SMJK CHUNG LING PULAU PINANG

PEPERIKSAAN PERTENGAHAN TAHUN 2018

CHEMISTRY FORM 5
TIME : 2 HOURS AND 30 MINUTES

NAME : ………………………………………………. CLASS : ……………..

Section A : [60 marks]

1. Diagram 1 shows an experiment to determine the empirical formula of copper

oxide

Hydrogen gas

Diagram 1

a) Table 1.1 shows the results of the experiment.

Description Mass , g
Mass of combustion tube + crucible 55.31
Mass of combustion tube + crucible + copper oxide 63.31
Mass of combustion tube + crucible + copper 61.71
Table 1.1
Based on the results above, determine the value of the following :
[Relative atomic mass : O =16, Cu = 64]
(i) The number of moles of copper [1m]

(ii) The number of moles of oxygen [1m]

(iii) The empirical formula [1m]

b) Name two materials used to prepare hydrogen gas in laboratory [2m]

c) Write a chemical equation based on the preparation of hydrogen gas in (b). [1m]

….………………………………………………………………………………………

d) Water is formed when hydrogen gas that comes out from the end of the
combustion tube is burnt in oxygen. Write the chemical equation [2m]

….……………………………………………………………………………………..

e) The function of anhydrous calcium chloride is to dry hydrogen gas. Name

another substance that can be used to replaced it. [1m]

….………………………………………………………………………………………

f) State how to determine that the reaction between copper (II) oxide with hydrogen
gas has completed. [1m]

….………………………………………………………………………………………
………………………………………………………………………………………….

2. A student investigate the reaction between marble chips and hydrochloric acid.
23g of marble chips are placed into a conical flask that contains excess
hydrochloric acid. The total mass of the flask and its content is recorded every 60
seconds using an electronic balance.

Time 0.0 1.0 2.0 3.0 4.0 5.0 6.0

( min)
Balance 120.0 114.5 111.5 110.5 109.7 109.3 109.3
reading
(g)
Mass of 0 5.5
carbon
dioxide
gas (g)
Table 2
a) Complete Table 2 [1m]
b) Explain why the balance reading decreases during the experiment. [1m]

….………………………………………………………………………………………

………………………………………………………………………………………….

c) How can a student tell when the reactions has completed? [1m]

….………………………………………………………………………………………
d) What is the purpose of stuffing the opening of the conical flask with cotton wool?
[1m]

….……………………………………………………………………………………
e) Explain why the mass of the flask and its contents becomes constant after the
fifth minute. [1m]

….………………………………………………………………………………………

………………………………………………………………………………………….

f) You are told that the density of gaseous carbon dioxide is 1.97 g dm-3. calculate
the volume of gas released during this experiment under room temperature and
pressure. [2m]

g) (i) If the student repeated the experiment using the same materials but using
downward water displacement method to determine the volume of gas released.
Draw a diagram to show the set-up of apparatus. [2m]
(ii) Write an ionic equation for the reaction between marble chips and hydrochloric
acid. [2m]

….……………………………………………………………………………………

3. Element A reacts with oxygen gas to form a colourless liquid B. The freezing
point of liquid B is 0 oC .
Diagram 3.1 shows the cooling curve of liquid B.

Diagram 3.1

a) (i) Name the states of matter at region QR. [1m]

….……………………………………………………………………………………….
(ii) State the melting point of liquid B. [1m] …………………………………………..

( iii) Draw the arrangement of particles at t1 minute [1m]

(iv) Based on the cooling curve, the temperature remains constant from t2 to t3. Give
your reason. [2m]

….………………………………………………………………………………………

………………………………………………………………………………………….

b) Table 3.1 shows the number of protons and nucleon number of six elements G, J,
K, L, M and N.

Element G J K L M N
Number 4 6 8 10 11 20
of
protons
Nucleon 9 12 16 20 23 39
number
Table 3.1

(i) Define the meaning of nucleon number. [1m]

….………………………………………………………………………………………

…………………………………………………………………………………………
(ii) Draw the electron arrangement of atom M [1m]

(iii) Write the electron arrangement for atom G and atom N [2m]

Atom G
Atom N

(iv) Predict the physical state of L at room condition. [1m]

….……………………………………………………………………………………

4. The flow chart shows the series of reactions for solid A and its other compounds.
a) Name gas C. [1m]

….……………………………………………………………………………………….
b) State the anion that will result in the formation of gas C. [1m]

….……………………………………………………………………………………….

c) (i) Write the ionic equation for the formation of precipitate E. [1m]

….………………………………………………………………………………….
(ii) Name the reaction for the formation of precipitate E [1m]

….……………………………………………………………………………………….

(iii) Calculate the maximum mass of white precipitate E produced if 50 cm3 of 2.0
mol dm-3 solution D reacts with excess sodium chloride solution. [3m]
[Relative atomic mass Pb = 207, Cl = 35.5,Ca = 40, Mg = 24, Al= 27, Zn= 65 H = 1,
O = 16 ]
d) Determine the cation of solid A [1m]
Cation

e) Write a chemical equation to show the reaction of solid A reacts with nitric acid
to form solution D [1m]

….……………………………………………………………………………………….
f) State the substance that change solution D to dry solid A [1m]

….……………………………………………………………………………………….

5. Diagram 5 shows the flow chart for the industrial manufacture of sulphuric acid
and the production of fertiliser Z.

Diagram 5
Based on diagram above, answer the following question:
a) Name the process of manufacturing sulphuric acid [1m]

….……………………………………………………………………………………..

b) Name the substance Q [1m]

….……………………………………………………………………………………
c) Write the chemical equation when sulphur trioxide reacts with substance Q to
form oleum. [1m]

….………………………………………………………………………………………
d) State catalyst X and temperature Y. [2m]

Catalyst X

Temperature Y

e) Sulphuric acid produced can be used to react with ammonia to form fertiliser Z.
Write the formula of fertiliser Z. [1m]

….……………………………………………………………………………………….
f) Excess sulphur dioxide gas that is emitted to the air will result in acid rain. Write
a chemical equation for the formation of acid rain. [1m]

….……………………………………………………………………………………
g) (i) A farmer discovered that his maize plants were not growing well due to poor
soil. As a chemistry student, suggest a chemical substance to help to overcome
the problem. [1m]
….…………………………………………………………………………………….
(ii) Explain how the chemical works. [2m]

….……………………………………………………………………………………..

….……………………………………………………………………………………..

6. Diagram 6 shows the location of six elements in the Periodic Table.

Diagram 6
a) Elements P and U are in the same group.
(i) Which element is more reactive ? [1m]…………………………………………

(ii) Give reasons for your answer in (a) (i) [3m]

b) Draw the chemical compound formed between P and T [2m]

c) Draw the formation of S2 [2m]

d) Name element P and Q [2m]

Element P
Element Q

Section B [20marks]
7. The information below is about alkene X.

 Carbon 85.7 %
 Hydrogen 14.3 %
 Relative molecular mass is 56
 Relative atomic mass of H is 1 and C is 12

(a) Based on the information above,

(i) Find the empirical formula
(ii) Determine the molecular formula
(iii) Name alkene X
(iv) State the functional group of alkene X
(v) Write the general formula for its homologous series.
(vi) Draw and name 2 isomers

[10m]

(b) Table below shows the results of latex coagulation.

Procedure Observations
Formic acid is added to latex Latex coagulates immediately
Ammonia solution is added to latex Latex does not coagulate.

Explain why coagulation of latex occurs when formic acid is added to latex. [5m]

(c ) Draw and name the compounds below [4m]

(i) CH3 CH3 CH (CH3) CH2 C ( CH2CH3)3

(ii) CH2CHC (CH3)2CHCHCH3

(d) Draw 1-chloro-4-ethyl-2-methyl-4-propylhelptane [1m]

Section C [20 marks ]

8. (a) The following are the formulae of two compounds :

Fe2O3 Na2O

(i) Based on the two formulae, state the oxidation number for iron and sodium. [2m]
(ii) Name the compounds based on the IUPAC nomenclature system [2m]
(iii) Explain the difference between the names of the two compounds based on the
IUPAC nomenclature system [2m]
(iv) Calculate the oxidation number of chromium in K2Cr2 O7 [1m]
[Given that the oxidation number of K =1, O = -2]
(v) Below is the equation of a reaction.

Mg (s) + CuSO4 (aq) ----------> Cu (s) + MgSO4 (aq)

Write half-equations to represent the oxidation and reduction process. [2m]

b ) The following are the apparatus and materials needed in the electrolysis of 2.0
mol dm-3 copper (II) chloride solution.

 Carbon electrodes
 2.0 mol dm-3 copper (II) chloride solution
 Batteries
 Electrolytic cell
 Connecting wires and crocodile clips

Use a labelled diagram to explain how this electrolysis occurs.

Your explanation should include the ions that are present , reasons for the formation
of product, half equations and all the possible observations at the anode and cathode.
[11m ]

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TengPW TharmBB KhorCS