Introduction • The process in which a substance or substances undergo change to produce new substances with new properties is called chemical reaction. • The substances which take part in a chemical reaction are called reactants. • The substances obtained from a chemical reaction are called products. Reactants Products Hydrogen + Oxygen Water Chemical Equation • Chemical equation is the method of representation of a chemical reaction with the help of symbols and formula of the substances involved in it. • E.g.- when hydrogen and oxygen react to form water in general , it is represented as: Hydrogen + Oxygen Water -But as a chemical equation H2 + O2 H2O Reactants Product Types of Chemical Reactions
1) Addition or combination or synthesis
reaction 2) Decomposition or dissociation or analysis reaction 3) Displacement or replacement reaction I. Single displacement reaction II. Double displacement reaction 4) Acid-base or neutralization reaction 1. Addition or Combination or Synthesis Reaction The type of reaction where two o more than two elements or compounds combine to from a single new compound is called a combination reaction. E.g.:-Fe(s)+S(s) FeS (s) Iron + Sulfur Ferrous sulfide 2. Decomposition or Dissociation Reaction The type of reaction in which the molecules of a compound break down into molecules of two or more different compounds is called a decomposition reaction. a) By using heat: 2KCLO3 2KCL + 3O2 Potassium chlorate Potassium chloride + Oxygen b) By electricity: 2H2O(l) Electrolysis 2H2 (g)+O2 (g) Water Hydrogen + Oxygen c) By catalyst: 2H2O2 MnO 2 2H2O + O Hydrogen peroxide Water + Oxygen - MnO2 (Manganese dioxide acts as a positive catalyst) d) By light: 2AgBr (s) Light 2Ag(s)+Br2(g) Silver bromide Silver + Bromine 3. Displacement or Replacement Reaction *The type of reaction in which an atom or a group of atoms (radical) present in a molecule of the chemical compound is displaced by another atom or a group of atoms (radical) is called displacement reaction. *It has two types: a) Single displacement reaction: The reaction in which a less reactive element or a radical in the compound is replaced by more reactive elements is called single displacement reaction. E.g.: Fe (s) + CuSO4(aq) FeSO4(aq) + Cu (s) Iron(II)+Copper(II) Sulfate Iron(II)Sulfate+ Copper(II) b) Double displacement reaction: The type of reaction in which two reacting compounds exchange their corresponding their corresponding part or a radical of the compound to form two new compounds is called double displacement reaction. E.g.AgNO3(aq)+NaCl(aq) NaNO3(aq)+AgCL Silver nitrate + Sodium chloride Sodium nitrate + Silver chloride 4. Acid-Base Reaction *The reaction in which an acid reacts with a base to form salt and water is called acid-base reaction. *Both acid and base lose their properties and form new compounds with different properties during the acid-base reaction. *E.g. CaO + 2HCl CaCl2 + H2 * Calcium oxide + Hydrogen chloride Calcium chloride + Water Factors Affecting Chemical Reaction
* The amount of the reactant changed into the products per
second is called rate of chemical reaction. i.e., Rate of reaction=
*There are several factors that affect the rate of a chemical
reaction. Some of them are: a) Temperature: The rate of a chemical reaction increases with the rise of temperature. For every 10°C rise in temperature, the reaction rate almost becomes double. b) Pressure: Some chemical reactions take place only when reactants are subjected to a higher pressure than the atmospheric pressure. c) Physical state of the reactants (surface area): For the reactions to occur, the reactants must come into contact with each other. The rate of reaction also depends upon the particles size of the reactants. d) Light: Some chemical reactions take place by the action of light energy. Such reactions are called photochemical reactions. Light energy activates the molecules and increases the rate of reaction. E.g. 2AgBr (s) Light 2Ag (s) + Br2 (g) -Silver bromide is decomposed by light. e) Catalyst: A catalyst is a substance which though present in a small quantity alters the rate (either accelerates or retards) of a chemical reaction without being changed or used up. The catalyst do not undergo any chemical change. - Catalysts are of two types: i) Positive Catalyst: It accelerates the rate of the reaction. E.g. 2H2O2 MnO 2 2H2O + O2 - MnO2 (Manganese dioxide) acts as a positive catalyst and increases the rate of chemical reaction. ii) Negative Catalyst: It retards the rate of the reaction. E.g. 2H2O2 Glycerine 2H2O + O2 - Glycerine acts as a negative catalyst and decreases the rate of chemical reaction. -Characteristics of catalyst: i) It does not start a reaction. It simply alters the rate of reaction already started. ii) It remains unchanged in mass and chemical composition at the end of the reaction. iii) A catalyst is specific in its action, i.e. a given catalyst can be used for a particular reaction only, not for all reactions f) Concentration: The rate of reaction usually increases with an increase in the concentration of reactant, i.e. higher the concentration of the reactants, the faster the reaction. It is because the reaction takes place due to the collisions between atoms or molecules. - Exothermic Reaction: A chemical reaction which proceeds with the evolution of heat energy is called exothermic reaction. E.g. C (s) + O2(g) CO2(g) + Heat Carbon + Oxygen Carbon dioxide + Heat -Endothermic Reaction: A chemical reaction which proceeds with the absorption of heat energy is called endothermic reaction. E.g. CaCO3(s) + Heat CaO(s) + CO2(g) Calcium carbonate+ Heat Calcium oxide + carbon dioxide Thank you