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GRAVIMETRYA.

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|CHAPTER-3 UNIT-3 P.A.

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•SYLLASUS:
Principle and step invoved in qravimetric

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of - piecipiation
analysis. Purity th precipiole Co

and post preclpeaion, Estimatlon of borium sulprate.

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P
.Gravitnctry:
It is o quantitafve anaeis involving the detertoi naion
LL

pUre fonm ie.

of uveigh/amount f Subsjoncs in t
cf precipitate by pecipitotion eactlon.
in te fom
in soliol foum
E

Grouimctry
W

Gvavi + Metry
uDAUremt dutuminatin
E
R
A

Solution Solid mass

C

pyecipiak flfred

Calculaled..

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PRINCIPLE

It is baced on the prinipe that i invole

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CoDversjon of ons/element pure form
to its

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by precipation reoction, whjeh Can

bigh and quantify.

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STEPS INVOLVED IN GRAVIM eTRY

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It involves the Several seps

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Sampling - preporation of olution.
0 P
Preipilation
Diqestion ostuald ripring
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flteration
9
latking
Drying
/ Tgnition
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Weighing
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Colculation
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we have to prepase solutnon

subsance in
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by dissolving cf
dissolved and reoction take
Solvet owhich Jt
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place.
witbdrawn ftom th
C

suifablo subsane /sample is

• the

pulk matuia.
ßa (l2t CoNC. S0y BasOy t 2H

Barium chlorida Rojum sulphate

ppt
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Precipi lation NOw, for preparotion

preparotion ofpreci pilate,
we have to add precipilating reoqert
for nake a a solutjon

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precipitake cF substanca in
pocoss of
of formaton of solid)

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Q
solutien, when chemical e0con tao place
• Preciptation is necQesay to ceNvert subconco (no
pure form.

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its

d. Hys04

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Pigestion (0stuald ipening It s Sthaller
aa proceIs in

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hich hu a pasticles of
preci pilate is Convertecd
P indo larqers Ohe by
allouing 0 precipijete o tand in the presena
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of mother liquor.
conain precipitate.
•Mother liquor is a Solution
tha
. is allouecd t sfand for 12-24
In this, precipak
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hoUrs at foom fenp

•to increasa the tak of diqstion, tenperatue ik vajsed.
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@ In ths process, precipiate ts saparot

fltroion
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liquor by ysing
out from tu mother
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paper
fAlter Paper i.e. whatna's flter
used ,
vetajng the solid wich is
• filter Papar
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the
as residue allouws the liquid to pass
termed
C

thiovqh wich is collected

cllected bolou) is Caled fittate.

G
Washing Noua, doring -thìs process, precipitale
6)
COamjnaed wit inp urifie
Some

we hoveto wash thatprecipto

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by using warm water r with

uoith suitable solvert for
temoye the mpurites from the preciputoe.

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6 Drying Drying or gnition it used to remove the

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is
water from the preipàlate which occurs
during wasing

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•The ding Can bo by heating at lo'c to

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120c fo 2

Iqution an ba on at
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much higher tempesotUre,
P
which is Usvatly required f precipitate muct ba
be
Converted o a MONe
suitable fom for eighing
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Weigang Afia dnying, take esidue (peopikete)

in toom tempo aure and, eigh aceurotely

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on balonce.
anatal
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(8) Colcubtion
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. XS
purity ofE
R

subsanca
A
C

where,
resjdue C
pre)pitaJe)
t weight of
Giavimeric facor
W= wejqt of Sample
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PURITY OF PREUPITATe|

Sepauae out from th

Whenhe preciputate is saparate

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precipilake
Solution, it is not aluys pure le. the

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s Conaminated wit amour of impurites.
of impuvities depends
depends upon the
These amoUt

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noture and conditton of precipolae.

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• It Is Mainl of uo types

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O co- precipiaion

D Post- precipitation
P
It Condition/ procoss in
O o-precipation
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precipijate is Contaminated
|durig fororotion of precipahishich the
substanG shich are
during qravimefry by those
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Soluble in
moner liquor.
types
• It mainly of
to
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(s

a) Surfac adsorption
In this, mpuriies are adsovbod
tha surfas of precipikak.
E

b) Occlusion - In this, impur ties qet trappd insjde

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during gowth oft

precipitate
A

precipitoe cnstals.
on Basoy precipatate in al kali rntrates.
AgI adsobs
C

ondition /process in
Post- precipilatihon > It is 0

which the impuritea qet

After -formotion of precipiale
edse adsorbad te" Cutfaco precpitak
on

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affer ik formation

mainl twhen
th preiptoae is allous to

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.
pre sence af moner liquor
Stand sf

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ESTIMATION OF RARIUM SULPHATE

(Sulphat
In ofmoun F

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gravimehry analysi, th
is estimatrd uantitatiyely barium sulphate.

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. Bariumn sulphae BaSOy

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Molecula wught 23349/mol P
Principle:
In tnis, dil. Suphurie add (HzS0) s addd to
LL

the dil. olution ofbarium Choride (Rach) wich

ne Rarium sulpate.
-forms white precipilak
ofof
(Basoy ) + 24C4
E

H SOy
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Procedure:
bove to prepare solution of
firstty
E

nd dissol ved
Sample 0-08 Q
qm ofBacl
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in Of distilled water
l000
A

Conc. ths0y and dissolved

tak0 of

| in lo0 of distilled we.

C

Solution
Pippute Out Of Bach
i)
beaRer.
n) Add soluton

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and Moko Volume upto loO m with

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distilled water.
) NOu, heot tno olution am make solutiop bot.

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v) Add dil. t4so droçuise Solution urtil the
procipitae is not epavated ou

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v) NOus, filtered washd and dried t.

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Cal culation:
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P
EXS
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substana
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|APPLICATIONS of GRAvIMETRY

solutions.
anolysis of standod
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Used

onalyais requiring (auracy) ie. it is ttm

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Used

but accuracy (accurate eAult).

CoNSuMing show bitu
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• Used in determinaioh of
C

chloride silver .eWoride

lead chromate ele..

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