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CBSE

Chapter Wise Weightage of chemistry CBSE Class 12


CBSE-2019

At 300 K, 36 g of glucose present per litre in its solution has an


osmotic pressure of 4.98 bar. If the osmotic pressure of the
solution is 1.58 bar at the same temperature, what would be its
concentration?
Section C 3 Marks
CBSE-2019

At 300 K, 36 g of glucose present per litre in its solution has an


osmotic pressure of 4.98 bar. If the osmotic pressure of the
solution is 1.58 bar at the same temperature, what would be its
concentration?
Section C 3 Marks
CBSE-2019

At 300 K, 36 g of glucose present per litre in its solution has an


osmotic pressure of 4.98 bar. If the osmotic pressure of the
solution is 1.58 bar at the same temperature, what would be its
concentration?
Section C 3 Marks
Solution:
CBSE-2018

Calculate the freezing point of a solution containing 60g of


glucose (Molar mass = 180 g Mol-1) in 250 g of water.
(kf of water = 1.86 K kg mol-1)
Section C 3 Marks
CBSE-2018

Calculate the freezing point of a solution containing 60g of


glucose (Molar mass = 180 g Mol-1) in 250 g of water.
(kf of water = 1.86 K kg mol-1)
Section C 3 Marks
CBSE-2018

Calculate the freezing point of a solution containing 60g of


glucose (Molar mass = 180 g Mol-1) in 250 g of water.
(kf of water = 1.86 K kg mol-1)
Section C 3 Marks
Solution:
Delhi 2019, CBSE-2019,

Section C 3 Marks
Delhi 2019, CBSE-2019,

Section C 3 Marks
Delhi 2019, CBSE-2019,

Section C 3 Marks
Solution:
Case Study

Liquid-liquid solutions can be classified into ideal and non-ideal


solutions on the basis of Raoult's law. The solutions which
obey Raoult's law over the entire range of concentration are
known as ideal solutions. The ideal solutions have two other
important properties. The enthalpy of mixing of the pure
components to form the solution is zero and the volume of
mixing is also zero.

When a solution does not obey Raoult's law over the entire
range of concentration, then it is called non-ideal solution. The
vapour pressure of such a solution is either higher or lower
than that predicted by Raoult's law.
Section D 4 Marks
Which of the following statement(s) is/are true for an ideal
solution?

No heat is absorbed or evolved when the


A components are mixed

Volume of solution = sum of volume of two


B component

Intermolecular attraction forces between A-A and B-


C B are equal to A-B

D All of the above


Which of the following statement(s) is/are true for an ideal
solution?
Which of the following statement(s) is/are true for an ideal
solution?

No heat is absorbed or evolved when the


A components are mixed

Volume of solution = sum of volume of two


B component

Intermolecular attraction forces between A-A and B-


C B are equal to A-B

D All of the above


I. n-hexane + n-heptane
II. acetone + ethanol
III. bromoethane + chloroethane
IV. benzene + toluene
Which of the following combination is an example of ideal
solutions?

A I, II, III

B III, IV, I

C II, III, IV

D IV, I, II
I. n-hexane + n-heptane
II. acetone + ethanol
III. bromoethane + chloroethane
IV. benzene + toluene
Which of the following combination is an example of ideal
solutions?

A I, II, III

B III, IV, I

C II, III, IV

D IV, I, II
Addition of carbon disulphide to acetone, dipolar interactions
between solute-solvent are ....A.... than interactions among
solute-solute and solvent-solvent molecule. Here, A refers to

A Larger

B Same

C Weaker

D None of these
Addition of carbon disulphide to acetone, dipolar interactions
between solute-solvent are ....A.... than interactions among
solute-solute and solvent-solvent molecule. Here, A refers to
Addition of carbon disulphide to acetone, dipolar interactions
between solute-solvent are ....A.... than interactions among
solute-solute and solvent-solvent molecule. Here, A refers to
Addition of carbon disulphide to acetone, dipolar interactions
between solute-solvent are ....A.... than interactions among
solute-solute and solvent-solvent molecule. Here, A refers to
Addition of carbon disulphide to acetone, dipolar interactions
between solute-solvent are ....A.... than interactions among
solute-solute and solvent-solvent molecule. Here, A refers to

A Larger

B Same

C Weaker

D None of these
Assertion (A) : Osmotic Pressure is a colligative property.
Reason (R) : Osmotic pressure is directly proportional to molarity

Both Assertion (A) and Reason (R) are true and Reason
A
(R) is the correct explanation of the Assertion (A)
Both Assertion (A) and Reason (R) are true, but Reason
B
(R) is not the correct explanation of the Assertion (A)

C Assertion (A) is true and Reason (R) is false

D Assertion (A) is false and Reason (R) is true


Section A 1 Marks
Assertion (A) : Osmotic Pressure is a colligative property.
Reason (R) : Osmotic pressure is directly proportional to molarity
Assertion (A) : Osmotic Pressure is a colligative property.
Reason (R) : Osmotic pressure is directly proportional to molarity
Assertion (A) : Osmotic Pressure is a colligative property.
Reason (R) : Osmotic pressure is directly proportional to molarity
Assertion (A) : Osmotic Pressure is a colligative property.
Reason (R) : Osmotic pressure is directly proportional to molarity

Both Assertion (A) and Reason (R) are true and Reason
A
(R) is the correct explanation of the Assertion (A)
Both Assertion (A) and Reason (R) are true, but Reason
B
(R) is not the correct explanation of the Assertion (A)

C Assertion (A) is true and Reason (R) is false

D Assertion (A) is false and Reason (R) is true


Solution:
Both assertion (A) and Reason (R) are correct statements, and
Reason (R) is the correct explanation of the Assertion (A).

Colligative property depends on the no. of solute particles


irrespective of their nature relative to the total no. of particles
present in the solution.

Osmotic pressure depends upon the no. of particle of solute,


i.e., molarity of solute.

Hence osmotic pressure is a colligative property.


CBSE-2016

Section B 2 Marks
CBSE-2016

Section B 2 Marks
CBSE-2016

Section B 2 Marks
Solution:
2 M glucose has a higher boiling point than 1 M of glucose.

Since on increasing the no of moles of solute the molality also


increases which is directly proportional to an elevation in boiling
point.

Thus, the boiling point of the 2M of glucose will be greater than


1M glucose.
CBSE-2020

A solution contains 5.85 g NaCl (Molar mass = 58.5 g mol-?)


per litre of solution. It has an osmotic pressure of 4.75 atm at
27°C. Calculate the degree of dissociation of NaCl in this
solution. (Given : R = 0.082 L atm K-1 mol-1) itd
Section C 3 Marks
CBSE-2016

Section B 2 Marks
CBSE-2016

Section B 2 Marks
Solution:
Solution:
Assertion (A): When the divers come towards surface their
capillaries get block, which is painful and dangerous to life.
Reason (R): There is release of the dissolved gases as the
pressure decreases and leads to the formation of bubbles of
nitrogen in the blood.
Section A 1 Marks

A Both A and R are correct; R is the correct explanation of A

B Both A and R correct; R is not the correct explanation of A

C A is correct; R is incorrect

D R is correct; A is incorrect
Assertion (A): When the divers come towards surface their
capillaries get block, which is painful and dangerous to life.
Reason (R): There is release of the dissolved gases as the
pressure decreases and leads to the formation of bubbles of
nitrogen in the blood.
Section A 1 Marks
Assertion (A): When the divers come towards surface their
capillaries get block, which is painful and dangerous to life.
Reason (R): There is release of the dissolved gases as the
pressure decreases and leads to the formation of bubbles of
nitrogen in the blood.
Section A 1 Marks
Assertion (A): When the divers come towards surface their
capillaries get block, which is painful and dangerous to life.
Reason (R): There is release of the dissolved gases as the
pressure decreases and leads to the formation of bubbles of
nitrogen in the blood.
Section A 1 Marks
Assertion (A): When the divers come towards surface their
capillaries get block, which is painful and dangerous to life.
Reason (R): There is release of the dissolved gases as the
pressure decreases and leads to the formation of bubbles of
nitrogen in the blood.

A Both A and R are correct; R is the correct explanation of A

B Both A and R correct; R is not the correct explanation of A

C A is correct; R is incorrect

D R is correct; A is incorrect
Section C 3 Marks
NCERT Exemplar

Among the following, the aqueous solution with the highest


boiling point is:
Section A 1 Marks

A 1.0 M NaOH

B 1.0M Na2SO4

C 1.0M NH4NO3

D 1.0 M KNO3
Section C 3 Marks
NCERT Exemplar

Among the following, the aqueous solution with the highest


boiling point is:
Section A 1 Marks
Section C 3 Marks
NCERT Exemplar

Among the following, the aqueous solution with the highest


boiling point is:
Section A 1 Marks
Section C 3 Marks
NCERT Exemplar

Among the following, the aqueous solution with the highest


boiling point is:
Section A 1 Marks
NCERT Exemplar

Among the following, the aqueous solution with the highest


boiling point is:

A 1.0 M NaOH

B 1.0M Na2SO4

C 1.0M NH4NO3

D 1.0 M KNO3
Solution:
CBSE 2014

Calculate the boiling point elevation for a solution prepared by


adding 10 g of CaCl, to 200 g of water. (K, for water = 0.512 K
kg mol-, molar mass of CaCl2 = 111 g mol-).
Section B 2 Marks
CBSE 2014

Calculate the boiling point elevation for a solution prepared by


adding 10 g of CaCl2, to 200 g of water. (K, for water = 0.512 K
kg mol-, molar mass of CaCl2 = 111 g mol-).
Section B 2 Marks
CBSE 2014

Calculate the boiling point elevation for a solution prepared by


adding 10 g of CaCl, to 200 g of water. (K, for water = 0.512 K
kg mol-, molar mass of CaCl2 = 111 g mol-).
Section B 2 Marks
Solution:

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