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Solve for
= (0.03) (23.6torr) = 0.71 torr
Freezing Point Depression
Freezing point depression (f) is defined as
the freezing point of pure solvent ( Tpure
solvent) minus the freezing point of the
solution (Tsolution)
f = Tpure solvent – Tsolution
is proportional to the concentration of the
solution f = Kf m
Where, Kf = molal freezing-point depression
constant (unit 0C/m)
m = molality
Freezing Point Depression
Sample Problem: Calculate the freezing
point depression of a solution containing
651g of ethylene glycol in 2505g of water.
The molar mass of ethylene glycol is
62.01g/mol, the Kf of water is 1.860C/m
G: 651g ethylene glycol (MM = 62.01g/mol)
2505g H2O; Kf H2O =1.860C/m
R: freezing-point depression of solution (f)
E: f = Kf m
S: Solve for the molality
moles solute 651g
= =10.50 mol
(ethylene glycol) 62.01g/mol
10.50 mol
molality = =4.19 m
2.505kg
Solve for
= (1.860C/m) (4.19m) =7.790C
Boiling Point Elevation
Boiling point elevation (b) is defined as the
boiling point of the solution (Tsolution) minus
the boiling point of the pure solvent ( Tpure
solvent)