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INTRODUCTION
Globally, the demand for diesel fuel reigns supreme among oil products, prompting
widespread reliance on this energy source. The Philippines actively addresses this demand by
importing diverse crude oils from numerous countries, underscoring the global significance of
diesel as a primary fuel. The pervasive demand and consumption of diesel fuel contribute to the
dynamic fluctuations observed in oil prices. This economic ripple effect, coupled with the
sustainable energy solutions. Diesel exhaust, notorious for its adverse impact on both human
health and the environment, amplifies the need for innovative approaches in the energy sector.
biodiesel production standing out as a promising solution. The innovative approach involves
blending biodiesel with traditional diesel fuel, offering a sustainable and eco-friendly alternative.
attributes, emerges as a beacon of hope in mitigating the dual concerns of resource depletion and
environmental degradation. With its low emission profile, biodiesel is poised to revolutionize the
energy landscape, presenting a viable path towards a more sustainable future. This research
initiative, therefore, takes center stage in the pursuit of practical solutions, seeking to design,
fabricate, and rigorously test a specialized machine. This machine is engineered with the purpose
of transforming waste cooking oil feedstock into biodiesel, with methanol and Potassium
Hydroxide serving as pivotal catalysts in the intricate chemical process. The adoption of waste
cooking oil as the primary feedstock not only addresses the ecological challenges posed by its
disposal but also accentuates the economic viability of biodiesel production by tapping into a
readily available resource. In essence, this study endeavors to propel sustainable energy practices
forward, recognizing the pivotal role of biodiesel as a transformative force in the global energy
landscape.
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1.2 Statement of the Problem
This study addresses several key issues pertaining to the design, fabrication, and testing
of a biodiesel production device utilizing waste cooking oil. Specifically, this study aims to
1.3 Objectives
The general objective of the study is to design, to fabricate and to test a device that will
produce biodiesel oil from waste cooking oil and to test the biodiesel produced. Specifically, it
aims:
3. To design and fabricate a pre-treatment unit, mixing unit and reacting unit.
This study addresses the pressing environmental concern of waste cooking oil disposal.
By repurposing this commonly discarded byproduct as a feedstock for biodiesel production, the
research contributes to reducing environmental pollution. Waste cooking oil is notorious for
clogging drains and causing ecological harm when improperly disposed of, and its conversion
This study tackles the global demand for diesel fuel and the associated environmental
impact. As diesel fuel remains a primary energy source worldwide, the study's focus on
designing a device for biodiesel production aligns with the quest for cleaner and more
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sustainable energy alternatives. Biodiesel, derived from waste cooking oil, not only diminishes
reliance on finite fossil fuels but also offers a renewable and eco-friendly substitute that
Economically, the study holds significance by exploring the viability of waste cooking oil
as a resource for biodiesel production. Given that waste cooking oil is abundantly available and
often treated as a waste product, its utilization for biodiesel can potentially offer a cost-effective
alternative to conventional diesel fuels. This economic angle is particularly relevant in the
context of fluctuating oil prices and the quest for more stable and sustainable energy sources.
Researchers emphasis on the transesterification method, along with the design and
landscape in sustainable energy production. The outcome of the study could potentially inform
the development of efficient and scalable biodiesel production technologies, fostering innovation
Lastly, the comparative analysis of different biodiesel blends adds a layer of practical
significance. Understanding how various blends perform allows for informed decision-making
regarding the optimal composition of biodiesel, considering factors such as efficiency, emissions,
and overall performance. This comparative analysis contributes valuable insights to the ongoing
efforts to enhance the quality and efficacy of biodiesel as a viable alternative to traditional diesel
fuels.
The study's scope is limited to the design, fabrication, and testing of a biodiesel
The study may encounter limitations related to resource availability, including financial
constraints and access to specialized equipment. These limitations may influence the scale and
temperature and humidity, which could impact the transesterification process and the overall
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The study will focus on waste cooking oil as the primary feedstock; however, variations
in the composition of waste cooking oil may introduce some degree of variability in the biodiesel
production process.
The study's duration may limit the assessment of the long-term performance and
durability of the fabricated biodiesel production device. Long-term effects on components and
overall efficiency may require extended observation beyond the study period.
Biodiesel: A renewable fuel from biological sources such as waste cooking oil, with
Transesterification: The chemical process involved in converting waste cooking oil into
biodiesel, where triglycerides react with alcohol (methanol) in the presence of a catalyst
Biodiesel Production Device: A specialized machine designed and fabricated for the
Pre-treatment Unit: The component of the biodiesel production device responsible for
preparing waste cooking oil by removing impurities and enhancing its suitability for the
transesterification process.
Mixing Unit: A component of the biodiesel production device that facilitates the thorough
blending of waste cooking oil, methanol, and catalyst to initiate the transesterification
reaction.
Reacting Unit: The segment of the biodiesel production device where the
transesterification reaction takes place, leading to the conversion of waste cooking oil
Waste Cooking Oil: Cooking oil that has been used in food preparation and is no longer
suitable for its original purpose, often discarded as waste, but repurposed in this study as
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Methanol: A type of alcohol used as a reactant in the transesterification process, aiding in
the reaction between waste cooking oil and methanol, facilitating the production of
biodiesel.
Efficiency: The measure of how well the biodiesel production device converts waste
cooking oil into biodiesel, considering factors such as yield, energy consumption, and
evaluated in the study to assess and compare their performances in terms of efficiency
and emissions.
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CHAPTER II
This chapter presents the related literature and studies after the thorough and in-depth
Biomass is organic, meaning it is made of material that comes from living organisms. The
source of biofuels production is commonly known as biomass, this source can be ‘converted to
liquid or gaseous fuels such as ethanol, methanol, methane and hydrogen (Awogbemi et al,
2021a: Dahiya, 2015). Two biofuel products are mainly produced are knowns as ethanol and
biodiesel (Awogbemi and Kallon, 2021). Biodiesel is a fuel that is produced from vegetable oils
or animal fats, and it acts as an alternative for fuel for diesel engines (Awogbemi et al, 2021b:
Zanzi, et al., 2006 : Leidel, 2014). Ethanol is produced from sugarcane, corn, and sugar; is used
as an additive for automotive gasoline production (Awogbemi et al, 2021c: Manochio, et al.,
2017).
alternative to petroleum and other fossil fuels, particularly in light of rising petroleum prices and
growing concern about fossil fuels' impacts to global warming. Biofuels help to reduce the
carbon footprint of transportation and other businesses by utilizing our planet's carbon cycle.
Every gallon of biofuel that substitutes a gallon of fossil fuel contributes to a reduction in
greenhouse-gas emissions. Thus, substituting biofuels for fossil fuels has the potential to lessen
some of the negative elements of fossil fuel extraction and usage, such as conventional and
greenhouse gas (GHG) pollutant emissions, exhaustible resource depletion, and reliance on
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A Biofuel Plant is a machine that is used to convert biomass into liquid fuel, known as
“biofuels”. Biodiesel is made under the process called transesterification, where oil goes through
five chambers namely: reactor, separator, methanol removal, neutralisation and washing, and
finally a dryer. The process allows the removal of the glycerine component of the oil, to allow
thinner, less viscous solutions which remain liquid in lower temperatures (Awogbemi et al,
Mono-alkyl esters, also known as methyl esters, of vegetable oils, animal fats, or other
traditional petrodiesel for use in compression-ignition engines. Many significant fuel qualities
are determined by the fatty acid esters that make up biodiesel. Because feedstocks with widely
variable fatty acid compositions can be utilized for biodiesel synthesis, the composition of the
biodiesel is dependent on the composition of the parent feedstock. The utilization of various
feedstocks is also important in terms of boosting biodiesel supply and socioeconomic challenges
(Knothe, 2017).
O.G. Tiro, et al (2021) "Designing a Domestic Biodiesel Generation Machine for Rural
Communities". Three designs of the biodiesel pilot plant were generated in converting the waste
cooking into biodiesel. The most convenient design was the pilot plant ‘one reactor tank’ since it
is cost-efficient due to fewer components. The Biodiesel production machine has one reactor
tank, whereby it operates as a multifunctional reactor tank unit. There is one motor pump, that is
used for transporting oil from the filtering tank to the processor tank and used for recirculation of
the biodiesel for the purification process. The inline filter is connected to the recirculation pipe
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system to filter out the solid catalyst. The stirrer is used for mixing oil, methanol and catalyst and
Khan, et al (2022) in their study "Innovative biodiesel production plant: Design, development,
and framework for the usage of biodiesel as a sustainable EDM fluid" The conversion reaction
was carried out for 20 L of used cooking oil and 4 L of methanol. The biodiesel production yield
of 95.8% was observed for a 1:6 M ratio of methanol and used cooking oil using 200 gm of KOH
catalyst at 60 °C for 1 h. Using biodiesel during the spark machining process can reduce
Abijith, et al (2019) it shows that the design and fabrication of a small-scale equipment
which is fully automated, rather than a simple laboratory apparatus. A yield of 95 wt% biodiesel
was achieved at 1 wt% KOH, 60 C, 9:1 methanol: fish oil ratio and 30 min reaction time .The
biodiesel so obtained was evaluated for the physical properties such as density, viscosity and
flash and fire point. The castor oil biodiesel produced was blended with different concentrations
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Chapter III
This chapter presents the method of research, the method of gathering data, and the
research tools.
The design and fabrication of the prototype is conducted in Barangay Ayala and Triplet
Street, Zamboanga City. The data gathering is conducted in one of the researchers house in Putik
Zamboanga City.
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The design consists of two tanks namely the filtering tank (black) and the processor tank.
There are two motor pumps, with the first one transporting oil from the filtering tank to the
processor tank, and the second one recirculating the biodiesel for the purification process.
The catalyst soot filter is connected in line with the motor pump to the catalyst soot filter
after the production of biodiesel. The motor is connected to the stirrer via a pulley system since it
would not be safe to connect it directly to the stirrer on top of the processor tank. The stirrer
helps with mixing the reactants to produce biodiesel. This machine is mobile, this makes it easy
to be moved and placed at any location, the pipes are transparent, and this helps in discharging of
glycerine to be able to separate glycerine from biodiesel. Some valves control the flow of the
mixture.
In the first stage, the waste cooking oil is filtered to remove debris, this is achieved by
using the carbon filter sheet placed at the inlet of the tank. The valve below the storage tank will
be opened to allow the oil to be siphoned by the motor pump to the processor tank through a
pipe. After the transportation of oil is complete, the oil inlet valve on the processor tank is
closed. Due to the strict budget, the system used to mix catalyst and methanol will not be
included in the project, therefore the catalyst and methanol will be prepared outside the current
machine. The mixture is poured manually at the inlet located at the top of the processor tank. The
motor is activated to allow the rotor to mix the reactants. The heater is used to increase the
temperature of the reactants to meet the minimum temperature for activation of the
For the separation process, the stirring system and heater are turned off for the mixture to
be allowed to settle down for 24 hours. Due to gravity and different densities, the product in the
mixture will separate. The glycerine will situate itself at the bottom, while the biodiesel will be at
the top. The discharge valve situated at bottom of the processor tank is opened to allow the
glycerine to be removed, with the help of the transparent pipe it will be easy to notice the colour
change during a discharge, to know that all the glycerine has been fully removed then the valve
is closed.
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For biodiesel purification, warm water is employed for the washing process to remove all
the impurities, contaminants, and volatile substances to decrease the possibility of emulsification,
the mixing take about 1 hour. The mixture is allowed to settle for 24 hours for the water by-
products to be drawn to the bottom of the container by gravity. The discharge valve at bottom of
the processor tank is opened again, but this time the water by-products to be removed and
afterwards the valve is closed. The motor pump linked to the processing tank is turned on, and
the valve in line with that motor is opened, allowing the biodiesel to recirculate for purification.
This process can take some time, and the quality of the biodiesel can be seen via transparent
pipes. The biodiesel is then ready for usage after it has been purified.
According to (Awogbemi et al, 2021b: Chuah et al, 2015) the properties of waste cooking oil are
given in Table 1.
Interpolation using the values in Table 1 the mean density of waste cooking oil at 25 ℃ (room
(25−20)(901.95−915.67)
ρ 2= +915.67
(40−25)
3
ρ2=911.11kg /m
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V k 2=(t 2−t 1 )¿ ¿
(55−40)(26.28−51.04)
V k 2= +51.04
(60−40)
2
V k 2=32.47 mm /s
Calculations for mass of waste cooking oil occupying 88% capacity of 500 litres as shown in the
equation below;
m
ρ=
V
m=ρV
m=337.12 kg
According to Engineering tool box, 2021, the densities of methanol are given as Table 2.
Mass of methanol,
m=ρV
m=58.19 kg
Energy requirement,
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q=( 65−25 ) [ ( 337.12 ) (1.67 ) + ( 58.19 ) ( 2.53 ) ]
q=28408.44 kJ
Stirring Speed of 350 rpm is suitable for this reaction as it induces high biodiesel yields
for the first minutes of reaction and at the same time no foam is formed (Peiter, et al., 2020). For
shaft connected to the motor, assuming that the power is 1.5 kW (Table 3).
Height 1078.46 mm
Diameter 25 mm
P
T=
2 πN
1500
T=
2 π (350)
T =0.68 N ∙ m
4
πd
T=
32
4
π (0.025)
T=
32
−8 4
T =3.835 x 10 m
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Tr
τ=
J
(0.68)(0.0125)
τ=
3.835 x 10−8
2
τ =0.222 MN /m
Angle of Twist,
TL
θ=
GJ
(0.68)(1.07846)
θ=
(77.2 x 109 )¿ ¿
θ=4 ° x 10−7
The cost analysis was used to give the estimated cost of components based on the raw
materials, manufacturing processes, and distribution costs. The components of the lowest costs
offered by various suppliers were chosen to construct the analysis based on the findings of
product cost research. The price shown in Table 5 is for a single quantity of a component,
whereas the total cost is for the entire number of quantities desired. The overall cost of the
machine is the sum of the total costs of all desired component amounts.
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Catalyst Soot Filter 1 230 230
The caster wheels should be locked, when doing the production of the biofuel.
Avoid the use of devices that can generate sparks near an open container of
methanol.
When adding the catalyst, make sure the methanol is not exposed to air by closing
the valve connecting the methanol tank and pre-mixing the methanol and catalyst
tank.
The wastewater used for washing, should not be used for other purposes.
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CHAPTER IV
The results were obtained and compared with EN14214 standards. Ten samples were
Viscosity at
3.5-5 4.2
40oC mm2/s
Sulphur % 0.01 0
The samples were tested according to B100, B80, B60, B40, B20 blends and compared the
ariations of density, viscosity and calorific value as shown in the Table II.
Table 4.1 Density, Viscosity and Calorific Values of Different Biodiesel Samples
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B40 855 3.5 40.38
Density of the biodiesel samples were varied between the range of 840-880 kg/m 3 and
viscosity of the samples were differed between 3.2-4.2 mm 2/s. Average calorific value of the
B100 samples was 38.22 MJ/kg and average calorific value B20 samples was 41.55 MJ/kg which
Fig. 5 and Fig. 6 describe the variation of power and break specific fuel consumption of the
B100, B60 blend and biodiesel sample. The fluctuations are well established under the range of
required standards and break specific fuel consumption of biodiesel is significantly higher than
80
70
Power(kW)
60
50
40
30
20
10
17
500
Consumption(g/kWh)
Break Specific
450 Fuel
400
350
300
250
200
150
100
50
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CHAPTER V
5.1 Conclusion
Biodiesel production is not a new concept for the modern world of technologies.
parameters (acid value and FFA content, viscosity and fatty acid profile of the used oil) is
The process parameters of biodiesel production are changing due to fluctuation of FFA value of
the oil samples. Once the FFA value is identified, the defined equations of the experiment can be
used to calculate the exact amount of alcohol and catalyst quantities. Other than that design
parameters of the pilot scale model explain the process requirements of an actual design. This
plant can be implemented in large scale biodiesel production with required modifications.
Extraction of biodiesel from waste cooking oil would be an immense advantage specially for
developing countries where the disposal of waste cooking oil can be measured in higher number.
The results of the research obtained within the limits of standard values. Because of that it can be
concluded the process development of biodiesel production from waste cooking oil is well
optimized. Blended samples of B40 and B20 maintain a close relation towards the petro diesel
where it can be directly used for the compression ignition engines without having any
modifications. Biodiesel production and usage will significantly reduce unburned hydrocarbons,
carbon monoxide, and particulate matter from tail pipe emissions. The results on engine power
and break specific fuel consumption of B100 and B60 biodiesel are in the range of comparable
limitations with respect to the biodiesel. This emphasized that any blended samples can be used
The major focus of the research based on the development of a well optimized pilot scale
biodiesel production plant where small and medium industries can be engaged with. Comparable
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budget, easy handling of process requirements, optimized process parameters and availability of
resources will be the added advantages for the local consumers comparing to the conventional
processes. Most of developing countries are reluctant of using biodiesel and the defined process
parameters will be prime aspects of get used to this technology. This process can be considered
as an important solution for the energy crisis as well as the environmental pollution.
5.2 Recommendation
As a result of the findings and conclusion of this study, the following are hereby recommended:
1. The heating coil must be placed in a location that it can fully heat the liquid in the
container.
2. Provide more tests in the biodiesel fuel such as emission test. Use dynamometer to
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