Professional Documents
Culture Documents
1
Chapter 4: Air Pollution Control
Prepared by: Nur Ain Bt Mohd Zainuddin
Course Learning Outcome
2
Chapter 4: Air Pollution Control
4.1 Legal and Administrative Systems for Air
Pollution Control
3
Chapter 4: Air Pollution Control
4.1 Legal and Administrative Systems for Air
Pollution Control
AIR POLLUTIONS
MATERIALS
AND GLOBAL
STRUCTURES WARMIN ACID RAIN
G
5
Chapter 4: Air Pollution Control
4.1 Legal and Administrative Systems for Air
Pollution Control
6
Chapter 4: Air Pollution Control
4.1 Legal and Administrative Systems for Air
Pollution Control
Environmental
Quality Act 1974
LAWS AND
CLEAN AIR
REGULATIO REGULATION 2014
NS
7
Chapter 4: Air Pollution Control
4.1 Legal and Administrative Systems for Air
Pollution Control
CONTROL
MEASURES
AIR POLLUTION CONTROL SYSTEM–
WET SCRUBBER, BAG FILTERS, CYCLONE,
ELECTROSTATIC PRECIPITATOR ETC.
Product recovery
The needs of production and product quality
Compliance to ISO 14001
Good corporate and social responsibility
Chapter 4: Air Pollution Control 9
4.1 Legal and Administrative Systems for Air
Pollution Control
A COMPLETE AIR POLLUTION CONTROL SYSTEM
SHOULD
COMPRISES THE FOLLOWING COMPONENTS :
APCS
DUCTING
STAC
K
SUCTION
HOOD AIR POLLUTION
CONTROL EQUIPMENT
FAN
Chapter 4: Air Pollution Control 10
4.1 Legal and Administrative Systems for Air
Pollution Control
AIR POLLUTION CONTROL TECHNOLOGY FOR DUST
EMISSION CONTROL
BAG FILTER
CYCLONE PARTICUL
ATE
SCRUBBE
R
BIOFILT
Chapter 4: Air Pollution Control 12
ER
4.1 Legal and Administrative Systems for Air
Pollution Control
INTRODUCTION TO
ENVIRONMENTAL
QUALITY (CLEAN
AIR) REGULATION
2014 AND
COMPLIANCE
Chapter 4: Air Pollution Control 13
4.1 Legal and Administrative Systems for Air
Pollution Control
Any fuel
Any industrial
burning
plant 14
Chapter 4: Air Pollution Control equipment
4.1 Legal and Administrative Systems for Air
Pollution Control
Stage III
(Operation stage)
- Proper
operation,
preventive
maintenance (plus
performance
monitoring)
Stage II
(constructio
n stage) - Stage I
Adequate (design
quality of stage) -
construction Adequat
e design
Regulation 13 is referring to
This regulations shall apply to
3 schedules which are :
:
1) Any premise that carry out
1) First Schedule –
burning process for
ACTIVITIES AND INDUSTRIES
industrial and trade
SUBJECT
THE BEST
TO
purposes including burning
TECHNIQUES
AVAILABLE ECONOMICALLY
of waste;
ACHIEVABLE (BAT)
2) Any premise or process that
2) Second Schedule – LIMIT
discharges air pollutants
VALUES TECHNICAL
into open air;
AND
3) Any industrial plant; and
3) STANDARDS
Third – LIMIT
4) Any fuel burning equipment
Schedule
VALUES AND TECHNICAL
STANDARDS (BY ACTIVITY OR
INDUSTRY)
PLANNING STAGE
Submit
Written Fuel • AS/PUB/N-APB
Notification Regulation 5 Burning • AS/PUB/N-JANA
Equipment
(Obligation
to Notify)
Chimney • AS/PUB/N-CHIMNEY
30 days
before any
• AS/PUB/N-BAGFILTER
work starts Air • AS/PUB/N-SCRUBBER
Pollutant • AS/PUB/N-CYCLONE
Control • AS/PUB/N-INS
System • AS/PUB/N-SPRAYBOOTH
• AS/PUB/N-ESP
Chapter 4: Air Pollution Control 19
4.1 Legal and Administrative Systems for Air
Pollution Control
WRITTEN NOTIFICATION
FORMS
CONSTRUCTION STAGE
Air pollution control systems need to be designed and constructed
in strict compliance with the minimum requirements and
specification as outline in Guidance Document for Fuel Burning
Equipments and Air Pollution Control Systems (GD APCS)
Submit
Written
Declaration
Regulation 7 (Air
Pollution • AS/PUB-DECLARE
Control System) Written
Declaration
Form
30 days after
commencement of
operations
WRITTEN DECLARATION
FORM
OPERATION STAGE
Submit
Emission
Declaration Regulation • AS/PUB-EMISSION
18 (Emission
Emission
Declaration
Declaration) Form
Reports
anually
Submit to DG
(30 days before work commence) Regulation 5(2)
Written Notification
CONSTRUCTION
Construction
AS-built Drawing
Written Declaration Regulation 7
(30 days after Air Pollution Control
System
OPERATION operation)
Operation
Emission Regulation 18
REPORTING Existing Emission
Declaration
Premises Declaration
Chapter 4: Air Pollution Control 25
4.1 Legal and Administrative Systems for Air
Pollution Control
AIR POLLUTION CONTROL
SYSTEM
Mentioned in Regulation 7 of CAR 2014
Every premise shall be equipped with Air Pollution
Control System (APCS)
APCS shall be designed and constructed by a
professional engineer
APCS must be operated by a competent person
who shall be on duty at all times during operation
hours
DAILY
MONITORINGChapter 4: Air Pollution Control 28
4.1 Legal and Administrative Systems for Air
Pollution Control
DAILY
MONITORI
NG
WEEKLY
MONITORI
NG
MONTHLY
MONITORI
NG
Effective method in
preventing pollution
BEST
and, where that is not AVAILABLE
practicable, generally
to reduce emissions
TECHNIQUES
into the air from the ECONOMICALL
industrial activities
and their impact on
Y ACHIEVABLE
the environment as a (BAT)
whole
Production of Waste
Power Generation
Petrochemicals Incineration
Storage &
Non-Ferrous Handling Non-Metallic
Metal Industry Petroleum (Mineral) Industry
Products
MAINTENANCE REQUIREMENTS
Promote a continuous maintenance culture within the
industry and to increase compliance
MONITORING
REQUIREMENTS
Proof of compliance with limit values
- The frequency of monitoring will depend on
the types of industries and types of air
pollutants
Periodic
measurements
Continuous
measurements
CONTINUOUS EMISSION
MONITORING
Refer to the specification in these documents
REGULATION 12 : OPACITY
SMOKE LIMIT VALUES
TO RINGELMANN AND EXEMPTI
ACCORDING
OPACITY ON
No 2 Ringelmann Chart in
> No 1 Ringelmann
Chart 5 minutes aggregate within
1 hour period
>20%
Transmissiomete No 2 Ringelmann Chart in
15 minutes aggregate within
r (1 minute 24 hours period
averaging time )
At Start-up
No 2 Ringelmann
Chart
Example :
Type of pollutants : Multi cyclone to collect LIMIT
course dusts VALUE
Concentration of TPM
Total Particulate FOR TPM
emitted from the
Matters
stack is 400 mg/m3.
Black Smoke
Example :
Type of pollutants : Wet Scrubber To Scrub LIMIT
pollutants VALUE
Concentration of NO2
Total Particulate from
generated
the incineration FOR NO2
emitted from the
Matters process
Non Methane Volatile stack is 200 mg/m3.
Organic Compound
Acid Gaseous (i.e :
Hydrogen Chloride,
Sulfur Dioxide
etc.)
NO2 concentration emitted exceeds the
limit value.
INCOMPLY
Chapter 4: Air Pollution Control 46
4.1 Legal and Administrative Systems for Air
Pollution Control
OFFENSE
2012 EVERGREEN FIBREBOARD Regulations 25 - Solid particles
BERHAD , JOHOR concentration in other
operations
2012 HI-EX FABRICATOR Regulation 38 - Erection etc. of
ENGINEERING SDN BHD, chimney.
JOHOR
2013 TBH TIMBER SDN BHD , Regulation 40 -
KELANTAN Control equipment to be in
operation
EQR (Motor Vehicles Noise) 1987 EQR (Control Emission from Diesel
Engines) 1996
Properties
Chapter 4: Air Pollution Control 49
4.1 Legal and Administrative Systems for Air
Pollution Control
3 Guidance Document : Design and Operation of Air Pollution Control System 7(1)
http://www.doe.gov.my/portalv1/wp-
content/uploads/2015/01/Peraturan-
peraturan_kualiti_alam_sekeliling_udara_bersih
_2 014.pdf
4.2 Control
Devices For
Particulate
Contaminants
53
Chapter 4: Air Pollution Control
4.2 Control Devices for Particulate
Contaminants.
APPROACHES TO
CONTAMINANT CONTROL
DILUTION CONTROL AT
SOURCE
1) Dilution
– Accomplished using tall stacks
• Penetrate the inversion layer and disperse the
contaminant
• Reduce the ground-level conc
– Means of spreading air contaminant
– Diluting air contaminant to harmful level and less
noticeable near the source
– Only short-term control measure
Available methods to
control primary
particles
• Spray Tower
• Wet Cyclone
Wet
Collector
scrubber
• Venturi
Scrubber
Fabric
Filter ESP
Chapter 4: Air Pollution Control 62
4.2 Control Devices for Particulate
Contaminants.
Settling chamber
To effectively trap
the particles from
flowing out
Baffled chamber
Chapter 4: Air Pollution Control 63
4.2 Control Devices for Particulate
Contaminants.
Advantages Disadvantages
• Simple in design • Require a large
and operation space for
• Remove particle installation
>50 μm • Low efficiency for
• Employ gravity to small particles
separate particles
65
Chapter 4: Air Pollution Control
4.2 Control Devices for Particulate
Contaminants.
CENTRIFUGAL COLLECTORS
2.1. Cyclones
• Centrifugal force
– generated by spinning of gas
– Magnitude depends on particle
mass, gas velocity within cyclone
and cyclone diameter
• Solid particles are thrown to the
walls as gas spirals upward
• Separation efficiency depends on
centrifugal force exerted on particles.
• Relatively inexpensive to
operate.
• Can handle large volumes of
gases, T up to 980°C.
• Used in many applications e.g.
cement plants, petroleum
refinery, etc.
Advantages Disadvantages
• Serve as both • Cannot handle wet,
exhaust fan and fibrous material
dust collector. (can accumulate on
• Widely used in blade).
ceramics, food, • Requires higher
pharmaceutical. power input than
cyclone.
76
Chapter 4: Air Pollution Control
4.2 Control Devices for Particulate
Contaminants.
3) Wet collectors
• Incorporating particles into liquid droplets by
impingement or interception during gravitational
settling
• Efficiency depends on energy consumed in the
air-to-water contact
Directly proportional
to pressure drop
3) Wet collectors
Advantages Disadvantages
• Provide efficient, low-cost • High or fluctuating pressure
solutions to air pollution drop.
problems. • High maintenance cost if
• Can handle hot and moist collecting corrosive materials.
gases. • Not recommended for use
where high plume rise is
important.
• Disposal problems of the
particulates – require other
treatment.
78
Chapter 4: Air Pollution Control
4.2 Control Devices for Particulate
Contaminants.
Venturi scrubber
SprayChapter
tower4:scrubber
Air Pollution Control 87
4.2 Control Devices for Particulate
Contaminants.
91
Chapter 4: Air Pollution Control
4.2 Control Devices for Particulate
Contaminants.
Bag Filter or Bag House
Advantages Disadvantages
• Have wide application • Cannot be used with explosive
• 99% removal efficiency for a wide range materials.
of particle sizes. • High installation cost .
• Can handle large volumes of gas – 25 to • Require a great deal of space for
1000 m3/s. industrial operation.
• Low pressure drops. • Only operate at peak efficiency within a
• Can operate continuously with little limited temperature range
maintenance. • May use excessive power if buildup of
• Can be used to collect acid or tar mists. collected material causes ‘spark over’.
• Inefficient if buildup suppresses the
corona discharge from negative
electrode.
100
Chapter 4: Air Pollution Control
Electrostatic Precipitators
Process Selection
A) Settling Chamber
B) Simple Cyclone
C) High-efficiency
Cyclone
D) Electrostatic
Precipitator
E) Spray Tower wet
scrubber
F) Venturi Scrubber
G) Bag Filter
1. Problem 9.10
2. Problem 9.11
3. Problem 9.12
4. Problem 9.17
5. Problem 9.18
6. Problem 9.21
Major treatment
processes
Catalytic
can be done via: Absorption reduction
Stripping
Wet
Scrubbing
Chapter 4: Air Pollution Control 108
4.3 Control Devices for Gaseous Contaminants.
1. ADSORPTION
• Adsorption is the adhesion of molecules of
gas, liquid, or dissolved solids to a surface
(adsorbent).
• Involves passing a stream of effluent gas
through a porous solid material (adsorbent)
• Adsorption of adsorbate on adsorbent can be
either by physical or chemical
Physical Adsorption
– Condensation of gases and vapors on solid above dew
point
– Depends upon van der Waals force
– The higher the boiling point, the greater the amount
adsorbed
– Directly proportional to the amount of solid surface
available
– Accompanied by capillary condensation within the pores
– Small amount of heat is liberated
– Process relatively rapid and readily reversible
– By lowering pressure/increasing temperature, adsorbed
gas can be desorbed
Chapter 4: Air Pollution Control 110
4.3 Control Devices for Gaseous Contaminants.
Chemical adsorption/chemisorption
– Gas molecule forms a chemical bond with the adsorbent
– Gas is strongly held to the solid surface by valence forces
– A slower process since displacement of atoms must occur in
molecules
– Releases greater amount of heat & require more energy
– Results in formation of single layer of molecules on solid
surface
– Process is irreversible – chemical nature of adsorbate have
been altered
– Amount of gas adsorbed depends on pressure and temperature
– Example: Catalysed reactions, chemisorption of CO on NH3
Adsorbents
• Key characteristics of solid adsorbents
1. Preferential affinity for specific substances,
e.g:
• Alumina, bauxite, silica gel – affinity for polar
such as water. → used as drying agent. Zeolite Molecular sieves
Adsorbents
2. Surface-to-volume ratios
• Provided by internal pores
• Can be increased by activating some adsorbent, e.g.:
– Activated carbon – treating with steam
– Activated alumina – reactivated by heating to 175 to 325oC
Strontium sulfate
Fuller’s Earth
Zeolite
Chapter 4: Air Pollution Control Silica gel 114
4.3 Control Devices for Gaseous Contaminants.
Adsorption equipment
• Can be designed with fixed, moving or
fluidized beds
• Fixed bed
– Vertical or horizontal cylindrical shell
– Adsorbent used is activated carbon in layers of 1.3
cm thick (thin-bed adsorbers) or >1.3 cm (deep-
bed adsorbers)
Fluidized adsorber
• Contains a shallow, floating bed of adsorbent .
• Air flows upward, expanding the bed, suspending &
fluidizing the adsorbents.
• Provides intimate contact between gaseous
contaminant & adsorbent.
• Decontaminated air leaves at top of unit.
• Application
– Adsorb organic vapors from dry cleaning, degreasing, solvent
extracting
• Recovery of valuable material from organic vapor is sometimes
economically feasible when concentrations of organic vapors is high.
• E.g. Reinluft Process collects SO2 from flue gas to get H2SO4.
2) ABSORPTION
• A.k.a scrubbing
• A fluid permeates or is dissolved by a liquid or
solid.
• Contaminated effluent gas (absorbate or
solute) is brought into contact with liquid
absorbent (solvent)
• Utilize chemical (reactive) or physical
(nonreactive) change to remove pollutants
…Absorption
• Amount of gas absorbed depends on
– properties of gas and solvent
– Pressure of gas above the solution (Henry’s Law)
– Temperature of the system
– Packing used – turbulence, flow rate and type
• Application
– Control of SO2,NOx,H2S, Cl2, NH3
– Removal of HC in asphalt plants, varnish cookers
– Recovery of products, e.g acetic acid, chloroform.
Absorbent (solvent)
• Good solubility solvent if:
– Chemically similar to the solute
– Low viscosity
• Other characteristics of solvents:
– Have low freezing point
– Low in toxicity, noncorrosive
– Relatively nonvolatile
– Nonflammable
– Chemically stable
– Inexpensive, readily available
Application of absorbers
• Installed at power plants to control SO2 emission.
Efficiency of 80% - 90%.
• Not efficient in NOx removal. Efficiency of 20% using
limewater.
• Main absorbents used in SO2 absorption process:
– Alkalies (sodium and ammonia)
• Sodium – not volatile and have no fume problem
• Ammonia – Ammonium sulfate byproduct is more desirable
– Alkaline earths (calcium and magnesium)
• Compound being used – MgO, CaO, CaCO3
Absorption units
• Designed to provide
– intimate contact between gas and liq
– Optimum diffusion of the gas in solution
• Selection depends on number of scrubbers to
be used
– Single - removes both particulate and gaseous in a
single unit
– Two separate units for gaseous and particulates.
Spray
tower
Absorption Plate /
Venturi
tray
scrubber Units tower
Packed
towers
Chapter 4: Air Pollution Control 126
4.3 Control Devices for Gaseous Contaminants.
Spray towers
• Absorbing liq, usually
water, is sprayed thru
contaminated gas.
• Water-contaminant soln
falls downward.
• Clean gas exits thru outlet
valve at top of unit.
• Moisture eliminators
reduce moisture in gas
before release.
Disadvantages of absorbers
Perforated plate
Packed towers
Packing is used to increase the
contact time between vapor and liquid
Berl saddle
Pall ring
Intalox Raschig
saddle ring
• Materials of packing
– Has large surface-to-volume ratio
– Has large void ratio to minimize the
resistance of gas flow
– Lightweight and unbreakable
Operation:
• Countercurrent flow – gas from bottom, liquid from
top.
• Liq flows over surface of packing in a thin film.
• Highly efficient for gaseous removal
• Disadvantage – easily clogged if gas of high
particulate is introduced
Chapter 4: Air Pollution Control 134
4.3 Control Devices for Gaseous Contaminants.
Venturi scrubber
Venturi Scrubber
• For particulate & gaseous
contaminants.
• Co-current unit –
gas/particulate and
absorption solution
Venturi Scrubber
3) CONDENSATION
• 2 basic types: – surface & contact condensers
Types of condensers
Clean
Dirty Air
Air In Outlet
Condensers are simple, relatively inexpensive devices that normally use water or air to
cool and condense a vapor stream. Condensers are typically used as pretreatment
devices. They can be used ahead of adsorbers, absorbers, and incinerators to reduce
the total gas volume to be treated by more expensive control equipment.
Chapter 4: Air Pollution Control 140
4.3 Control Devices for Gaseous Contaminants.
Condensers
4) COMBUSTION
• Important air-pollution control process
• Convert the air contaminants to innocuous CO2
and water
• Push oxidaton rxn to completion.
• 4 basic elements for efficient combustion to
occur
– Oxygen
– Temperature
– Turbulence
– time
Chapter 4: Air Pollution Control 142
4.3 Control Devices for Gaseous Contaminants.
O2 T
time turbulence
• Keep O2 well
• For sufficient burning mixed with
combustible
• Increasing stack height subs
• Provided by
baffles or
Chapter 4: Air Pollution Control injection 143
nozzles
4.3 Control Devices for Gaseous Contaminants.
Direct-
Flame
Thermal
Catalytic
Direct-flame combustion
• Waste gases are burned directly in a
combustor
• Burn by own – if sufficient heat value
and O2 content
• Frequently used in petrochemical
plants and refineries
• Flares
– usually open-ended combustion units
– Safe means of disposing highly
combustible waste gases
Chapter 4: Air Pollution Control 145
4.3 Control Devices for Gaseous Contaminants.
• Disadvantages of flares
– Burn at high temp and long periods – cause
formation of oxides of nitrogen
– Produce visible smoke or soot
– Waste large amount of heat energy
• Economical when the waste gas contribute >50%
of the total heating value for incineration
Thermal combustion
• Advantages
– Well-designed unit can produce odorless steam
plumes
– Clean stream of hot air produced can be used as a
heat source for other operation
Catalytic combustion
• Used when combustible materials is low.
• Consist of preheating and catalytic section
• High efficiency 95 -98% eff.
• Efficiency depends on
– Contaminant conc
– Gas stream T
– O2 conc
– Contact time
– Type of catalyst
Catalytic combustion
• Have been used to control SO2, NOx, HC, CO
• Catalyst: Platinum (most effective for NOx), Palladium and
ceramic materials
• Advantages:
– Lower T (200°C for CO to CO2 conversion)
– Catalyst accelerates rxn, reduce time
(20 to 50 times less time than thermal incinerator)
• Disadvantages:
– High maintenance cost
– Catalytic poisoning