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Strengthening/Hardening Mechanisms
Heat treatment can be used to remove the effects of strain hardening. Three
things can occur during heat treatment:
1. Recovery
2. Recrystallization
3. Grain growth
Recovery
When a stain hardened material
is held at an elevated
temperature an increase in
atomic diffusion occurs that
relieves some of the internal
strain energy. Remember that
atoms are not fixed in position
but can move around when they
have enough energy to break
their bonds. Diffusion increases
rapidly with rising temperature
and this allows atoms in severely
strained regions to move to
unstrained positions. In other
words, atoms are freer to move around and recover a normal position in the
lattice structure. This is known as the recovery phase and it results in an
adjustment of strain on a microscopic scale. Internal residual stresses are
lowered due to a reduction in the dislocation density and a movement of
dislocation to lower-energy positions. The tangles of dislocations condense
into sharp two-dimensional boundaries and the dislocation density within
these areas decrease. These areas are called subgrains. There is no
appreciable reduction in the strength and hardness of the material but
corrosion resistance often improves.
Recrystallization
At a higher temperature, new, strain-free grains nucleate and grow inside the
old distorted grains and at the grain boundaries. These new grains grow to
replace the deformed grains produced by the strain hardening. With
recrystallization, the mechanical properties return to their original weaker and
more ductile states. Recrystallization depends on the temperature, the amount
of time at this temperature and also the amount of strain hardening that the
material experienced. The more strain hardening, the lower the temperature
will be at which recrystallization occurs. Also, a minimum amount (typically 2-
20%) of cold work is necessary for any amount of recrystallization to occur.
The size the new grains is also partially dependant on the amount of strain
hardening. The greater the stain hardening, the more nuclei for the new
grains, and the resulting grain size will be smaller (at least initially).
Grain Growth
If a specimen is left at the high temperature beyond the time needed for
complete recrystallization, the grains begin to grow in size. This occurs
because diffusion occurs across the grain boundaries and larger grains have
less grain boundary surface area per unit of volume. Therefore, the larger
grains lose fewer atoms and grow at the expense of the smaller grains. Larger
grains will reduce the strength and toughness of the material.