Nama : Anisa Wiranda

NIM : 1802953 (SPS Pendidikan Kimia)

Tugas – 4

3.7) Molybdenum has a BCC crystal structure, an atomic radius of 0.1363 nm, and an
atomic weight of 95.94 g/mol. Compute and compare its theoretical density with the
experimental value found inside the front cover.
Jawab:
R = 0,1363 nm = 0,1363 x 10-7 cm
A(Molybdenum) = 95,94 g/mol
𝑛 𝐴(𝑀𝑜𝑙𝑦𝑏𝑑𝑒𝑛𝑢𝑚)
Pakai persamaan 𝜌= 𝑉𝐶 𝑁𝐴

Untuk BCC, n = 2 atoms/unit cell maka VC = a3

4𝑅 3
𝑉𝐶 = ( )
√3
𝑛 𝐴(𝑀𝑜𝑙𝑦𝑏𝑑𝑒𝑛𝑢𝑚)
Sehingga, 𝜌 = 𝑉𝐶 𝑁𝐴
𝑛 𝐴(𝑀𝑜𝑙𝑦𝑏𝑑𝑒𝑛𝑢𝑚)
𝜌= 4𝑅 3
( ) 𝑁𝐴
√3

(2 𝑎𝑡𝑜𝑚𝑠/𝑢𝑛𝑖𝑡 𝑐𝑒𝑙𝑙)(95,94 𝑔/𝑚𝑜𝑙)

𝜌= (4)(0,1363 𝑥 10−7 𝑐𝑚)
3
[ ] / (𝑢𝑛𝑖𝑡 𝑐𝑒𝑙𝑙) (6,02 𝑥 1023 𝑎𝑡𝑜𝑚𝑠/𝑚𝑜𝑙)
√3

191,88
𝜌 = (0,031187866 𝑥 10−21 )(6,02 𝑥 1023 ) 𝑔/𝑐𝑚3

191,88
𝜌 = 18,77509533 𝑔/𝑐𝑚3

𝜌 = 10,2199 ≈ 𝟏𝟎, 𝟐𝟐 𝒈/𝒄𝒎𝟑   ekperimen

 teoritis = 10,28 g/cm3

3.8) Calculate the radius of a palladium atom, given that Pd has an FCC crystal structure, a
density of 12.0 g/cm3 , and an atomic weight of 106.4 g/mol.
Jawab:
 = 12,0 g/cm3
A(Palladium) = 106,4 g/mol
𝑛 𝐴(𝑃𝑎𝑙𝑙𝑎𝑑𝑖𝑢𝑚)
Pakai persamaan 𝜌= 𝑉𝐶 𝑁𝐴

Untuk FCC, n = 4 atoms/unit cell maka Vc = 16R3√2

 𝑛 𝐴(𝑃𝑎𝑙𝑙𝑎𝑑𝑖𝑢𝑚)
𝜌= 𝑉𝐶 𝑁𝐴
(4 𝑎𝑡𝑜𝑚𝑠/𝑢𝑛𝑖𝑡 𝑐𝑒𝑙𝑙)(106,4 𝑔/𝑚𝑜𝑙)
𝜌 = (16𝑅3
√2)(6,02 𝑥 1023 𝑎𝑡𝑜𝑚𝑠/𝑚𝑜𝑙)
(4 𝑎𝑡𝑜𝑚𝑠/𝑢𝑛𝑖𝑡 𝑐𝑒𝑙𝑙)(106,4 𝑔/𝑚𝑜𝑙)
𝑅 3 = (16)(𝜌)(√2)(6,02 𝑥 1023 𝑎𝑡𝑜𝑚𝑠/𝑚𝑜𝑙)
(4 𝑎𝑡𝑜𝑚𝑠/𝑢𝑛𝑖𝑡 𝑐𝑒𝑙𝑙)(106,4 𝑔/𝑚𝑜𝑙)
𝑅 3 = (16)(12,0 𝑔/𝑐𝑚3 )(√2)(6,02 𝑥 1023 𝑎𝑡𝑜𝑚𝑠/𝑚𝑜𝑙)
425,6
𝑅 3 = 1634,604604 𝑥 1023 𝑐𝑚3

𝑅 3 = 0,0026036878 𝑥 10−21 𝑐𝑚3

3
𝑅 = √0,0026036878 𝑥 10−21 𝑐𝑚3
𝑅 = 0,13757 𝑥 10−7 𝑐𝑚 ≈ 0,1376 𝑥 10−7 𝑐𝑚
𝑹 = 𝟎, 𝟏𝟑𝟕𝟔 𝒏𝒎

3.9) Calculate the radius of a tantalum atom, given that Ta has a BCC crystal structure, a
density of 16.6 g/cm3 , and an atomic weight of 180.9 g/mol.
Jawab:
 = 16,6 g/cm3
A(Tantalum) = 180,9 g/mol
𝑛 𝐴(𝑇𝑎𝑛𝑡𝑎𝑙𝑢𝑚)
Pakai persamaan 𝜌=
𝑉𝐶 𝑁𝐴

Untuk BCC, n = 2 atoms/unit cell maka VC = a3

4𝑅 3 64𝑅 3
𝑉𝐶 = ( ) =
√3 3√3
𝑛 𝐴(𝑇𝑎𝑛𝑡𝑎𝑙𝑢𝑚)
𝜌= 𝑉𝐶 𝑁𝐴
(2 𝑎𝑡𝑜𝑚𝑠/𝑢𝑛𝑖𝑡 𝑐𝑒𝑙𝑙)(180,9 𝑔/𝑚𝑜𝑙)
𝜌= 64𝑅3
( )(6,02 𝑥 1023 𝑎𝑡𝑜𝑚𝑠/𝑚𝑜𝑙)
3√3

(3√3)(2 𝑎𝑡𝑜𝑚𝑠/𝑢𝑛𝑖𝑡 𝑐𝑒𝑙𝑙)(180,9 𝑔/𝑚𝑜𝑙)

𝑅3 = (64)(𝜌)(6,02 𝑥 1023 𝑎𝑡𝑜𝑚𝑠/𝑚𝑜𝑙)

(3√3)(2 𝑎𝑡𝑜𝑚𝑠/𝑢𝑛𝑖𝑡 𝑐𝑒𝑙𝑙)(180,9 𝑔/𝑚𝑜𝑙)

𝑅 3 = (64)(16,6
𝑔/𝑐𝑚3 )(6,02 𝑥 1023 𝑎𝑡𝑜𝑚𝑠/𝑚𝑜𝑙)
1879,96795
𝑅 3 = 6395,648 𝑥 1023 𝑐𝑚3

𝑅 3 = 0,002939448 𝑥 10−21 𝑐𝑚3

3
𝑅 = √0,002939448 𝑥 10−21 𝑐𝑚3
𝑅 = 0,1432 𝑥 10−7 𝑐𝑚
𝑹 = 𝟎, 𝟏𝟒𝟑𝟐 𝒏𝒎
3.10) Some hypothetical metal has the simple cubic crystal structure shown in Figure 3.23. If
its atomic weight is 74.5 g/mol and the atomic radius is 0.145 nm, compute its density.

Jawab:
A = 74,5 g/mol
R = 0,145 nm = 0,145 x 10-7 cm
𝑛𝐴
Pakai persamaan 𝜌=𝑉
𝐶 𝑁𝐴

Pada gambar 3.23, n = 1 atom/unit cell maka Vc = (2R)3

𝑛𝐴
𝜌=𝑉
𝐶 𝑁𝐴

(1 𝑎𝑡𝑜𝑚/𝑢𝑛𝑖𝑡 𝑐𝑒𝑙𝑙)(74,5 𝑔/𝑚𝑜𝑙)

𝜌 = [(2)(0,145 𝑥 10−7 𝑐𝑚)]3 / (𝑢𝑛𝑖𝑡 𝑐𝑒𝑙𝑙)(6,02 𝑥 1023 𝑎𝑡𝑜𝑚𝑠/𝑚𝑜𝑙)
74,5
𝜌 = 0,14682178 𝑥 102 𝑔/𝑐𝑚3
74,5
𝜌 = 14,682178 𝑔/𝑐𝑚3

𝝆 = 𝟓, 𝟎𝟕𝟒 𝒈/𝒄𝒎𝟑