[Type the document title] Thermodinamika

Teknik Kimia

1. For the system methanol (1) / methyl acetate (2), the following equations provide a
reasonable correlation for the activity coefficients:

Where:
A = 2.771-0.00523 T

Find:
a. P and yi, for x1=0.6 and T=330K (BULB P)
b. P and xi, for y1=0.3 and T=330K (DEW P)
c. T and yi, for x1=0.4 and P=90kPa (BULB T)
d. T and xi, for y1=0.40 and P=90kPa (DEW T)

Rumus-rumus:

BULB P/T DEW P/T

Jawab:

a. P and yi, for x1=0.6 and T=330K (BULB P)

 x1 = 0.6
 x2 = 0.4

Antoine equation:

3643.31
 𝑃1 𝑠𝑎𝑡 = 16.59158 − 330−33.424 = 74.217902
2665.54
 𝑃2 𝑠𝑎𝑡 = 14.25326 − 330−53.424 = 101.050431
 𝐴 = 2.771 − (0.00523 (330 𝐾)) = 1.0451
 𝐺𝑎𝑚𝑚𝑎 1 = 1.0451(0.42 ) = 1.18200955
 𝐺𝑎𝑚𝑚𝑎 2 = 1.0451(0.62 ) = 1.4567909
 [Type the document title] Thermodinamika
Teknik Kimia

BULB P/T

𝑃 = (0.6 x 74.217902 x 1.18200955) + (0.4 x 101.050431 x 1.4567909) = 111.519501

0.6 𝑥 1.18200955 𝑥 74.217902

𝑦1 = 111.519501
= 0.47198706

𝑦2 = 1 − 0.47198706 = 0.52801294

b. P and xi, for y1=0.3 and T=330K (DEW P)

 y1 = 0.3
 y2 = 0.7
 𝐴 = 2.771 − (0.00523 (330 𝐾)) = 1.0451
3643.31
 𝑃1 𝑠𝑎𝑡 = 16.59158 − = 74.217902
330−33.424
2665.54
 𝑃2 𝑠𝑎𝑡 = 14.25326 − 330−53.424
= 101.050431
 [Type the document title] Thermodinamika
Teknik Kimia

Dilakukan iterasi untuk memperoleh nilai P, x1 dan x2

Hasil iterasi, diperoleh nilai:

P = 114.476272
X1 = 0.261821
X2 = 0.738179

c. T and yi, for x1=0.4 and P=90kPa (BULB T)

 x1 = 0.4
 x2 = 0.6

Diperoleh T pada 323.387 K dan P = 89.999 Kpa

 [Type the document title] Thermodinamika
Teknik Kimia

0.4 𝑥 1.47504236 𝑥 74.217902

𝑦1 = 89.9999
= 0.36737021

𝑦2 = 1 − 0.36737021 = 0.63232979

2. Data untuk system ethyl ethanoate (1) dan nepthane (2) pada 70OC adalah:

Tentukan DEW P pada 70OC dan y1=0.05

Dari hasil iterasi diperoleh:

 x1 = 0.030447
 x2 = 0.969553
 Gamma 1 = exp(0.95 x 0.969553) = 2.44252
 Gamma 2 = exp(0.95 x 0.030447) = 1.000881
1
 DEW P = 0.05 0.95 = 42 Kpa
∑ + x 40.5
2.44252 x 79.80 1.000881