1 Pathi * 31-08-06

Sri Chaitanya IIT- JEE Academy

RAMAN BHAVAN - VIJAYAWADA
CHEMISTRY - ASSIGNMENT
[Stoichiometry]
SVS
Jr.IIT
******************************************************************************************
1. 0.7 gm of a sample Na
2
CO
3
. XH
2
O were dissolved in water and the volume was made to 100ml. In this 20 ml of this
solution requires 19.8 ml of N/10 HCl for neutralization. The value of X is
1)7 2) 3 3) 2 4) 5
2. 20 ml of X M HCl neutralises completely 10 ml of 0.1 M NaHCO
3
solution and a further 5 ml of 0.2 M Na
2
CO
3
solution to methyl orange end point. The value of X is
1) 0.167 M 2) 0.133 M 3) 0.15 M 4) 0.2 M
3. RH
2
can replace Ca
+2
in hard water RH
2
+Ca
+2

RCa+2H
+
1 lit of hard water after passing through RH
2
has H
+
=0.01 M. Hence hardness of water in ppm of Ca
+2
is
1) 100 2) 200 3) 50 4) 125
4. N
2
+3H
2

2NH
3
molecular weight of NH
3
and N
2
are x
1
, x
2
their equivalent weights are y
1
and y
2
. Then y
1
- y
2
is
1)
1 2
2
6
x x -
2)
2 1
2
6
x x -
3) 3x
1
- x
2
4) 3x
2
- x
1
5. One gram of a mixture Na
2
CO
3
, NaHCO
3
in 2 : 1 molar ratio requires x equivalents HCl for neutralisation. The
mixture is strongly heated and react with HCl. Howmany equivalents of HCl is required?
1) 2x 2) x 3) 3x / 4 4) 3x/2
6. A solution contains Na
2
CO
3
and NaHCO
3
. 10 ml of the solution required 2.5 ml of 0.1 M H
2
SO
4
for neutralisation
using phenolphthalein as indicator. Then methyl orange is added 2.5 ml of 0.2 M H
2
SO
4
is required. The amounts of
Na
2
CO
3
, NaHCO
3
in 1 lit solution is
1) 5.3 gm, 4.2 gm 2) 5.3 gm, 6.2 gm 3) 4.22 gm, 5.3 gm 4) 6.3 gm, 5.3 gm
7. The weight of magnesium which has same number of atoms are present in 8 gm of methane is
1) 48 gm 2) 120 gm 3) 60 gm 4) 56 gm
8. What is the volume (in lit) of oxygen at STP required for complete combustion of 32 gm of CH
4
1) 44.8 2) 89.6 3) 22.4 4) 179.2
9. What are the oxidation numbers of nitrogen in NH
4
NO
3
1) +3, -5 2) -3, +5 3) +3, -6 4) +2, +2
10. Which one of the following elements show different oxidation state
1) sodium 2) fluorine 3) chlorine 4) potassium
11. 50 gm of calcium carbonate was completely combusted in air. What weight of the residue (in grams) is
1) 2.8 2) 28 3) 44 4) 4.4
12. Howmany moles of acidified FeSO
4
can be completely oxidised by one mole of KMnO
4
1) 10 2) 5 3) 6 4) 2
13. MnO
2
+4HCl

MnCl
2
+H
2
O+Cl
2
. The equivalent weight of HCl is
1) 73 2) 36.5 3) 18.25 4) none

2 Pathi * 31-08-06
14. How many moles of electrons weight one kilogram
1) 6.023 x 10
23
2)
31
1
10
9.108

3)
4
6.023
10
9.108
-

4)
8
1
10
9.108 6.023

15. In a reaction 4 mole of electrons are transferred to one mole of HNO

3
. The possible product obtained due to reaction
1) 20.5 mole of N
2
2) 1 mole of NO
2
3) 0.5 mole of N
2
O 4) 1 mole of NH
3
16. 100 ml of 1M KMnO
4
oxidised 100 ml H
2
O
2
in acidic medium. Volume of same KMnO
4
required
( )
4 2
MnO MnO
-
in alkaline medium to oxidise 100 ml of H
2
O
2
will be
1)
100
3
ml
2)
500
3
ml
3)
300
3
ml
4) none
17. Atomic weight of Barium is 137.34. The equivalent weight of Barium in BaCrO
4
used as oxidising agent in acidic
solution is
1) 137.34 2) 45.78 3) 114.45 4) 68.67
18. X litres of carbon monoxide is present at STP. It is completely oxidised to CO
2
. The volume of CO
2
formed is 11.207
litres at STP. What is value of X is in litres
1) 22.4 lit 2) 11.207 3) 5.6 4) 44.828
19. 4 gm of hydrocarbon on complete combustion gave 12.571 gm of CO
2
and 5.143 grams of H
2
O. What is the
emperical formula of hydrocarbon
1) CH 2) CH
2
3) CH
3
4) C
2
H
3
20. A mixture of carbonates of two bivalent metals contains 13.6% of one metal. If 2.5 gm of the mixture liberates 1.33
gm of CO
2
. The % by weight of the other metal is
1) 13.6 2) 12.6 3) 13.84 4) 12.84
21. 1 gm of mixture of CaCO
3
and NaCl reacts completely with 120ml of N/10 HCl. The percentage of NaCl in the
mixture is
1) 40% 2) 50% 3) 60% 4) 66%
22. The sodium salt of an acid dye contains 7% of sodium. What is the minimum molar mass of the dye
1) 336.5 2) 286.5 3) 300.6 4) 306.5
23. One gram of Na
3
AsO
4
is boiled with excess of solid KI in presence of strong HCl. The iodine evolved is absorbed
in kI solution and titrated against 0.2 N hypo solution.
AsO
4
-3
+2H
+
+2I
-

AsO
3
-3
+H
2
O+I
2
Calculate the volume of thiosulphate consumed Aw of As =75
1) 48.1 ml 2) 38.4 ml 3) 24.7 ml 4) 30.3 ml
24. Mixture X=0.02 mol of [CO(NH
3
)
5
SO
4
]Br and 0.02 mol [CO(NH
3
)
5
Br]SO
4
was prepared in 2 lit of solution
1 lit of mixture X +excess AgNO
3
=y
1 lit of mixture X +excess BaCl
2
=z
No. of moles y and z are
1) 0.01, 0.01 2) 0.02, 0.01 3) 0.01, 0.02 4) 0.02, 0.02
25. Assertion (A) : Oxidation number of carbon in CH
2
O is zero
Reason (R) : CH
2
O is formaldehyde. It is a covalent compound
1) Both A and R are correct and R is correct explanation of A
2) Both A and R are correct and R is not correct explanation of A
3) A is true but R is false 4) A is false but R is true
3 Pathi * 31-08-06
26. Assertion (A) : White P reacts with NaOH, the products are PH
3
. NaH
2
PO
2
. The reaction is an example of
disproportionation reaction
Reason (R) : In disproportionation reaction one substance acts as oxidising and reducing agent
1) Both A and R are correct and R is correct explanation of A
2) Both A and R are correct and R is not correct explanation of A
3) A is true but R is false 4) A is false but R is true
27. Assertion (A) : HNO
2
acts as an oxidising as well as reducing agent.
Reason (R) : The oxidation number of nitrogen remains same
1) Both A and R are correct and R is correct explanation of A
2) Both A and R are correct and R is not correct explanation of A
3) A is true but R is false 4) A is false but R is true
29. For the reaction H
3
PO
4
+Ca(OH)
2

CaHPO4+2H
2
O
1 mole 1 mole
The statements are
I) equivalent weight of H
3
PO
4
is 49
II) the resulting mixture neutralizes by1 mole KOH
III) CaHPO
4
is acidic salt
Correct set is
1) I, II 2) II, III 3) I, III 4) I, II, III
30. Study the following table
Compound Weights compound taken
I) CO
2
(44) 4.4 gm
II) NO
2
(46) 2.3 gm
III) H
2
O
2
(34) 6.8 gm
IV) SO
2
(64) 1.6 gm
Which two compounds have least weight of oxygen
1) II, IV 2) I & III 3) I & II 4) III & IV
31. When ammonium nitrate is gently heated, an oxide of nitrogen is formed. What is the oxidation state of nitrogen in this
oxide
1) +4 2) +5 3) +2 4) +1
32. Two grams of sulphur is completely burnt in oxygen to form SO
2
. In this reaction what is the volume (in litres) of
oxygen consumed at STP
1)
16
22.4
2)
22.4
16
3)
22.4
32
4)
32
22.4
33. A self contained breathing apparatus uses KO
2
, to convert the CO
2
and H
2
O in exhailed air into oxygen, as shown by
the equation
4KO
2
+2H
2
O+4CO
2

4KHCO
3
+3O
2
How many molecules of oxygen gas will be produced from 0.0468 gm of CO
2
that is exhaled in a typical breath
1) 4.8 x 10
20
2) 6.4 x 10
20
3) 8.5 x 10
20
4) 1.9x 10
20
34.
3 2
6 3 H X Cl H O ClO
- + -
+ + + The value of X is
1)
4e
-
2)
5e
-
3)
6e
-
4)
7e
-
35. When thiosulphate ion is oxidised by iodine, which one of the following ion is produced
1)
2
3
SO
-
2)
2
4
SO
-
3)
2
4 6
S O
-
4)
2
2 6
S O
-
4 Pathi * 31-08-06
36. The oxidation number of carbon in CH
2
O is
1) -2 2) +2 3) 0 4) +4
37. If three electrons are lost by a ion M
+3
. Its final oxidation number would be
1) 0 2) +2 3) +5 4) +6
38. Oxidation number of phosphorous in Mg
2
P
2
O
7
is
1) +1 2) +3 3) +5 4) +7
39. Which one shows +6 oxidation state
1)
4
MnO
-
2)
2
6
( ) Cr CN
-
3)
2
6
NiF
-
4) CrO
2
Cl
2
40. The oxidation number of sulphur in S
8
, S
2
F
2
and H
2
S respectively are
1) 0, +1, -2 2) +2, +1, -2 3) 0, +1, +2 4) -2, +1, -2
41. Sulphuryl chloride SO
2
Cl
2
reacts with water to give a mixture of H
2
SO
4
and HCl. No. of moles of Al(OH)
3
required
to neutralise the solution formed by adding 3 mol of SO
2
Cl
2
to excess water
1) 2 2) 4 3) 6 4) 3
42. 10 ml of H
2
O
2
solution (volume strength =x) required to 10 ml of
4
0.56
N
KMnO
solution in acidic medium. Hence x
is
1) 0.1 2) 10 3) 100 4) 0.01
43. Mass of KHC
2
O
4
required to reduces 100 ml of 0.2 N KMnO
4
in acidic medium is X gm and to neutralise 50 ml of
0.04 M Ca(OH)
2
is Y gm then
1) 5x =2y 2) 5x =y 3) 2x =5y 4) 5y =x
44. In the mixture of (NaHCO
3
+Na
2
CO
3
) in 1 : 1 molar ratio vol of HCl required is x ml with methyl orange and y ml
with phenolphthalein indicator in same titration. The relation between x and y is
1) x =3y 2) y =3x 3) x =6y 4) y =6x
45. In the mixture of NaHCO
3
and Na
2
CO
3
volume of a given HCl required is x ml with phenolphthalein indicator and
further y ml required with methyl orange indicator. Hence volume of HCl for complete reaction of NaHCO
3
is
1) y - x 2) x - y 3) 2y - x 4) 2x - y
46. When one gram mol of KMnO
4
reacts with HCl, the volume of chlorine liberated at NTP will be
1) 11.2 lit 2) 22.4 lit 3) 44.8 lit 4) 56 lit
47. 3.18 gr. of pure Cu heated in a steam of oxygen for some time gain weight with the formation of CuO. The final weigth
is 3.92. What percent of copper remains unoxidised
1)

6.5 2)

6.9 3)

7.6 4)

7.9
48. 0.5 gr of fuming H
2
SO
4
(oleum) is diluted with water. This solution is completely neutralised by 26.7 ml of 0.4 N
NaOH. The percentage of free SO
3
in the sample is
1) 30.6% 2) 40.6% 3) 20.6% 4) 10.6%
49. In an experiment 50 ml of 0.1 M solution of a metallic salt reacted exactly with 25 ml of 0.1M solution of Na
2
SO
3
.
In reaction
2
3
SO
-
is oxidisedd to
2
4
SO
-
. The original oxidation number of metal in the salt is +2. What would be
thenew oxidation number of the metal
1) 0 2) 2 3) 4 4) 1
50. On heating H
2
O
2
decomposes to give oxygen. Under these conditions 1 mol gas occupies 24 lit. 100 ml of X M H
2
O
2
produces 3 lit of O
2
. The value of X is
1) 0.125 2) 1.25 3) 2.5 4) 0.25
51. One mole of a mixture of CO and CO
2
requires exactly 20 gm NaOH in the solution for complete conversion of all
CO
2
into Na
2
CO
3
. Remaining gas was oxidised into CO
2
. How many of gram of NaOH required to convert into
5 Pathi * 31-08-06
Na
2
CO
3
1) 40 2) 20 3) 60 4) 80
52. The no. of moles of KMnO
4
that will be needed to react completely with 1 mole ferrous oxalate in acidic solution is
1) 2/5 2) 3/5 3) 4/5 4) 1/5
53. Oxalic acid reacts with concentrated H
2
SO
4
to give a mixture of two gases. When this mixture is passed through
caustic potash, one of the gases is absorbed. What is the product formed by the absorbed gas with caustic potash
1) K
2
SO
4
2) K
2
HCO
3
3) K
2
CO
3
4) KOH
54. 0.078 grams of hydrocarbon occupy 22.414 ml volume at STP. The empirical formula is CH. The molecular formula
is
1) C
2
H
2
2) C
6
H
6
3) C
8
H
8
4) C
4
H
4
PROBLEMS
PART - A
1. One gram of mixture of Na
2
CO
3
and NaHCO
3
was treated with excess of dilute HCl. The volume of CO
2
evolved
was found to be 240cc at 27C and 778.5mm pressure. Calculate the percentage composition of the mixture.
2. 25 ml of a solution containing 0.2 g of impure sample of H
2
O
2
reacts with 0.316 gm KMnO
4
in presence of H
2
SO
4
.
(i) Find out purity of H
2
O
2
(ii) Calculate the volume of dry oxygen evolved at 27C and 750 mm mercury pressure.
[Ans : 124.7 ml]
3. 15 cc of a gaseous sample believed to contain ethylene (C
2
H
4
) and acetylene (C
2
H
2
) require 45cc of oxygen for
complete combustion. Determine the percentage composition of the mixture.
[Ans : 0 ml]
4. Find out the volume in ml of 0.1 N HCl required to react completely with 1g mixture of sodium bicarbonate and
sodium carbonate containing equimolecular amounts of the two compounds.
5. Two elements P and Q form two compounds P
2
Q
3
and PQ
2
. If 0.3 moles of P
2
Q
3
weight 31.8 g and as many moles
of PQ
2
weight 18.6g, what are the atomic weights of P and Q.
[Ans : P =26 and Q =18]
6. Calculate the equivalent weights of each oxidant and reductant in
a) FeSO
4
+KClO
3
KCl +Fe
2
(SO
4
)
\3
Ans : Eq. wt. of FeSO
4
=152, Eq. wt. of KClO
3
=20.42.
b) Na
2
SO
3
+Na
2
CrO
4
Na
2
SO
4
+Cr(OH)
3
Ans : Eq. wt of Na
2
SO
3
=63, Eq. wt. of Na
2
CrO
4
=54
c) Fe
3
O
4
+KMnO
4
Fe
2
O
3
+MnO
2
[Ans : Eq.wt of Fe
3
O
4
=232, Eq. wt of KMnO
4
=52.67]
7. 5.5 g of a mixturee of FeSO
4
7H
2
O and Fe
2
(SO
4
)
3
9H
2
O required 5.4 ml of 0.1 N KMnO
4
solution for complete
oxidation. Calculate moles of hydrted ferric sulphate in mixture.
[Ans :
3
9.5 10 moles
-
]
8. In an ore, the only oxidizable material is Sn
+2
. This ore is titrated with a dichoromate solution containing 2.5 g of
K
2
Cr
2
O
7
in 0.5 litre. A 0.40 g sample of the ore required 10.0 cm
3
of titrant to reach equivalence point. Calculate the
percentage of tin in ore.
[Ans : 15%]
9. An element A in a compound ABD has an oxidation no A - n. It is oxidised by Cr
2
O
7
-2
in acid medium. In an
experiment
3
1.68 10
-

mole of K
2
Cr
2
O
7
was required for
3
3.36 10
-

mole of the compound ABD. Calculate new

oxidation state of A.
[Ans : 3 - n]
10. 4.215 gm of a metallic carbonate was heated and then CO
2
evolved was found to measure 1336 ml at 27C and 700
6 Pathi * 31-08-06
mm pressure. What is equivalent weight of metal.
[Ans : 12, 15]
11. 50 ml of an aqueos solution of H
2
O
2
was treated with an excess of KI solution in dil. H
2
SO
4
the liberated iodine
required 20 ml of 0.1 N Na
2
S
2
O
3
solution for complete reaction. Calculate concentration of H
2
O
2
in g/litre.
[Ans :
1
0.68glit
-
]
12. 25 ml of H
2
O
2
solution were added to excess of acidified solution of KI. The iodine so liberated required 20 ml of 0.1
N Na
2
S
2
O
3
for titration. Calculate the strength of H
2
O
2
in terms of noramlity percentage and volume.
[Ans : 0.448 volume]
13. KMnO
4
oxidises
+n
X
ion to
3
XO
-
itself changing to Mn
+2
in acid solution.
3
2.68 10
-

moles of
+n
X
requires
3
1.61 10
-

moles of
4
MnO
-
. What is the value of n ? Also calculate the atomic mass of X, if the weight of 1g
equivalent of
n
XCl is 56.
[Ans : 97]
14. 1g sample of AgNO
3
is dissolved in 50 ml of water.It is titrated with 50 ml of KI solution. The AgI precipitated is
filtered off. Excess of KI in filtrate is titrated wit M/10 KIO
3
in presence of 6M HCl till
I
-
converted to ICl. It
required 50 ml of M/10 KIO
3
solution. 20 ml of the same stock solution of KI requires 30 ml of M/10 KIO
3
under
similar conditions. Calculate % of AgNO
3
in sample.
The reaction is KIO
3
+2KI +6HCl 3ICl +3KCl +3H
2
O.
[Ans : 85%]
15. A sample of MnSO
4
4H
2
O is strongly heated in air. The residue (Mn
3
O
4
) left was dissolved in 100 ml of 0.1 N
FeSO
4
containing dil. H
2
SO
4
. This solution was completely reacted with 50 ml of KMnO
4
solution. 25 ml of this
KMnO
4
solution was completely reduced by 30 ml of 0.1 N FesO
4
solution. Calculate the amount of MnSO
4
4H
2
O
in sample.
16. The gases produced whe 18 gm carbon reacts with 5 litres of oxygen gas at 18C and 5 atm pressure are treated with
0.5 litres of 2M NaOH. Calculate the concentration of Na
2
CO
3
, NaHCO
3
produced by the reaction of CO
2
with
NaOH. CO has no reactions under these condition.
[Ans : Na
2
CO
3
=0.816M, NaHCO
3
=0.36 M]
17. A 20.0 g of mixture Cu
2
S and CuS was treated with 400 cm
3
of 0.75 M KMnO
4
solution in acidic medium, producing
SO
2
, Cu
2+
and Mn
2+
.The SO
2
was boiled off and the excess
4
MnO
-
was titrated against 1.0 M Fe
2+
solution. The
volume consumed of the latter was found to be 350 cm
3
. Compute the percent of Cu
2
S in the original mixture.
[Ans : 42.1%]
18. 30 ml of a solution containing 9.15 g/litre of an oxalate K
x
H
y
(C
2
O
4
)
z
nH
2
O are required for titrating 27 ml of 0.12N
NaOH and 36 ml of 0.12 N KMnO
4
separately. Calculate x, y, z and n. Assume all H atoms are replaceable and x,
y, z are in the simple ratio of g atoms.
[Ans : KH
3
(C
2
O
4
)
2
. 2H
2
O]
19. 25 ml of a solution of Ferric alum Fe
2
(SO
4
)
3
. (NH
4
)
2
SO
4
. 24H
2
O containing 1.25 g of the salt was boiled with iron
when the reaction Fe +Fe
2
(SO
4
)
3
3FeSO
4
occured. The unreacted iron was filtered off and solution treated
with 0.107 N KMnO
4
in acid medium. What is titre value ? If Cu had been used in place of Fe, what would have been
titre value.
[Ans: 36.36 ml, 24.2 ml]
20. 0.5 g mixture of K
2
Cr
2
O
7
and KMnO
4
was treated with excess of KI in acidic medium. Iodine liberated required 100
cm
3
of 0.15N sodium thiosulphate solution for titration. Find the percent amout of each in the mixture.
[Ans : 14.6%, 85.4%]
21. An aqueous solution containing 0.1 gm KIO
3
(M wt =214) was treated with excess KI solution. The solution was
acidfied with HCl. The liberated I
2
consumed 45 ml of thiosulphuric solution. Calculate the molarity of thiosulphate
solution.
[Ans : 0.062 M]
7 Pathi * 31-08-06
22. 25.0 cm
3
of a solution containing Na
2
CO
3
and NaOH required 10 cm
3
of 1.0 M H
2
SO
4
for neutralization when
phenolphthalein was used as the indicator. Whereas when methyl orange was used, it required 15 cm
3
of the same
acid for neutralization. Calculate the masses of Na
2
CO
3
and NaOH per lit of the solution.
[Ans : 42.4g, 16.0 g]
23. A solution contains Na
2
CO
3
and NaHCO
3
. Twenty cm
3
of this solution requires 5.0 cm
3
of 0.1 M H
2
SO
4
solution for
neutralization using phenolphthalein as the indicator. Methyl orange is then added when a further 5.0 cm
3
of 0.2 M
H
2
SO
4
was required. Calculate the masses of Na
2
CO
3
and NaHCO
3
in one litre of this solution.
[Ans : 5.3 g, 4.2 g]