t2
I  dx   2t 2  1 dt
2 tan 2 x  1
1 2t 2  1  1 1  1 
  2
dt    1  2  dt
2 2t  1 2  2t  1 

1  tan
 t
1
2t  
C
2 2 
 
1 1  2 
 tan x  tan 1  C
2 2 2  cot x 
1 1  cot x 
 tan x  tan 1  C
2 2 2  2 
1 1 1 1
 A &B  4 A2  4   1 and 32 B 2  32   4
2 2 2 4 8
7. & 8.
1
I   sec 2 x  cos ec 4 xdx   dx
cos x  sin 4 x
2

sec 4 x sec2 x
 dx
tan 4 x
t  tan x  dt  sec2 xdx & sec2 x  1  t 2
2 2

I 
1  t  1 2 
dt    4  2  1 dt
4
t t t 
1
  cot 3 x  2cot x  tan x  C
3
1
 K    L  1& M  2
3
1
Then 3K + L – M = 2 and 9K 2  2L  9   2 1  3
9
9. & 10.
 x2  x   x2  1  t  1 dt
  x 4  9    x 4  9  xdx   t 2  9  2
dx 

When t  x 2  dx  2 xdx
1 2t 1 1
  2 dt   2 dt
4 t 9 2 t 9
1 1 1 t 3
 ln t 2  9   ln C
4 2 23 t  3
1 4 1 x2  3
 ln x  9  ln 2 C
4 12 x  3

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32 3
1 1 1 1 1 1
 A  & B   8 A3 2  8     8     8   1 and 48 B  48   4
4 12 4 2 8 12
11.

2 2
Equation of circle can be written as  x  4    y  5   81
2 2
Note that  x  2   y  3 represents distance of point  x, y  from
2 2
point A  2, 3 . If  x, y  lies on the circle, then
 x  2    y  3 is least
when  x, y  are coordinates of R and maximum if  x, y  are coordinates of S where
RS is the diameter of the circle through A.
2 2
p  CR  AC  9   4  2   5  3   9  2 2
q  CS  AC  9  2 2

5
1
12. 
I   x  x2  1  dx   5
dx
x  x 12

1
Let x  x 2  1  t  x 2  1  x 
t
on subtracting these two expressions, we get
1 1  1
2x  t   x   t  
t 2 t 
1 1
 dx  1  2  dt
2 t 
 1
 1  2  dt
1 t  1 1 1 1
I    dt  dt
2 t5 2  t5 2  t7
1  1 1 
  4  6C
2  4t 6t 
4 6
1 1

  x  x2  1 
8
 12

x  x2  1  C 
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1 1 5
 A , B  A B  
8 12 24
tan x tan x sec 2 x
13. I  dx   dx
a  b tan 2 x 1  tan 2 x  a  b tan 2
2 2 t2  a
2
Let a  b tan x  t  tan x 
b
2 tdt
 2 tan x  sec 2 xdx 
b
1 1 dt dt
I  2
 2
b  t a t ba
1  b  1
 
1  t 
 tan 1  C
ba  ba 

2 x12  5 x9
14.  3
dx
 x5  x3  1
Dividing by x15 in numerator and denominator
2 5
 dx
x3 x 6
  1 1 3
1  2  5 
 x x 
1 1
Substitute 1  2  5  t
x x
 2 5 
  3  6  dx  dt
x x 
 2 5
  3  6  dx  dt
x x 
This gives,
2 5
 dx
x3 x6  dt 1 1 x10

  1 1 3  t 3 2t 2   C  3
 C  2
C
1  2  5 
 1 1
2 1  2  5  2  x 5
 x 3
 1
 x x   x x 

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x x  x 2 x  1  ln x  1
15. Let I   dx
x4 x  1
Let x x  t then x x 1  ln x  dx  dt
 1
t  1 dt tt 
2
1 1
I   4  tan  C
t 1 2  2 
 
 x 1 
1  x  xx 
 tan 1  C
2  2 
 
1
 f  x   x x , f   x   0  x x 1  ln x   0  x 
e

x 1 x 1
16. f  x   2
dx   2
dx
 x ln x  1  1
x 2  ln x  
 x
1 1
 2
 x x dx
2
 1
 ln x  
 x
1 1 1 
Let t  ln x  then dt    2  dx
x x x 
dt 1
 f  x   2    C
t t
x
 C
1  x ln x
Given that f(x) = 1  1 = 1 + C  C = 0
x
 f  x 
1  x ln x
x
Lt 
x 0 1  x ln x
0
x 0

 Lt  x ln x  0 
x 1
Lt  Lt  0. (using L Hospital Rule)
x  1  x ln x x   1  ln x 

1 1  x ln x
 f  x  dx   x dx  ln x   x ln x  x   C
f(x) is discontinuous when x ln x = 1
1
 ln x  it has only one solution
x

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i.e f(x) is undefined at exactly one point.

Hence f(x) is discontinuous at exactly one point in  0, 
x2 y2
17. An equation of normal to the hyperbola   1 at  2sec , tan   is
4 1
2 x cos   y cot   5 ….. (i)
5 5
Its intercepts on the axes are cos and , respectively
2 cot 
 5 5
The intercepts are positive and equal, 0    , and 
2 2cos  cot 
1
 sin  
2

 
6
We can write (i) as 3 x  3 y  5
 5 
or y  x   
 3
2
x2 y 2  5 
This will touch the ellipse 2  2  1 if    a 2m 2  b2  a 2  b2
a b  3
3 2

5
 a  b2   5
cos x
18. I  dx
3
sin x  3 sin 5 x
1
3
cos x sin x
 4
1  sin 3 x
2
3
2 31
Let t  sin x than dt  sin cos xdx
3
3
dt 3 3 1  23 
I  2 1
 tan t  C  tan  sin x   C
1 t2 2 2  
Hence the value of m = 3 and n = 2 so m + n = 5

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1 1
19. Let f  x   
x  1  x  1  x 2  x  1
3

1 A Bx  C
f  x    2
 x  1  x  x  1 x  1 x  x  1
2

 1  A  x 2  x  1   Bx  C  x  1
Comparing the coefficients of x2 , x , and constants
0 = A + B, 0 = -A + B + C, 1 = A + C
 A = 1/3, B = -1/3 & C = 2/3
1 x 2
 
1 1  2 x  4
 f  x  3  2 3 3  
x  1 x  x  1 3 x  1 6 x 2  x  1
1 2x  1 1
 
3  x  1 6  x  x  1 
2
1   3  
2 2

 x      
 2  2  
 
dx
 3
x 1
1 1 1  2x  1 
 log x  1  log x 2  x  1  tan 1  C
3 6 3  3 
1 x 1
1  2x  1 
log tan 1 
 C
3 2
x  x 1 3  3 
1 1
Hence the value of   so  3 .
3 
PHYSICS
20. (C)
For standing vibrating in its nth overtone

= ( n  1) th harmonic (n  1) 
2
 (n  1) x 
y  2 A sin   cos  t
 L 
1
For x  , 2 A  a and n  3 .
3
  4   
y   a sin     cos t
   3 
4  3
= a sin cos t = a   cos t
3  2 
 3a
i.e., at x  , the amplitude is .
3 2
21. (D)
22. (D)
23. (D)
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3 2
vB  v A  v A , vC  v A  vA
100 100
3 2
vB  vC  8 ; vA  vA  8
100 100
5
or v A   8 or v A  160 Hz .
100
24. (684)
25. (676)
 V  V0 
n '  n 
 V 
26. (5)
The relation between pressure amplitude and displacement amplitude is given as
   2 f 
pmax  BAk  (v 2 p ) A    v3  A  
v  v 
pmax
Hence, displacement amplitude, A 
2 f  v
1.13  10 3 Pa

2 (1665 Hz )(1.21 kg m 3 )(343 ms 1 )
= 0.26 10 9 m  0.26 nm
27. (3)
The intensity of the wave in terms of the pressure amplitude
( pmax ) 2 (1.13 103 Pa ) 2
I 
2v 2(1.21 kg m 3 )(343 ms 1 )
= 1.5 nWm 2 .
28. (80)
Mass per unit lengths of PQ,
0.06 1
m1  
4.8 80
Mass per unit length of QR,
0.2
m2 
2.56
Speed of wave in wire PQ.
T
v1   80 ms 1
m1
29. (7)
Speed of wave in wire QR,
T
v2   32 ms 1
m1
Time taken by pulse to reach from P to R
4.8 2.56
=   0.14sec .
v1 v2
30. (ABC)
If equation of a wave pulse is y  f (ax  bt )
b
The speed of wave is in negative x-direction for y  f (ax  bt ) and positive x-direction for
a
y  (ax  bt ) . Comparing this from given equation we can find that speed of wave is
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5
 1.25 ms 1 and it is traveling in negative x-direction.
4
31. (ABCD)
32. (CD)
1 2 3
t  0, , , ,……. are times at which maximum are obtained
( f1  f 2 ) ( f1  f 2 ) ( f1  f 2 )
1/ 2 3/ 2 5/2
t , , , ….. are times at which minima are obtained.
( f1  f 2 ) ( f1  f 2 ) ( f1  f 2 )
33. (AD)
34. (BC)
d cot 0 d cot 0
v0  t0  ; t0 
2 2v0
For t  t0 ; f ap  f0
For t  t0 ; f ap  f 0 .
35. (D)
36. (8)

 n2  n1  ( N 1)n .
37.. (2)
V V V
n  n0  nC   
2 4 4
1 n ' 
n   
 n  '
38. (3)
If P is order of resonances then length of air column

  (2 p  1)  L
4
V 330
(2 p  1)  L  (2 p  1) 1
4n 4  500
233
 p  p  3 (p takes only integer)
66
CHEMISTRY
39. Conceptual
40. Conceptual
41. Ether, alcohol, alkene
42. In tyndall effect, refractive indices of dispersed phase and dispersion medium differ
greatly in magnitude.
Micelles are formed by surfactant at CMC or above CMC and at Kraft temperature or
above Kraft temperature.
43. i, iv, v, viii
44. ii, iii, vi, vii, ix
45-46.

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NARAYANA IIT ACADEMY IN SR IIT STAR SC_JEE ADV_2021_P1 (WTA-41) SOL
OH OH
ONa
SO3H
Br SO 3Na
Conc.H2SO4 (i) NaOH
(ii) Br2
SO 3H
M .W . 254 SO 3Na

dil. H2SO4,

OH
Br

M .W .173

47.
OH
Br Br Br Br

B= C=

Br Br
1+3=4

48.
OH
Br Br

Br 315  0.16  50.40 g

49. Conceptual
50. Conceptual
51.
- C Br
OΘ
antibonding
CH3
O
NaOMe * NGP -NaBr
* MeOH MeO Br
MeOΘ Br SN 2 O
Θ
mechanismOMe OMe *
attach less hindered
side
Above reaction proceeds via SN2 mechanism and involves neighbouring group
participation
52.

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NARAYANA IIT ACADEMY IN SR IIT STAR SC_JEE ADV_2021_P1 (WTA-41) SOL

53. Conceptual
54. Migratory aptitude
55. X=2, Y=3, Z=4
56.
OH

A) B) Phenol - PKa 9.98

PKa 9.31

OH
OH
NO 2

OH
D)
C) O PKa 3.83
NO 2
PKa 3.96
OH
OH OH
O 2N NO 2

E) G)
F)
PKa 18 PKa 8.28
PKa 0.38 NO 2
NO 2

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