TRANSITION ELEMENTS

Tin / stanum

𝟒 +¿+𝟖 𝑯 𝑶¿
𝟐
𝟐 + ¿+𝟓 𝑺𝒏 ¿
❑ +¿ → 𝟐 𝑴𝒏 ¿
 𝟓 𝑺𝒏𝟐 +¿ + 𝟐 𝑴𝒏 𝑶 𝟒 +𝟏𝟔 𝑯 ¿

 High heat of atomisation / High bond energy of the bond

• Nitrogen fixation by bacteria .

• Production of nitrogen oxides by car engine or lightning.
 𝑵 𝑯 𝟒 𝑪𝒍 ( 𝒔 )+ 𝑵𝒂𝑵 𝑶 𝟐 ( 𝒔 ) → 𝑵 𝟐 ( 𝒈 ) + 𝑵𝒂𝑪𝒍 ( 𝒔 )+𝟐 𝑯 𝟐 𝟎(𝒍 )

 From -3 ( In ) and +3 ( in ) to 0 ( in )

The reaction is explosive.

 It contributes to acid rain.

Oxides of nitrogen are reduced to nitrogen

An ion which formed when a metallic ion is bonded
to a group of ligand by dative bonds.

Ligand that can donate more than one lone pair electrons.
  ¿
  

A stronger ligand is able to displace a weaker ligand

from the complex ion.

• Transition metal ions have incomplete 3d-subshell .

• D1 to d9 , d-d electronic transition is possible.
• Non-transition metals have either completely-filled 3d-orbitals
or no 3d electrons or no d-d electronic transition.