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Enhanced Oil Recovery Series
CHEMICAL METHODS
Series Editor
ABDOLHOSSEIN HEMMATI-SARAPARDEH
Shahid Bahonar University of Kerman, Kerman, Iran
This page intentionally left blank
CHEMICAL METHODS
Edited by
ABDOLHOSSEIN HEMMATI-SARAPARDEH
Shahid Bahonar University of Kerman, Kerman, Iran
MAHIN SCHAFFIE
Shahid Bahonar University of Kerman, Kerman, Iran
MOHAMMAD RANJBAR
Shahid Bahonar University of Kerman, Kerman, Iran
MINGZHE DONG
University of Calgary, Calgary, Canada
ZHAOMIN LI
China University of Petroleum (East China), Beijing, China
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This book and the individual contributions contained in it are protected under copyright by the Publisher (other than
as may be noted herein).
Notices
Knowledge and best practice in this field are constantly changing. As new research and experience broaden our
understanding, changes in research methods, professional practices, or medical treatment may become necessary.
Practitioners and researchers must always rely on their own experience and knowledge in evaluating and using any
information, methods, compounds, or experiments described herein. In using such information or methods they
should be mindful of their own safety and the safety of others, including parties for whom they have a professional
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To the fullest extent of the law, neither the Publisher nor the authors, contributors, or editors, assume any liability
for any injury and/or damage to persons or property as a matter of products liability, negligence or otherwise, or from
any use or operation of any methods, products, instructions, or ideas contained in the material herein.
Library of Congress Cataloging-in-Publication Data
A catalog record for this book is available from the Library of Congress
British Library Cataloguing-in-Publication Data
A catalogue record for this book is available from the British Library
ISBN: 978-0-12-821931-7
Contributors xi
Preface xv
Acknowledgments xvii
2. Polymer flooding 33
Forough Ameli, Saber Moghadam, and Samiye Shahmarvand
2.1 Introduction 33
2.2 Classification of EOR polymers 34
2.3 Polymers features and screening criteria 36
2.4 Polymer rheology 43
2.5 Polymer as fracturing fluid in oil reservoir 50
2.6 Polymer adsorption 51
2.7 Displacement mechanisms in polymer flooding 52
2.8 Fractional flow curve analysis 56
2.9 Polymer flooding performance 60
2.10 Polymer flooding in heavy oil recovery 62
2.11 Polymer flooding design and offshore experiences 65
2.12 Modeling and simulations 68
2.13 Upscaling 74
2.14 Laboratory tests and interpretation of the results 75
2.15 Field cases 79
2.16 Injection scheme 83
2.17 Operation problems 84
2.18 Well pattern 86
2.19 Surface facilities 87
2.20 Economics and feasibility study of polymer flooding processes 89
References 92
v
vi Contents
Index 479
Contributors
Arastoo Abdi
Enhanced Oil Recovery (EOR) Research Centre, IOR/EOR Research Institute, Shiraz
University, Shiraz, Iran
Yaser Ahmadi
Petroleum and Chemical Engineering Department, Ilam University, Ilam, Iran
Forough Ameli
School of Chemical Engineering, Petroleum and Gas, Iran University of Science and
Technology, Tehran, Iran
Morteza Asemani
Department of Geology, Faculty of Earth Sciences, Kharazmi University, Tehran, Iran
Sefatallah Ashoorian
Institute of Petroleum Engineering, School of Chemical Engineering, College of Engineering,
University of Tehran, Tehran, Iran
Marjan Ashrafizadeh
Department of Chemical Engineering, College of Engineering, University of Tehran, Tehran,
Iran
Saman Bagherpour
Separation Processes & Nanotechnology Lab, Faculty of Caspian, College of Engineering,
University of Tehran, Tehran, Iran
Zahra Bahmani
Enhanced Oil Recovery (EOR) Research Centre, IOR/EOR Research Institute, Shiraz
University, Shiraz, Iran
Hassan Divandari
Department of Petroleum Engineering, Shahid Bahonar University of Kerman, Kerman, Iran
Morteza Jami
School of Petroleum and Chemical Engineering, Universiti Teknologi Brunei,
Bandar Seri Begawan, Brunei Darussalam
xi
xii Contributors
Sabber Khandoozi
Enhanced Oil Recovery (EOR) Research Centre, IOR/EOR Research Institute; Petroleum
Engineering Department, School of Chemical and Petroleum Engineering, Shiraz University,
Shiraz, Iran
Hossein Mehrjoo
Department of Petroleum Engineering, Shahid Bahonar University of Kerman, Kerman, Iran
Saber Moghadam
School of Chemical Engineering, Petroleum and Gas, Iran University of Science and
Technology, Tehran, Iran
Majid Mohammadi
Department of Energy Engineering, Qom University of Technology, Qom, Iran
Saeid Norouzi-Apourvari
Department of Petroleum Engineering, Shahid Bahonar University of Kerman, Kerman, Iran
Meysam Nourani
Ugelstad Laboratory, Department of Chemical Engineering, Norwegian University of Science
and Technology (NTNU), Trondheim, Norway
Ali Rahimi
Department of Petroleum Engineering, Marvdasht Branch, Islamic Azad University, Marvdasht,
Iran
Behnam Ranjbar
Enhanced Oil Recovery (EOR) Research Centre, IOR/EOR Research Institute, Shiraz
University, Shiraz, Iran
Amin Rezaei
Department of Petroleum Engineering, School of Chemical and Petroleum Engineering, Shiraz
University, Shiraz, Iran
Masoud Riazi
Enhanced Oil Recovery (EOR) Research Centre, IOR/EOR Research Institute; Petroleum
Engineering Department, School of Chemical and Petroleum Engineering, Shiraz University,
Shiraz, Iran
Mohsen Riazi
Department of Petroleum Engineering, Shahid Bahonar University of Kerman, Kerman;
Enhanced Oil Recovery (EOR) Research Center, IOR/EOR Research Institute, Shiraz
University, Shiraz, Iran
Saeid Sadeghnejad
Department of Petroleum Engineering, Faculty of Chemical Engineering, Tarbiat Modares
University, Tehran, Iran
Contributors xiii
Mehdi Safari
Department of Petroleum Engineering, Curtin University, Miri, Malaysia
Mehdi Sedighi
Department of Chemical Engineering, University of Qom, Qom, Iran
Samiye Shahmarvand
School of Chemical Engineering, Petroleum and Gas, Iran University of Science and
Technology, Tehran, Iran
Amin Sharifi
Enhanced Oil Recovery (EOR) Research Centre, IOR/EOR Research Institute; Petroleum
Engineering Department, School of Chemical and Petroleum Engineering, Shiraz University,
Shiraz, Iran
Preface
Oil production is generally divided into three stages, namely primary, secondary, and
tertiary [enhanced oil recovery (EOR)]. After the primary and secondary stages, only part
of the oil is produced and the remaining hydrocarbons should be produced by EOR.
Generally, EOR can produce up to 75% oil. EOR techniques are also applicable to
unconventional reservoirs such as tight gas, oil sands, coal bed methane, and shale oil res-
ervoirs. EOR methods are generally classified into thermal recovery, gas injection, chem-
ical injection, and new emerging technologies such as microbial, electrical, mechanical,
and chemical leaching.
Chemical Methods, the first book in the Enhanced Oil Recovery Series, helps engineers
to focus on the latest developments in one of the fast-growing areas of EOR. The book
presents the latest research and practical applications specific to chemical EOR methods.
Chapter 1 focuses on the fundamentals and applications of chemical EOR methods. In
Chapters 2–5, the main chemical methods, namely polymer flooding, use of surfactants,
alkaline flooding, and alkaline surfactant polymers, are described. Chapter 6 presents the
technique of improved oil recovery by gel technology for water shutoff and conformance
control. Chapters 7–9 describe new emerging chemical methods such as smart water
flooding, natural surfactant flooding, and hybrid chemical methods. Chemical EOR
methods in unconventional reservoirs are covered in Chapter 10. The last chapter,
Chapter 11, explains formation damage during chemical flooding.
All the chapters have been peer reviewed by the editors and have been accepted after
considering the editors’ comments and suggestions. The book will be helpful for all sci-
entists/researchers involved in petroleum engineering, EOR, and reservoir engineering.
It will also help graduates, postgraduates, and PhD candidates to understand the funda-
mentals and applications of chemical methods.
Abdolhossein Hemmati-Sarapardeh
Editor of Enhanced Oil Recovery Series
xv
Acknowledgments
I express my sincere thanks to all the editors and authors for their timely contribu-
tions. The successful completion of this book is the result of the cooperation of many
individuals, and I express my gratitude to all of them, especially the editors of this
book—Prof. Mahin Schaffie, Prof. Mohammad Ranjbar, Prof. Mingzhe Dong, and
Zhaomin Li.
I also acknowledge the support provided by Timothy Bennett, Ali Afzal-Khan, Katie
Hammon, and Kamesh Ramajogi from Elsevier in completing the publication process. I
express my profound gratitude and thanks to Amin Rezaei from Shiraz University for
designing the cover image for this book.
Abdolhossein Hemmati-Sarapardeh
Editor of Enhanced Oil Recovery Series
xvii
CHAPTER 1
1.1 Introduction
With the rapid industrialization of economies, the necessity for natural resources has
grown rapidly. The easy-to-develop oilfields have long been identified. Finding new
economically viable fields, however, is becoming increasingly difficult [1]. Therefore,
the essential goal of oil industries is to improve the recovery factor of mature oilfields
by using EOR technologies [2, 3]. Fig. 1.1 shows that the yearly oil and gas demand
is on the rise; therefore, petroleum-related countries should boost oil exploitation.
Fig. 1.2 depicts three phases of oil recovery. Almost two-thirds of the original oil in place
(OOIP) remains before the EOR phase [6]. There are several reasons for the remaining
oil, including heterogeneities, capillary forces, and unfavorable mobility ratios [7].
Table 1.1 shows the substantial amounts of oil that have been recovered after two stages
of recovery.
To improve overall displacement efficiency (macroscopic and microscopic) and
recover remaining oil in a reservoir, two main EOR techniques need to be applied,
which can be either thermal or nonthermal [16–19]. It has been established that nonther-
mal methods are more effective than thermal methods to recover trapped oil. Figs. 1.3
and 1.4 illustrate the classification of EOR methods with additional details.
In comparison to all nonthermal methods, chemical methods have been shown to
have higher efficiency and lower cost. This is likely a consequence of lowering the
IFT, altering wettability, and enhancing viscosity by the best possible method [20].
Fig. 1.5 shows common chemical EOR methods, along with a combination of those
methods that will be discussed further. In the severe situations, such as elevated pressure
and temperature and high salinity, the alkaline-surfactant-polymer combination has more
efficacy [22].
The primary goal of chemical EOR is to act on one or more of the following aspects:
mobility (application of water-polymer solutions to increase viscosity), wettability of the
rock, and interfacial tension. Consequently, factors that affect recovery should be
100%
Other renewables
Wind/Solar
80% Nuclear
40%
Oil
20%
Coal
0%
2016 2040
Fig. 1.1 World crude oil demand [4].
Producon
2ary Recovery /
Pressure
Maintenance
3ary Recovery
(EOR)
Time
Fig. 1.2 Production framework for the different recovery stages [5].
Now we know the three hidalgos, who did not resemble each other
in the slightest degree.
(To be continued.)
QUATRAIN.
To dash irradiant on the barren shore
The wave is born; the lark to sing and soar;
To traffic with the sun upsprings the tree—
Man only has no certain destiny.
—H. C. H.
EXTRACTS FROM THE LOG OF THE
“RITA”
BEING A DISCONNECTED ACCOUNT OF THE DOINGS OF SOME
ARTISTS ON A SUMMER CRUISE....
“First day out. We can scarcely realize we have left behind the heat, the noise,
and the dust of the city for three weeks. Far to the north, overhung by clouds
of noisome smoke, our late prison is gradually sinking from sight. Only the
tallest spires and houses can be seen. As the distance grows greater our
hearts grow lighter, and dance in unison with the leaping waves. The day is a
miracle of light and color,—
and
we’re
a happy
crew!”
“Came
very
near
being
wrecked
last night. Even the moon was full—but that fact saved the lives of all on
board. Spike made a sketch this morning that will explain better than words.”
“The fashionable portrait painter’s man and girl flirting on the shore turned
out to be rather clever devices for frightening crows. He has been advised to
consult an oculist.”
“The Skipper complained this evening of “feeling queer in the head,” and
the Duke made unkindly reference to the moon (which is known to have a
peculiar influence in certain cases), but got “sat on” for his inopportune display
of wit. Fuzzie’s allusion to the banquet in the cabin last night was perhaps
more truly explanatory.”
“Sailing
close to
shore,
—and enjoying the
beautiful glimpses of
field and wood seen
through the golden
haze of a summer
afternoon.
What a
glorious
land!”
“For his marvelous success in mixing salads, the Duke, who studied the
culinary art in Paris and Rome, has been made Second Mate.”
“Three days out. The Languid Aquarellist insisted this morning on going
ashore and shooting ducks—wild ones. After he had almost decimated a
farmer’s prize flock of pekins (without noticing their barnyard confidence in
man)—he was promoted by the Captain for excellent gunnery, and the
addition to the yacht’s stores.”
“Tomson, (of the Barber’s-Own School), spent the entire afternoon trying to
convince Miss ⸺ that his own peculiar method of painting is the acme of art.
Miss ⸺ seemed delighted with his efforts, and thinks his pictures are “just
lovely.” She wants him to attempt an imaginary portrait of the sea serpent.
Owing to the ceaseless motion of the boat, Tomson’s pictures are decidedly
impressionistic.”
—“And then Bill Weatherbones gave us his version of the great naval
combat at Santiago, in which he took a very prominent part. ‘I tole yer how it
wuz,’ Bill began; ‘it wuz dis way, sur. I wuz a-settin’ on de aft hatch a-smokin’ a
cigar Bill Sampson giv’ me, an’ Bill an’ Winnie Schley wuz a-workin’ out a little
game wid de cards. Bill t’rowed down his papes an’ sed,—
“I
aint
got
no
luck,
I got to shake yuse fellers. Mc. he’s sent me de wire to go over an’ chin dat
man Shafter, wot’s runnin’ de army push, an’ make him git a move on hisself.”
“Don’t go, Bill,” sez I, “send one o’ de gang, it’s too hot fer yer, wot’s de good
yer workin’?” “Dem aint me orders,” sez Bill, den turnin’ to Winnie Schley, he
giv’ him de stern look, an’ sed, “Winnie, yer do de stunts here till I gets back
wid meself, an’ if de Spaniels tries ter get out de bottle squirt de guns on ’em.”
“I’m on,” sez Winnie, an’ he giv’ me de wink, “if de farmers shows up I shoots.”
Den de Admiral he gits in his little ya’t an’ sails off. Winnie den piped up de
grog all eround, an’ de game went on ag’in. I aint much stuck on de game de
navy push puts up, it’s on de squar’, an’ so I set dere gappin’ an’ feedin’ me
face, while de boys plays. All of a sudding I seen over dere where de guy
Hobson sinked de Merrymac some smoke. I wunk t’ meself, but didden say
nothin’ to break de boys up, but soon Winnie Schley looked up an’ seen it.
“Hully gee!” he yelled, “de blokes is a-chasin’ out,” an’ he grabbed a bunch o’
flags an’ did de signal act o’ his life. He worked dose flags till he looked like a
skirt dancer. De udder ships looked like a back yard wid de clothes-line full of
red-flannel shirts from de wavin’ de guys put up. “Git dem guns loaded,” yelled
Schley, “yuse blokes look lively, dere.” Boom! busted out one o’ de big guns,
an’ de noise it knock de win’ outten me works. It hit de Spaniel an’ turned him
bottom upwards; when he come up ag’in he shot his gun at us, but it wuz half
a mile too high. Schley he rung out de joyous laugh. “Dere optics aint no
good,” sez he, den he lets anudder ball go at him dat went clean t’rough him
an’ hit anudder ship two miles off an’ sunk it in a minnit. Den up comes
anudder Spaniel, an’ I seen⸺’”
“The steering gear is a little rattled: a puff of wind blew a lock of Mate
Fuzzie-Wuzzie’s hair into the wheels, and instantly the vessel swung round.
The engine was stopped, and in the excitement that ensued, a case of
champagne was almost lost overboard. We had to run backward for a mile
and a-half to disengage Fuzzie’s hair from the machinery. Fuzzie has been
reduced.”
“Spike’s interest in the war has grown to be a matter of serious
inconvenience to all on board. He has literally covered the yacht with
Military
and
Naval
cartoons.
The boat will certainly have to be re-painted. This morning he came on deck
with a drawing he did sometime during the night, which represents Uncle Sam
admonishing Spain to stop kicking the “yaller dorg”—Cuba. It’s not half bad,
but his claim of it’s being the best yet made on the war is a little strong. He
has been so busy admiring it all day he has not thought to make any others—
and we have had time to breathe.”
“We
came
to
anchor
this evening near the wreck of the “Two Sisters,” in the vicinity of which—on
the shore—was situated a dog-pound, containing some two hundred canines
awaiting execution.... We enjoyed a night of delightful rest.”
“The Skipper went out on his bicycle gig to take a survey of the harbor, but the
roadway was running so high he found it difficult to make any headway,
and had to return to the yacht.”
“Curly has been pronounced unfit for the duties of an able-bodied seaman,
and has been handed over to the Duke for treatment. It is suspected he is
afflicted with some curious, and hitherto unknown, form of love. Yesterday the
Duke administered a very carefully prepared shrimp salad, but it failed utterly
to bring about the desired results. He’s still very pensive, and seems to wish to
be alone. Grave symptoms indeed. Ever since our last visit ashore, when he
was seen walking through the fields with a tall, willowy creature of undeniable
attractiveness, he has been very dejected and apathetic.
We shall
try
keel-hauling
as a
last resort,
—but trust it will not be necessary.”
“The last glimpse of the glorious old Bay, and the last day afloat. The cruise
has been one of continuous delight, but we can not but regret the end has
come, and we must tread the bricks of uninteresting streets instead of the
swaying deck of the Rita. But, as Bill Weatherbones would say, “Wot’s de
use? Man aint born to be happy,
—an’
dats
straight.”
THE END