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Dated: 23 / 09 / 2016
Attempt any 3 questions from the following:
1. What is Carnot engine? Describe its construction, working and derive an expression for its efficiency. Prove that the
efficiency of a Carnot engine is less than 100 % above absolute temperature of the sink. (2009, 2011)
2. Write down the two statements of second law of thermodynamics and prove their equivalence. (2010)
a. State the First Law of Thermodynamics. Also explain isobaric or isothermal process (2008)
b. Using the 1st law for two isotherms of an ideal gas at different temperature, show that Cp-Cv = R. Give reason
why the specific heat at constant pressure is greater than the specific heat at constant volume? (2008, 2010)
3. State the basic assumptions of KMT of gases. On its basis, derive expression for pressure of a gas. Also show that the
absolute temperature of an ideal gas is proportional to the avg. kinetic energy of the molecules. (2003, 2007, 2010)
4. What do you mean by entropy? Describe the second law of thermodynamics in terms of entropy. (2009)
5. Define linear expansion. Prove that (2001, 2002, 2004, and 2006). How does the concept of linear expansion
help the fabrication of bimetallic strips? Explain the working o the Bimetallic Strip in thermostat. (2008)
6. Define heat capacity, specific heat & molar specific heat. Write down the mathematical relation & their units.
Establish the equation of relation b/w the Molar specific heat & common specific heat. (2007)