QUANTUM NUMBER

It describes subshell

01
It describes shell or
orbit value from 0 to n-1 MAGNETIC
n = 1, 2, 3, 4,........ l=0 s l=2 d QUANTUM NUMBER
PRINCIPLE K, L, M, N,........ l=1 p Value of m = -l _
< m_ < l
l=3 f
QUANTUM NUMBER Total values of m = 2l +1
n = 4
UNCERTAINTY In nth Shell ,
Number of subshells = n
It describes size &
energy of shell.
AZIMUTHAL Orbital angular
momentum
l
l
=
=
0
1
m
m
=
=
0
-1, 0, +1
QUANTUM NUMBER
PRINCIPLE 1 h l = 2 m = -2, -1, 0, +1, +2
= l (l+1) , =
Number of orbitals = n2 r n2 E 2π l = 3 m = -3, -2, -1, 0, +1, +2, +3
n2
Max. number of electrons =2n2
Maximum no. of orbital
It defines the angular
in a subshell =2l + 1
momentum
nh Maximum no. of electrons
mvr =
h 2π in a subshell =4l + 2
Δx.Δp >
- 4π SPIN
QUANTUM NUMBER
h If l=2
Δx.mΔv >
- 4π 1) Orbital = d CLOCKWISE (+ 1/2 )
Q. Which of the following set of quantum

Q. Find angular momentum of Q. Find maximum no.of e- having numbers is correct?

2) No. of orbitals = 2(2+1)=5 SPIN
Q. According to Heisenberg's uncertainty principle, n l m s

Δx.Δp >
h
- 4π which of the following is correct ? (i) 2s orbital (ii) 3d orbital (i) n=4,s= -1/
1) 4 0 0 +1/
2 (dxy,dxz,dyz,dx -y ,dz ) ANTICLOCKWISE
(ii) n=3,l=1,m=0
2 2 2

a) If Δx = 0 then Δp = ∞
2 2) 5 2 3 -1/
2
(- 1/2 )
(iii) 4p orbital (iv) e- in 4 th orbit (iii) n=2,l=0 (iv) n=3,l=1 3) 2 -1 0 +1/ 3) Total e-s = 2(2l+1)= 10 e-s
b) If Δv = 0 then Δp = 0 2

c) If Δp = 0 then Δx = ∞ 4) 6 3 0 -1/
2
4) Orbital angular momentum =
d) All are correct
= 2(2+1) = 6
Q. Find uncertainty in velocity, if uncertainty

a)
position is equal to uncertalnty in momentum.
h
2 πm b)
1
2m
h
π
c)
1 h
d)
1 h
STRUCTURE OF ATOM
m π 2 mπ

Q. The uncertainty involved in the measurement of SHAPE OF ORBITALS

velocity within a distance of 0.1A0 is: Electrons are filled in the
ENERGY OF ORBITALS 1) s orbital - Spherical shape
a) 5.79 x 10 m/s b) 5.79 x 107 m/s
Aufbau increasing order of energy
6

c) 5.79 x 108 m/s

principle
d) 5.79 x 105 m/s
1s < 2s < 2p < 3s < 3p
2) p orbital - dumb bell shape < 4s < 3d .........
1) Mono electronic species
Energy defined upon n 3) d orbital - double dumb bell shape
FILLING OF
Angular momentum 3s, 3p, 3d NODES ATOMIC ORBITAL
1s < 2s = 2p < 3s = 3p = 3d e- wave function
E 2s, 2p
in n orbital
th
2

= mvr= n
1s probability of finding the Pauli‛s No two electrons can have same
electrons four quantum numbers
2) Multi electronic species exclusion
* Node Probability of finding the principle 1s3- against Pauli‛s exclusion
Orbital angular momentum 3s < 3p < 4s < 3d electron is zero. principle

= l(l+1) (n+l) rule * Node plane Plane; where = 0

2

As (n + l) ,E * Radial nodes n-l-1

Spin angular momentum If (n + l) is same, then n E * Angular nodes = l Pairing is only takes place
after each orbital is
= s(s+1)
Orbital 2s 3d
* Total nodes = n-1 Hund‛s singly occupied.
(n+l)
n = 2 n = 3
l = 2
rule Against Hund‛s rule
l = 0

PHYSICS
value
n+l = 2 n+l = 5

WALLAH