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Board Question Paper : March 2015
BOARD QUESTION PAPER : MARCH 2015
Note:
i. All questions are compulsory.
ii. Answers to the two sections are to be written in the same answer book.
iii. Figures to the right hand side indicate full marks.
iv. Write balanced chemical equations and draw neat and labelled diagrams, wherever necessary.
v. Use of logarithmic table is allowed.
vi. Answer to every question must be started on a new page.
SECTION – II
Q. 5. Select and write the most appropriate answer from the given alternatives for each
sub-question: [7]
ii. Which of the following complexes will give a white precipitate on treatment with a solution
of barium nitrate?
(A) [Cr(NH3)4SO4]Cl (B) [Co(NH3)4Cl2]NO2
(C) [Cr(NH3)4Cl2]SO4 (D) [CrCl2(H2O)4]Cl
iv. Primary and secondary nitroalkanes containing -H atom show property of ________.
(A) chain isomerism (B) tautomerism
(C) optical isomerism (D) geometrical isomerism
499
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Std. XII Sci.: Perfect Chemistry ‐ II
Q.6. Answer any SIX of the following : [12]
i. Write a note on Friedel Craft’s acylation.
ii. How is ethylamine prepared from methyl iodide?
iii. What are antibiotics? Give ‘two’ examples.
iv. Explain, why are boiling points of carboxylic acids higher than corresponding alcohols.
v. How are proteins classified on the basis of molecular shapes?
vi. What are interstitial compounds? Why do these compounds have higher melting points than
corresponding pure metals?
vii. Write the structures and IUPAC names of the following compounds:
a. Adipic acid
b. -methyl butyraldehyde
viii. Explain with examples, branched and linear polymers.
Q.7. Answer any THREE of the following: [9]
i. On the basis of valence bond theory explain the nature of bonding in [CoF6]3 ion.
Write the IUPAC name of [Co(NO2)3 (NH3)3].
ii. Define lanthanoid contraction. Explain its effects.
iii. Write mechanism of Aldol addition reaction.
iv. Define carbohydrates. What are reducing and non-reducing sugars?
Q.8. Answer any ONE of the following: [7]
i. Write a note on Gabriel phthalimide synthesis.
What are biodegradable polymers and non-biodegradable polymers? Write ‘one example’ of
each.
Explain cationic detergents.
ii. How is carbolic acid prepared from the following compounds:
a. Aniline
b. Chlorobenzene and steam at 698 K?
Draw structure of DDT. Write its environmental effects.
Mention ‘two’ physical properties of carbolic acid.
500
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Board Question Paper : October 2015
BOARD QUESTION PAPER : OCTOBER 2015
Note:
i. All questions are compulsory.
ii. Answers to the two sections are to be written in the same answer book.
iii. Figure at the right hand side indicate full marks.
iv. Write balanced chemical equations and draw neat and labelled diagrams, wherever necessary.
v. Use of logarithmic table is allowed.
vi. Answer to every new question must be started on a new page.
SECTION – II
Q.5. Select and write the most appropriate answer from the given alternatives for each
sub-question: [7]
i. Which among the following reducing agents is NOT used to reduce acetaldehyde to ethyl
alcohol?
(A) Na-Hg and water (B) Zn-Hg and conc. HCl
(C) H2-Raney Ni (D) LiAlH4/H+
ii. Acetaldehyde, when treated with which among the following reagents does NOT undergo
addition reaction?
(A) Ammonia (B) Hydroxylamine
(C) Ammoniacal silver nitrate (D) Semicarbazide
501
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Std. XII Sci.: Perfect Chemistry ‐ II
iii. How are the following compounds prepared?
a. Benzyl alcohol from benzyl chloride.
b. Propan-1-ol from propanal
iv. What is the position of iron (Z = 26) in periodic table? Explain why is Fe3+ more stable than
Fe2+?
502
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Board Question Paper : March 2016
BOARD QUESTION PAPER : MARCH 2016
Note:
i. All questions are compulsory.
ii. Answers of both the sections should be written in same answer book.
iii. Draw well labelled diagrams and write balanced equations wherever necessary.
iv. Figures to the right indicate full marks.
v. Use of logarithmic table is allowed.
vi. Every new question must be started on a new page.
SECTION – II
504
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Functional Groups of Organic Compounds
Representation of the
No. Class of the compound Functional group Example
class (General formula)
i. Alkanes R–H CH3 CH3
(Saturated) C C Ethane
xi. Aldehydes C H H C H
R C H
O O O
(Formyl or aldehydic) Formaldehyde
CH3 C H
O
Acetaldehyde
xii. Ketones C R C R CH3 C CH3
O O O
(Keto or oxo) Acetone
O O O
(Carboxyl group) Formic acid
505
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Std. XII Sci.: Perfect Chemistry ‐ II
O O O
(Amido group) Acetamide
506
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NOTES
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NOTES