MODUL BIMBINGAN EMaS 2007

Module 1

JABATAN PELAJARAN TERENGGANU

BIMBINGAN EMaS TAHUN 2007

CHEMISTRY
FORM 4

MODULE 1
THE STRUCTURE OF THE ATOM CHEMICAL FORMULAE AND EQUATIONS
PANEL EN. CHE MALEK HJ. MAMAT TN. HJ. JAAFAR BAJURI TN. HJ. WAN RUSLI WAN SULAIMAN EN. ZULKIFLI ABDULLAH PN. HJH. NOR PAIZAH HASSAN SBPI BATU RAKIT, KUALA TERENGGANU SM SAINS SULTAN MAHMUD, K. TRG SMKA SHEIKH ABD. MALEK, K. TRG SMKA TOK JIRING, KUALA TERENGGANU SM TEKNIK BESUT, BESUT

MODUL BIMBINGAN EMaS 2007

Module 1

SECTION A
1 Graph 1 shows the temperature against time of solid substance X when heated. Substance X is an organic compound and flammable.

Temperature / 0C

Q 80

P Time/s 30 360

GRAPH 1 (a) Draw a diagram of the set-up of the apparatus used to determine the melting point of substance X.

[ 2 marks] (b) (i) State the melting point of substance X .................................................................................................................................. [ 1 mark]

MODUL BIMBINGAN EMaS 2007

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(ii) What is the state of matter of substance X at : PQ : ................................................................................................................................ RS : ............................................................................................................................... [ 2 marks] (iii) Explain why the temperature remains constant from Q to R? ......................................................................................................................................... ......................................................................................................................................... [ 2 marks] (iv) State how the movement of substance X particles changes between R and S during heating. .. [ 1 mark] (c) If substance X cooled to the room temperature without stirring, draw the graph of temperature against time obtained.

[ 2 marks] (d) Predict the substance X ................................................................................................................................................ [ 1 mark]

MODUL BIMBINGAN EMaS 2007

Module 1

Lactic acid is an acid produced in milk by bacteria, causes a sour taste. Table 2 shows the percentage composition by mass of each element in lactic acid.

Element Carbon Hydrogen Oxygen

Percentage 40.00 6.67 53.33 TABLE 2

(a)

Based on the information above, calculate the empirical formula of lactic acid. [Relative atomic mass : H = 1 ; C = 12 ; O = 16 ]

[ 3 marks] (b) Relative molecular mass of lactic acid is 90. Determine the molecular formula of lactic acid.

[ 2 marks] (c) Calculate the number of hydrogen atom in 1 mol of lactic acid? [ NA = 6.02 10 23 ]

[ 1 mark] (d) Calculate the number of moles of 4.5 g lactic acid. [Relative atomic mass : H = 1 ; C = 12 ; O = 16 ]

[ 1 mark]

MODUL BIMBINGAN EMaS 2007

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(e)

Vinegar or ethanoic acid has a similar empirical formula with lactic acid. (i) Given that three molecules of ethanoic acid have the same mass as two molecules of lactic acid. What is the relative molecular mass of ethanoic acid?

[ 1 mark] (ii) Determine the molecular formula of ethanoic acid.

[ 2 marks]

Table 3 shows formula of four ions. Name of ions Formula of ions Silver ion Zinc ion Nitrate ion Chloride ion

Ag

Zn

2+

NO3-

Cl-

TABLE 3

(a) Write the formulae for each compound below : (i) (ii) (iii) (iv) Silver nitrate Zinc chloride Silver chloride Zinc nitrate : ....................................................................................................... : ....................................................................................................... : ....................................................................................................... : ....................................................................................................... [2 marks]

(b) When silver nitrate solution is added to zinc chloride solution, white precipitate, silver chloride and zinc nitrate solution are formed. (i) Identify the reactants and products of the reaction. Reactants : .................................................................................................................. Products : .................................................................................................................. [2 marks] (ii) Write the chemical equation for the reaction occurs in (b). ....................................................................................................................................... [1 mark]

MODUL BIMBINGAN EMaS 2007

Module 1

(c) The following equation shows the decomposition of silver nitrate by heat.

2AgNO3

2Ag + 2NO2

+ O2

If 85.0 g of silver nitrate is heated completely, calculate : (i) the mass of silver formed. [ Relative atomic mass : N =14; O = 16; Ag =108 ]

[ 3 marks] (ii) the volume of oxygen gas formed at room conditions. [ Molar volume : 24 dm3 at room conditions]

[ 2 marks]

MODUL BIMBINGAN EMaS 2007

Module 1

SECTION B
4 (a) Matter is made up of tiny and discrete particles. (i) What is meant by matter? [ 1 mark] (ii) State 3 types of particle that made up matter. [ 3 marks] (b) You are shopping at the 2 nd floor of the shopping mall. Suddenly you smell the delicious aroma of cookies being bake. When you look down, there is the Famous Amos Cookies stall on the first floor. Based on the above situation, explain what happen refering to the kinetic theory of matter. [ 2 marks] (c) (i) Describe the experiment to determine the freezing point or the melting point of naphthalene (ii) Draw a labelled diagram of the experiment. [ 14 marks]

(a) What is meant by the empirical formula ? [ 1 mark] (b) The colour of oxide M is green Metal M is grey Oxide M can be reduced to metal M when heated with hydrogen.

(i)

Draw the labelled diagram of the experiment.

(ii) Describe the experiment conducted to determine the empirical formula of oxide M. State the observation and precuationary steps taken in your experiment. Also show all the calculation steps to get the empirical formula. (iii) Write the chemical equation of the reaction. [ Relative atomic mass : O = 16 ; metal M = 24 ] [ 16 marks] (c) The empirical formula of oxide M cannot be determine by heating oxide M with magnesium. Explain why? [ 3 marks]

MODUL BIMBINGAN EMaS 2007

Module 1

SECTION C
[ PAPER 3 ] 6 A student carried out an experiment to determine the empirical formula of magnesium oxide. Set-up of apparatus of the experiment are shown in Figure 6. Step Set-up of apparatus
Lid

Crucible

1
Digital balance

31.1745 g

Lid

Crucible

Magnesium ribbon Digital balance

33.5744 g

lid

Crucible

White magnesium oxide powder

3
Digital balance

35.1744 g

FIGURE 6 (a) State one observation and its related inference in the experiment [ 3 marks]

MODUL BIMBINGAN EMaS 2007

Module 1

(b)

Record the reading to two decimal places for : The mass of crucible and lid = g g ... g [ 3 marks]

The mass of crucible, lid and magnesium ribbon = The mass of crucible, lid and magnesium oxide =

(c)

(i)

Calculate the mass of magnesium that has been used

[ 3 marks] (ii) Calculate the mass of oxygen which reacted with magnesium

[ 3 marks] (iii) Based on your answer in (c) (i) and (ii), how many moles of magnesium and oxygen are there in the magnesium oxide used? [Use the information that the relative atomic mass : Mg = 24 ; O = 16 ]

[ 3 marks] (d) Determine the empirical formula of magnesium oxide.

[ 3 marks] END OF QUESTION