Tổng Quan Về Nhà Máy Đạm Phú Mỹ

TNG CNG TY DU KH VIT NAM
CNG TY PHN M V HO CHT DU KH

NH MY M PH M
NHIT LIT CHO MNG QU V

N THM NH MY M PH M
www.congnghedaukhi.com - 2008
TNG QUAN V NH MY M PH M
Ch u t: Tng cng ty Du kh Vit Nam

Nh thu: Technip - Italia v
Samsung Enginering - Hn quc
Tng vn u t :
450 triu USD
Cng ngh:
an mch v Italia
CC MC QUAN TRNG
Khi cng xy dng nh my:

3/2001
Ngy nhn kh vo nh my:
24/12/2003
Ngy ra sn phm ammonia u tin: 4/2004
Ngy ra sn phm ur u tin:
4/06/2004
Ngy bn giao sn xut cho ch u t:
21/9/2004
Ngy khnh thnh nh my:
15/12/2004
TNG CNG TY DU KH VIT NAM

CNG TY PHN M V HO CHT DU KH
NH MY M PH M
A CH: Khu cng nghip Ph M I, Huyn Tn Thnh, Tnh B Ra, Vng Tu
NGUYN LIU DNG TRONG NH MY
NGUYN LIU CHNH DNG CHO NH MY

Kh thin nhin: CH4, C2H6, C3H8, C4H10
Kh ng hnh m Bch H, Kh thin nhin t bn
trng Nam Cn Sn v cc b khc thuc thm lc
a pha Nam.
Lng kh tiu th: 450 x 106 Nm3/nm.
c tnh v thnh phn kh:
Nhit : 18-36 0C.
p sut: 40 Bar
Trng lng phn t: 18,68 g/mol
Nhit tr: 42,85 MJ/m3 hay 40613,4 BTU/m3
Thnh phn: C1=83,31%. C2=14,56%. C3=1,59%.
iC4=0,107%. nC4=0,109%.
CC LOI HO CHT DNG TRONG NH MY

TT
HO CHT
MC CH S DNG
Dung dch MDEA
KH CO2
Dung dch antiform
Kim sot lng bt
N2 ( mua b xung)
Trao i, bt kn
xygen Scavenger
Loa b oxy, th ng ho kim loi
Axit Sulfuaric (H2SO4 98 %)
Ti sinh nha, b xung dung dch ccbamat
NaOH
Ti sinh nha
Tc nhn c ch n mn MD4100
c ch n mn
Cht chng cu cn Atiscaling
chng cu cn trong nc lm mt
Nha trao i ion
Kh khong nc
10
Dung dch Photphat Natri
iu chnh pH
11
Tc nhn kim ho (Alkalin NA 880

hoc Triact 1800)
Kim ho v c ch n mn
12
Javen
Dit khun trong qu trnh x l nc th v nc

sng lm mt
S 1: S CNG NGH CA NH MY
in
Nc tun hon
Sng
Th
Vi
Nc
lm mt
Nc thi
Kh CO2
Xng ph tr
Hi nc
Xng
Amnic
Amnic
Hi nc
Xng
Ur
Ur ht
2200 t/ngy
Xng
sn phm
Nc lm mt
Kh t nhin
Ur thnh
phm
SN PHM CHNH CA NH MY
NH3: 1,350 tn NH3 /ngy (Cng ngh Haldor Topsoe - an mch)
UREA: 2,200 tn Urea /ngy (Cng ngh SnamProgetti - Italia)
IN: 21MWh
XNG TNG HP AMONIA

(CNG SUT 1350 T/NGY, CNG NGH HALDOR TOPSOE)
S 2: DY CHUYN SN XUT AMNIC
Khng kh ( t)
CO2 i tng hp Ur
( 1600 t/ngy)
Hi nc
Kh t
nhin
Kh Lu
hunh
Reforming
Chuyn ha
Kh CO2
CO
Mtan ha
Tng hp
Amnic
Amnic
thnh phm
1350 t/ngy
S 3: CNG ON KH LU HUNH
Kh t nhin
Thp Hyr
ha
Thp hp
th Lu
hunh
10-R-2002
A/B
10-R-2001
Kh sch ti l
Reforming
Phng trnh phn ng trong 10-R-2001:

R-S-H + H2
t = 380 o C
Xt : Co-Molipden
RH + H2S
Phng trnh phn ng trong 10-R-2002 A/B:

ZnO + H2S
t = 400 o C
ZnS + H2O
S 4: CNG ON REFORMING
Kh nhin liu (Kh t)
Hi nc
Kh cng ngh
Khng kh
L
Reforming
s cp
L
Reforming
th cp
10-H-2001
10-R-2003
Chuyn ha CO
Phng trnh phn ng trong 10-H-2001:

CH4 + 2H2O
CnH2n+2 + 2H2O
t = 650/780 o C
Xt : Ni-Mg
CO2 + 4H2 - Q
Cn-1H2n + CO2 + 3H2 Q
Phn ng ph :
CO2 + H2
CO + H2O - Q
t=oC
to / Xt
Phng trnh phn ng trong 10-R-2003 :

CH4 + 2O2
CO2 + 2H2O
t
( Khng
kh c 21%
O2 v- 2008
79% N2 )
www.congnghedaukhi.com
Kh Reforming
Thp chuyn
ha CO nhit
cao
Thp chuyn
ha CO nhit
thp
10-R-2004
10-R-2005
Kh chuyn ho
Phng trnh phn ng 10-R-2004 :

CO + H2O
t = 360 430 o C
Xt : Fe, Cr, Cu
CO2 + H2 + Q
Phng trnh 10-R-2005 ging nh trn.

Nhit 195 220 oC
Xc tc Cu, Zn, Al
S 5: CNG ON CHUYN HA CO THNH CO2 v H2

S 6: CNG ON KH CO2
Cc phn ng kh CO2 bng dung dch MDEA:
R3N + H2O + CO2 = R3NH+ + HCO32R2NH + CO2 = R2NH2+ + R2N COO-
D.D DMEA
Kh c
kh CO2
Thp
hp
th
CO2
Kh CO2 thun i
tng hp URE
Thp
ti sinh
CO2
Kh chuyn ho
Qa trnh hp th CO2 c thc hin iu kin nhit 45oC v p sut 27 bar

Qu trnh ti sinh c thc hin iu kin nhit 90oC v p sut 0,34 bar
Kh loi CO2
Kh i tng hp
Amnic
Thp Mtan
ha
Thp tch
kh ln cui
10-R-3001
10-V-3001
Condensate

CO + 3H2
CO2 + 4H2
t = 300 320 o C , 27 bar

Xt :Ni, Cr, Zn
t = 300 320 o C
Xt : Cr, Cu, Zn
CH4 + H2O + Q
CH4+ + H2O + Q
S 7: CNG ON MTAN HA
Thp gia
nhit.
10-H-5001
Thp
tng hp
Amnic
10-R-5001
Bn tch
lng/hi
Bn cha
Amnic
10-V-5002

N2 + 3H2
t = 360 450 o C
Xt : Fe, Ca, K/ Al
Amnic i
tng hp Ur
2NH3 + Q
T l phn ng :
1:3 , P=137 atm
Hiu sut p/ :
25%
S 8: CNG
ON TNG HP AMNIC
BN CHA AMONIA LNG

DUNG TCH 30.000 m3, NHT LM VIC -330C, P SUT 0,1 Bar
XNG TNG HP URE

Cng sut: 2200 tn ure/ngy
Cht lng: - Hm lng N2: 46,3 %
- C ht 1,4 - 2,8mm: > 95 %
- m: < 0,4 %
- Hm lng Biuret: < 1 %
CO2
NH3, CO2
Amnic
Tng hp
cao p
31%NH3; 14,6%CO2:
20% H2O; 34% ure
Hi nc
Phn hy
trung p
Phn hy
thp p (4
(19,5 bar)
bar)
DD Ure 6063% KL
DD ure 6971% KL
C c
chn
khng
Thp to
ht
(Kt tinh
132 oC)
Xng
ng bao
DD ure
99,75% KL
Phng trnh phn ng tng hp ure:

2NH3 + CO2
t = 188 o C
NH2COONH4+ Q
(1)
(Cacbamat)
Phng trnh phn ng phn hy Cacbamat:
P = 157 atm
NH2COONH4
t = 188 o C
P = 157 atm
NH2COONH4 + H2O
NH2CONH2 + H2O - Q (2)

(Ur)
t = 160 150 o C
P = 19 5 atm
2NH3 + CO2 - Q (3)
Phn ng hnh thnh Biuret:

2NH2CONH2
NH2CONHCONH2 + NH3 (4)
CNG NGH TNG HP UR
S 9: S
SN PHM UREA
Urea:
- Cng sut: 2200 tn / ngy

- C ht 1,4-2,8mm: > 95 %
- Hm lng N2 > 46,3 %
- m: < 0,4 %
- Hm lng Biuret: < 1%
XNG SN PHM
Nh kho Ur ri:
Dung lng cha: 150.000 Tn
Nhit kho: T ng iu chnh trnh kt tng Ur
Nh ng bao Ur:
Dung lng cha: 15.000 tn
S dy chuyn ng bao: 06, trong 1 dy xut t ng ra
xe
Cng sut ng bao: 4800 Tn/Ngy
XNG PH TR
H thng lm lnh nc tun hon: Cng sut: 36000 m3/h
H thng nc kh khong: Cng sut: 150 m3/h
H thng sn xut N2: Cng sut: 190 Nm3 kh N2 + 50 lt N2
lng/h
H thng x l nc thi gm:
H thng x l nc nhim du: 20 m3/h
H thng x l nc nhim NH3: 5 m3/h
H thng x l nc sinh hot: 50 m3/ngy
T hp tuabin kh:
My pht in (Gastubine): 21MW/h
H thng sn xut hi nc 40 bar: 40 v 140 t/h
My pht in (iezen) d phng: 650 v 450 kw
Trm bm nc sng lm mt: 2 bm, 4100 m3/h.
Nhit nc vo thp lm lnh 39-40oC.

Nhit nc sau lm lnh: 30-34 oC
GII THIU V CNG TC QUN L MI TRNG

I.CC NGUN CHT THI C TRONG NH MY
vCht thi rn: rc thi sinh hot, ph liu pht

sinh trong qu trnh bo dng, cc loi xc tc
rn ht hiu lc s dng.
vCht thi lng: cc dng cht thi cha ho
cht, du, nc thi sinh hot, nc lm mt.
vCht thi kh: kh thi t Gasturbine, l hi ph
tr, h thng Primary refomer, nh thp to ht
v h thng uc t
CHT THI RN
V CC BIN PHP X L
Khi lng cht thi rn: khong 730 tn/nm.
Thnh phn cht thi rn:
- Rc thi sinh hot v c cy kh: chim lng ln c
thu gom vn chuyn bi Cng ty v sinh th huyn
Tn Thnh.
- Cc ph liu pht sinh trong qu trnh bo dng:
(khng ng k) phoi tin, st thp vn, gi lau khng
i hi x l c bit s c phn loi, thu gom, vn
chuyn v tha b bi Cng ty v sinh th Huyn Tn
Thnh.
- Cht xc tc v cc rc thi c hi khng cn hiu qu
s dng s c thu gom ring v hp ng vi Cng
ty chuyn mn x l,(mi thay 50 tn).
LNG NC S DNG
V NGUN CUNG CP NC
1.
Nc ngt c cung cp bi cng ty cp nc tnh

B Ra-Vng Tu. Nhu cu s dng ca nh my 150
m3/h; Trong 120 m3/h c s l dng cho sn
xut hi nc, 30 m3/h c s l dng cho sinh
hot v cc hng nc ra trong nh my.
2 Nc sng Th Vi dng b sung cho h thng nc
lm mt 2000 m3/h, nc sng nhn vo nh my
c b sung cht ng cn, cht dit khun v c
s dng vo cc thit b trao i nhit trong dy
chuyn sn xut sau c tun hon lm lnh
s dng li v mt phn c thi b.
LNG NC THI
V NGUN TIP NHN NC THI
1.
2.
3.
4.
Lng nc lm mt thi: 1700 m3/h. Nc lm mt ch dng

cho cc thit b trao i nhit gin tip nn khng b nhim ho
cht. Do vy nc c thi qua ng thi chung ca khu cng
nghip in-m ra sng Th Vi.
Lng nc thi nhim du: 20 m3/h. Nc nhim du ch yu
c pht sinh t cc cm my nn, c thu gom vo h thng
rnh v ng ring dn v h thng x l nc nhim du, nc
sau khi x l c thi qua h thng thi chung.
Lng nc thi sinh hot: 50 m3/ngy, c thu gom t cc b
pht vo ng ng ring dn v h thng x l nc sinh hot,
nc sau khi x l c thi ra h thng thi chung.
Thi nc ma: nc ma c thu gom t cc rnh trong nh
my c chy qua 2 cng ti cng s 2 vo ng thi nc
ma chung ca khu cng nghip ra sng Th Vi.
PH BO V MI TRNG
I VI NC THI NP
- S ph k khai phi np hng thng: 2.116.905 ng.

- Thi gian bt u phi np ph nc thi: t thng
10/2004.
- S ph np theo yu cu ca s TNMT tnh BR-VT
(Qu IV/2004 v thng 1,2/2005) l: 19.052.145 ng.
CC BIN PHP BO V MI TRNG
I.
X L CHT THI
-
H thng x l nc nhim du: 20 m3/h

H thng x l nc sinh hot: 50 m3/ngy.
H thng x l nc nhim NH3.
Thu gom x l cht thi rn
II. GIM ST MI TRNG

III. KIM TRA, BO DNG, HIU CHUN
THIT B, KIM NH, PHNG NGA V
X L KP THI CC IM R R HO
CHT C, D CHY N.
HE THONG X LY NC NHIEM DAU

Du
Nc
nhim
du
B tch du
bng trng lc
V1
Bm
du
B cha du
BA3
Du
TB ng t
V2
Nc
Bm nc thi
B cha nc
tch du
s b- BA1
TB tuyn
ni=KK
Z5
Thng
cha du
Thng
cha du
Cht ph nh
TB tch
du
CPI-V4
(Tm thp)
Bn cha
cui TK5
Cht keo t
Bn trn
nhanh - TK3
B lc a
chc nng
V6
Bn keo t
TK4
B lc
than hot
tnh V7
Nc a x ly
Tng du
max < 5mg/l
H THNG X L NC NHIM DU
H THNG X L NC NHIM DU
HE THONG X L NC THI SINH HOT
Nc thi
sinh hot
B cn bng
BA1
Lc rc Z1
B oxy ho
BA2 A/B
B phn
hu vi sinh
BA6 A/B
Bm x
bn
bn
B lng
BA3 A/B
Nc
Bun
B n nh
bn
BA4
Bn d
Natri hypoclorua
Nc x l
B clo hoa
BA5
TB lc
FL1
B nc lc
BA7
B nc sch
BA8
H THNG X L NC THI SINH HOT
3. X L NC NHIM AMONIAC
(H thng c)
uc t
B cn bng
ca thp
lm mt
Nc nhim
NH3
B cn bng
TB trao i nhit
B CHA V THP CHNG

X L NC NHIM AMONIAC
CC NGUN KH THI
KH THI T XNG NH3 V PH TR
ng khi
Refomer
10-SK-2001
ng khi Gastur
10-B-9001
ng khi Boiler
10-B-8001
221.080
346.200
45.080
Nhit (oC)
162
236
151
Thnh phn
(mg/Nm3)
- xy
- CO
- SOx
- NOx
- Bi
3%
max 150
max 250
-
15 %
max 150
max 103
8,0
3%
max 150
max 250
-
Thng s
Lu lng
(Nm3/h)
TCVN
6991:2001
150
150
300
400 **
**(TCVN 59391995)
KH THI T XNG URE

(TI NH THP TO HT V UC T 20-PK-1001)
TT
1
Danh mc
Khng kh x t nh thp
to ht:
- Lu lng (Nm3/h)
- Nhit (oC)
- Bi Ure (mg/Nm3)
- NH3 (mg/Nm3)
Kh thi t uc t:
- Lu lng (Nm3/h)
- NO2 (mg/m3)
- NH3 (mg/m3)
Ch tiu
760.000
45
35
30
700
42
Max 60
Tiu chun
50 (TC NHTG)
30 (TCVN 69912001)
(KCN=0,6; Kv=1
Q< 5000 m3/h)
600
60
BIN PHP GIM THIU NHIM KHNG KH

H THNG THU GOM V X L KH THI
Cc kh thi t nh my d t tiu chun c php thi ra mi trng (theo
TCVN 6991-2001), nhng vn cha nng cc cht nhim cao hn so vi tiu
chun cht lng KK xung quanh. Do , trong nh my lp t cc ng khi
c cao kh thi pht tn ti mt t t tiu chun KK xung quanh.
TT
K hiu
Tn ng thi
Chiu cao
10-SK-2001
ng khi TB Reforming th cp
40 m
10-B-8001
ng khi ni hi ph tr
30 m
10-B-9001
ng khi my tuc bin kh
30 m
20-Z-1008
uc t thp to ht
110 m
40-PK-1001/1002
uc t kh tng hp / kh NH3
45 m
20-PK-1005
uc t thp p Xng Ure
110 m
NG KHI
H THNG UC T
H thng uc t kh tng
hp:
- Cng sut: 298,190 kg/h
H thng uc t amonic :
- Cng sut: 349,674 kg/h
H thng uc t: H thng
uc t s oxy ho cc kh
d chy, c v kh d n mn
thnh cc hp cht t c hi.
H thng bo m hiu sut
t chy cao v c cao
phn tn tt, gim nng
cc cht nhim.
CHNG TRNH GIM ST MI TRNG

GIM ST MI TRNG KHNG KH
Gim st bng 2 trm quan trc t ng t 2 v tr chin lc

trong nh my theo hng gi ch o. Cc d liu c truyn
v my tnh trung tm 15 pht/ln, Gm: bi, NH3, CO, NO2.
TT Tn v tr
Ch tiu gim st
Trm quan trc s 1 (40-EMS-1001) Bi, NH3, CO, NO2
Trm quan trc s 2 (40-EMS-1002) Bi, NH3, CO, NO2
QUAN TRC NGUN NC THI

(Phng KTCL n/m v TT QT-PTMT thc hin)
K hiu
V tr
Tn xut
Thng s
N1
Nc thi nhim du
40-KP-2001
2 ln/tun
pH, Hm lng du, nhit
N2
Nc thi sinh hot

40-PK-2002
2 ln/tun
pH, Nhit , COD, TSS, Clo.
N3
Nc lm mt thi
2 ln/tun
Nhit pH, TSS, TDS, COD, Tng

du, NH3, Clo, cng, c..
2 ln/tun
Nhit pH, TSS, TDS, COD, Tng

du, NH3, Clo, cng, c..
Nc sng Th vi ,
nc sinh hot vo
nh my.
Cht lng nc thi, 6 thng/ln (do Tt c cc ch tiu, do Trung tm

kh thi trong v ngoi TT QT-PTMT
phn tch v quan trc mi trng
n/m
tnh BR-VT
tnh BR-VT thc hin.
thc hin)
- 2008
KT QU PHN TCH NC SNG TH VI

(DO TRUNG TM QT-PTMT TNH BR-VT THC HIN NGY 14/3/2006)
.v
Nc sng
vo n/m
Nc sng
TV cch im
x 30m v
pha thng
lu
Nc sng TV
cch im x
30m v pha h
lu
Nc thi sau khi

lm mt
pH
mg/l
7.2
7.3
7.3
7.4
(6-8.5)
Cht rn l lng
(TSS)
mg/l
7.2
28
346
25
(100)
COD
mg/l
60.3
60.0
54
60.7
(100)
BOD5
mg/l
18.5
42
24.0
19.5
( 50)
Nit dng
Amoni
mg/l
3.52
3.09
3.38
0.70
( 1)
Tng Nit
mg/l
4.20
3.48
6.38
3.36
(60)
Tng pht pho
mg/l
0.18
0.16
0.77
0.22
Clorua
mg/l
16096
15954
16195
18536 (1000)
Tong Du
mg/l
< 0.3
0.5
0.8
1.2
430
(-)
Ch tiu
Tng Colifom
MPN/100ML
23
240 - 2008
(30)
(5000)
NHNG PHNG PHP BO V MI TRNG

KHC C P DNG TRONG NH MY
Trang b b phn cch m, gim thanh cho cc

thit b ng. Nhn vin lm vic cc khu vc
n cao c trang b bt tai chng n.
Trang b cc u d kh c, d chy n (34
ci), c nhn vin AT gim st lin tc 24/24h
bng my o xch tay Scut SCT 096-2560.
Trang b h thng iu khin ng ngt khn
cp, van x v uc t. Bo dng, hiu chun
kp thi cc thit b
Lp m cy xanh: >20% tng din tch nh
my.
Nh my c lc lng ng cu cc tnh hung
khn cp.
CHN THNH CM N

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TNG CNG TY DU KH VIT NAM

CNG TY PHN M V HO CHT DU KH

NHIT LIT CHO MNG QU V

Ch u t: Tng cng ty Du kh Vit Nam

Khi cng xy dng nh my:

Ngy khnh thnh nh my:

TNG CNG TY DU KH VIT NAM

NGUYN LIU DNG TRONG NH MY

NGUYN LIU CHNH DNG CHO NH MY

CC LOI HO CHT DNG TRONG NH MY

Dung dch MDEA

Dung dch antiform

Kim sot lng bt

Loa b oxy, th ng ho kim loi

Axit Sulfuaric (H2SO4 98 %)

Ti sinh nha, b xung dung dch ccbamat

Cht chng cu cn Atiscaling

Nha trao i ion

Dung dch Photphat Natri

Tc nhn kim ho (Alkalin NA 880

Dit khun trong qu trnh x l nc th v nc

XNG TNG HP AMONIA

S 2: DY CHUYN SN XUT AMNIC

Phng trnh phn ng trong 10-R-2001:

Phng trnh phn ng trong 10-R-2002 A/B:

Phng trnh phn ng trong 10-H-2001:

Cn-1H2n + CO2 + 3H2 Q

Phng trnh phn ng trong 10-R-2003 :

Phng trnh phn ng 10-R-2004 :

Phng trnh 10-R-2005 ging nh trn.

S 5: CNG ON CHUYN HA CO THNH CO2 v H2

Qa trnh hp th CO2 c thc hin iu kin nhit 45oC v p sut 27 bar

Phng trnh phn ng trong 10-R-3001:

t = 300 320 o C , 27 bar

Phng trnh phn ng trong 10-R-5001:

1:3 , P=137 atm

BN CHA AMONIA LNG

XNG TNG HP URE

Phng trnh phn ng tng hp ure:

NH2CONH2 + H2O - Q (2)

2NH3 + CO2 - Q (3)

Phn ng hnh thnh Biuret:

NH2CONHCONH2 + NH3 (4)

- Cng sut: 2200 tn / ngy

Nhit nc vo thp lm lnh 39-40oC.

GII THIU V CNG TC QUN L MI TRNG

vCht thi rn: rc thi sinh hot, ph liu pht

Nc ngt c cung cp bi cng ty cp nc tnh

Lng nc lm mt thi: 1700 m3/h. Nc lm mt ch dng

- S ph k khai phi np hng thng: 2.116.905 ng.

CC BIN PHP BO V MI TRNG

H thng x l nc nhim du: 20 m3/h

II. GIM ST MI TRNG

HE THONG X LY NC NHIEM DAU

HE THONG X L NC THI SINH HOT

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