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Biomass Energy with Carbon Capture and Storage (BECCS)
Biomass Energy with Carbon Capture
and Storage (BECCS)
Edited by
Clair Gough
University of Manchester, UK
Patricia Thornley
University of Manchester, UK
Sarah Mander
University of Manchester, UK
Naomi Vaughan
University of East Anglia, Norwich, UK
Amanda Lea-Langton
University of Manchester, UK
This edition first published 2018
© 2018 John Wiley & Sons Ltd
All rights reserved. No part of this publication may be reproduced, stored in a retrieval system, or transmitted, in any
form or by any means, electronic, mechanical, photocopying, recording or otherwise, except as permitted by law. Advice
on how to obtain permission to reuse material from this title is available at http://www.wiley.com/go/permissions.
The right of Clair Gough, Patricia Thornley, Sarah Mander, Naomi Vaughan and Amanda Lea-Langton to be identified as
the author(s) of the editorial material in this work has been asserted in accordance with law.
Registered Office(s)
John Wiley & Sons, Inc., 111 River Street, Hoboken, NJ 07030, USA
John Wiley & Sons Ltd, The Atrium, Southern Gate, Chichester, West Sussex, PO19 8SQ, UK
Editorial Office
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Wiley also publishes its books in a variety of electronic formats and by print-on-demand. Some content that appears in
standard print versions of this book may not be available in other formats.
10 9 8 7 6 5 4 3 2 1
v
Contents
4 Pre‐combustion Technologies 67
Amanda Lea‐Langton and Gordon Andrews
4.1 Introduction 67
4.2 The Integrated Gasification Combined Cycle (IGCC) 68
4.3 Gasification of Solid Fuels 69
4.4 Carbon Dioxide Separation Technologies 76
4.4.1 Physical Absorption 76
4.4.2 Adsorption Processes 77
4.4.3 Clathrate Hydrates 77
4.4.4 Membrane Technologies 77
4.4.5 Cryogenic Separation 78
4.4.6 Post‐combustion Chilled Ammonia 78
4.5 Chemical Looping Processes 78
4.6 Existing Schemes 79
4.7 Modelling of IGCC Plant Thermal Efficiency With and Without
Pre‐combustion CCS 80
4.8 Summary and Research Challenges 85
References 87
Index 291
xiii
List of Contributors
Naomi Vaughan
School of Environmental Sciences
University of East Anglia
Norwich
UK
xvii
Foreword
This book is essential reading for anybody interested in understanding the role that
biomass energy with carbon capture and storage (BECCS) can play in the transition to
a low‑carbon economy and the challenge of achieving the targets embedded in the Paris
Agreement. It is the first comprehensive assessment of the technical, scientific, social,
economic, ethical and governance issues associated with BECCS.
There is no doubt that human activities are changing Earth’s climate with adverse
consequences for socio‐economic sectors, ecological systems and human health.
Recognising the danger associated with human‐induced climate change, literally every
government in the world signed the Paris Agreement (the United States has since with‑
drawn from the agreement), which called for the increase in global average temperature
should be held to well below 2 °C above pre‐industrial levels and to pursue efforts to
limit the temperature increase to 1.5 °C above pre‐industrial levels. To realise these tar‑
gets requires a rapid transition to a low‑carbon economy involving unprecedented
global cooperation and dramatic energy‐system transformations, and most models
require global net negative emissions of greenhouse gases in the second half of this
century through the widespread use of BECCS.
Key issues associated with BECCS such as the social and environmental sustainability
of biomass production, sustainability of supply, state of pre‐ and post‐combustion tech‑
nologies, energy penalty due to carbon capture, investment and operating costs, scale
required to deliver global net negative emissions, life‐cycle analyses and accounting
systems for greenhouse gas emissions and governance structures are all critically
assessed in this book.
The analysis suggests that BECCS is a workable technology, but scaling up from the
individual project level to the global scale requires a massive enhancement of the tech‑
nical, biological, logistical, governance and social processes associated with BECCS.
The analysis also suggests that the 1.5 °C target may be impossible to achieve without
BECCS or other negative emissions processes and that without BECCS the carbon price
in 2050 to achieve the 2 °C target could be doubled to about 300$/tCO2. Unfortunately,
current uncertainties in technology development, enabling frameworks and policy
development restrict quantification of the magnitude of global net negative emissions
that can be delivered by BECCS, and hence its role in limiting human‐induced climate
change.
Given the potential role that BECCS can play in limiting the magnitude of human‐
induced climate change, it is imperative that governments and the private sector
significantly enhance their research, development and demonstration agendas for this
xviii Foreword
Preface
There is a growing and significant dependence on biomass energy with carbon capture
and storage (BECCS) in future greenhouse gas emission scenarios in global integrated
assessment models, and it has become central to the discourse around achieving a tar-
get of 2 °C global average temperature rise. This reliance on BECCS hinges on its poten-
tial to deliver so‐called negative emissions in order to maintain a sustainable atmospheric
concentration of CO2 cost-effectively. As a young and untested group of technologies,
there are many uncertainties associated with BECCS and there is strong imperative to
understand better the conditions for and consequences of pursuing this group of
technologies. BECCS technologies may offer a role in offsetting hard‐to‐abate sectors
(e.g. agriculture and aviation) or may enable an ‘overshoot’ in reaching cumulative emis-
sions budgets in the context of delayed action on mitigation. However, there is very little
practical experience of implementing the technology in commercial applications and,
indeed, relatively little research into its potential and the conditions for realising its
deployment. This book aims to set out the technical and scientific parameters of deliv-
ering BECCS technologies within the wider social, economic and political context in
which it sits, giving the reader a broad understanding of the key issues and potential
consequences of pursuing BECCS.
To understand BECCS, what it can offer and how it might contribute to climate‐
change mitigation, it is essential to consider the variety of technical and non‐technical
constraints in a joined‐up manner. Bringing together modern biomass energy systems
with CCS not only presents technical and scientific challenges but also, to be delivered
at scales large enough to contribute to substantive negative emissions, depends on other
factors, such as geopolitics and supply chain integration and may have significant impli-
cations at a societal level. This book brings the issues together in a clear and accessible
way that will support a more informed debate around the potential for this technology
to unlock negative emissions.
xxi
List of Abbreviations/Acronyms
Part I
BECCS Technologies
3
1.1 Introduction
Changes in our climate are driven by human activity such as agriculture, deforestation and
burning coal, oil and gas. The single most significant driver of climate change is the increase
in the greenhouse gas carbon dioxide (CO2) in our atmosphere from the combustion of
fossil fuels. Efforts to limit the impacts of climate change focus on reducing the emissions
of CO2 and other greenhouse gases and adapting to live with the changing climate. In
recent years, a third approach has gained significant attention: action to remove CO2 from
the atmosphere and store the CO2 for long timescales (over hundreds of years). Recent
negotiations under the UN Framework Convention on Climate Change (UNFCCC) deliv-
ered the 2015 Paris Agreement, which set a target of limiting global average temperature
rise to ‘well below 2 °C’ (the 2 °C target having been agreed within the UNFCCC in 2010)
while ‘pursuing efforts to limit the temperature increase to 1.5°C’ (UNFCCC, 2015). These
are ambitious goals that will require immediate and radical emissions reductions if they are
to be met. The idea of introducing ‘negative emissions’ is born out of the gap between the
current trajectory in global emissions and the pathway necessary to avoid dangerous cli-
mate change. The most prominent proposal for achieving such negative emissions is to use
biomass as a feedstock to generate electricity (or produce biofuels or hydrogen), capture
the CO2 during production and store it underground in geological reservoirs – biomass
energy with carbon capture and storage, or BECCS for short. However, the negative emis-
sions concept remains just that, a concept; in principle, technologies such as BECCS can
deliver net CO2 removal at a project scale, or potentially at a global scale sufficient to
impact atmospheric concentrations of CO2 and associated global average temperatures – but
in practice, this potential has yet to be accessed at anything like a global scale. This book
explores the challenges of unlocking negative emissions using BECCS.
Future climate change is most commonly explored using a suite of models that
represent the Earth’s climate system, the physical and socio‐economic impacts of a
changing climate and the greenhouse gases and other drivers generated by the global
Biomass Energy with Carbon Capture and Storage (BECCS): Unlocking Negative Emissions, First Edition.
Edited by Clair Gough, Patricia Thornley, Sarah Mander, Naomi Vaughan and Amanda Lea-Langton.
© 2018 John Wiley & Sons Ltd. Published 2018 by John Wiley & Sons Ltd.
4 Biomass Energy with Carbon Capture and Storage (BECCS)
economy and energy systems. Integrated assessment models (IAMs) are used to create
scenarios of future emissions that are used by climate and impact models. The growing
and significant dependence on BECCS in future emissions scenarios in global IAMs has
placed BECCS at the centre of the discourse around achieving targets of 2 °C global
average temperature rise and, following the 2015 Paris Agreement, 1.5 °C. This reliance
on BECCS hinges on its potential to remove CO2 from the atmosphere in order to
maintain a sustainable atmospheric concentration of CO2 in a cost‐effective manner.
There are many different technical options that could deliver negative emissions via
BECCS and these vary in their technology readiness level (TRL). Some of the closer‐to‐
market BECCS technologies are composed of component parts that have been proven
and tested, but integration and deployment have not yet been demonstrated at com-
mercial scale. Consequently, there remain significant uncertainties associated with
BECCS performance and costs. Understanding the potential for, and implications of,
pursuing BECCS requires an interdisciplinary approach. It has been suggested that
BECCS could play a role in offsetting hard‐to‐abate sectors (e.g. agriculture and avia-
tion) or enable delayed action on mitigation. While the atmospheric concentration of
CO2 continues to rise and policy objectives focus on limiting warming to 1.5 °C, it
becomes increasingly likely that a means of delivering negative emissions will be
required. Whether or not limiting warming to 1.5 °C is feasible without negative emis-
sions remains unclear. In 2018, the IPCC will deliver a special report devoted to under-
standing the emissions pathways and impacts associated with 1.5 °C.
Despite its significance within the formal policy goals, there is very little practical
experience of implementing the technology in commercial applications and limited
research into the practicalities of implementation and conditions for accelerating deploy-
ment. Combining modern biomass energy systems with CCS not only presents technical
and scientific challenges but, to be implemented at scales large enough to deliver global
net negative emissions, also depends on other factors, such as geopolitics and supply‐
chain integration and may have significant societal implications. To understand BECCS,
what it can offer and how it might contribute to climate‐change mitigation, it is essential
to consider the technical and non‐technical constraints in a holistic manner.
This book aims to provide a comprehensive assessment of BECCS, describing the
technology options available and the implications of its future deployment. While there
is a rich literature relating to bioenergy and carbon capture and storage (CCS) sepa-
rately, there is currently very little published research on the integration of these com-
ponents. Our aim is to address this gap, bringing together technical, scientific, social,
economic and governance issues relating to the potential deployment of BECCS as a key
climate‐change mitigation approach. The uniqueness of the book lies in bringing these
subjects together and imposing order on the disparate sources of information. Doing
this in a clear and accessible way will support a more informed debate around the
potential for this technology to deliver deep cuts in emissions.
1.2 Climate‐Change Mitigation
In its Fifth Assessment Report (AR5), the Intergovernmental Panel on Climate
Change (IPCC, 2014) identified four so‐called representative concentration pathways
(RCPs), describing time‐dependent ranges of atmospheric greenhouse gas concentration
Understanding Negative Emissions From BECCS 5
trajectories, emissions and land‐use data between 2005 and 2100 (van Vuuren et al.,
2011). Created by IAMs, each RCP is associated with emissions pathways that result in
atmospheric concentrations correlated with different levels of radiative forcing; these are
RCP2.6 (i.e. a radiative forcing of 2.6 W m−2), RCP4.5, RCP6, RCP8.5 (IPCC, 2014).
Greenhouse gas concentrations within each RCP are associated with a probability of
limiting temperature rise to below certain levels; only the lower concentrations within
RCP2.6 are considered ‘likely’ (i.e. associated with a greater than 66% chance) to limit
global atmospheric temperature rise to below 2 °C, or ‘more unlikely than likely’ (i.e. a
less than 50% chance) for 1.5 °C (IPCC, 2014). The RCPs provide a consistent framework
for analysis in different areas of climate‐change research – for example, by climate mod-
ellers to analyse potential climate impacts associated with the pathways (including pro-
jected global average temperature rise) and in IAMs to explore alternative ways in which
the emissions pathways for each RCP could be achieved (i.e. mitigation scenarios) under
different economic, technological, demographic and policy conditions (IPCC, 2014; van
Vuuren et al., 2011). The shared socio-economic pathways (SSPs) offer a further frame-
work for IAMs to explore alternative emission pathways, by detailing different socioeco-
nomic narratives that are consistent with the RCPs (O’Neill et al., 2017).
Climate‐change mitigation policies are focused around limiting the increase in the
global average temperature as described earlier. Achieving these targets is dependent
on tight limits to cumulative emissions of CO2 (and other greenhouse gases) in order to
stabilise their atmospheric concentration. The cumulative emissions associated with a
particular temperature goal is known as a carbon budget – the remaining budget for a
66% chance of keeping temperatures below a 2 °C increase is 800 Gt CO2 (from 2017)
(Le Quéré et al., 2016). With global emissions currently at about 36 Gt CO2/year, this
equates to about 20 years at current emissions rates before the budget is exceeded; until
emissions are reduced to near zero, atmospheric CO2 concentration will continue to
rise (ibid).
In this context, by offering a route to delivering negative emissions, BECCS appears
to be an attractive approach to potentially enabling mitigation costs to be reduced,
more ambitious targets to become feasible than would otherwise be possible or allow-
ing a delay to the year in which emissions will peak by enabling removal of CO2 from the
atmosphere in the future (Friedlingstein et al., 2011; van Vuuren et al., 2013). Typically,
scenarios that are ‘likely’ to stay within 2 °C include such an overshoot in the concentra-
tion achieved through large‐scale deployment of carbon dioxide removal (CDR) tech-
niques (i.e. BECCS or afforestation) (IPCC, 2014).
A large majority of the pathways that deliver atmospheric CO2 concentrations con-
sistent with the 2 °C target (and indeed many of those associated with temperature
increases up to 3 °C) require global net negative emissions by about 2070 (Fuss et al.,
2014). The range of CO2 removal through BECCS assumed in the IPCC scenarios is
typically between 2 and 10 Gt CO2/year by 2050 (Fuss et al., 2014; van Vuuren et al.,
2013) with a median value of around 608 Gt CO2 cumulatively removed by 2100 using
BECCS (Wiltshire et al., 2015). Global net negative emissions are achieved when the
amount of CO2 removed from the atmosphere is greater than emissions from all other
anthropogenic (i.e. resulting from or produced by human activities Allwood et al., 2014)
sources (Fuss et al., 2014). When discussing the contribution of negative emissions from
BECCS, it is useful to distinguish between three metrics that are typically used (Gough
et al., 2018), as described in Figure 1.1:
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"I don't fancy life is easier to milkmaids than to any one
else," I answered. "I think it is as easy here as anywhere,
don't you?"
She laid her head on my lap and cried as if her heart would
break.
"I did, last night," said she; "and he told me I was making
myself ill to no purpose, and that the exercises appointed
were enough for me. But St. Clare and the other Saints
used a great many more austerities than these."
"See how humble dear Sister Catherine is," said Sister Mary
Paula. "She begged to be allowed to perform this public
penance because she said she had sinned against charity."
"The one who last lived here, child. Never mind, now. I trust
her soul hath gotten grace for all, and that she is resting
with the Saints in Paradise. But how we are ever going to
make these rooms fit for the Queen and her family, is more
than I can guess."
"Aye, child. There, I have let the cat out of the bag, but
never mind. You would have heard it before long, at any
rate. Yes, children, her Grace being in these parts, and
having somehow heard of the sanctity of our Lady's shrine
in the garden, and of our many holy relics, has chosen our
poor house in which to make a retreat, and she is coming
next week to remain a month with us."
"Why, yes, in one way it is, and yet I could have wished her
Grace had chosen some other house. I don't fancy an inroad
of giddy girls from the Court, I must say."
"Well, well, we will hope for the best. Do you and Amice set
all these chairs out into the garden to begin with, and give
them a good beating and dusting, and I will take order for
the sweeping and washing of the floors, and that being in
hand, we will overlook the tapestry and see what can be
done to mend it."
Amice complied, but there was no more sport for her. She
was plunged at once into discomfort, and began looking at
herself, as usual.
"I did not think I needed any such humiliation, but no doubt
Mother knows best," said she, presently. "I don't think I put
myself forward very much."
"Of course you don't, and I have no notion that Mother had
any such matter in her head," said I. "Don't give it another
thought. See how oddly the velvet of this chair is spotted,
as with drops of water."
"I know it," she said, in a kind of despairing tone. "O yes! I
do need to have my pride mortified. But I shall never be a
Saint, after all."
"I'll tell you what, child," said Mother Gertrude, who had
come upon us unawares, in the noise we were making. "You
are a deal more likely to make a Saint if you stop thinking
about yourself and turning yourself inside out all the time.
Saints, daughter, cannot be made, to my thinking. You can
make artificial flowers to look very pretty at a distance, but
if you want a real live plant, with sap, and leaves, and
flowers, and fruit, you must needs give it time to grow."
July 14.
"I fear her Grace will think them very plain and bare!" said
Mother Gertrude.
"Her Grace, Sister, does not come hither seeking for ease
and luxury!" answered Mother Superior. "Moreover, being a
kind and gracious lady, she will doubtless be satisfied with
the best we have to offer. You have done well, dear Sisters
and children, and I thank you for your pains."
"And how are her Grace's attendants to be accommodated?"
asked Mother Gertrude.
CHAPTER X.
St. Mary Magdalene, July 21.
OUR great guests have come, and are safely settled, and
her Grace is pleased to approve of her rooms, specially the
one furnished with linen. She asked whose was the
invention, and being told by Mother Superior that it was one
of the pupils (for that is the name we young ones go by),
she sent her her thanks and a pretty Psalter, as a token of
approbation. I never was more delighted, not only for the
sake of Amice, who is far oftener blamed than commended,
but because dear Mother Gertrude was so pleased. One
never can tell how Amice will take anything, she has so
many notions; but she came herself and showed the book
to me, saying how glad she was to possess a whole Psalter
of her own.
"I believe you are right!" she said, considering. "The pot of
ointment St. Mary Magdalene gave our Lord could be no
such great gift to Him, and yet He showed Himself pleased
with that, as no doubt He would if some little child had
given Him a handful of shells, or wild flowers."
Although her Grace must needs have been very weary with
her journey, she was at early mass this morning, and
partook of the sacrament with great devotion, as did
Mistress Patience and Master Griffith. Mistress Bullen did
not, I suppose, from lack of preparation.
"Really! And you kept the news to yourself all that time!
How wonderful!"
"I don't see anything wonderful!" said Sister Bridget, who
understands everything quite literally: "Mother Gertrude
told me not to tell, and so, of course, I could not, if I had
wished it."
"You are a good soul, and I wont tease you," said Sister
Anne, who has far more of generosity with her than her
Sister. "But say now, Sister Bridget, is it not a wonderful
thing that a real Queen should come and lodge under our
roof?"
"You know, Sister Anne, that our Lord dwells here all the
time—Father Fabian says so—and He is much greater than
any Queen."
July 24th.
Her Grace has fallen into a settled way of life, and methinks
seems already happier than when she came. She keeps all
the hours, and also spends much time in prayer at the
shrine of our Lady, in the garden. It was a favorite place of
my own, but of course I do not intrude on her. I went this
morning before I thought she would be up, meaning to say
prayers for my father, from whom I have not heard, when,
on entering the little chapel, I found her Grace before me. I
would have retired noiselessly, but her Grace looked round,
and seeing me, she beckoned me to come and kneel beside
her.
"And, do you know, little Rosamond, that you are partly the
cause of my coming here?" Then as I hesitated what to say,
she continued: "I had heard before of this shrine of our
Lady's, which had been hallowed by the prayers of St.
Ethelburga long ago, and being one day in conversation
with your kinsman, Lord Stanton, I questioned him about it.
He, seeing my interest, offered to bring me his cousin, Sir
Stephen Corbet, who, he said, had a daughter in the house,
and could tell me more than himself. I remembered the
good knight, and was glad to see him again; and he coming
to me, we held long discourse together. He told me the
house was of the best repute, both for sanctity of manners
and good works, though 'twas not of the strictest order—
that the Superior was a lady of good family and breeding,
that the situation was pleasant, and the air sweet and
wholesome. On farther question, he also said that you were
here, and seemed very happy; and also that watching
before the shrine of our Lady in the garden, you had
received from her a most comfortable assurance concerning
your mother, who had died suddenly without the
sacraments. This determined me to seek this house as a
place to hold a religious retreat, thinking that perhaps the
same grace might, unworthy as I am, be vouchsafed to me,
who am sorely in need."
"And was that all?" she said. "Was there no sign from the
Holy Image—no light nor voice?"
"I told her there was none—it was only that some influence
seemed sweetly to bring to my mind, and open to my
apprehension the words I had so often read before."
"And was that all?" said the Queen, once more; and again
she sighed heavily. I knew it was not my place to speak, far
less to instruct her, but something seemed to bid me not
hold my peace.
So we went and sat down at the old nun's feet and laid our
matters before her, asking her to advise us how we should
demean ourselves before the Queen.
"Well, well," she said: "so her Grace has chosen you out of
all the family to wait on her. I wish the honor may not bring
you ill will. But you deserve it, for you are good maidens,
good maids!" And she stroked our heads with her trembling,
withered hands. "You are kind to the old and the simple,
and that is sure to bring a blessing. Only be not set up in
your own conceits, for pride is a sin—one of the seven
deadly sins—and court favor is vainer than thistle-down and
more changeable than the wind."
"Surely, child. Have you never read his life? When I was a
young lady in London—I wot not if the usage is kept up—
devout persons used often to buy lame or sickly swine of
the drovers, and putting the saint's mark on them, turn
them loose in the street. Every one fed them, and they soon
learned to know their benefactors. I have seen mine
honored uncle—for my mother had a brother who was a
merchant and Lord Mayor—I have seen my good uncle
followed by two or three lusty porkers, grunting and
squealing for the crusts which the good man dispensed from
his pocket. The Franciscans have ever been kind to animals;
and St. Francis loved the birds, especially. He would never
have torn in pieces the sparrow that came into church, as
St. Dominic did."
"I wonder whether St. Dominic ever read that verse in the
Psalter, about the sparrow finding a nest wherein to lay her
young?" remarked Amice.
"Did I know her? Aye, indeed, child! Did I not have the
principal care of her, under the Mother Superior that was
then? But that was long ago. Mother Gertrude was a young
woman then, and Mother Superior that now is, was just
professed. It was in the weary times of the civil wars, in
Henry Sixth's day, that the poor lady came here, and she
lived in those rooms twenty years—twenty years, children—
and never saw a face save Mother Superior's and mine, and
latterly Mother Gertrude's, when she began to divide the
charge with me."