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Enthalpy of Solution.
The enthalpy of solution of a substance is the energy change when one mole of a
substance dissolves in water.
Worked example 1.
5g of ammonium chloride, NH4Cl, is completely dissolved in 100cm3 of water.
The water temperature falls from 21oC to 17.7oC.
5g 1.38 kJ
So 53.5 g 53.5/
5 x 1.38 = 17.77 kJ mol-1.
8g 2.42 kJ
So 80g 80/
8 x 2.42 = 24.2 kJ mol-1.
Rearranging DH = -cmDT
DH
Gives DT =
-cm
3.35
DT = = -5.34 oC
-4.18 x 0.15