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CHAPTER
MEC 451
4 Thermodynamics
Lecture Notes:
MOHD HAFIZ MOHD NOH
HAZRAN HUSAIN & MOHD SUHAIRIL
Faculty of Mechanical Engineering
Universiti Teknologi MARA, 40450 Second Law of
Shah Alam, Selangor
Thermodynamics
Introduction
Satisfying the first law alone does not ensure that the process will take
place.
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Kelvin-Planck statement
No heat engine can have a
thermal efficiency 100
percent.
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Heat Engines
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The work-producing
device that best fit into
the definition of a heat
engine is the steam
power plant, which is
an external combustion
engine.
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Thermal Efficiency
Desired Result
th
Required Input
For a heat engine the desired result is the net work
done and the input is the heat supplied to make
the cycle operate. 7
MEC 451 – THERMODYNAMICS
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Wnet , out
th
Qin
where
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Wnet , out
th
Qin
Qin Qout
Qin
Qout
1
Qin 9
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QL T
L
QH TH
TL
th , rev 1
TH
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QH QH QL
COPHP COPR
Wnet , in QH QL Wnet , in
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Carnot Cycle
Process Description
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Example 4.1
Solution:
A steam power plant
produces 50 MW of net Wnet , out
th
work while burning fuel QH
to produce 150 MW of
50 MW
0.333 or 33.3%
heat energy at the high 150 MW
temperature. Determine
the cycle thermal Wnet , out QH QL
efficiency and the heat QL QH Wnet , out
rejected by the cycle to 150 MW 50 MW
the surroundings. 100 MW
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MEC 451 – THERMODYNAMICS
Faculty of Mechanical Engineering, UiTM
Example 4.2
A Carnot heat engine receives 500 kJ of heat per cycle from a high-
temperature heat reservoir at 652ºC and rejects heat to a low-
temperature heat reservoir at 30ºC. Determine :
(a) The thermal efficiency of this Carnot engine
(b) The amount of heat rejected to the low-temperature heat
reservoir
Solution:
TH = 652oC
TL QL TL
QH th , rev 1
TH QH TH
HE
WOUT
(30 273) K (30 273) K
1 0.328
QL (652 273) K (652 273) K
TL = 30oC 0.672 or 67.2% QL 500 kJ (0.328)
164 kJ
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MEC 451 – THERMODYNAMICS
Faculty of Mechanical Engineering, UiTM
Example 4.3
An inventor claims to have developed a refrigerator that maintains
the refrigerated space at 2ºC while operating in a room where the
temperature is 25ºC and has a COP of 13.5. Is there any truth to his
claim?
Solution:
TH = 25oC
QL TL
COPR
QH QH QL TH TL
(2 273) K
R
Win
(25 2) K
QL
1196
.
TL = 2oC
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MEC 451 – THERMODYNAMICS
Faculty of Mechanical Engineering, UiTM
Entropy
This relates to the 2nd law since the 2nd law predicts
that not all heat provided to a cycle can be
transformed into an equal amount of work, some heat
rejection must take place.
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Entropy Change
dS 0
S2 S1
i. Pure substances:
Any process: Δs = s2 – s1 (kJ/kgK)
Isentropic process: s2 = s1
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T2 P2
s2 s1 C p , av ln R ln
T1 P1
for isentropic process
k
P2 v1
P1 s const . v2
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Example 4.5
Steam at 1 MPa, 600oC, expands in a turbine to 0.01 MPa. If the
process is isentropic, find the final temperature, the final enthalpy of
the steam, and the turbine work.
Solution:
s1 8.0311 kgkJ.K
Wout m h1 h2
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T2 Tsat @ P2 45.81o C
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Example 4.6
Steam at 1 MPa, 600°C, Solution:
expands in a turbine to 0.01
Theoretically:
MPa. The isentropic work
of the turbine is 1152.2 wa h1 h2 a
isen ,T
kJ/kg. If the isentropic ws h1 h2 s
efficiency of the turbine is
wa isen ,T ws
90 percent, calculate the
actual work. Find the 0.9 1153
actual turbine exit
temperature or quality of
1037.7 kJ
kg
the steam.
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State 1
P1 1 MPa h1 3698.6 kg
kJ
T1 600o C s1 8.0311 kgkJ. K
State 2s
sat.mixture
P2 0.01 MPa
kJ
x2 s 0.984
s2 s s1 8.0311 kg . K
h 2545.6 kJ
2s kg
wa h1 h2 a State 2a
h2 a h1 wa
P2 0.01 MPa sup erheated
2660.9 kJ
kg h2 a 2660.9 kJ
kg T
2a 86.85o
C
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MEC 451 – THERMODYNAMICS
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Example 4.7
Air enters a compressor For isentropic process of IGL
k 1
and is compressed
T2 s P2 k
adiabatically from 0.1 MPa,
27°C, to a final state of 0.5 T1 P1
0.4/1.4
MPa. Find the work done 0.5
T2 s 27 273
on the air for a compressor 0.1
isentropic efficiency of 80 475.4 K
percent. Then
Wc , s
Wc , s Wc ,a 220 kJ
Wc , s h2 s h1 isen ,c kg
m
CP T2 s T1 33
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