KIM TRA GIA K MN HA PHN TCH 1 (2011-2012)

THI GIAN: 45 PHT.

Cu 1(6): Thm t t n ht 50,0 mL dung dch KOH 0,015M vo 100,0 mL dung dch A cha HCl
0,0015M v H2S bo ha (0,100M).
a. Xc nh thnh phn gii hn ca dung dch.
b. Tnh nng cc cu t ti thi im cn bng trong dung dch thu c.
c. Tnh th tch dung dch KOH 0,01 M cn thm vo 100,0 mL dung dch A thu c dung
dch c pH = 7,0.
Cu 2 (4): Tnh hng s bn iu kin ca phc NiY 2- trong dung dch m NH3 1M + NH4Cl
1,738M. Bit nng ban u ca Ni2+ nh hn rt nhiu so vi nng ban u ca NH3.
Cc hng s:
H2S: pKa1 = 7,0; pKa2 = 12,92. NH4+: pKa = 9,24.
H4Y: pKa1-4 = 2,0; 2,67; 6,27; 10,95.
lg NiY 2 18, 62 . lgNi(NH3)1-5 = 2,67; 4,80; 6,40; 7,50; 8,10.