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Steel industry

co-products

Legislation should encourage


the sustainable use of steel
industry co-products.
02 Steel industry co-products

Introduction

Over the past 20 years, use of the steel


industry’s co-products has increased Main solid co-products per steelmaking route1
significantly. (average outputs in kg/tonne crude steel)

Innovative technology developments and ~ 400


synergies with other industries have brought kg/tonne steel
the steel industry ever closer to its goal of zero 450
3
waste to landfill. 20

Solid co-products (in kg/tonne crude steel)


400

In this paper, co-products refer to materials 350


126
that are produced in parallel to or, as a 300
consequence of, the production of a primary
~ 200
product and which have a potential value. 250
kg/tonne steel
200
13
The main solid co-products produced during 150
275
iron and crude steel production are slags (90%
by mass), dust and sludge. 100
169
50
On average, the production of one tonne of steel
results in around 200 kg of co-products for the 0
electric arc furnace (EAF) route and 400 kg for
Blast furnace Electric arc
the blast furnace - basic oxygen furnace (BF- (BF) - Basic oxygen furnace (EAF)
BOF) route. furnace (BOF) route route

Alongside solid co-products, process gases from Ironmaking slag (BF) Steelmaking dust and
sludge (BOF)
coke ovens, BFs or BOFs are also important Steelmaking slag (BOF)
steelmaking co-products. Steelmaking slag (EAF)
Ironmaking dust and
sludge (BF) Steelmaking dust and
sludge (EAF)
1
Steel Industry By-products report, worldsteel 2010

5.7%
4.3%
4.4% Use of iron and steelmaking slags in
Europe*2 in 2016 - total 41 Mt
1.2%
1%

6.8%
Cement, concrete additive, etc. Fertiliser
Road construction Other

46.8% Metallurgical use Interim storage


Hydraulic engineering Landfill

*At a global level, percentages vary from region to region


29.8%
2
EUROSLAG – The European Slag Association, 2017
Steel industry co-products 03

Key points
from this report

Governments
should support
research into new
Legislation applications of
should clearly co-products, The steel
differentiate such as the industry can be a
co-products from development of reliable partner,
waste to facilitate Carbon Capture providing heat
their use and and Use (CCU) and electricity
improve their technology applied to local
perception. to process gases. communities.

Legislation should
not apply stricter Legislators
regulations on the should take a The growing use
use of co-products; holistic approach of steel industry
on the contrary when assessing co-products will
they should be the sustainability make a significant
given preferential of steel industry contribution to the
treatment. co-products. circular economy.

The use of steel


industry co-products

Co-products from the steel industry Some examples of common uses of • Emulsions from mills and used oil –
have many uses within the industry steel industry co-products: reducing agent in blast furnaces or used
itself, in other industries and in wider • Blast furnace slag – substitute for clinker in coke plants.
society. In some cases, it is the physical in cement-making
properties that determine the use, such • Steelmaking slag – aggregates in road In all cases, using a steel industry co-
as steelmaking slag used as aggregates construction, soil improvement product as a substitute for an equivalent
in road construction; and sometimes it • Process gases – heat and electricity product will improve resource efficiency
is the chemical composition e.g. process production and contribute to the circular economy.
gases used as fuel to produce heat and/ • Dust and sludge – internal and external
or electricity. Valuable non-ferrous metals use of iron oxides and alloying elements
can also be recovered from slags, dust • Petrochemicals from cokemaking – tar,
and sludge when the concentrations are ammonia, phenol, sulphuric acid and
sufficient. naphthalene for the chemical industry
04 Steel industry co-products

Ongoing technological Regulatory Circular economy, resource


development framework efficiency and zero waste
Technological development in the Beneficial use of steelmaking co- The use of co-products has contributed
production and processing phases, with products will reduce the energy and to a material efficiency rate in the steel
the aim of producing co-products with emissions required to make equivalent industry of 96.3% worldwide1 (average
uniform and improved properties, is a products. Their use should therefore be of all steel industry efficiency rates).
continuous effort. New technologies will given preferential treatment, or at least Our goal is the 100% efficient use of raw
further increase co-product usage rates be encouraged. materials and zero waste.
and, more importantly, expand their use
by improving the quality of the materials worldsteel believes it should be possible Co-products can be used during the
recovered. to substitute equivalent products for steelmaking process or sold for use by
co-products within the same legal other industries. This increases resource
Recent developments include demand framework. This should include the efficiency, prevents landfill waste and
management and refocusing the application of identical quality and reduces CO2 emissions. The sale of
production process to better control the environmental testing requirements these co-products is also economically
properties of the co-products. and limits for primary and secondary sustainable. It generates revenues for
materials. For example, leachate levels steel producers and forms the base of a
Public and for slags used in road construction viable industry worldwide.
political perception should also be applicable to natural
aggregates of diverse geological origin. Minimising waste and ensuring
Today, there is no uniform legal resources remain in use for as long
definition of co-products; it varies from Furthermore, the development of as possible are key to achieving a
country to country and sometimes even international/regional quality standards sustainable circular economy.
between different pieces of legislation. for applications of co-products would
When co-products are not clearly improve their public and political For example, replacing Portland cement
differentiated from waste, it creates perception. with slag cement in concrete can
unnecessary hurdles for their use and save up to 59% of the embodied CO2
transport as well as issues around public Legislation should in the best case emissions and 42% of the embodied
and political perception. give precedence to the use of co- energy required to manufacture
products or should at least avoid concrete and its constituent materials2.
It is necessary to clearly differentiate stricter requirements for their use.
co-products from waste in legislation There is a need for a holistic
to improve the perception of co- approach in the use of co-products
products and to encourage their use. where all environmental, energy and
resource aspects are considered.

The use of co-products should be


encouraged, thereby saving natural
resources and energy.

Circular economy
Ensuring the maximum value
of resources through product
design, recovery and reuse,
remanufacturing and recycling.

Zero waste
Ensuring that raw materials
and co-products are fully
utilised and no material is
going to landfill.

1
Sustainable Steel - Indicators 2019 and
the steel supply chain, worldsteel
2
Slag Cement Association
Steel industry co-products 05

Value for the community


Research
› use of process gases
In order to use more of the steel industry’s Process gases (from the coke
co-products and achieve the maximum oven, BF and BOF) once cleaned
benefit from this use, research into are used internally to produce
processes, processing and applications is steam and to fuel reheating
continuously being conducted. furnaces or they can be used as
reducing agents in the BF. They
For example, research is ongoing in the field are also used as fuel in power
of Carbon Capture and Use (CCU), which plants to produce electricity either
focuses on the transformation of process on or off site. Typically, part of
gases and their subsequent use, for example, this electricity is then fed back
in the chemical industry. into the steel plant while part is
used by local communities or
To make further progress, however, the neighbouring industries.
steel industry would benefit greatly from
partnerships with other industry sectors as When gases are fully utilised,
well as government support. they can provide between 60 to
100% of the plant’s electricity
This would also increase knowledge requirements3 depending on the
among policy makers and hopefully configuration of the plant. The
initiate discussions on the necessary legal gases are flared only if no other
frameworks. option is available.

 esearch into new applications of


R Legislative frameworks that
co-products would greatly benefit from promote the use of process
increased government support. gases would save fossil fuels
and reduce CO2 emissions from
There should be strong support for the gases that are still flared.
use of co-products in legislation and the
development of new applications should Partnerships with local
be promoted. communities should be
encouraged as the steel
industry can be a reliable
partner, providing process
gases, steam or excess heat to
the local community.

Once cleaned, process


gases from iron and
steelmaking are used
as fuel in power plants
to produce electricity
either on or off site.

3
Energy use in the steel
industry, worldsteel, 2014
06 Steel industry co-products

Increase
Prevent resource
landfill waste efficiency

The use of
co-products
Reduce CO2 should be Generate
emissions revenue
encouraged to:

Preserve
Create
virgin
value
material

Industry application › Value for other industries ›


Recycling of iron From construction to
bearing materials healthcare to agriculture

A number of co-products with a high iron content Tar is a cokemaking co-product that is used as a seal
are generated throughout the steelmaking process. coating material in the construction sector and to
These include dust and sludge from the wet and dry produce paints and synthetic dyes. As a medication,
abatement equipment, mill scale from the hot rolling tar can be further processed and used in applications
mill and iron ore and sinter fines. such as soap and shampoo to treat dandruff and skin
conditions (psoriasis).
The valuable iron content from these co-products is
recovered and returned to the steelmaking process, Sulphur is used to vulcanise rubber and manufacture
replacing virgin material and contributing to a more sulphuric acid but is also used in insecticides and
efficient use of resources. fertilisers. These are just a few examples that
demonstrate the value of co-products for many
industries, presenting an environmental advantage by
preserving virgin materials.
Steel industry co-products 07

Other metallics
Limestone Iron ore Coal Scrap Scrap Electricity (DRI, HBI,
pig iron)

Basic Oxygen Electric Arc


Furnace Steelmaking Furnace Steelmaking

Blast furnace Basic oxygen Electric arc


(ironmaking) furnace furnace
(steelmaking)

Outputs

Steel Waste

Dust and sludge Chemicals

Internal and external Input material for


use of iron oxides and
alloying elements
Co-products the chemical industry
and
Process their uses Emulsions
gases and used oils

Heat and Reducing


electricity agents
Slag

Cement Road Fertilisers and Armour stones Sea forestation


construction liming materials for hydraulic
in agriculture engineering

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