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Organic Chemistry Marathon Full Notes
Organic Chemistry Marathon Full Notes
Alkanes
Alkenes
AKOOK
CA
Alkanes .
Methane
-
/ -
H
#
L
Hydrocarbons
.
saturated -
I
/ compands having
compounds having carson in Hydrogen
carbon-carbon
atoms
bonds
single
1OWLY)
-
ON
suffix IUPAL
prefix-
.
/ -
I
pentag on
I Jians -
.
all
auf V
auf
.
octagon
and
IT als ave
anc
aus
a
meth
are
auf
ass
Ethane
pent and
~ Alkanc
B
Ethan
auf
methane ,
<
66 Alkane
↓ -
Alkane
Hexand ↓
↳ a
Draw
h
-
he / hie = uponds
-
17
Ethane
T Taikan
/Latons
.
↓ / & M
-C Saturated mydrocarsons
.
H I
V I 1
c -
C
u -
L -
H
H
-I I
9
Displayed formulae
-
1H H
CHU
Displayed For walke
.
a -
M F .
Alkams
.
10
.
11
H
-
Number
The & type of
I
H => ch different atoms in
"
Methaul H L
-- onemolecule .
H
I
-
&
Ete
H
Ethaul
Hacke
propane
but all H H H
-C z Cete
I I
H
pentance H - L -
-
#It
,
nex all
-
- - Heyzate/atto
I
L -
-
=
-
ChyyyeH
I I
-
I
- 2 -
L -
L
-
-
,
& ,
Catchy
I I , 1 ,
C C
-
-
--
Ttin
I-
structural formula
I F
6 F
.
>
cheChyCheche
-
Molecular Formula
.
T ↓ ↓ ↓ -
-4 4 4
-
-
pentance
Ches CheechyHe
- - - - -
↓ ↓ ↓
--
- -
-
-
L I
# H No .
atoms ONLY
11
u
-
- L - Hydrocarson
I
H
!t - Not saturated
-
.
Chu
Exte >
-
inten + 2
s
Cuttio
Us Hij
"
50 #25th announ
Fatue
.
Ye
,
btw an
a
kno
it does not fit the GF of allows
No , be
,
i
.e
.
cultente
+60 .
=ottyz
/Set set za+ z
.
Alkana-He
Name
Displayed
6.
M .
G F .
.
- -
case increases a
decrease
CH6
CHS i
Cuttio
"
↳ Hiz I
Resistance to flow
Hil
-
(4) -
-
paint volatility
a viscosity
.
Boxing
-
-
decreases . increases
-
chemical reactions
.
-
L -
/ v =
⑭ D
① combustion
Reaction v
substitution
②
⑪ wacking/pyrolysis
.
12 , PNy 1 Fy
Sabatitation
Reaction .
-> X
Alkanes + Halogens
light
> V
sullizkan
.
+
Alkanes Halogens
! ultra voilet
Light
Fa :
Minencollisions
Reaction
photochemical
-
·
Halogenoalames
Elk s
O right
. -
-- H
H
substitution
monosules
-
.
& H
I
Hydrogen
chlorida
-
.
H L + a -
-
1
-
light
> H-
-
O
I + H -4
- I
G
I
H oth + 1 > -
CHyC + H1H
chlorin v
methan Chloromethane
m
-
O
C
I
H-
c -
a + c - d - +
- -
c -
⑪+ H -
1
~
I I -
> Chedly dichoromethane
H chycl + My -
+ HC
C
O
1 > H
- k H + H-
1 a-1 - - -
H - -
+
↑
&
↓ -Trichlorometha
chec + 12 >
CAC
+ Hd
-
- C
x -y
I - H - H + H
-
4
H--- O +
- I
C
14 + H
cAdy +
1 >
-
/
.
methane
Tetrachloro
-
uv right
-
-
+ Kary >
-
11
>
- EH5Pr + HE
CHO + By
F
6 times
- The
① combustion
-
↓ Any fuel -
barns in excess
-
of to give or
-
too an large
-
amounts .
energy of
~
Balc
Bal H
Ha
Bal O > 12
+
-
Alkams + 02
4
2xn
=
= 4
-2xx
cu + 202 > - CO2 +2He O
=6
2xa = 7 2xa
2[EH
~
> 2002 1 + 320]
Ye
x=
-
+
-
2xa
-
2xa = 10 ~
~ n =4
-2xx
24 +
Pe
> =-14/y 4002 + 5↳
/
z0 J
2xx = 10
a =
5
2xn = 27
- z
=
11
+ 11 %
> 1002 + 8420
H
-
2
Incomplete combustion
.
&
-
surns in
which
limited by
Any fuel
small amounts
to giveco in to in
of
.
energy
limited
-
+ Hy0
cha + of -
xx2 = 5
-
3Hy0]
2 to +
He +
200
+ He
EgHg + 02 >
-
02 > 1 + 20
H,0 + -
soz
-
-
- r-r-r
1-1 - -
C
-
-
-
-
2 -
- c -
(PAH
soot (C) /unburnt HC , particulates
,
wacking
-
alkane .
HC are broken
less useful saturated
when larger -
↑ temp (1550X
↑ pressure 11 Goatm)X
zolite/won)·
Catalyst (Aeon 1
Absence Of
cracking
-
T2H26
Alon
Temp
↑ prese
% ot22 + O
sure >
-
-
LI
intra >
- St
-
+ -
butene
O
#
inte >
- He + 25th +
-
-
10
propane forms ,
z mous of
th
ethene
↓
pentere
Exy
banproduct
-
L th
-
one or -
Cyto >
-
# +
E
> Goo +
g)
Gottee
-
in armand
more useful
Smarter chain
He are
①
⑦ provides a source of y
③ provides a source of gasonu/petrol. (tsis)
.
making plastics /polymers)
① provides feedstock
for
Im
-
I-
exene.
Ma
hydrocarbona
.
unsaturated
/ cat atoms
at least one ONLY
carbon-carbon boud
which is not a
single
Lond
#
Alkene
ene
ent
prefix ene
eve
ene
81 Octene .
-
ene
eve
eul
we
musat
- US
7
T1I
etent
1-
T
-
-H Buteue It
-
H H .
displayed #
H
11
I
↑
(c HEHH
I
L H
CHzcHy
=
V -
- -
c -
S
I I
# H
↓
in I
cute
litt
y
methene-uns
He
propense
-
HHH
I I I
etwent
+m +
4
H 2 =a - -
- -
H
=CHUHe
CH =
CHCAM .
↓
HH 4
!- E
- C H
-
I
H
H
tomore
Ethe
YuHg
How Alkenes
cracking
of alames T
studied bore).
-
-
H H
11
11 =L
-
-
- -
u
T
Hy
11 # #
446 Hz
>
-
Elte +
-
O
Akanes
tracking
↑ Temp
↑ pres
> Alkenes
.
Aloe
No
-
,
oxygen
chemical Reactions
Alkenes .
L
> Brea C
-
=1 -
Reaction
① Addition
② combustion v
(end).
③ polyneration
.
combustion
-
c
-2xa
=
x 2
2Hy
=
-> 2002 +
EH + 302
[I
Bal
2[ta + * 2 >
-
3002
1
+zitza 7
I
2xn = A
n =
1/2
-
2xn = 4
- n =2
Eth +2 >
-
200 + yo
/
2xa =6
a= 1 -
Forly ↑
one product
formed 3
is
E6
u
Addition reaction
(Hydrogenation)
,
Addition ty
① He/g)
Atten
of ·
H H Alkene
2009
2008
↑ weat
1100
-
H
I
H
1
-
S 1 H
Nick) H
H - L- L
-
H H H
-
+
- -
↓
c L
-
-
-
- (150am)
~
-
-
emeneHy -
ethane
Nich
Exc +
Hy 2007 Ete
wat 200 # H H&
-k
I
I
-
+ H - H Mi(s)
>
-
. - c -
I
c -
c
-
C - It
&
-
-
I
-
N
I
-
I #
I Hi
If
&
>
Cutto
-
cutte + He
kina oil
cumsat).
Halogenation
② Addition of Halogens -
[Foom]
-
# H H
' H
Hi 4 -H
1
-
= C -H + 1 -
>
-
C -
C
H -
-
- I'a
12
-
12th +
W
/
[water Hagmankams
Bromine
-
k *
--- -
I I
2 c L
-
+ Em
-
c G1 = c -
L
- -
law)
-
I
-↓
&
cute >
- Cuttstrz
+
By >
- Colourless
.
orange
Era
decolonise
F
* -
(1)
- 12
↓
Traumat
Addition
[nania]
.
Braint L
-
- Cly
Hydro Halogenation
HC
Hydrogen
- I
adition
⑪ -
11
-
-- 44
L Halakene
-th >
+ Ha- EH5C -
↳ orange >/Remans -
.
Haloalkans
+Pay can) -
>
Alkent .
Hydration
.
Note :
-
g1]
bends
of steam (He/
⑪ Addition show all
.
-
.
H H
HH
x+-
k H
'
-
H-
-
H- -H +
1
=
Snoo
~ -- O
It
-h +
+2019) toou
alcohol .
phosphoric acia]
[acidified acuous -
-
2
Alkanes
Absence O2 ,
earlie
substituent grtp wil 420/91 .
T
pi Go atm
It
:
-
HerOn/Atcaul
He
L 000*
V
Haloalkanes
-
latmosphere-lookba
00 -N
Alcohol .
6000
-
N =
. I
-
displayed
, 11
H
***
I H > - 1 -
x
+ H - H
-
c
- -
= c -
C- u
-
-
I
I
I
-
-
I
-
L
&Ho
cute +
Heg > 9
.
-
r 1
-
alconol .
-
/
· soren
inegar
-
-
. >
volatile -
gues,
-
Accou
j
sat componen ,
Shydroxy, group]
↓
namienefa. -
CH
H
Che oh
k
oct
methane of
H -
-
Eman of
H H
CHeHzH
4
H
k -
-
o -
H
H
↳ Hy ON
-
Butane of
I
*
popanyo
H HH
it
-y k o H
-
- -
c -
c
#
Huta
↳ H
H
-
I
c
111
-
↑
-
H
I
- o - H
ChyCHyChyCHO
H
#
atachycityof
/
CHyH
# off it # HH
111 11 I
H Ac
-
l -
1 -
ok
H -c
-
-
-
111
HHH ↓
↓ CHeCHeCHyOH
CHACH(OH) M
# c c
- -
-
ok
H c - -
-
I I
CHOH I
In H H
H
CH5OH
-
G F
-
.
CHyH
YukaOH
Intentio
15 H1 of
Alcohol -
19C
"Hea of
① Add .
Ex Akes .
(Hydration).
-
etuantol.
& 200
Gu T Els oH
+
Hey & He HYaw)
-
↓ bath .
↓
exene
[00 KPA] ethano
ail
ac ,
cuts
>
-
Sutto-
+
g
C =-1
11-
- t + Hot-kick I I
-
I 11
&
② Fermentation
-
(of quose)
Yeast
>
grape-- water -
>
↓
ethanok bury E
airtight
[10-15days]
> yeast etuarol + carsundiaxim
-
gurse ,as 256
& denatured
25-45 %
-
- -
yeast + Z Co2
2CH50H
pa
>
setting sam
-
(1) (g) .
&
-
Absence of
Oz
↓
[Respires AnaerobicallyJ1
dil. sol
*
I 15) .
-
(6) -
① Asence of of
Ho + 2
place
to give
termutation takes
⑤
⑧ > EH5OH +
1219)
Chican- (1)
Fractional distillation obtain ↑ etwand.
⑦ to a conc
.
L
Bata
process - Shower vs -
mydration
Disadv
Fermentation Adv
-
process .
Resources process
Eguse zenmabe]
·
is
Fable
Fontimos process] -
source
② reading
chemical reactions
of Monda
.
/
① combustion v
v
⑦ oxidation
⑪ esterification ICA .
2xx = 1
-
-- n = My
I
+attyc
If
> - 12
che + 0
↳ 'T0'
2xa = 4
CHE of -
thot
->
- 2002 thyo 7
2xx = 4 -
101
- ~ + htzo
+h > 300-
o
resty-
-
acidified aqueous potassium Manganate (i).
3
.
oxidation .
carboxylic acid
vinegar
- .
H
H Example Tolowi -
I I kMnOu/At CAN) I
of H-c -c
=
0
H Ho
C
[O] f
-
wat
-
-
-
↳
I
In I ot
H
H
j
H Emaniaa
X
H
I
H
I
& .
2ea] H
250] >
I
H- c -
- -
H + -
H - - - 10 + Hy
H
I
it I ot
Acids
carboxylic
-
.
· + 123181772015 fri
know
0 + 923355694666-Sulaiman
·
Scarboxylchem
.
↓
#ST
1 : 00 AM
Alcohol .
② oxidation carboxylic //
arids -
H H
kMnOu/g -
-
11 H
H c -
oh 2(0)>
I
+ Hy
2
+
-
c
-
- -u
=
a
H
-
-
1 I weat
- O 11
H H # of
H
examp &
etampic
H
acid
-
H
I
+
I
4
o
H
201 Hz0
-
+ > +
- -
-
-
It
I
H #
propaneof #
H
-
c
-
I
-
I
-
-
0
I
I OH
H H
H
↳
"
Lactobacter
.
bacteria
Loz
oxysm in the air
3
bacteria uses the
[
The acctobacter
vinegar
.
H H
# I
&
1 -
1
I
-o
+ 20 >H
-
-
- -
-a
-
- #
20
H- I I
I
I H H OH
H
H
Acids
carboxylic .
acids
#you, ANO
weak organic .
-
,
L
-
ionises in (a) sol
partially
4
41-
chacoocan- citycoo At
--
I I drogen ion .
cool)
emanate
↳ ion
-
Aikant of
① metancois and
metant of
Aland oir
methaneoir
acid
acid
I ② enant ana
⑪ Butau oic
a
acid .
pentanoic
.
acc
⑤ -
Draw
.
O
- v
Fat
H -
-
ot
-
① methanoic acid -
I
>
② Ethanoic acid
-
H H O
⑪ propanoic
acid > -
# -
-kid-oh
acd i i
④ Butanoic -
>
⑤ pentanoic
acid -C-
I"-ot -
11
↓ 111
O
-oh
-c
c -c
-
- c -
I
111
ethanoate -
oxiation .
H O
I Il
↓
-
0
-
c
H
- L -
I
etand H
H
# O
H H
Ill
H - k-d -
an + 20 >
-
H - 1 - -of +H
S
11
H
H H
paltanol anoic
Balt
acid
!
O
I
11/
D F .
4I F
M . .
O
↓
-
↓
" ot # cool
H # cool >
-
-
-
-
-
-
-
-
! ou Chycook
--
>
-
My
"I
--- or
He o - Ets
10
c
Il
krk -k
I
- c - ot
H
tentH)
I A F -
1
>
-
carboxylic
-
.
acid I cool
IC
i'c'c A .
EHy col
-
1-
carboxyla
① Etazense
-
⑦ esterification -
.
① metal + Ad >
- sal + Hy
H
mg + 2 cook >
-
(*
coolymg +
-
I ziecor-Xmq
+
/ate'
S
etamox-
.
acid
ethanoate
salt water
② Aud + Metal
Hydroxide >
- +
↓ ↓
HCOOH + Nao-
> HoN + Hy
↓ ↓
Nalt
#cop
+
metal carbonate > salt-water
-
↓
2CHCOOH + >
Naycor- H + 12
↓ ↓
ICACOG I NA
It
sodium emano
Sodium
water +
etanoic t sodium >
- etanate +
carson dioxide
acid carbonate .
-
+He
Ichcool +
mgo
>
-
(Heng
↓
200x mgt
↓
H
24
I -
H - L
-
mg
I
estrification .
conc HesOucan)
.
ester
Anon-
carboxylic
Hi
+
wat 200
-
"Food 11
fa
y sente
Eropy
↑
-
atte
etanoic and -
+ propanol -
>
-
+ water
Heat 200
cor. Hy sou
# O
I Il
111
c 1 -
of
-
O L H
-
H
- -
- C - L
11
I
CHeCOOCHaCycH
↓ ↓
.
exanoate propyl
propyl
emanate
etuart of A
ethanoic acid as -
O I
I
I
-10-10-
Il
CHACOOCHCHes
-
1
-
↓
I
ethanoate
etryl
-
methanoic acid ethanol OH H
- T
O
COOHeche
H - L
"-I-L!
- D
- H
metrarcate
ethyl
mo .
+ move-large
small
.
macue
Butanoic acid propanol
-
-
O
111
L 1 -i - 1 - (
Hockeye
-
-
p - c -
- -
111
/
I I
&
este linkage OH H
.
Butarate
propyl -
-----
11
Butaneate
etayl
O
111
-
-
- - c p
(
- -
2 - r - 1
-
-
-
111I
petyl propanoate
CHCHzCHeCHOCOLACAM .
-
&
I
Il
2
!
-
-n -L -c
-
- c
-
o -
#Hete
1
I I
etryl Butate
CHHCHOCOLA
D
I
Il
I +o ---
-
I I I
L - -
-
↓
11
I ethanate
But Y
Homologous seric 7
Advanced Navy
ISOENC
-
Homologous series
T
-
-
same teatures
- family .
with the :
A family of compones
L an atom
send
,
or a
responsible
group atoms
for the
,
or a
chemical properties
specific
Axanes X
-
of a
family (tomo 3). .
1
Alkenes' =
Alcohols : - of (hydroxyl)
1A :
-cooH (carboxyl)
Haloalkanes : -X
chemical Reactions
③
Similar
a
Alcohol
Acac
]
Cho Che
Jatz Et offJatz y
-a
↳
che I Butane
-
L - - -
- -
-
11
I
I select the
O
Alkanes Advanced Naving longest
unbroken
&
.
ce
-
-
'c'chain
- -
,
11 112 I4
Butane we
② an
start
- - - u - 1 -
L -
( I 11
VI - -+] 5 is the
-
.
closest
lower 3
.
itf
I
propane
propor
L to
u --
2-methyl
-
-
I
L I
1-
I
I - -
-
-
1
ethane
-
H
C ethane
-
- methane
Butaut
Che of
1111 I I I I
c 1 u - c
-
c
-
I
------
-
-
0
-
- - - -
11 I
I I 11 S
Butent
uz
1
Alkane .
Alkes, Alcohol/
, Halaicanes
① = Chty
-
-
= c -
2 13 14 He =
unbroken's chain
-
Baut -
ens
w/'f g
⑪ nu ② start where
- L
1- c
- -
I
-
c I M -
I z 1
n I =c L
-
-
I I -
U I
↓
↓ But-2-ene
CHCH = CACHes 2-methyl prop-l-ene
① I
i 320
1 = 1
u u
-
c =c
-
prop-1-enc prop-l-ene
Alcohol .
Not -
o ,
10I 12 in
----- (
- - c
O C
11214
-
u
- -
I 11 11
propan-1-o) propane-ol
Buttan-1-01 .
Butan-2-ol
Q Ot
o
1111
① I & I
I
1 -c -c
- 7
-
CCHyMeH
-
- --L
-
c
11
-
-
↓
,
↓ ,↓
I
T
I
U c
-
L
-
-
C -
c -
111
ci CHICH(OH) Chychr
11 212
-
c -c -
C
propan
-
↑chloro
d
I
4
I
2-chloro propane
4-4
-
-
structural isomers
compounds wy the
&
same M
-
-
F but diff structural
Forumla ↓
↓ diff Names .
cuts
-
,
-
Cuts cults
11
11
I 111 -
u=
-6
-
-
oc -1 -2 I
-
~
I I
.
Bot-2-ene
Balt-l-ene
Cuts C5H
I
I I I I 1111
--
c= c
-c
- c
-
c = c -
c -
- -
I 1
I 1
12 U 4221
V= L
cc
-
L
-
C = c -c
-
Palt-lene
But-1-eve
/
chain
Isomers
Acana) ↓
[
- = -It
No
1 - E 2 2
-
p
Cuts
But-I-eve Bout-2-eve
2 -
Methyl prop-1-ene
c= c
-
C
c
-
c
-
C
u= c -
I-u
Thes,
-v =
↓
O
-
11
-
-
-
C
Il _ c
-
L
I
C-
I I H I I
H, 0 +60
C
1121h - c
11 12
-
Hi
- -
L
i
-
r -1 ---
-
I
I S
I I
1-chloropropane 2-chloropropane
Alcohol
[
↑ * I
i o i
i I
40 -
-
L
Ho-TT
c - -
-
.
CH, 0 60
Bentzare) propainto
,
Beut-1-en
polymerisation .
unit
small unit+ small unit + small int > large
-
↓ Ismall molecules). ↓
monomer + Monour + monou > Polymer
-
- -
many
large modules formed
run
polymers :
(monomers) join .
together
-
small molecules
↓
Macromolecules
.
Raynes
/ Yonausation
Addition
.
-
-
~ Alas
.
paymisation
:
Addition I
monomers must have
- = wond
.
m
polyeture X
.
NemP
[zeigu at
fritt
-
I
with
3
Repea
sma eve fit
moron
2 Repeat units
Raychloroethane
-I -
-
I-
Polychloroethane
n( ) >
-
fi
poly tetrafluoro eune
#I I
c
-
L -
c
-
L
-
F F
c -
-
C
I I
↑ F
above or below the
.
opene
poly
)
#
I N
H
( I'
- -
1 If I -
H -
"He ive
- L
- I
-Am
H -
polybut-2-ene
.
- H
H H
H
111
H
I -
1
↓u
-
1=
polybut-rene
#
-
- 11
/
-
HH is -
5 But-2-eve
tuent
I
film
.
Eacteria/decayed by
↳ chemically unreactive (c-c)
↳ No active
-
site [bacteria
wond
.
cannot]
↓ sites
① disposal in landfill
raying
[collect ,
separated , melted -
Te
products
newJ
[
*
J
.
bacteria
Degradable
starch- Sagradable
↳ additives - >
light
polycturne
- /Addition).
-
① insulator -
food
⑦ unreactive-store
.
③ righter to
carry
.
condensation
- to form a
in which React
monomers together
and another
.
small molecule
polymer
/ - -man-made
con
synthetic Natural ~
v ~
Terylene (PET) rates , X starch protein
.
Nylon
,
,
-
synthetic
Hookh) y cook
Nylon (66)
-
dicarboxylicacia diamine
-
-
O v
I
a
I
↓
Ho-k -/
ij I
An! "
CCC)- -
,
-
OH (21
wit
I Repeat
-
O
& H H
O I -
1 N
Il -
(polypeptide
-
synthetic
-
- -
c
/
polyamide
-
.
Nylon >
-
--
-
CON
amisde
Fabric
clothing , ,
of
pope
Ho-
-
Fishing nets
- H
kage at
,
-
/-
/
Ho
- ou Y
X Hydrolysis
.
wr -air] -
H-NB
-
.
2 Terylene
dic A.
O
did
H
OH
! 0
Ho-H
-
-
Lester
· -
-
" um
D -
-
polyesters
,
bed liven
.
water bottles ,
clothing ,
Natural
jerotin >
Amino Acida-
monomers :
Amino
acids +
-reset side
-OH
crains
H
H = oH
⑧I
O
Il -
- N -D -
-N--l
I amide linkage
Nat polyamides
Prof :
·
"
Ny66 syn
.
FatSpayets] Natural
Teryuney
starch -
- starch
gurose surose
--B-0-0- H Ho
Ho
H
con Addition
.
.
cond Add
↓
Addition tel
-
conden #X .
an eraa
by product
-
retro-chain homochain
at
are
Mon similar
was-donbesond
or
twodify
at least a .
g +
iii'
-
- c
- 1 ~
L
-
-
I
A-A-A-A
-
/
"
A-B-A-B -
↓ ---
-
- H
>
19)
(4)