JA

AWAHAR
R VIDYA MANDIR
SHYAMALII, RANCHI – 834002

 
Che
emistry Asssignment : Class  (1
12) 

SSOLUTION
1. Deefine the teerms, ‘osmo osis’ and ‘o
osmotic preessure’. What is the advantage of o using
ossmotic presssure as com mpared to oother colligaative properrties for thee determinaation of
mo olar massess of solutes in
i solutionss ?

2. What
W mass of NaCl (mollar mass = 58.5 g/moll) must be dissolved in n 65 g of water
w to
wer the freeezing point by 7.5°C? T
low The freezingg point deprression constant, Kf forr water
is 1.86 K Kg mol
m .Assum
-I me van’t Hofff factor for NaCl
N is 1.87
7.

3. What
W mass of ethylene glycol (mollar mass = 62 gmol-I) must be ad dded to 5.500 Kg of
wer the freeezing point of water frrom 0°C to
waater to low o -10°C? (Kf for water = 1.86
KK
Kgmol )
-I

4. Differentiate between
b mo
olarity and molality of a solution.

5. 5 g of an unk
15 known moleecular substance was dissolved
d in
n 450 g of water.
w The reesulting
so
olution freezzes at -0.34
4°C. What iss the molarr mass of th
he substancce? (Kf for water
w =
1.8
86 KKgmol )
- I

6. Staate the following: (i) Raoult’s law

w in its gen
neral form in referencce to solutio
ons (ii)
Heenry’s law about
a partiaal pressure of
o a gas in mixture.
m

7. A solution prepared by dissolving

d 8
8.95 mg of gene
g fragmeent in 35.0 ml
m of waterr has an
ossmotic presssure of 0.335 torr at a 25°C. Asssuming thhe gene fraagment is a non-
eleectrolyte, caalculate its molar
m mass.

8. What
W mass off NaCl mustt be dissolvved in 65.0 g of water tot lower thee freezing point
p of
waater by 7.500°C? The frreezing poin nt depressiion constan
nt (Kf)for water
w is 1.86
6 °C/m.
Asssume van’tt Hoff factorr for NaCl is 1.87

9. What
W is mean
nt by ‘reversse osmosis’ ?

10. (a)) Define the follow

wing terms: (i) Mole fraaction (ii) IIdeal solutio
on ?

(b) 15.0 g of an unk known moleecular mateerial is dissolved in 45 50 g of watter. The

resultting solution
n freezes att -0.34°C. What
W is the molar
m mass of
o the materrial? (Kf
for waater = 1.86 KKgmol-I )

(c)) Explaain the follow

wing : (i) H
Henry’s law about disso
olution of a gas in a liqu
uid. (ii)
Boilin
ng point elevvation constant for a so
olvent.

(d) A solution of glyycerol (C3H8O3 ) in water

w was pprepared byy dissolvingg some
glycerrol in 500 g of water. This solutio
on has a boiling point of 100.42°CC. What
mass of glycerol was dissolvved to makee this solutio
on?
 JA
AWAHAR
R VIDYA MANDIR
SHYAMALII, RANCHI – 834002

11. (aa) State Raoult’s laaw for a so

olution containing volatile compo
onents. How
w does
Raoullt’s law beco
ome a speciial case of Henry’s
H law??

(b
b) 1.00 g of a non--electrolytee solute dissolved in 5 50 g of bennzene lowerred the
freeziing point off benzene b by 0.40 K. Find the molar mass off the solute.. (Kf for
benzeene = 5.12 KKgmol
K -I )

(cc) Define the follow

wing terms: (i) Ideall solution (ii) Azeotro
ope (iii) Osmotic
O
pressure.

(d
d) A solu
ution of gluccose (C6H12O6) in wateer is labelled
d 10% by weight.
w Whatt would
be thee molality of
o the solutio
on ? (Molar mass of glu ucose = 180 g/mol)

12. (a)
( Define the follow
wing terms: (i) Molariity (ii)Mo
olal elevatio
on constant (Kb)

(b
b) A soluution contaiining 15 g urea
u (molar mass = 60 g/mol) per litre of soluution in
waterr has the same osmoticc pressure (isotonic)
( n of glucose (molar
ass a solution
mass = 180 g/mol) in water. Calculate the mass o of glucose present
p in one litre
of its solution.

(cc) Whatt type of deeviation is sshown by a mixture o

of ethanol and
a acetonee? Give
reaso
on?

(d
d) A solu
ution of glucose (molarr mass = 18
80 g/mol) in
n water is laabelled as 10% (by
mass)). What wo ould be the molarity and molalityy of the solution? (Den nsity of
solutiion = 1.2 g/m
ml)

13. Why does a solution containing no

W on-volatile solute
s have higher boilling point th
han the
pure solventt? Why is eleevation of b
boiling pointt a colligativve property?

14. Calculate thee freezing point

p of thee solution when
w 31 g oof ethylene glycol (C2H6O2) is
dissolved in 500 g of waater.( Kf for water
w = 1.86 KKgmol )
-I

15. (aa) Gas (A

A) is more soluble
s in w
water than gas
g (B) at th he same tem
mperature . Which
one of the two gaases will havve the higheer value of Kh and why ?

(b
b) In nonn ideal solu
ution, what type of dev
viation show
ws the formation of maaximum
boilin
ng azeotropees ?

(cc) Calculate the boiiling point o

of solution when
w 4 g off MgSO4 (M = 120 g/mol) was
dissollved in 100
0 g of waterr ,assumingg MgSO4 un ndergoes coomplete ionisation.
(Kb fo
or water = 0.52 K Kg mo ol )
-I
 JA
AWAHAR
R VIDYA MANDIR
SHYAMALII, RANCHI – 834002

 
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e  Assignme
ent : Classs  (12) – Chemistry : B
By. Mr. B N
N Jha 
 JA
AWAHAR
R VIDYA MANDIR
SHYAMALII, RANCHI – 834002