JEE (Main + Advanced) 2021

JEE (Main + Advanced) 2021

ENTHUSE COURSE
ENTHUSE COURSE

RACE - 40 INORGANIC CHEMISTRY

MM : 30 TIME : 30 Min.

Only one correct

1. Phosphine is prepared by the reaction of
(A) White -P and HNO3 (B) White-P and H2SO4 (C) White-P and NaOH (D) White-P and H2S
1. fuEu esa ls dkuS lh vfHkfØ;k ls QkLQhu curh g\
S
(A) 'osr P rFkk HNO3 (B) 'osr P rFkk H2SO4 (C) 'osr P rFkk NaOH (D) 'osr P rFkk H2S
1. Ans.(C)
2. With respect to halogens, four statements are given below
(I) The bond dissociation energies for halogens are in the order: I2 < F2 < Br2 < Cl2
(II) The only oxidation state is -1
(III) The amount of energy required for the excitation of electrons to first excited state decreases
progressively as we move from F to I
(IV) They form HX2–. species in their aqueous solutions (X = halogen)
The correct statements are
(A) I, II, IV (B) I, III, IV
(C) II, III, IV (D) I, III
2. gy
S kstu ds lanHkZ esa fuEu pkj dFku fn;s x;s gS
(I) gyS kstu ds fy, ca/k fo;kstu ÅtkZ ds eku dk Øe gS I2 < F2 < Br2 < Cl2
(II) vkWDlhdj.k voLFkk -1 gS
(III) tc ge F ls I dh vksj c<+rs gS rks bysDVªkuksa ds izFke mÙksftr voLFkk rd mÙkstu ds fy, vko';d ÅtkZ dh
ek=k mÙkjksÙkj c<+rh gS
(IV) gy S kstu muds tyh; foy;u esa HX2– Lih'kht cukrs gaS (X = gSykstu)
lgh dFku g&S
(A) I, II, IV (B) I, III, IV
(C) II, III, IV (D) I, III
2. Ans.(D)
3. Which one of the following information about the compounds is correct?

Compound Oxidation No. of P–OH No. of P–H No. of P=O

state of P bonds bonds bonds
[I] H3PO2
1+ 2 1 0
Hypophosphorous acid
[II] H4P2O5
3+ 2 2 2
Pyrophosphorous acid
[III] H4P2O6
4+ 2 2 2
Hypophosphoric acid
[IV] H4P2O7
5+ 3 1 4
Pyrophosphoric acid
(A) I (B) III (C) IV (D) II

INORGANIC / R # 40 E-1 /2
 JEE (Main + Advanced) 2021
ENTHUSE COURSE

3. fuEu esa ls dkuS lh lwpuk,sa fn;s x;s ;kfS xd ds fy;s lgh gS&
P dh vkWDlhdj.k P–OH dh ca/k P–H dh ca/k P=O dh ca/k
;kfS xd
voLFkk la[;k la[;k la[;k
[I] H3PO2
1+ 2 1 0
gkbiksQkWLQksjl vEy
[II] H4P2O5
3+ 2 2 2
ik;jksQ
s kWLQksjl vEy
[III] H4P2O6
4+ 2 2 2
gkbiksQkWLQksfjd vEy
[IV] H4P2O7
5+ 3 1 4
ik;jksQkWLQksfjd vEy
(A) I (B) III (C) IV (D) II
3. Ans. (D)
O O Bond
P – O 2Þ
Sol. H4P 2O 5 HO—P—O—P—OH
P – H 2Þ
H H P= O 2Þ
4. Which of the following compound is used for estimation of CO ?
(A) I2 O 4 (B) I4O9 (C) I2O7 (D) I2O5
4. CO ds vkadyu ds fy,] fuEu esa ls dkuS ls ;kfS xd dk iz;ksx fd;k tkrk g&
S
(A) I2 O 4 (B) I4O9 (C) I2O7 (D) I2O5
4. Ans. (D)
5. Sugar becomes black when comes in contact with conc. H2SO4. It it because of -
(A) Oxidising property of conc. H2SO4 (B) Reducing property of conc. H2SO4
(C) Dehydrating property of conc. H2SO4 (D) Decolourisation property of conc. H2SO4
5. tc 'kdZjk lkUnz H2SO4 ds lEidZ esa yk;k tkrk gS rks og dkyh gks tkrh gAS bldk dkj.k gS -
(A) lkUnz H2SO4 dk vkWDlhdkjd xq.k (B) lkUnz H2SO4 dk vipk;d xq.k
(C) lkUnz H2SO4 dk futZyhdkjd xq.k (D) lkUnz H2SO4 dk jaxghu djus dk xq.k
5. Ans. (C)
6. Sulphuric acid is manufactured by the Contact Process. Which step does NOT involve :
(A) Burning of sulphur or sulphide ores in air to generate SO2.
(B) The SO2 produced is purified by removing dust and other impurities such as arsenic compounds.
(C) Conversion of SO3 to SO2 in the presence of a catalyst (V2O5).
(D) Absorption of SO3 in H2SO4 to give Oleum (H2S2O7).
6. lY¶;qfjd vEy dks lEidZ izØe }kjk fufeZr fd;k tkrk gSA fuEu esa ls dkSulk in lfEefyr ugha gS&
(A) SO2 cukus ds fy, lYQj ;k lYQkbM v;Ld dks ok;q esa tykuk
(B) mRikfnr SO2 dks] /kwy rFkk vU; v'kqf¼;ks a tSls vklsZfud ;kSfxd dks fu"dkflr dj 'kq¼ djuk
(C) mRizsjd (V2O5) dh mifLFkfr esa SO3 dk SO2 esa :ikUrj.k
(D) H2SO4 esa SO3 ds vo'kks"k.k ls vksfy;e (H2S2O7) iz kIr djuk
6. Ans. (C)

E-2 /2 INORGANIC / R # 40
 JEE (Main + Advanced) 2021
ENTHUSE COURSE

7. Incorrect statement for ozone is

I. More reactive than oxygen. II. It reacts with Hg and stop its mobility in test tube.
III. It is carcinogenic. IV. It can oxidise moist KI to KIO4.
(A) II (B) I, III (C) III, IV (D) II, III, IV
7. vkstksu ds fy, dkSulk dFku vlR; gS \
I. ;g vkWDlhtu ls vf/kd fØ;k'khy gAS II. ;g Hg ls fØ;k djds ij[kuyh esa Hg dh xfr'khyrk jksd nsrk gS
III. ;g daSljtU; gAS IV. ;g ue KI dks KIO4 esa vkWDlhd`r djrk gAS
(A) II (B) I, III (C) III, IV (D) II, III, IV
7. Ans. (C)
Ozone oxidises moist KI to I2.
8. Which of the following match is irrelavant.
Gas Absorbers
(A) CO Cu2Cl2 (aq)
(B) PH3 CuSO4 (aq)
(C) O3 Oil of Cinnamon
(D) N2 Turpentine oil
8. fuEu esa ls dkSulk feyku vlaxr gSA
xS l vo'kks " kd
(A) CO Cu2Cl2 (aq)
(B) PH3 CuSO4 (aq)
(C) O3 nkyphuh (Cinnamon) dk rsy
(D) N2 rkjihu (Turpentine) dk rsy
8. Ans. (D)
One or more than one may be correct :
9. Which of the following methods can be used to produce phosphine gas ?
(A) Ca3P2 + H2O ¾¾
® (B) PH4I + KOH ¾¾
®

(D) White P + NaOH ¾¾¾¾ ®

inert
(C) Heating of H3PO2 atmosphere

9. fuEu esa ls dkuS lh fof/k;ksa dk] QkLQhu xSl cukus esa iz;ksx fd;k tk ldrk gAS
(A) Ca3P2 + H2O ¾¾
® (B) PH4I + KOH ¾¾
®

vfØ;
(C) H3PO2 dks xeZ djus ij (D) 'osr P + NaOH ¾¾¾¾
ok;qe.My ®

9. Ans. (A, B, C, D)
10. The reaction that does not produce nitrogen is
(A) heating (NH4)2Cr2O7 (B) NH3 + excess of Cl2
(C) heating of NaN3 (D) heating of (NH4)2CO3
10. Ans.(B, D)

INORGANIC / R # 40 E-3 /2